TWI683037B - 於製造一半導體裝置時用於選擇性移除矽氮化物的蝕刻溶液 - Google Patents
於製造一半導體裝置時用於選擇性移除矽氮化物的蝕刻溶液 Download PDFInfo
- Publication number
- TWI683037B TWI683037B TW107119087A TW107119087A TWI683037B TW I683037 B TWI683037 B TW I683037B TW 107119087 A TW107119087 A TW 107119087A TW 107119087 A TW107119087 A TW 107119087A TW I683037 B TWI683037 B TW I683037B
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- Prior art keywords
- alcohol
- ether
- etching solution
- glycol
- silicon nitride
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K13/00—Etching, surface-brightening or pickling compositions
- C09K13/04—Etching, surface-brightening or pickling compositions containing an inorganic acid
- C09K13/06—Etching, surface-brightening or pickling compositions containing an inorganic acid with organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/66—Chemical treatment, e.g. leaching, acid or alkali treatment
- C03C25/68—Chemical treatment, e.g. leaching, acid or alkali treatment by etching
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K13/00—Etching, surface-brightening or pickling compositions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/44—Compositions for etching metallic material from a metallic material substrate of different composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02041—Cleaning
- H01L21/02043—Cleaning before device manufacture, i.e. Begin-Of-Line process
- H01L21/02046—Dry cleaning only
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/30604—Chemical etching
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/30604—Chemical etching
- H01L21/30608—Anisotropic liquid etching
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31105—Etching inorganic layers
- H01L21/31111—Etching inorganic layers by chemical means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/34—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies not provided for in groups H01L21/18, H10D48/04 and H10D48/07, with or without impurities, e.g. doping materials
- H01L21/46—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/428
- H01L21/461—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/428 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/465—Chemical or electrical treatment, e.g. electrolytic etching
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- General Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Weting (AREA)
- Cleaning Or Drying Semiconductors (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762515351P | 2017-06-05 | 2017-06-05 | |
| US62/515351 | 2017-06-05 | ||
| US15/990,000 US11186771B2 (en) | 2017-06-05 | 2018-05-25 | Etching solution for selectively removing silicon nitride during manufacture of a semiconductor device |
| US15/990000 | 2018-05-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201903207A TW201903207A (zh) | 2019-01-16 |
| TWI683037B true TWI683037B (zh) | 2020-01-21 |
Family
ID=62528355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW107119087A TWI683037B (zh) | 2017-06-05 | 2018-06-03 | 於製造一半導體裝置時用於選擇性移除矽氮化物的蝕刻溶液 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US11186771B2 (enExample) |
| EP (1) | EP3422392B1 (enExample) |
| JP (2) | JP7015214B2 (enExample) |
| KR (1) | KR102141447B1 (enExample) |
