TWI334860B - Process for the preparation of perfluoroalkanesulfonic acid esters and salts thereof - Google Patents
Process for the preparation of perfluoroalkanesulfonic acid esters and salts thereof Download PDFInfo
- Publication number
- TWI334860B TWI334860B TW091136281A TW91136281A TWI334860B TW I334860 B TWI334860 B TW I334860B TW 091136281 A TW091136281 A TW 091136281A TW 91136281 A TW91136281 A TW 91136281A TW I334860 B TWI334860 B TW I334860B
- Authority
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- Taiwan
- Prior art keywords
- chloride
- anhydride
- group
- alkyl
- carbonate
- Prior art date
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- 239000002253 acid Substances 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 19
- 150000002148 esters Chemical class 0.000 title claims abstract description 7
- 150000003839 salts Chemical class 0.000 title abstract description 23
- 238000002360 preparation method Methods 0.000 title abstract description 4
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 24
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- -1 carboxylic acid halide Chemical class 0.000 claims description 15
- 150000008064 anhydrides Chemical class 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 14
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- MXVMRHIWTSFDPU-UHFFFAOYSA-N 2-chlorobenzenecarboximidamide Chemical compound NC(=N)C1=CC=CC=C1Cl MXVMRHIWTSFDPU-UHFFFAOYSA-N 0.000 claims description 5
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 5
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 4
- 239000003153 chemical reaction reagent Substances 0.000 claims description 4
- 230000002079 cooperative effect Effects 0.000 claims description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- KEQAKMCQBPAICI-UHFFFAOYSA-N (2-bromobenzoyl) 2-bromobenzoate Chemical compound BrC1=CC=CC=C1C(=O)OC(=O)C1=CC=CC=C1Br KEQAKMCQBPAICI-UHFFFAOYSA-N 0.000 claims description 2
- OLENANGIJWDOPG-UHFFFAOYSA-N (2-chlorobenzoyl) 2-chlorobenzoate Chemical compound ClC1=CC=CC=C1C(=O)OC(=O)C1=CC=CC=C1Cl OLENANGIJWDOPG-UHFFFAOYSA-N 0.000 claims description 2
- DZJZPASJHDOOQA-UHFFFAOYSA-N (3-bromobenzoyl) 3-bromobenzoate Chemical compound BrC1=CC=CC(C(=O)OC(=O)C=2C=C(Br)C=CC=2)=C1 DZJZPASJHDOOQA-UHFFFAOYSA-N 0.000 claims description 2
- MABIZNQZHSUZCA-UHFFFAOYSA-N 1-bromo-2-(dichloromethyl)benzene Chemical compound ClC(Cl)C1=CC=CC=C1Br MABIZNQZHSUZCA-UHFFFAOYSA-N 0.000 claims description 2
- ABEMHAGGXXXPMX-UHFFFAOYSA-N 2-chlorobenzamide;hydrochloride Chemical compound Cl.NC(=O)C1=CC=CC=C1Cl ABEMHAGGXXXPMX-UHFFFAOYSA-N 0.000 claims description 2
