TWI564262B - 高ｃｔｅ之硼矽酸鉀核心玻璃與包含其之玻璃物件 - Google Patents
高ｃｔｅ之硼矽酸鉀核心玻璃與包含其之玻璃物件 Download PDFInfo
- Publication number
- TWI564262B TWI564262B TW102107036A TW102107036A TWI564262B TW I564262 B TWI564262 B TW I564262B TW 102107036 A TW102107036 A TW 102107036A TW 102107036 A TW102107036 A TW 102107036A TW I564262 B TWI564262 B TW I564262B
- Authority
- TW
- Taiwan
- Prior art keywords
- glass
- mole
- equal
- core layer
- glass composition
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims description 436
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 title description 5
- 229910052700 potassium Inorganic materials 0.000 title description 5
- 239000011591 potassium Substances 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims description 270
- 239000012792 core layer Substances 0.000 claims description 85
- 239000010410 layer Substances 0.000 claims description 80
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 43
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 35
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 32
- 238000009792 diffusion process Methods 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 229910052796 boron Inorganic materials 0.000 claims description 12
- 239000007791 liquid phase Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 7
- 229910001385 heavy metal Inorganic materials 0.000 claims description 7
- 239000006059 cover glass Substances 0.000 claims description 5
- 239000006025 fining agent Substances 0.000 claims description 5
- 239000008395 clarifying agent Substances 0.000 claims description 4
- 239000005328 architectural glass Substances 0.000 claims 2
- 230000005693 optoelectronics Effects 0.000 claims 2
- 238000007670 refining Methods 0.000 claims 1
- 239000005340 laminated glass Substances 0.000 description 27
- 239000011734 sodium Substances 0.000 description 24
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 22
- 230000004927 fusion Effects 0.000 description 22
- 238000000034 method Methods 0.000 description 19
- 230000008569 process Effects 0.000 description 18
- 229910052783 alkali metal Inorganic materials 0.000 description 15
- 150000001340 alkali metals Chemical class 0.000 description 15
- 239000006060 molten glass Substances 0.000 description 14
- 238000002955 isolation Methods 0.000 description 12
- 238000003475 lamination Methods 0.000 description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000005342 ion exchange Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000000470 constituent Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 238000005496 tempering Methods 0.000 description 5
- 239000006063 cullet Substances 0.000 description 4
- 238000003286 fusion draw glass process Methods 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000156 glass melt Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 2
- 238000004031 devitrification Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000005341 toughened glass Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000003280 down draw process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/02—Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Liquid Crystal (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261604869P | 2012-02-29 | 2012-02-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201343590A TW201343590A (zh) | 2013-11-01 |
