TWI412622B - 用於應力的SiN膜的胺基乙烯基矽烷前驅物 - Google Patents
用於應力的SiN膜的胺基乙烯基矽烷前驅物 Download PDFInfo
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- TWI412622B TWI412622B TW098137987A TW98137987A TWI412622B TW I412622 B TWI412622 B TW I412622B TW 098137987 A TW098137987 A TW 098137987A TW 98137987 A TW98137987 A TW 98137987A TW I412622 B TWI412622 B TW I412622B
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- Prior art keywords
- decane
- bis
- group
- vinyl
- allyl
- Prior art date
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- 239000002243 precursor Substances 0.000 title claims abstract description 30
- JKAIQRHZPWVOQN-UHFFFAOYSA-N aminosilylethene Chemical compound N[SiH2]C=C JKAIQRHZPWVOQN-UHFFFAOYSA-N 0.000 title abstract description 4
- 239000010408 film Substances 0.000 claims abstract description 67
- 238000000034 method Methods 0.000 claims abstract description 26
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims abstract description 21
- 238000000151 deposition Methods 0.000 claims abstract description 13
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 56
- -1 aminovinylcyclodecane Chemical compound 0.000 claims description 35
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 25
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 19
- 239000001257 hydrogen Substances 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 claims description 14
- 229910021529 ammonia Inorganic materials 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 229910052715 tantalum Inorganic materials 0.000 claims description 8
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 8
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 7
- 230000008021 deposition Effects 0.000 claims description 7
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 7
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 6
- HPENIWFHQIWIHL-UHFFFAOYSA-N CCCCCCCCC(C(C=C)(C=C)NC(C)C)NC(C)C Chemical compound CCCCCCCCC(C(C=C)(C=C)NC(C)C)NC(C)C HPENIWFHQIWIHL-UHFFFAOYSA-N 0.000 claims description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000000524 functional group Chemical group 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- KDFMKVKTUCEEPQ-UHFFFAOYSA-N C(C)(C)NC(=CCCCCCCCCCCC)NC(C)C Chemical compound C(C)(C)NC(=CCCCCCCCCCCC)NC(C)C KDFMKVKTUCEEPQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 4
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 claims description 4
- 229910052734 helium Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- BBICMTJAUPFALZ-UHFFFAOYSA-N CN(CC)C(C(C=C)(C=C)N(C)CC)CCCCCCCC Chemical compound CN(CC)C(C(C=C)(C=C)N(C)CC)CCCCCCCC BBICMTJAUPFALZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000001307 helium Substances 0.000 claims description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 3
- ZBNLMCNHHAWLOB-UHFFFAOYSA-N C(C)(C)NC(=CCCCCCCCCCC)NC(C)C Chemical group C(C)(C)NC(=CCCCCCCCCCC)NC(C)C ZBNLMCNHHAWLOB-UHFFFAOYSA-N 0.000 claims description 2
- ZIMCWQKZXWNJDC-UHFFFAOYSA-N C(C)N(CC)C(C(C=C)(C=C)N(CC)CC)CCCCCCCC Chemical compound C(C)N(CC)C(C(C=C)(C=C)N(CC)CC)CCCCCCCC ZIMCWQKZXWNJDC-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- OGNIRUSROLJRSJ-UHFFFAOYSA-N dodec-1-en-1-amine Chemical compound CCCCCCCCCCC=CN OGNIRUSROLJRSJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052754 neon Inorganic materials 0.000 claims description 2