- NLUZTURLLBODRD-UHFFFAOYSA-N NC(C(C(Cl)=CC=C1)=C1Cl)=O.Cl Chemical compound NC(C(C(Cl)=CC=C1)=C1Cl)=O.Cl NLUZTURLLBODRD-UHFFFAOYSA-N 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 claims description 2
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 claims description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 2
- 125000000962 organic group Chemical group 0.000 claims description 2
- JJSOANNTEVSOOJ-UHFFFAOYSA-N (2,3,4,5-tetrachlorobenzoyl) 2,3,4,5-tetrachlorobenzoate Chemical compound ClC1=C(Cl)C(Cl)=CC(C(=O)OC(=O)C=2C(=C(Cl)C(Cl)=C(Cl)C=2)Cl)=C1Cl JJSOANNTEVSOOJ-UHFFFAOYSA-N 0.000 claims 2
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 1
- PQQZYNVQDUZLTQ-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzoate Chemical compound ClC1=CC=CC(C(=O)OC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl PQQZYNVQDUZLTQ-UHFFFAOYSA-N 0.000 claims 1
- IUILGHBUWUXVBP-UHFFFAOYSA-N (4-bromobenzoyl) 4-bromobenzoate Chemical compound C1=CC(Br)=CC=C1C(=O)OC(=O)C1=CC=C(Br)C=C1 IUILGHBUWUXVBP-UHFFFAOYSA-N 0.000 claims 1
- BVYUYDBWQMSOKM-UHFFFAOYSA-N (4-bromophenyl)methanamine;hydron;chloride Chemical compound Cl.NCC1=CC=C(Br)C=C1 BVYUYDBWQMSOKM-UHFFFAOYSA-N 0.000 claims 1
- YMXAYMSJCVGYEM-UHFFFAOYSA-N 1-Chloro-2-(chlorophenylmethyl)benzene Chemical compound C=1C=CC=C(Cl)C=1C(Cl)C1=CC=CC=C1 YMXAYMSJCVGYEM-UHFFFAOYSA-N 0.000 claims 1
- FCSFSWLSKOMQFX-UHFFFAOYSA-N 1-chloro-3-[chloro(phenyl)methyl]benzene Chemical compound C=1C=CC(Cl)=CC=1C(Cl)C1=CC=CC=C1 FCSFSWLSKOMQFX-UHFFFAOYSA-N 0.000 claims 1
- UFUIZPCXYRUNPZ-UHFFFAOYSA-N 2,2,2-trichloroethanimidamide;hydrochloride Chemical compound Cl.NC(=N)C(Cl)(Cl)Cl UFUIZPCXYRUNPZ-UHFFFAOYSA-N 0.000 claims 1
- HKWAITKWZBCFRF-UHFFFAOYSA-N 2,3-dichlorobenzamide;hydron;chloride Chemical compound Cl.NC(=O)C1=CC=CC(Cl)=C1Cl HKWAITKWZBCFRF-UHFFFAOYSA-N 0.000 claims 1
- ZJYYNRKPASTBIR-UHFFFAOYSA-N 2,4-dichlorobenzamide hydrochloride Chemical compound Cl.ClC1=C(C(=O)N)C=CC(=C1)Cl ZJYYNRKPASTBIR-UHFFFAOYSA-N 0.000 claims 1
- NSTREUWFTAOOKS-UHFFFAOYSA-N 2-fluorobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1F NSTREUWFTAOOKS-UHFFFAOYSA-N 0.000 claims 1
- HPGWEJVEFOYUFN-UHFFFAOYSA-N 3,5-dichlorobenzamide hydrochloride Chemical compound Cl.NC(=O)C1=CC(Cl)=CC(Cl)=C1 HPGWEJVEFOYUFN-UHFFFAOYSA-N 0.000 claims 1
- JNVGBGACTRLBBA-UHFFFAOYSA-N C1=CC=C(C=C1)C(C2=CC(=C(C(=C2F)F)F)F)(F)Cl Chemical compound C1=CC=C(C=C1)C(C2=CC(=C(C(=C2F)F)F)F)(F)Cl JNVGBGACTRLBBA-UHFFFAOYSA-N 0.000 claims 1
- 150000001733 carboxylic acid esters Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 14
- 239000003990 capacitor Substances 0.000 abstract description 7
- 239000003792 electrolyte Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 description 23
- 239000011541 reaction mixture Substances 0.000 description 22