| TWI564262B true TWI564262B (zh) | 2017-01-01 |
Family
ID=47884557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW102107036A TWI564262B (zh) | 2012-02-29 | 2013-02-27 | 高ｃｔｅ之硼矽酸鉀核心玻璃與包含其之玻璃物件 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9512030B2 (enExample) |
| EP (1) | EP2819960B1 (enExample) |
| JP (1) | JP6190827B2 (enExample) |
| KR (1) | KR101775208B1 (enExample) |
| CN (1) | CN104364213B (enExample) |
| IN (1) | IN2014DN07757A (enExample) |
| TW (1) | TWI564262B (enExample) |
| WO (1) | WO2013130700A1 (enExample) |
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| US9302937B2 (en) | 2010-05-14 | 2016-04-05 | Corning Incorporated | Damage-resistant glass articles and method |
| TWI572480B (zh) | 2011-07-25 | 2017-03-01 | 康寧公司 | 經層壓及離子交換之強化玻璃疊層 |
| US9868664B2 (en) | 2012-02-29 | 2018-01-16 | Corning Incorporated | Low CTE, ion-exchangeable glass compositions and glass articles comprising the same |
| TWI614227B (zh) | 2012-02-29 | 2018-02-11 | 康寧公司 | 低ｃｔｅ之無鹼硼鋁矽酸鹽玻璃組成物及包含其之玻璃物件 |
| CN104936912A (zh) * | 2012-10-04 | 2015-09-23 | 康宁股份有限公司 | 具有玻璃层和玻璃陶瓷层的制品以及该制品的制造方法 |
| IN2015DN03050A (enExample) | 2012-10-04 | 2015-10-02 | Corning Inc | |
| US9434632B2 (en) * | 2013-02-26 | 2016-09-06 | Corning Incorporated | Glass forming apparatus and method |
| KR102255630B1 (ko) | 2013-08-15 | 2021-05-25 | 코닝 인코포레이티드 | 중간 내지 높은 ｃｔｅ 유리 및 이를 포함하는 유리 물품 |
| EP3831785A1 (en) | 2013-08-15 | 2021-06-09 | Corning Incorporated | Alkali-doped and alkali-free boroaluminosilicate glass |
| WO2015148618A1 (en) * | 2014-03-27 | 2015-10-01 | Corning Incorporated | Glass article |
| KR102433785B1 (ko) * | 2014-05-07 | 2022-08-18 | 코닝 인코포레이티드 | 적층 유리 제품 및 이의 형성방법 |
| WO2015179489A1 (en) * | 2014-05-21 | 2015-11-26 | Corning Incorporated | Alkali-doped and alkali-free boroaluminosilicate glass |
| US11097974B2 (en) | 2014-07-31 | 2021-08-24 | Corning Incorporated | Thermally strengthened consumer electronic glass and related systems and methods |
| KR20170047291A (ko) * | 2014-08-21 | 2017-05-04 | 코닝 인코포레이티드 | 적층 유리 제품에서 기포를 방지하는 방법 및 이로부터 형성된 적층 유리 제품 |
| WO2016033040A1 (en) | 2014-08-28 | 2016-03-03 | Corning Incorporated | Apparatus and method for cutting a glass sheet |
| EP3186076A1 (en) * | 2014-08-28 | 2017-07-05 | Corning Incorporated | Laminated glass article with ion exchangeable core and clad layers having diffusivity contrast and method of making the same |
| WO2016057590A1 (en) | 2014-10-07 | 2016-04-14 | Corning Incorporated | Glass article with determined stress profile and method of producing the same |
| US10562272B2 (en) | 2014-12-08 | 2020-02-18 | Corning Incorporated | Laminated glass article with low compaction and method for forming the same |
| US11472730B2 (en) * | 2015-06-02 | 2022-10-18 | Corning Incorporated | Laminated glass article with tinted layer |
| US12338159B2 (en) | 2015-07-30 | 2025-06-24 | Corning Incorporated | Thermally strengthened consumer electronic glass and related systems and methods |
| WO2017066243A1 (en) | 2015-10-14 | 2017-04-20 | Corning Incorporated | Laminated glass article with determined stress profile and method for forming the same |
| WO2017079540A1 (en) * | 2015-11-05 | 2017-05-11 | Corning Incorporated | Laminated glass article with determined modulus contrast and method for forming the same |