- JNLOCSOBPDIZCF-UHFFFAOYSA-N N1(CCCC1)C(CCCCCCCCC)(C=C)N1CCCC1 Chemical compound N1(CCCC1)C(CCCCCCCCC)(C=C)N1CCCC1 JNLOCSOBPDIZCF-UHFFFAOYSA-N 0.000 claims 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 3
- 239000000376 reactant Substances 0.000 claims 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 125000005271 tributylamino group Chemical group 0.000 claims 2
- PPWXVBZFIPIWAX-UHFFFAOYSA-N 2-cyclohexylethenamine Chemical compound NC=CC1CCCCC1 PPWXVBZFIPIWAX-UHFFFAOYSA-N 0.000 claims 1
- MWSJZNDJYPNARD-UHFFFAOYSA-N 3-methyldodec-1-ene Chemical compound CCCCCCCCCC(C)C=C MWSJZNDJYPNARD-UHFFFAOYSA-N 0.000 claims 1
- PRCSZTAFMUTDTA-UHFFFAOYSA-N C(=C)C(CCCCCCCCC)C=C Chemical compound C(=C)C(CCCCCCCCC)C=C PRCSZTAFMUTDTA-UHFFFAOYSA-N 0.000 claims 1
- YNSOHMKFQPDTRM-UHFFFAOYSA-N C(C)(C)(C)NC(=CCCCCCCCCCCC)NC(C)(C)C Chemical compound C(C)(C)(C)NC(=CCCCCCCCCCCC)NC(C)(C)C YNSOHMKFQPDTRM-UHFFFAOYSA-N 0.000 claims 1
- VRTRQZOVVNFGDF-UHFFFAOYSA-N C(C)N(CC)C(=CCCCCCCCCCC)N(CC)CC Chemical compound C(C)N(CC)C(=CCCCCCCCCCC)N(CC)CC VRTRQZOVVNFGDF-UHFFFAOYSA-N 0.000 claims 1
- YEOULPUTYPMCAG-UHFFFAOYSA-N CCCCCCCCCC(CC=C)(N1CCCC1)N2CCCC2 Chemical compound CCCCCCCCCC(CC=C)(N1CCCC1)N2CCCC2 YEOULPUTYPMCAG-UHFFFAOYSA-N 0.000 claims 1
- SEJOFYPFJXKBCV-UHFFFAOYSA-N CCCCCCCCCC=C(NC(C)C)NC(C)C Chemical compound CCCCCCCCCC=C(NC(C)C)NC(C)C SEJOFYPFJXKBCV-UHFFFAOYSA-N 0.000 claims 1
- VSIJIMVAVJOQDX-UHFFFAOYSA-N CN(CC)C(=CCCCCCCCCCC)N(C)CC Chemical compound CN(CC)C(=CCCCCCCCCCC)N(C)CC VSIJIMVAVJOQDX-UHFFFAOYSA-N 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- DIXBSCZRIZDQGC-UHFFFAOYSA-N diaziridine Chemical compound C1NN1 DIXBSCZRIZDQGC-UHFFFAOYSA-N 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 238000007736 thin film deposition technique Methods 0.000 claims 1
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 claims 1
- 229910052581 Si3N4 Inorganic materials 0.000 abstract description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 abstract description 3
- 239000010409 thin film Substances 0.000 abstract description 3
- YOZCOPYRQLXIDM-UHFFFAOYSA-N 1-N,1-N'-di(propan-2-yl)-3-silylprop-1-ene-1,1-diamine Chemical compound C(C)(C)NC(=CC[SiH3])NC(C)C YOZCOPYRQLXIDM-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- WWDXBDRBEKUZOS-UHFFFAOYSA-N n-[bis(ethenyl)-(propan-2-ylamino)silyl]propan-2-amine Chemical compound CC(C)N[Si](C=C)(C=C)NC(C)C WWDXBDRBEKUZOS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 230000035882 stress Effects 0.000 description 62
- 238000005516 engineering process Methods 0.000 description 5
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 4
- ZQTDLOJTSVNHEH-UHFFFAOYSA-N dodec-1-en-3-amine Chemical compound C=CC(CCCCCCCCC)N ZQTDLOJTSVNHEH-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000005669 field effect Effects 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 235000012431 wafers Nutrition 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical group [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- MSMBMPVUCWOJPY-UHFFFAOYSA-N 1-N,1-N'-ditert-butyldecane-1,1-diamine Chemical compound C(C)(C)(C)NC(NC(C)(C)C)CCCCCCCCC MSMBMPVUCWOJPY-UHFFFAOYSA-N 0.000 description 1
- VQOXUMQBYILCKR-UHFFFAOYSA-N 1-Tridecene Chemical compound CCCCCCCCCCCC=C VQOXUMQBYILCKR-UHFFFAOYSA-N 0.000 description 1