- 238000003756 stirring Methods 0.000 description 18
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- 238000009835 boiling Methods 0.000 description 13
- 238000001816 cooling Methods 0.000 description 13
- 238000005160 1H NMR spectroscopy Methods 0.000 description 12
- 238000010992 reflux Methods 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- OIRDBPQYVWXNSJ-UHFFFAOYSA-N methyl trifluoromethansulfonate Chemical compound COS(=O)(=O)C(F)(F)F OIRDBPQYVWXNSJ-UHFFFAOYSA-N 0.000 description 11
- 238000004821 distillation Methods 0.000 description 8
- WEVYAHXRMPXWCK-FIBGUPNXSA-N acetonitrile-d3 Chemical compound [2H]C([2H])([2H])C#N WEVYAHXRMPXWCK-FIBGUPNXSA-N 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 7
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 7
- 238000005481 NMR spectroscopy Methods 0.000 description 6
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 6
- 238000004293 19F NMR spectroscopy Methods 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000011245 gel electrolyte Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000000875 corresponding effect Effects 0.000 description 3
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 3
- UVECLJDRPFNRRQ-UHFFFAOYSA-N ethyl trifluoromethanesulfonate Chemical compound CCOS(=O)(=O)C(F)(F)F UVECLJDRPFNRRQ-UHFFFAOYSA-N 0.000 description 3
- 229940095102 methyl benzoate Drugs 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 125000003107 substituted aryl group Chemical group 0.000 description 2
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 2
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 description 1
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- LYKVCCHDBARSHV-UHFFFAOYSA-N 1-[chloro(phenyl)methyl]-4-nitrobenzene Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(Cl)C1=CC=CC=C1 LYKVCCHDBARSHV-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- PQYGNIRJOCANCU-UHFFFAOYSA-N 1-bromo-4-(dichloromethyl)benzene Chemical compound ClC(Cl)C1=CC=C(Br)C=C1 PQYGNIRJOCANCU-UHFFFAOYSA-N 0.000 description 1
- ALKWTKGPKKAZMN-UHFFFAOYSA-N 1-chloro-4-[chloro(phenyl)methyl]benzene Chemical compound C=1C=C(Cl)C=CC=1C(Cl)C1=CC=CC=C1 ALKWTKGPKKAZMN-UHFFFAOYSA-N 0.000 description 1
- IWDFHWZHHOSSGR-UHFFFAOYSA-N 1-ethylimidazole Chemical compound CCN1C=CN=C1 IWDFHWZHHOSSGR-UHFFFAOYSA-N 0.000 description 1
- LTKMTXLIAZLQHS-UHFFFAOYSA-N 1-methylpyridine Chemical compound CN1C=CC=C=C1 LTKMTXLIAZLQHS-UHFFFAOYSA-N 0.000 description 1