| CN (1) | CN109054838A (enExample) |
| IL (1) | IL259799B2 (enExample) |
| SG (1) | SG10201804769SA (enExample) |
| TW (1) | TWI683037B (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190051656A (ko) * | 2017-11-07 | 2019-05-15 | 삼성전자주식회사 | 식각 조성물, 실리콘 질화막의 식각 방법, 및 반도체 소자의 제조 방법 |
| KR102362365B1 (ko) * | 2018-04-11 | 2022-02-11 | 삼성에스디아이 주식회사 | 실리콘 질화막 에칭 조성물 및 이를 이용한 에칭 방법 |
| WO2020091020A1 (ja) | 2018-11-02 | 2020-05-07 | 公立大学法人名古屋市立大学 | 多能性幹細胞由来腸管オルガノイドの作製法 |
| CN111363550A (zh) * | 2018-12-26 | 2020-07-03 | 上海新阳半导体材料股份有限公司 | 选择性刻蚀液组合物及其制备方法和应用 |
| US11929257B2 (en) * | 2019-03-11 | 2024-03-12 | Versum Materials Us, Llc | Etching solution and method for aluminum nitride |
| EP3938465B1 (en) * | 2019-03-11 | 2025-07-09 | Versum Materials US, LLC | Etching solution and method for selectively removing silicon nitride during manufacture of a semiconductor device |
| EP3963036B1 (en) * | 2019-05-01 | 2024-07-10 | FUJIFILM Electronic Materials U.S.A, Inc. | Method of etching semiconductors |
| KR102803329B1 (ko) * | 2019-08-29 | 2025-05-07 | 에스케이이노베이션 주식회사 | 식각 조성물, 이를 이용한 절연막의 식각방법 및 반도체 소자의 제조방법 |
| KR102675055B1 (ko) * | 2019-09-18 | 2024-06-12 | 오씨아이 주식회사 | 실리콘 질화막 식각 용액 및 이를 사용한 반도체 소자의 제조 방법 |
| JP7512378B2 (ja) * | 2019-10-09 | 2024-07-08 | インテグリス・インコーポレーテッド | 湿式エッチング湿式エッチング組成物及び方法 |
| CN110878208A (zh) * | 2019-11-08 | 2020-03-13 | 湖北兴福电子材料有限公司 | 一种提高氮化硅蚀刻均匀性的酸性蚀刻液 |
| CN110846040A (zh) * | 2019-11-08 | 2020-02-28 | 湖北兴福电子材料有限公司 | 一种高容硅量磷酸基蚀刻液及其配制方法 |
| CN116134588A (zh) * | 2020-07-30 | 2023-05-16 | 恩特格里斯公司 | 用于选择性蚀刻氮化硅膜的组合物和方法 |
| CN116195036A (zh) * | 2020-08-24 | 2023-05-30 | 巴斯夫欧洲公司 | 用于选择性蚀刻硅-锗材料的组合物及其用途和方法 |
| KR102315919B1 (ko) * | 2021-01-26 | 2021-10-22 | 연세대학교 산학협력단 | 비인산계 실리콘 질화막 식각 조성물 및 이를 이용한 식각방법 |
| KR102325905B1 (ko) * | 2021-03-22 | 2021-11-12 | 연세대학교 산학협력단 | 실리콘 질화막 식각 조성물 및 이를 이용한 식각방법 |
| KR20230173103A (ko) * | 2021-04-22 | 2023-12-26 | 카오카부시키가이샤 | 에칭액 |
| FR3122664B1 (fr) * | 2021-05-05 | 2024-06-28 | Dehon | Composition de defluxage d’assemblages electroniques |
| US12012540B2 (en) | 2021-05-26 | 2024-06-18 | Entegris, Inc. | Compositions and methods for selectively etching silicon nitride films |
| EP4098729A1 (en) * | 2021-06-01 | 2022-12-07 | Cipelia | Non-flammable, volatile and aqueous cleaning composition |
| WO2022264631A1 (ja) | 2021-06-14 | 2022-12-22 | ラサ工業株式会社 | エッチング液組成物 |
| KR102782691B1 (ko) * | 2021-11-10 | 2025-03-19 | 연세대학교 산학협력단 | 실리콘 질화막 식각 조성물 및 이를 이용한 식각방법 |
| CN115353886B (zh) * | 2022-08-31 | 2023-08-25 | 湖北兴福电子材料股份有限公司 | 一种磷酸基蚀刻液及其配制方法 |
| KR20250044782A (ko) | 2022-12-08 | 2025-04-01 | 라사 인더스트리즈, 리미티드 | 에칭액 조성물 |
| CN116218528B (zh) * | 2022-12-08 | 2025-04-22 | 湖北兴福电子材料股份有限公司 | 一种高选择性且低泡的蚀刻液 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4945452B1 (enExample) | 1969-05-13 | 1974-12-04 | ||
| JPS5640682B2 (enExample) | 1972-02-01 | 1981-09-22 | ||
| US4373656A (en) | 1981-07-17 | 1983-02-15 | Western Electric Company, Inc. | Method of preserving the solderability of copper |
| US5472562A (en) | 1994-08-05 | 1995-12-05 | At&T Corp. | Method of etching silicon nitride |
| US6162370A (en) | 1998-08-28 | 2000-12-19 | Ashland Inc. | Composition and method for selectively etching a silicon nitride film |
