TWI343834B - Catalyst systems for preparing phthalic anhydride - Google Patents

Catalyst systems for preparing phthalic anhydride Download PDF

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Publication number
TWI343834B
TWI343834B TW093112422A TW93112422A TWI343834B TW I343834 B TWI343834 B TW I343834B TW 093112422 A TW093112422 A TW 093112422A TW 93112422 A TW93112422 A TW 93112422A TW I343834 B TWI343834 B TW I343834B
Authority
TW
Taiwan
Prior art keywords
weight
catalyst
surface area
bet surface
gram
Prior art date
Application number
TW093112422A
Other languages
English (en)
Chinese (zh)
Other versions
TW200505566A (en
Inventor
Sebastian Storck
Juergen Zuehlke
Samuel Neto
Frank Rosowski
Original Assignee
Basf Ag
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Application filed by Basf Ag filed Critical Basf Ag
Publication of TW200505566A publication Critical patent/TW200505566A/zh
Application granted granted Critical
Publication of TWI343834B publication Critical patent/TWI343834B/zh

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
TW093112422A 2003-05-23 2004-05-03 Catalyst systems for preparing phthalic anhydride TWI343834B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10323818A DE10323818A1 (de) 2003-05-23 2003-05-23 Katalysatorsysteme zur Herstellung von Phthalsäureanhydrid

Publications (2)

Publication Number Publication Date
TW200505566A TW200505566A (en) 2005-02-16
TWI343834B true TWI343834B (en) 2011-06-21

Family

ID=33441317

Family Applications (1)

Application Number Title Priority Date Filing Date
TW093112422A TWI343834B (en) 2003-05-23 2004-05-03 Catalyst systems for preparing phthalic anhydride

Country Status (15)

Country Link
US (2) US7687425B2 (enExample)
EP (1) EP1628763B1 (enExample)
JP (1) JP4829113B2 (enExample)
KR (1) KR100996479B1 (enExample)
CN (1) CN1795049B (enExample)
AT (1) ATE372827T1 (enExample)
BR (1) BRPI0410472B1 (enExample)
DE (2) DE10323818A1 (enExample)
ES (1) ES2290712T3 (enExample)
MX (1) MXPA05012454A (enExample)
PL (1) PL1628763T3 (enExample)
RU (1) RU2005140086A (enExample)
TW (1) TWI343834B (enExample)
WO (1) WO2004103561A1 (enExample)
ZA (1) ZA200510369B (enExample)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10334132A1 (de) 2003-07-25 2005-04-07 Basf Ag Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung
WO2005115615A1 (de) * 2004-05-29 2005-12-08 Süd-Chemie AG Katalysator sowie verfahren zur herstellung von phthalsäureanhydrid
DE102004026472A1 (de) * 2004-05-29 2005-12-22 Süd-Chemie AG Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid
EP1814660A1 (de) * 2004-11-18 2007-08-08 Basf Aktiengesellschaft Verwendung von titandioxidgemischen zur herstellung von katalysatoren
ZA200707387B (en) * 2005-03-02 2008-12-31 Sued Chemie Ag Method for producing a multi-layer catalyst for obtaining phthalic anhydride
DE102005009473A1 (de) * 2005-03-02 2006-09-07 Süd-Chemie AG Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid
ZA200708804B (en) * 2005-05-22 2009-01-28 Sued Chemie Ag Multi-layered catalyst for producing phthalic anhydride
DE102005026360A1 (de) * 2005-06-07 2006-12-28 Basf Ag Verfahren zur Präformierung von Oxidationskatalysatoren
EP2024085A1 (de) * 2006-05-19 2009-02-18 Basf Se Katalysatorsystem zur herstellung von carbonsäuren und/oder carbonsäureanhydriden
EP1860091A1 (de) * 2006-05-23 2007-11-28 Süd-Chemie Ag Katalysator enthaltend Titandioxid, insbesondere zur Herstellung von Phthalsäurenanhydrid
EP2035138A1 (de) * 2006-06-20 2009-03-18 Basf Se Katalysatorsystem und verfahren zur herstellung von carbonsäuren und/oder carbonsäureanhydriden
BRPI0720411A2 (pt) 2006-12-21 2013-12-31 Basf Se Processo para oxidação em fase gasosa, e, sistema catalisador para a realização de processos de oxidação em fase gasosa
US8311837B1 (en) * 2008-06-13 2012-11-13 West Corporation Mobile voice self service system
DE102009041960A1 (de) 2009-09-17 2011-04-07 Süd-Chemie AG Verfahren zur Herstellung einer Katalysatoranordnung für die Herstellung von Phthalsäureanhydrid
DE102009049173A1 (de) 2009-10-13 2011-04-21 Süd-Chemie AG Reaktoranordnung zur katalytischen Gasphasenoxidation
CN102612406A (zh) * 2009-11-20 2012-07-25 巴斯夫欧洲公司 用于制备羧酸和/或羧酸酐的在至少一个催化剂层中具有锑酸钒的多层催化剂及具有低热点温度的制备邻苯二甲酸酐的方法
DE102010006854A1 (de) 2010-02-04 2011-08-04 Süd-Chemie AG, 80333 Verfahren zur Gasphasenoxidation von Kohlenwasserstoffen
DE102010012090A1 (de) 2010-03-19 2011-11-17 Süd-Chemie AG Verfahren zur katalytischen Gasphasenoxidation von Kohlenwasserstoffen und Katalysereaktionsvorrichtung
US20110230668A1 (en) * 2010-03-19 2011-09-22 Basf Se Catalyst for gas phase oxidations based on low-sulfur and low-calcium titanium dioxide
US8901320B2 (en) 2010-04-13 2014-12-02 Basf Se Process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride
US8859459B2 (en) 2010-06-30 2014-10-14 Basf Se Multilayer catalyst for preparing phthalic anhydride and process for preparing phthalic anhydride
WO2012001620A1 (de) * 2010-06-30 2012-01-05 Basf Se Mehrlagenkatalysator zur herstellung von phthalsäureanhydrid und verfahren zur herstellung von phthalsäureanhydrid
US9212157B2 (en) 2010-07-30 2015-12-15 Basf Se Catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride
JP5973436B2 (ja) * 2010-07-30 2016-08-23 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ｏ−キシレン及び／又はナフタレンを無水フタル酸に酸化するための触媒
US9029289B2 (en) 2012-07-16 2015-05-12 Basf Se Catalyst for preparing carboxylic acids and/or carboxylic anhydrides
DE102013000654B4 (de) * 2013-01-16 2020-10-15 Clariant International Ltd. Verfahren zur Optimierung der Aktivität eines Phthalsäureanhydrid-Katalysators
EP3013784B1 (de) 2013-06-26 2018-12-26 Basf Se Verfahren zum anfahren eines gasphasenoxidationsreaktors
CN105339337A (zh) 2013-06-26 2016-02-17 巴斯夫欧洲公司 制备邻苯二甲酸酐的方法
JP6257758B2 (ja) 2014-04-24 2018-01-10 クラリアント・インターナシヨナル・リミテツド 無水フタル酸を製造するための最適化された空隙率を有する触媒配置構成物
EP3047904A1 (en) 2015-01-22 2016-07-27 Basf Se Catalyst system for oxidation of o-xylene and/or naphthalene to phthalic anhydride
IT202100021746A1 (it) * 2021-08-11 2023-02-11 Polynt S P A Letto catalitico multistrato per la produzione di anidride ftalica.