- WPWWHXPRJFDTTJ-UHFFFAOYSA-N 2,3,4,5,6-pentafluorobenzamide Chemical compound NC(=O)C1=C(F)C(F)=C(F)C(F)=C1F WPWWHXPRJFDTTJ-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-M Methanesulfonate Chemical compound CS([O-])(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-M 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- CYZSXHKVKPUPOJ-UHFFFAOYSA-N NC(C(C(F)=C(C(F)=C1F)F)=C1F)=O.Cl Chemical compound NC(C(C(F)=C(C(F)=C1F)F)=C1F)=O.Cl CYZSXHKVKPUPOJ-UHFFFAOYSA-N 0.000 description 1
- JFDAOLRVQYKTRU-UHFFFAOYSA-N NNC(C(C(F)=CC=C1)=C1F)=O.Cl Chemical compound NNC(C(C(F)=CC=C1)=C1F)=O.Cl JFDAOLRVQYKTRU-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 239000002168 alkylating agent Substances 0.000 description 1
- 229940100198 alkylating agent Drugs 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- UQWLFOMXECTXNQ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)methylsulfonyl-trifluoromethane Chemical compound FC(F)(F)S(=O)(=O)[C-](S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F UQWLFOMXECTXNQ-UHFFFAOYSA-N 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- CACZFDSVATUTAM-UHFFFAOYSA-N ethyl methyl carbonate methyl propyl carbonate Chemical compound C(OC)(OCCC)=O.C(OC)(OCC)=O CACZFDSVATUTAM-UHFFFAOYSA-N 0.000 description 1
- 238000000806 fluorine-19 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- LGRLWUINFJPLSH-UHFFFAOYSA-N methanide Chemical compound [CH3-] LGRLWUINFJPLSH-UHFFFAOYSA-N 0.000 description 1
- VHFUHRXYRYWELT-UHFFFAOYSA-N methyl 2,2,2-trichloroacetate Chemical compound COC(=O)C(Cl)(Cl)Cl VHFUHRXYRYWELT-UHFFFAOYSA-N 0.000 description 1
- UXJRQNXHCZKHRJ-UHFFFAOYSA-N methyl 2,3,4,5,6-pentafluorobenzoate Chemical compound COC(=O)C1=C(F)C(F)=C(F)C(F)=C1F UXJRQNXHCZKHRJ-UHFFFAOYSA-N 0.000 description 1
- QNPFLTKQLFSKBY-UHFFFAOYSA-N methyl 2,6-difluorobenzoate Chemical compound COC(=O)C1=C(F)C=CC=C1F QNPFLTKQLFSKBY-UHFFFAOYSA-N 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 description 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000008177 pharmaceutical agent Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- PVFOMCVHYWHZJE-UHFFFAOYSA-N trichloroacetyl chloride Chemical compound ClC(=O)C(Cl)(Cl)Cl PVFOMCVHYWHZJE-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/26—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfonic acids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D207/323—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to the ring nitrogen atoms
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
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- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
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- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/037—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements with quaternary ring nitrogen atoms
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- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/56—Solid electrolytes, e.g. gels; Additives therein