| KR100812891B1 (ko) * | 2000-04-28 | 2008-03-11 | 메르크 파텐트 게엠베하 | 무기물 표면용 에칭 페이스트 |
| DE10150040A1 (de) * | 2001-10-10 | 2003-04-17 | Merck Patent Gmbh | Kombinierte Ätz- und Dotiermedien |
| AU2003257636A1 (en) * | 2002-08-22 | 2004-03-11 | Daikin Industries, Ltd. | Removing solution |
| DE102005033724A1 (de) | 2005-07-15 | 2007-01-18 | Merck Patent Gmbh | Druckfähige Ätzmedien für Siliziumdioxid-und Siliziumnitridschichten |
| CN101605869B (zh) * | 2006-12-21 | 2014-03-05 | 高级技术材料公司 | 选择性除去四氮化三硅的组合物和方法 |
| JP4947654B2 (ja) * | 2007-09-28 | 2012-06-06 | シャープ株式会社 | 誘電体膜のパターニング方法 |
| JP2010205839A (ja) * | 2009-03-02 | 2010-09-16 | Sharp Corp | 半導体装置の製造方法 |
| JP5699463B2 (ja) | 2010-07-06 | 2015-04-08 | 東ソー株式会社 | 窒化ケイ素のエッチング液及びエッチング方法 |
| JP2012033561A (ja) * | 2010-07-28 | 2012-02-16 | Sanyo Chem Ind Ltd | 窒化ケイ素用エッチング液 |
| JP2012099550A (ja) * | 2010-10-29 | 2012-05-24 | Sanyo Chem Ind Ltd | 窒化ケイ素用エッチング液 |
| TW201243030A (en) * | 2011-04-20 | 2012-11-01 | Applied Materials Inc | Selective silicon nitride etch |
| WO2012174518A2 (en) | 2011-06-16 | 2012-12-20 | Advanced Technology Materials, Inc. | Compositions and methods for selectively etching silicon nitride |
| JP5913869B2 (ja) * | 2011-08-31 | 2016-04-27 | 林純薬工業株式会社 | エッチング液組成物およびエッチング方法 |
| JP5490071B2 (ja) * | 2011-09-12 | 2014-05-14 | 株式会社東芝 | エッチング方法 |
| KR101782329B1 (ko) | 2011-10-18 | 2017-09-28 | 삼성전자주식회사 | 식각용 조성물 및 이를 이용하는 반도체 기억 소자의 형성 방법 |
| US9868902B2 (en) * | 2014-07-17 | 2018-01-16 | Soulbrain Co., Ltd. | Composition for etching |
| KR20170009240A (ko) | 2015-07-16 | 2017-01-25 | 동우 화인켐 주식회사 | 비불소계 실리콘 질화막 식각 조성물 |
| KR102443370B1 (ko) | 2015-11-20 | 2022-09-15 | 동우 화인켐 주식회사 | 실리콘 질화막 식각액 조성물 |
| US10400167B2 (en) * | 2015-11-25 | 2019-09-03 | Versum Materials Us, Llc | Etching compositions and methods for using same |
-
2018
- 2018-05-25 US US15/990,000 patent/US11186771B2/en active Active
- 2018-06-03 TW TW107119087A patent/TWI683037B/zh active
- 2018-06-04 KR KR1020180064165A patent/KR102141447B1/ko active Active
- 2018-06-04 EP EP18175806.1A patent/EP3422392B1/en active Active
- 2018-06-04 IL IL259799A patent/IL259799B2/en unknown
- 2018-06-05 SG SG10201804769SA patent/SG10201804769SA/en unknown
- 2018-06-05 CN CN201810570790.5A patent/CN109054838A/zh active Pending
- 2018-06-05 JP JP2018107498A patent/JP7015214B2/ja active Active
-
2021
- 2021-04-21 JP JP2021071961A patent/JP2021132212A/ja not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| Dongwan Seo et al , "Selective wet etching of Si3N4/SiO2 in phosphoric acid with the addition of fluoride and silicic compounds",Microelectronic Engineering,Vol. 118,2014,pages 66-71 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3422392A1 (en) | 2019-01-02 |
| SG10201804769SA (en) | 2019-01-30 |
| US20180346811A1 (en) | 2018-12-06 |
| IL259799A (en) | 2018-07-31 |
| EP3422392B1 (en) | 2021-07-21 |
| US11186771B2 (en) | 2021-11-30 |
| KR20180133226A (ko) | 2018-12-13 |
| IL259799B1 (en) | 2023-09-01 |
| JP2021132212A (ja) | 2021-09-09 |
| IL259799B2 (en) | 2024-01-01 |
| TW201903207A (zh) | 2019-01-16 |
| CN109054838A (zh) | 2018-12-21 |
| KR102141447B1 (ko) | 2020-08-05 |
| JP7015214B2 (ja) | 2022-02-02 |
| JP2018207108A (ja) | 2018-12-27 |
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