- ULUNQYODBKLBOE-UHFFFAOYSA-N 2-(1h-pyrrol-2-yl)-1h-pyrrole Chemical compound C1=CNC(C=2NC=CC=2)=C1 ULUNQYODBKLBOE-UHFFFAOYSA-N 0.000 description 1
- SBVRKPAUMVPMBD-UHFFFAOYSA-N C(C)(C)(C)NNC(=CCCCCCCCCC)NNC(C)(C)C Chemical compound C(C)(C)(C)NNC(=CCCCCCCCCC)NNC(C)(C)C SBVRKPAUMVPMBD-UHFFFAOYSA-N 0.000 description 1
- VJLWPUWREZEDHN-UHFFFAOYSA-N C(C)(C)(C)NNC(CCCC(CCCC)(C=C)C=C)NNC(C)(C)C Chemical compound C(C)(C)(C)NNC(CCCC(CCCC)(C=C)C=C)NNC(C)(C)C VJLWPUWREZEDHN-UHFFFAOYSA-N 0.000 description 1
- PXNFBQBRSWMSJF-UHFFFAOYSA-N C(C)N(CC)C(=CCCCCCCCCC)N(CC)CC Chemical compound C(C)N(CC)C(=CCCCCCCCCC)N(CC)CC PXNFBQBRSWMSJF-UHFFFAOYSA-N 0.000 description 1
- IQZHQMFSDNIDHK-UHFFFAOYSA-N CCCCCCCCCC=C(N(C)CC)N(C)CC Chemical compound CCCCCCCCCC=C(N(C)CC)N(C)CC IQZHQMFSDNIDHK-UHFFFAOYSA-N 0.000 description 1
- SLZVCFPRFRTEMM-UHFFFAOYSA-N CCCCCCCCCCC=C(N(C)C)N(C)C Chemical compound CCCCCCCCCCC=C(N(C)C)N(C)C SLZVCFPRFRTEMM-UHFFFAOYSA-N 0.000 description 1
- HAVLWIDLGIQUDA-UHFFFAOYSA-N CCCCCCCCCCC=C(NC(C)(C)C)NC(C)(C)C Chemical compound CCCCCCCCCCC=C(NC(C)(C)C)NC(C)(C)C HAVLWIDLGIQUDA-UHFFFAOYSA-N 0.000 description 1
- AJHQQZXZENJHAQ-UHFFFAOYSA-N CCCCCCCCCCCC=C(N(C)C)N(C)C Chemical compound CCCCCCCCCCCC=C(N(C)C)N(C)C AJHQQZXZENJHAQ-UHFFFAOYSA-N 0.000 description 1
- FWDMRJOUVBOZSM-UHFFFAOYSA-N CN(C)C(C(C=C)(C=C)N(C)C)CCCCCCCC Chemical compound CN(C)C(C(C=C)(C=C)N(C)C)CCCCCCCC FWDMRJOUVBOZSM-UHFFFAOYSA-N 0.000 description 1
- ATZQNZPMIVNZKD-UHFFFAOYSA-N CN(CC)C(=CCCCCCCCCCCC)N(C)CC Chemical compound CN(CC)C(=CCCCCCCCCCCC)N(C)CC ATZQNZPMIVNZKD-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- VASFARWEZGVIFQ-UHFFFAOYSA-N N1(CCCC1)C(C(C)(C=C)N1CCCC1)CCCCCCCC Chemical compound N1(CCCC1)C(C(C)(C=C)N1CCCC1)CCCCCCCC VASFARWEZGVIFQ-UHFFFAOYSA-N 0.000 description 1
- DSLDNHIMUXJRFR-UHFFFAOYSA-N N1(CCCC1)C(C(C=C)(C=C)N1CCCC1)CCCCCCCC Chemical compound N1(CCCC1)C(C(C=C)(C=C)N1CCCC1)CCCCCCCC DSLDNHIMUXJRFR-UHFFFAOYSA-N 0.000 description 1
- 239000004614 Process Aid Substances 0.000 description 1
- 229910008072 Si-N-Si Inorganic materials 0.000 description 1
- 206010042209 Stress Diseases 0.000 description 1
- 125000000641 acridinyl group Chemical group C1(=CC=CC2=NC3=CC=CC=C3C=C12)* 0.000 description 1
- 125000002009 alkene group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical class NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000012707 chemical precursor Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000006146 oximation reaction Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- ZZIZZTHXZRDOFM-XFULWGLBSA-N tamsulosin hydrochloride Chemical compound [H+].[Cl-].CCOC1=CC=CC=C1OCCN[C@H](C)CC1=CC=C(OC)C(S(N)(=O)=O)=C1 ZZIZZTHXZRDOFM-XFULWGLBSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005891 transamination reaction Methods 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/513—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using plasma jets
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
- C23C16/345—Silicon nitride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02205—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition
- H01L21/02208—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition the precursor containing a compound comprising Si