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- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
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- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/62—Liquid electrolytes characterised by the solute, e.g. salts, anions or cations therein
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
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- H01G11/60—Liquid electrolytes characterised by the solvent
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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- Saccharide Compounds (AREA)
Description
1334860 A7 B7 五、發明説明() 1 說明 (請先閲讀背面之注意事項再填寫本頁) 本發明係關於一種製備包含全氟烷磺酸基團之化合物 (特別是製備全氟烷磺酸酯),及關於進一步將之轉變成 鹽’以及關於所得化合物於電解質、及電池、電容器、超 電容器及電化學電池上之用途。 可攜式電子設備(例如,膝上型電腦及掌上型電腦、 手機及攝影機)的普及,因此,全球對於輕及高功效電池 的需求快速增加。鑒於對於電池之需求快速地增加及與此 有關之生態問題,具有長使用週期之可再充電電池的發展 之重要性持續增加。 鋰離子電池及高容量雙層電容器(即超或超高電容器 )代表現今技藝。在此二系統中,LiPF6S N(C2H5)4BF4形式 之水解敏感性及熱不穩定物質係現今使用作爲導電鹽者。 與潮濕空氣或與溶劑中殘餘水接觸,可快速形成HF。除了 有毒性外,HF在其週期行爲上有非常不利之效果,因此在 電化學電池之功效上有非常不利之效果。 經濟部智慧財產局員工消費合作社印製 已提出之替代物爲亞醯胺,如雙(三氟甲基磺醯基)亞醯 胺或雙(五氟乙基磺醯基)亞醯胺,或甲基化物,如三(三氟 甲基磺醯基)甲基化物及其衍生物。然而,具有五氟烷基磺 酸鹽陰離子之四級銨鹽及鱗鹽已被發展爲用於電化學電池 之導電性鹽。但是,這些鹽之合成係相當複雜,因爲,很 難去製備三氟甲基磺酸甲酯中間物。 有多種合成路徑可製得三氟甲基磺酸甲酯(Gramstad, J. Chem. Soc.,1 956,1 73- 1 80或 Beard, J· Org. Chem.,1973 本纸張尺度適用中國國家標準(CNS } A4规格(210 X 297公釐) -5- 1334860 A7 _ ,_B7 五、發明説明(2 ) (請先閱讀背面之注意事項再填寫本頁) (21),3673- 3677 )。然而,所述合成路徑均不適合用於大規 模化,因爲使用之起始物質(例如硫酸二甲酯)毒性強, 產率非常低,反應產物要加以純化,或者會形成危險副產 物或無用的產物,例如被硫酸二甲酯污染之硫酸。 因此,本發明之目的在於克服先前技藝之缺點,及提 供用於合成全氟烷磺酸烷酯及於其中可加以製得之導電性 鹽之簡易及經濟有效的方法。 可根據申請專利範圍第1及9項之方法達成此目的。特 別方法特徵述於附屬項第2至8項。 本發明之特徵在於全氟烷磺酸直接與碳酸二烷酯反應 製得全氟烷磺酸烷酯。例如全氟甲基磺酸可直接與碳酸二 甲酯反應。但是,所形成三氟甲基磺酸甲酯之產率低(相 較於實施例1 )。 較佳產率之製得係在全氟烷磺酸與碳酸二烷酯於消耗 水或醇之試劑存在下的較佳反應下,其中消耗水或醇之試 劑例如羧酸衍生物,其有機基在全氟烷磺酸中爲穩定的, 例如 經濟部智慧財產局員工消費合作社印製 0 〇 CF3S〇2〇H + R—^ + (CH3〇)2C〇 ——CF3S〇2〇CH3 + R-\ + HX + c〇2 X OMe 在本發明之目的上,羧酸衍生物爲其中羧酸中之羥基 被另一官能基(例如鹵基、羧基或磺醯)取代之化合物。 在本發明之目的上,所有羧酸衍生物基本上可被使用,只 本紙張尺度適用中國國家標準(CNS ) a4規格{ 2丨οχ2”公釐) -6- 1334860 A7 __B7_ 五、發明説明() 3 要其烷基或芳基(包括那些包含質子者)在全氟烷磺酸中 爲穩定的。 (請先閲讀背面之注意事項再填寫本頁) 令人驚訝地,全氟烷磺酸及羧酸衍生物之混合物的烷 基化反應可輕易地發生,及產生產率佳之經烷基化全氟烷 磺酸及羧酸酯。熟悉此項技藝者可使用習知方法(通常爲 分餾)而輕易地單離二化合物。 在一較佳具體例中,用於本發明方法之羧酸衍生物爲 羧酸鹵化物(特別是氯化物),羧酸酐或者經混合的羧酸 /磺酸酐。使用這些起始物質會在相當短的反應時間中得 到產率良好之酯。 特別佳之羧酸氯化物係選自:苯甲醯氯、對-硝基苯甲 醯氯、2,6-二氟苯甲醯氯、五氟苯甲醯氯、2-氯苯甲醯氯、 3-氯苯甲醯氯、4-氯苯甲醯氯、2-溴苯甲醯氯、3-溴苯甲醯 氯、4-溴苯甲醯氯、2,3-二氯苯甲醯氯、2,4-二氯苯甲醯氯 、2,6-二氯苯甲醯氯、3,4-二氯苯甲醯氯' 3,5-二氯苯甲醯 氯及三氯乙酸氯。 經濟部智慧財產局員工消費合作社印製 特別佳之羧酸酐爲苯甲酸酐、2,2’-二氯苯甲酸酐、 3,3’-二氯苯甲酸酐、4,4’-二氯苯甲酸酐、2,2’,3,3’-四氯苯甲 酸酐' 2,2',4,4’-四氯苯甲酸酐、2,2’,6,6’-四氯苯甲酸酐、 3,3’,4,4’-四氯苯甲酸酐、3,3’,5,5’-四氯苯甲酸酐、2-溴苯甲 酸酐、3-溴苯甲酸酐、4-溴苯甲酸酐或2,2’,6,6^四氟苯甲酸 酐。 熟悉此項技藝人士根據本發明所用之碳酸二烷酯基本 上可爲任何已知碳酸二烷酯。