| JP6923555B2 (ja) | 2016-01-12 | 2021-08-18 | コーニング インコーポレイテッド | 薄厚熱強化及び化学強化ガラス系物品 |
| US11795102B2 (en) | 2016-01-26 | 2023-10-24 | Corning Incorporated | Non-contact coated glass and related coating system and method |
| CN114751642B (zh) * | 2016-02-02 | 2024-02-23 | 肖特玻璃科技(苏州)有限公司 | 用于玻璃载体晶片的低cte硼铝硅酸盐玻璃 |
| WO2017146063A1 (ja) | 2016-02-26 | 2017-08-31 | 旭硝子株式会社 | ガラス板の強化方法、および強化ガラス板 |
| EP3904302A1 (en) * | 2016-04-08 | 2021-11-03 | Corning Incorporated | Glass-based articles including a metal oxide concentration gradient |
| KR102404232B1 (ko) | 2016-05-04 | 2022-06-02 | 코닝 인코포레이티드 | 알루미노실리케이트 색 유리 조성물 및 이를 포함하는 유리 제품 |
| CN106175413A (zh) * | 2016-08-22 | 2016-12-07 | 江苏金海玛电器有限公司 | 一种不粘锅具的制作方法 |
| CN115321818B (zh) * | 2016-11-30 | 2024-07-12 | 康宁公司 | 可熔合形成的汽车玻璃组合物、制品和层合物 |
| US11485673B2 (en) | 2017-08-24 | 2022-11-01 | Corning Incorporated | Glasses with improved tempering capabilities |
| US11214491B2 (en) | 2017-11-17 | 2022-01-04 | Corning Incorporated | Direct graphene transfer and graphene-based devices |
| TWI785156B (zh) | 2017-11-30 | 2022-12-01 | 美商康寧公司 | 具有高熱膨脹係數及對於熱回火之優先破裂行為的非離子交換玻璃 |
| JP7180689B2 (ja) * | 2018-12-21 | 2022-11-30 | 株式会社村田製作所 | 積層体及び電子部品 |
| CN113544101A (zh) * | 2019-03-07 | 2021-10-22 | 康宁股份有限公司 | 具有目标热膨胀系数的用于扇出型封装的玻璃载体及其制造方法 |
| TWI839488B (zh) * | 2019-03-29 | 2024-04-21 | 美商康寧公司 | 耐刮擦及抗損傷的疊層玻璃製品 |
| KR20210154825A (ko) | 2019-04-23 | 2021-12-21 | 코닝 인코포레이티드 | 확정 응력 프로파일을 갖는 유리 라미네이트 및 그 제조방법 |
| US11982835B2 (en) * | 2019-05-24 | 2024-05-14 | Nlight, Inc. | Apparatuses for scattering light and methods of forming apparatuses for scattering light |
| US11697617B2 (en) | 2019-08-06 | 2023-07-11 | Corning Incorporated | Glass laminate with buried stress spikes to arrest cracks and methods of making the same |
| WO2021095917A1 (ko) * | 2019-11-13 | 2021-05-20 | 엘지전자 주식회사 | 통신용 복합 유리 및 이의 제조 방법 |
| DE102020108867A1 (de) * | 2020-03-31 | 2021-09-30 | Schott Ag | Einschmelzglas und dessen Verwendung |
| US12492142B2 (en) | 2021-04-20 | 2025-12-09 | The Penn State Research Foundation | Glass compositions, glass articles, and methods of making the same |
| CN114380579A (zh) * | 2022-01-22 | 2022-04-22 | 中国振华集团云科电子有限公司 | 一种低介电常数低温共烧陶瓷材料及其生瓷带制备方法 |
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| US7315125B2 (en) * | 2002-08-24 | 2008-01-01 | Schott Ag | Aluminum-free borosilicate glass and applications thereof |
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- 2013-02-28 EP EP13709663.2A patent/EP2819960B1/en active Active
- 2013-02-28 US US14/380,433 patent/US9512030B2/en not_active Expired - Fee Related
- 2013-02-28 CN CN201380021236.7A patent/CN104364213B/zh active Active
- 2013-02-28 JP JP2014560011A patent/JP6190827B2/ja not_active Expired - Fee Related
- 2013-02-28 KR KR1020147026635A patent/KR101775208B1/ko not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2819960B1 (en) | 2022-07-13 |
| CN104364213A (zh) | 2015-02-18 |
| IN2014DN07757A (enExample) | 2015-05-15 |
| US9512030B2 (en) | 2016-12-06 |
| US20150037552A1 (en) | 2015-02-05 |
| JP6190827B2 (ja) | 2017-08-30 |
| WO2013130700A1 (en) | 2013-09-06 |
| CN104364213B (zh) | 2018-08-10 |
| EP2819960A1 (en) | 2015-01-07 |
| KR20140141601A (ko) | 2014-12-10 |
| KR101775208B1 (ko) | 2017-09-19 |
| TW201343590A (zh) | 2013-11-01 |
| JP2015512851A (ja) | 2015-04-30 |
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