- H01L21/02219—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition the precursor containing a compound comprising Si the compound comprising silicon and nitrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/36—Carbonitrides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/0217—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon nitride not containing oxygen, e.g. SixNy or SixByNz
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
- H01L21/02274—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition in the presence of a plasma [PECVD]
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Vapour Deposition (AREA)
- Formation Of Insulating Films (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11362408P | 2008-11-12 | 2008-11-12 | |
| US12/609,542 US8580993B2 (en) | 2008-11-12 | 2009-10-30 | Amino vinylsilane precursors for stressed SiN films |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201018741A TW201018741A (en) | 2010-05-16 |
| TWI412622B true TWI412622B (zh) | 2013-10-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW098137987A TWI412622B (zh) | 2008-11-12 | 2009-11-09 | 用於應力的SiN膜的胺基乙烯基矽烷前驅物 |
| TW100140431A TWI437117B (zh) | 2008-11-12 | 2009-11-09 | 用於應力的SiN膜的胺基乙烯基矽烷前驅物 |
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| Application Number | Title | Priority Date | Filing Date |
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| TW100140431A TWI437117B (zh) | 2008-11-12 | 2009-11-09 | 用於應力的SiN膜的胺基乙烯基矽烷前驅物 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US8580993B2 (enExample) |
| EP (2) | EP2465861A1 (enExample) |
| JP (2) | JP5175261B2 (enExample) |
| KR (2) | KR101396139B1 (enExample) |
| CN (2) | CN101899651B (enExample) |
| TW (2) | TWI412622B (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8580993B2 (en) * | 2008-11-12 | 2013-11-12 | Air Products And Chemicals, Inc. | Amino vinylsilane precursors for stressed SiN films |
| US8889235B2 (en) * | 2009-05-13 | 2014-11-18 | Air Products And Chemicals, Inc. | Dielectric barrier deposition using nitrogen containing precursor |
| US8637411B2 (en) | 2010-04-15 | 2014-01-28 | Novellus Systems, Inc. | Plasma activated conformal dielectric film deposition |
| US9373500B2 (en) | 2014-02-21 | 2016-06-21 | Lam Research Corporation | Plasma assisted atomic layer deposition titanium oxide for conformal encapsulation and gapfill applications |
| US9892917B2 (en) | 2010-04-15 | 2018-02-13 | Lam Research Corporation | Plasma assisted atomic layer deposition of multi-layer films for patterning applications |
| US9257274B2 (en) | 2010-04-15 | 2016-02-09 | Lam Research Corporation | Gapfill of variable aspect ratio features with a composite PEALD and PECVD method |
| US9997357B2 (en) | 2010-04-15 | 2018-06-12 | Lam Research Corporation | Capped ALD films for doping fin-shaped channel regions of 3-D IC transistors |
| US8460753B2 (en) | 2010-12-09 | 2013-06-11 | Air Products And Chemicals, Inc. | Methods for depositing silicon dioxide or silicon oxide films using aminovinylsilanes |
| US8647993B2 (en) * | 2011-04-11 | 2014-02-11 | Novellus Systems, Inc. | Methods for UV-assisted conformal film deposition |
| KR20160093093A (ko) | 2011-06-03 | 2016-08-05 | 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 | 탄소-도핑된 규소-함유 막을 증착시키기 위한 조성물 및 방법 |
| SG2013083654A (en) | 2012-11-08 | 2014-06-27 | Novellus Systems Inc | Methods for depositing films on sensitive substrates |