然而,較佳係選自碳酸二甲 本纸張尺度適用中國國家標準(CNS ) A4規格< 21〇><297公釐) -7- 1334860 A7 _._B7 五、發明説明(,) 4 酯、碳酸二乙酯、碳酸二丙酯、碳酸二丁酯、碳酸甲醋乙 酯及這些碳酸二烷酯之混合物。 (請先閲讀背面之注意事項再填寫本頁) 本發明方法較佳在室溫及1 5 0 °C間溫度進行,特別是5 〇 及U0°C間,更特別是70及l〇〇°C間。較佳反應時間在1及1〇 小時間,特別是2及5小時間。 根據本發明所製備全氟烷磺酸酯可藉由與XWy反應 進一步被轉變成對應之全氟院碌酸鹽, 其中 X爲P或N, R'、R2及R3係相同或不同’選擇性藉由單鍵或雙鍵直接連 接至彼此,及分別獨自或一起爲 -氣, -具有1至16碳原子之烷基,該烷基可部分或全部被進— 步較佳爲 F、Cl、、0(CnF(2„ + 1.〇H,)、 S〇2(CnF(2n + 1 — 〇H,)、或 CnFnnn.oH» (其中 6及 〇奚 2η+ 1 )所取代,未經取代或經取代芳基或未經取代或經取 代芳族雜環基, 經濟部智慧財產局員工消費合作社印製 -具有1至16碳原子之伸烷基的烷芳基,其可部分被進— 步較佳爲F、Cl、Br、NCh、CN、烷基 '芳基或雜環芳基取 代, -芳基’其可部分被進—步較佳爲F' ci、Br、N〇2、CN 、烷基、芳基或雜環芳基取代,或者 -芳族雜環基’其可部分被進—步較佳爲F、C1、以 NCh、CN、烷基、芳基或雜環芳基取代,
-8- 1334860 A7 ___B7_ 五、發明説明(c) 5 其中烷基上之一、二或三個CH2基團可被相同或不同雜原子 替代,雜原子較佳爲0、NH或具有1至6碳原子之N(烷基) > 及其中所有三個R基團不可同時爲全氟的或全氯的。 反應後,所形成全氟烷磺酸鹽沉澱或可用習知方法單 離。可將未反應全氟烷磺酸烷酯蒸餾掉。 此與酯之後續反應的進行較佳使用之化合物XRiW係 選自 (請先閎讀背面之注意事項再填寫本頁)
X(C2H5)3 ' X(C3Ht)3 ' X(C.H9)3 ' R3 I
R2 R2 其中 X及Y爲P或N, R1 ' R2及R3爲Η、烷基(較佳具有1至16碳原子),烷芳基 、芳基或雜環芳基, 經濟部智慧財產局員工消費合作社印製 其中環上及/或烷基上之一、二或三個CthS團可被相同或 不同雜原子替代,雜原子較佳爲0、NH或具有1至6碳原子 之N(烷基),其中環及/或烷基可部分或全部被進一步較佳 爲 F、Cl、N(CnF(2n+l -j)H*)2 ' 0(CnF(2n+l-i)Hx) ' S Ο 2 ( C n F ( 2 η + I . ”H:)' 或 CnFnnd-oHx (其中 l$n$6 及 0SxS2n+l)、烷芳 基、芳基、雜環芳基或雜環烷芳基取代。 較佳地本發明所製得全氟烷磺酸酯與選自下列化合物 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -9- 1334860 A7 B7 五、發明説明(。) 6 之xWr3反應以形成一鹽 R5 R4 R4 R3 R1
R2 N R3 R1
N R2 R1
R3 (請先閲讀背面之注意事項再填寫本頁) R4、 R1
、R2
R2 、S R1 R3 R2 R3
N 〇r ^R1 N-N R3人久 經濟部智慧財產局員工消費合作社印製 其中R1至R4係相同或不同,選擇性藉由單鍵或雙鍵直 接連接至彼此,及分別獨自或一起爲 -氫, -鹵素,較佳爲氟, -具有1至8碳原子之烷基,其可部分或全部被進一步較 佳爲 F、Cl、N(CnFun + l.〇Hx)2、0(CnF(2n + l- 〇Hx)、 S〇2(CnF(a„ + .-x)Hx) ' 或 CnF……χ)Ηχ (其中 lSn$6 及 OSxS 2n+l)、烷芳基、芳基或雜環芳基所取代, _芳基, -烷芳基, 本纸張尺度適用中國國家標準(CMS ) A4規格{ 210X297公釐) -10- 1334860 A7 B7 五、發明説明(7) -芳族雜環基, -雜環烷芳基。 (請先聞讀背面之注意事項再填寫本頁) 根據本發明製得之包含全氟烷磺酸基團之化合物(即 全氟烷磺酸酯及特別是其鹽)可用於電解質、電化學電池 、一級及二級電池、電容器及/或超或超高電容器,例如 用作溶劑或導電鹽。此處之鹽作爲導電鹽時可爲純的形式 或者其混合物的形式。此處之鹽用作導電鹽時可進一步與 熟悉此項技藝人士所知之鹽一起使用。此外,全氟烷磺酸 酯爲強的烷基化劑及適合用於將有機化合物烷基化,例如 ,用於製備藥劑及稻作保護劑。 經濟部智慧財產局員工消費合作社印製 本發明包含全氟烷磺酸基團之化合物,特別是其鹽, 可用於液態、凝膠狀、聚合體或固態電解質。在此方面, 可使用包含導電鹽及適當聚合物及/或適當溶劑之混合物 。在本發明之目的上,混合物一詞係包括組份之純混合物 、其中所包含之鹽爲聚合物或凝膠之混合物、及其中鹽及 聚合物或凝膠間存在化學及/或物理鍵結之混合物。在凝 膠狀電解質之情況下,除了鹽及聚合物外,混合物較佳包 含適當溶劑。 用於液態或凝膠狀電解質之溶劑特別佳爲非質子性溶 劑或其混合物,其適合用於一級或二級電池、電容器、超 電容器或電化學電池,例如,碳酸酯、酯、醚' 沙佛倫( sulfolane )或腈,例如,碳酸二甲酯、碳酸二乙酯、碳酸丁 二酯'碳酸丙二酯'碳酸乙二酯'碳酸乙酯甲酯'碳酸甲 酯丙酯、1,2-二甲氧基乙烷、1,2-二乙氧基乙烷、乙酸甲酯 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -11 - 1334860 A7 _ ,_B7_ 五、發明説明(。) 〇 (請先聞讀背面之注意事項再填寫本頁) 、γ-丁內酯、乙酸乙酯、丙酸甲酯、丙酸乙酯、丁酸甲酯' 丁酸乙醋、—甲基亞硕、二氧戊環、沙佛倫(sulfolane)、 乙腈' 丙烯腈、四氫呋喃' 2-甲基四氫呋喃或其混合物。 用於聚合體或凝膠狀電解質之聚合物較佳爲丙烯腈、 亞乙烯基二氟 '(甲基)丙烯酸甲酯、四氫呋喃、環氧乙烷、 砂氧院、偶磷氮(phosphazene)之寡聚物或共聚物或者上 述寡聚物及/或共聚物中至少二者之混合物,聚合物可爲 至少部分經交聯者。 上文及之後所述申請案、專利及公開案以及對應申請 案DE 101 63 458.7 ( 2001年12月21日申請)之全部揭示內 容倂入本申請案爲參考資料。 在沒有進一步說明下,認定熟悉此項技藝人士可在其 最大範疇下使用如上說明。