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DE2106796C3 (de) 1971-02-12 1981-09-24 Wacker-Chemie GmbH, 8000 München Verfahren zur Herstellung Festbettkatalysatoren mit einem Überzug aus Vanadiumpentoxid und Titandioxid
DE2238067C3 (de) 1972-08-02 1979-04-12 Wacker-Chemie Gmbh, 8000 Muenchen Verfahren zur Herstellung von Phthalsäureanhydrid
US5235071A (en) 1991-07-10 1993-08-10 Nippon Shokubai Co., Ltd. Catalyst for producing phthalic anhydride and process by using the same
FR2724461B1 (fr) * 1994-09-09 1996-12-20 Prolabo Sa Microsphere de latex biotinylee, procede de preparation d'une telle microsphere et utilisation en tant qu'agent de detection biologique
DE19519172A1 (de) * 1995-05-24 1996-11-28 Consortium Elektrochem Ind Trägerkatalysator für Gasphasenoxidationsreaktoren
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TW415939B (en) 1996-10-23 2000-12-21 Nippon Steel Chemical Co Gas-phase oxidization process and process for the preparation of phthalic anhydride
DE19707943C2 (de) * 1997-02-27 1999-07-08 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid und Katalysator hierfür
DE19823262A1 (de) * 1998-05-26 1999-12-02 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid
DE19823275A1 (de) * 1998-05-26 1999-12-02 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid durch katalytische Gasphasenoxidation von x-Xylol-/-Naphthalin-Gemischen
JP4557378B2 (ja) * 1999-06-24 2010-10-06 株式会社日本触媒 無水フタル酸の製造方法
CN1280979A (zh) 1999-06-24 2001-01-24 株式会社日本触媒 用于生产邻苯二甲酸酐的方法
DE10040827A1 (de) 2000-08-21 2002-03-07 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid
US20030023042A1 (en) * 2001-12-06 2003-01-30 Genentech, Inc. Secreted and transmembrane polypeptides and nucleic acids encoding the same
DE10206989A1 (de) 2002-02-19 2003-08-21 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid
DE10211446A1 (de) 2002-03-15 2003-10-02 Basf Ag Verfahren zur Herstellung eines Vanadium, Phosphor und Sauerstoff enthaltenden Katalysators
DE10231976A1 (de) 2002-07-15 2004-01-29 Basf Ag Strukturierte Katalysator-Schüttung
DE10323461A1 (de) 2003-05-23 2004-12-09 Basf Ag Herstellung von Aldehyden, Carbonsäuren und/oder Carbonsäureanhydriden mittels Vanadiumoxid, Titandioxid und Antimonoxid enthaltender Katalysatoren
DE10323817A1 (de) 2003-05-23 2004-12-09 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid

Also Published As

Publication number Publication date
US7687425B2 (en) 2010-03-30
EP1628763B1 (de) 2007-09-12
US20060276661A1 (en) 2006-12-07
KR100996479B1 (ko) 2010-11-24
BRPI0410472B1 (pt) 2014-01-28
ES2290712T3 (es) 2008-02-16
JP2007533426A (ja) 2007-11-22
RU2005140086A (ru) 2006-08-10
EP1628763A1 (de) 2006-03-01
TW200505566A (en) 2005-02-16
DE502004004958D1 (de) 2007-10-25
MXPA05012454A (es) 2006-02-22
CN1795049A (zh) 2006-06-28
ATE372827T1 (de) 2007-09-15
US7985705B2 (en) 2011-07-26
ZA200510369B (en) 2007-04-25
US20100210857A1 (en) 2010-08-19
KR20060015268A (ko) 2006-02-16
BRPI0410472A (pt) 2006-05-30
WO2004103561A1 (de) 2004-12-02
CN1795049B (zh) 2012-02-01
PL1628763T3 (pl) 2008-02-29
JP4829113B2 (ja) 2011-12-07
DE10323818A1 (de) 2004-12-09

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