| US9564312B2 (en) | 2014-11-24 | 2017-02-07 | Lam Research Corporation | Selective inhibition in atomic layer deposition of silicon-containing films |
| US10566187B2 (en) | 2015-03-20 | 2020-02-18 | Lam Research Corporation | Ultrathin atomic layer deposition film accuracy thickness control |
| KR20170019668A (ko) * | 2015-08-12 | 2017-02-22 | (주)디엔에프 | 플라즈마 원자층 증착법을 이용한 실리콘 질화 박막의 제조방법 |
| US9773643B1 (en) | 2016-06-30 | 2017-09-26 | Lam Research Corporation | Apparatus and method for deposition and etch in gap fill |
| US10062563B2 (en) | 2016-07-01 | 2018-08-28 | Lam Research Corporation | Selective atomic layer deposition with post-dose treatment |
| WO2018016871A1 (ko) * | 2016-07-22 | 2018-01-25 | (주)디엔에프 | 플라즈마 원자층 증착법을 이용한 실리콘 질화 박막의 제조방법 |
| US10037884B2 (en) | 2016-08-31 | 2018-07-31 | Lam Research Corporation | Selective atomic layer deposition for gapfill using sacrificial underlayer |
| US10269559B2 (en) | 2017-09-13 | 2019-04-23 | Lam Research Corporation | Dielectric gapfill of high aspect ratio features utilizing a sacrificial etch cap layer |
| CN114127890B (zh) | 2019-05-01 | 2025-10-14 | 朗姆研究公司 | 调整的原子层沉积 |
| KR20220006663A (ko) | 2019-06-07 | 2022-01-17 | 램 리써치 코포레이션 | 원자 층 증착 동안 막 특성들의 인-시츄 (in-situ) 제어 |
| KR102727074B1 (ko) * | 2020-03-19 | 2024-11-06 | 삼성디스플레이 주식회사 | 표시 장치 |
| TWI798765B (zh) * | 2020-07-24 | 2023-04-11 | 美商慧盛材料美國責任有限公司 | 用於鍺種子層的組合物及使用其的方法 |
| WO2023102376A1 (en) * | 2021-12-01 | 2023-06-08 | Lam Research Corporation | Deposition of high compressive stress thermally stable nitride film |
| CN114447435A (zh) * | 2022-01-21 | 2022-05-06 | 恒实科技发展(南京)有限公司 | 用于锂二次电池的非水电解液及其制备方法和应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200703469A (en) * | 2005-05-26 | 2007-01-16 | Applied Materials Inc | Method to increase the compressive stress of PECVD silicon nitride films |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2854787B2 (ja) * | 1993-08-31 | 1999-02-03 | 信越化学工業株式会社 | シリコーンゴム組成物の製造方法 |
| JP3430097B2 (ja) | 1999-12-22 | 2003-07-28 | 日本電気株式会社 | 薄膜トランジスタアレイ基板の製造方法 |
| JP2002246381A (ja) * | 2001-02-15 | 2002-08-30 | Anelva Corp | Cvd方法 |
| JP2004223769A (ja) * | 2003-01-20 | 2004-08-12 | Dainippon Printing Co Ltd | 透明積層フィルム、反射防止フィルム及びそれを用いた偏光板、液晶表示装置 |
| US7122222B2 (en) * | 2003-01-23 | 2006-10-17 | Air Products And Chemicals, Inc. | Precursors for depositing silicon containing films and processes thereof |
| US7579496B2 (en) * | 2003-10-10 | 2009-08-25 | Advanced Technology Materials, Inc. | Monosilane or disilane derivatives and method for low temperature deposition of silicon-containing films using the same |
| JP2005310861A (ja) | 2004-04-19 | 2005-11-04 | Mitsui Chemicals Inc | 炭化窒化珪素膜の形成方法 |
| US7129187B2 (en) * | 2004-07-14 | 2006-10-31 | Tokyo Electron Limited | Low-temperature plasma-enhanced chemical vapor deposition of silicon-nitrogen-containing films |
| US20060045986A1 (en) | 2004-08-30 | 2006-03-02 | Hochberg Arthur K | Silicon nitride from aminosilane using PECVD |
| JP2006120992A (ja) | 2004-10-25 | 2006-05-11 | C Bui Res:Kk | シリコン窒化膜の製造方法及びその製造装置 |
| US20060182885A1 (en) * | 2005-02-14 | 2006-08-17 | Xinjian Lei | Preparation of metal silicon nitride films via cyclic deposition |
| JP2006294485A (ja) | 2005-04-13 | 2006-10-26 | Konica Minolta Holdings Inc | 有機エレクトロルミネッセンス素子、その製造方法及び表示装置 |