因此,較佳具體例及實施例僅 視爲說明所揭示內容,絕非用於限制上。 所有NMR光譜係在Bruker WP 80 SY光譜儀上測量( 80_1 MHz,19F: 75.5 MHz )。 經濟部智慧財產局員工消費合作社印製 實施例1 19.4克(0.129莫耳)三氟甲基磺酸加至備有回流冷凝 器之圓底燒瓶,持續攪拌及使用冰浴冷卻下加入5.8 1克( 0.0646莫耳)碳酸二甲酯。反應混合物在使用油浴(油浴中 之溫度)於90°C下加熱3小時,直到停止放出氣體。冷卻至 室溫後,反應混合物在大氣壓下蒸餾。將12.3克透明無色液 體單離(沸點100_1〇2。(:),此混合物包含96.3%三氟甲基磺 -12- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 1334860 A7 B7 五、發明説明(9) 酸甲酯及3.7 %碳酸二甲酯。三氟甲基磺酸甲酯之產率爲 5 5.8% » (請先閱讀背面之注意事項再填寫本頁) 19F-NMR,ppm (溶劑:CDCh,內部標準:CChF) 74.86 s(CF3) 。'H-NMR,ppm (溶劑:CDCh,內部標準: TMS ) : 4.21 q ; J5h,f = 0.7 Hz。19F 及1Η 數據對應於三氟甲 基 fe 酸甲醋之文獻數據(E n c y c 1 〇 p e n d i a 〇 f R e a g e n t s f 〇 r Organic Synthesis, Editor in Chief Leo A. Paquette, Vol. 5, John Wiley and Sons Ltd., 1995, 36 1 8; J. Org. Chem., Vol. 38,No. 2 1, 1973,3673-3677 )。 實施例2 經濟部智慧財產局員工消費合作社印製 76.36克( 0.509莫耳)三氟甲基磺酸加至備有回流冷凝 器之圓底燒瓶,持續攪拌下於2分鐘期間加入71.60克( 0.5 09莫耳)苯甲醯氯。在此加入期間,溫熱混合物,及觀 察到放出氣體。在不冷卻反應混合物下,加入45.81克( 0.509莫耳)碳酸二甲酯,之後,反應混合物在使用油浴( 油浴中之溫度)於90°C下加熱10小時。冷卻至室溫後,反 應混合物在大氣壓下蒸餾,產生75.05克(89.9%)三氟甲基 磺酸甲酯之透明無色液體(沸點98-99°C)。 及1Η數據對應於示於實施例1中之三氟甲基磺酸甲 酯之文獻數據。 進一步將49.15克( 0.328莫耳)三氟甲基擴酸、46.10克 C 0.328莫耳)苯甲醯氯及29.49克( 0.328莫耳)碳酸二甲酯 加至持續攪拌下之蒸餾殘餘物中。之後,反應混合物在使 本纸張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) -13- 經濟部智慧財產局員工消費合作社印製 1334860 A7 _______B7 五、發明説明() 10 用油浴於90°C下加熱6小時,藉由蒸餾製得52.00克(96.8% )純三氟甲基磺酸甲酯。 三氟甲基磺酸甲酯在二連續反應中之平均產率爲92.6% 〇 在單離三氟甲基磺酸甲酯後,於減壓下蒸餾留下之反 應混合物(沸點範圍:89-91°C在2.7 kPa ),製得94.92克( 83.4%)苯甲酸甲酯。 'H-NMR,ppm (溶劑:CD3CN,內部標準:TMS ) : 3.86 s ( CHO - 7.52 m ( 3H) ,8.00 m ( 2H)。 蒸餾液體後所留下之蒸餾殘餘物爲苯甲酸,其可自乙 醇/水中結晶(熔點121-122°C)。 實施例3 29.77克(0.1 60莫耳)對硝基苯甲醯氯、15.00克( 0.167莫耳)碳酸二甲酯及24_07克(0.160莫耳)三氟甲基磺 酸於備有回流冷凝器之圓底燒瓶中混合,及在持續攪拌下 在油浴(油浴中之溫度)於約75°C下加熱2小時。冷卻至室 溫後,在大氣壓下將三氟甲基磺酸甲酯蒸餾出,產生18.57 克(產率:70.6%)透明無色液體(沸點98-99。〇 。 留下之固體蒸餾殘餘物主要係由對硝基苯甲酸甲酯組 成,其自甲醇結晶後,所製得爲淡黃色產物(25.0克,產率 :86.0%,熔點:93-94°C)。 實施例4 本纸張纽適用中關家標準(CNS ) A4胁(21QX297公釐)" ~ -14 - -----------Ίΐτ----:--- (請先閲讀背面之注意事項再填寫本頁) 1334860 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明(w) 11 20.84克(0.139莫耳)三氟甲基磺酸加至備有回流冷凝 器之圓底燒瓶,持續攪拌及使用冰浴冷卻下加入24.69克( 0.139莫耳)2,6-二氟苯甲醯氯及12.50克(0.139莫耳)碳酸 二甲酯。以油浴替代冰浴,反應混合物在80-11(TC下加熱4 小時(油浴中之溫度)並持續攪拌。在約70°C下開始放出 氣體。反應完全後,反應物冷卻至室溫,在大氣壓下將三 氟甲基擴酸甲酯蒸餾出,產生20.63克(產率:90.6%)透明 無色液體(沸點範圍98-99°C) » 在減壓下(沸點:90°C在2.0 kPa )蒸餾留下之反應混 合物,產生21.50克(產率:89.4%)純2,6-二氟苯甲酸甲酯 〇 19F-NMR,ppm (溶劑:CD3CN,內部標準:CC13F ) 1 1 1.50 t ( 2F ) ,JH,F = 7_0 Hz。 'H-NMR,ppm (溶劑:CD^CN,內部標準:TMS) : 3.92 s ( CH3 ) ,7.04 m ( 2H) ,7.53 m ( 1H)。 實施例5 16.08克(0.107莫耳)三氟甲基磺酸加至備有回流冷凝 器之圓底燒瓶,持續攪拌及使用冰浴冷卻下加入24.72克( 0.107莫耳)五氟苯甲醯氯及9.65克(0.107莫耳)碳酸二甲 酯。以油浴替代冰浴,反應混合物在80-11 (TC下加熱4小時 (油浴中之溫度)並持續攪拌。在約75°C下開始放出氣體 。反應完全後,反應物冷卻至室溫,在大氣壓下將三氟甲 基擴酸甲酯蒸餾出,產生14.81克(產率:84.2%)透明無色 本纸張认it用巾關家標準(CNS > A现fM 210X297公釐) ' -----T-----Φ-----—.