| US7875556B2 (en) | 2005-05-16 | 2011-01-25 | Air Products And Chemicals, Inc. | Precursors for CVD silicon carbo-nitride and silicon nitride films |
| ES2389665T3 (es) * | 2005-05-31 | 2012-10-30 | Toho Titanium Co., Ltd. | Compuestos aminosilánicos, componentes catalíticos y catalizadores para la polimerización de olefinas, y procedimiento para la producción de polímeros olefínicos con los mismos |
| JP2007092166A (ja) * | 2005-09-02 | 2007-04-12 | Japan Advanced Institute Of Science & Technology Hokuriku | 薄膜堆積装置、薄膜堆積方法及び化合物薄膜 |
| US20080142046A1 (en) * | 2006-12-13 | 2008-06-19 | Andrew David Johnson | Thermal F2 etch process for cleaning CVD chambers |
| US7790635B2 (en) * | 2006-12-14 | 2010-09-07 | Applied Materials, Inc. | Method to increase the compressive stress of PECVD dielectric films |
| US20100003483A1 (en) | 2007-02-05 | 2010-01-07 | Kazuhiro Fukuda | Transparent gas barrier film |
| JP5391557B2 (ja) * | 2007-02-28 | 2014-01-15 | 住友化学株式会社 | 共役ジエン系重合体、共役ジエン系重合体の製造方法及び共役ジエン系重合体組成物 |
| US8580993B2 (en) * | 2008-11-12 | 2013-11-12 | Air Products And Chemicals, Inc. | Amino vinylsilane precursors for stressed SiN films |
-
2009
- 2009-10-30 US US12/609,542 patent/US8580993B2/en not_active Expired - Fee Related
- 2009-11-09 TW TW098137987A patent/TWI412622B/zh not_active IP Right Cessation
- 2009-11-09 TW TW100140431A patent/TWI437117B/zh not_active IP Right Cessation
- 2009-11-11 KR KR1020090108666A patent/KR101396139B1/ko not_active Expired - Fee Related
- 2009-11-12 JP JP2009259203A patent/JP5175261B2/ja not_active Expired - Fee Related
- 2009-11-12 CN CN2009102468369A patent/CN101899651B/zh not_active Expired - Fee Related
- 2009-11-12 EP EP12159248A patent/EP2465861A1/en not_active Withdrawn
- 2009-11-12 CN CN201110404812.9A patent/CN102491990B/zh not_active Expired - Fee Related
- 2009-11-12 EP EP09175806A patent/EP2192207B1/en not_active Not-in-force
-
2012
- 2012-09-27 JP JP2012214658A patent/JP5508496B2/ja active Active
- 2012-12-28 KR KR1020120156542A patent/KR101553863B1/ko not_active Expired - Fee Related
-
2013
- 2013-11-04 US US14/070,957 patent/US20140065844A1/en not_active Abandoned
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200703469A (en) * | 2005-05-26 | 2007-01-16 | Applied Materials Inc | Method to increase the compressive stress of PECVD silicon nitride films |
Non-Patent Citations (1)
| Title |
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| Lauter et al., Macromolecules, 1999, 32. * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20100120262A1 (en) | 2010-05-13 |
| CN102491990B (zh) | 2015-12-09 |
| TWI437117B (zh) | 2014-05-11 |
| EP2192207A1 (en) | 2010-06-02 |
| EP2192207B1 (en) | 2012-06-20 |
| CN101899651A (zh) | 2010-12-01 |
| TW201211303A (en) | 2012-03-16 |
| JP2010118664A (ja) | 2010-05-27 |
| CN101899651B (zh) | 2012-12-26 |
| CN102491990A (zh) | 2012-06-13 |
| US20140065844A1 (en) | 2014-03-06 |
| KR20100053471A (ko) | 2010-05-20 |
| KR20130016171A (ko) | 2013-02-14 |
| JP2013016859A (ja) | 2013-01-24 |
| EP2465861A1 (en) | 2012-06-20 |
| US8580993B2 (en) | 2013-11-12 |
| KR101553863B1 (ko) | 2015-09-17 |
| JP5175261B2 (ja) | 2013-04-03 |
| KR101396139B1 (ko) | 2014-05-19 |
| JP5508496B2 (ja) | 2014-05-28 |
| TW201018741A (en) | 2010-05-16 |
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