訂----r —— (諳先閲讀背面之注意事項再填寫本頁) 1334860 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明(12) 液體(沸點範圍98-99°C)。 在減壓下(沸點:72°C在2.0 kPa )蒸餾留下之反應混 合物,產生21.45克(產率:79.7% )純五氟苯甲酸甲酯。 19F-NMR, ppm (溶劑:CD3CN,內部標準:CChF ) : · 139.58 dm ( 2F) ,-150.37 tt ( IF) ,-161.89 m ( 2F), J3 F,f = 2 0 _ 0 H z,J4 f , f = 4 · 4 H z。 'H-NMR,ppm (溶劑:CD3CN,內部標準:TMS ) : 3.96 s (' CH3 )。 實施例6 4.23克(0.0187莫耳)苯甲酸酐及2.53克(0.0187莫耳 )碳酸二甲酯加至備有回流冷凝器之圓底燒瓶,持續攪拌 及使用冰浴冷卻下加入2.81克(0.0187莫耳)三氟甲基磺酸 。以油浴替代冰浴,反應混合物在90-1 1 (TC下加熱4小時( 油浴中之溫度),並持續攪拌直到停止放出氣體。反應完 全後,混合物冷卻至室溫,在大氣壓下將三氟甲基磺酸甲 酯蒸餾出 > 產生0.55克(產率:17.9%)透明無色液體(沸 點範圍 99- 1 00°C)。 在減壓下(沸點範圍:88-93°C在2.0 kPa)蒸餾留下之 反應混合物,產生3.96克(產率:77.8% )實際上純的苯甲 酸甲酯。 'H-NMR,ppm (溶劑:CDiCN,內部標準:TMS) : 3.86 s ( CH3) > 7.52 m ( 3H ) ,8.00 m ( 2H )。 本纸張尺度適用中國國家標準(CNS ) A4規格< 210X297公釐) φ-----.1 訂;---l·I—蟬 (請先閲讀背面之注意事項再填寫本頁) -16- 1334860 A7 ___B7_ 五、發明説明() 13 實施例7 (請先閲讀背面之注意事項再填寫本頁) 10.73克( 0.0578莫耳)對硝基苯甲醯氯及6.84克( 0.0579莫耳)碳酸二乙酯加至備有回流冷凝器之圓底燒瓶, 持續攪拌及使用冰浴冷卻下加入8.68克( 0.0579莫耳)三氟 甲基磺酸。以油浴替代冰浴,反應混合物在100-1 l〇°C下加 熱5小時(油浴中之溫度),並持續攪拌直到停止放出氣體 。反應完全後,混合物冷卻至室溫,在大氣壓下將三氟甲 基磺酸乙酯蒸餾出,產生3_ 28克(產率:31.8%)透明無色 液體(沸點範圍114-116^)。 19F-NMR, ppm (溶劑:CDCh,內部標準:CChF) : -75.68 s ( CF3 )。 'H-NMR,ppm (溶劑:CDCh,內部標準:TMS ) : 1.51 t ( CH3 ) ,4.62 q ( CH〇 ,J3h,h = 7.0 Hz。 及1H-NMR數據對應於三氟甲基磺酸乙酯之文獻數 據(Eur. Polym. J_,Vol. 16, No. 9, 1 980, 861 -865 )。 實施例8 經濟部智慧財產局員工消費合作社印製 13.67克(0.0911莫耳)三氟甲基磺酸在-30°C下加至備 有回流冷凝器之圓底燒瓶,持續攪拌下於2分鐘期間加入 12.80克(0.0911莫耳)苯甲醯氯,混合物並緩慢地加以溫 熱。然後在不冷卻混合物下加入10.77克(0.09 12莫耳)碳 酸二乙酯。反應混合物在7 0-90°C下加熱4.5小時(油浴中之 溫度),並持續攪拌。在油浴溫度約70°C下停止放出氣體 。反應完全後,混合物冷卻至室溫,在大氣壓下將三氟甲 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -17 - 1334860 A7 B7 五、發明説明() 14 基磺酸乙酯蒸餾出,產生13.10克(產率:80.8% )透明無色 液體(沸點115°C) » (請先聞讀背面之注意事項再填寫本頁) ”F及沱-NMR數據對應於三氟甲基磺酸乙酯之文獻數 據(見實施例7 )。 在減壓下(沸點:l〇〇°C在2.0 kPa)蒸餾留下之反應混 合物,製得9.91克(產率:72.5%)純苯甲酸乙酯。 'H-NMR, ppm (溶劑:CD]CN ’ 內部標準:TMS ) : 1.35 t ( 3H > CH3) ’ 4.33 Q ( 2H,CHO,7.53 m ( 3H),8.00 m ( 2H ) ,J3H,H = 7_0 Hz。 'H-NMR數據對應於苯甲酸乙酯之文獻數據(The Aldrich Library of NMR Spectra, Edition II, Charles J Pouchert, Volume 2, 281)。 實施例9 經濟部智慧財產局員工消費合作社印製 17.74克(0.1182莫耳)三氟(甲基購酸加至備有回流冷 凝器之圓底燒瓶,持續攪拌下於2分鐘期間加入21.41克( 0.1 177莫耳)三氯乙醯氯,然後,不冷卻混合物下於5分鐘 期間加入10.60克(0.1177莫耳)碳酸二甲酯。緩慢地溫熱 反應混合物及在油浴中於80-1 0〇°C中加熱7小時(油浴中之 溫度)’並持續攪拌直到停止放出氣體。冷卻至室溫後, 混合物在大氣壓下蒸餾,產生17.48克(產率:90.5% )透明 無色液體之三氟甲基磺酸甲酯(沸點範圍98-10CTC)。 19F及1Η-NMR數據對應於文獻數據及前述實施例所述 者。 本纸張尺度適用中國國家標準(CNS ) A4規格{ 210X297公董) 1334860 A7 B7 五、發明説明() 15 進一步蒸餾留下之反應混合物(沸點範圍:1 52- 1 53°C ),製得15.16克(產率:72.6%)三氯乙酸甲酯。 (請先聞讀背面之注意事項再填寫本頁) 'H-NMR,ppm (溶劑:CD]CN,內部標準:TMS) : 3.98 s ( CH3 )。 實施例1 〇 將於50毫升乾己烷中之6.31克( 0.0768莫耳)甲基咪 唑加至備有回流冷凝器之圓底燒瓶,持續攪拌及以冰浴冷 卻下於20分鐘期間加入13.75克(0_0772莫耳)三氟甲基磺 酸乙酯。10分鐘後,然後移除冰浴,反應混合物回流1小時 (油浴溫度70-7 5 °C )。經由蒸餾移除己烷後,留下之反應 混合物維持在80-90°C及30-100 Pa真空下5小時,產生19.80 克(產率:99.1% )三氟甲基磺酸1-甲基-3-乙基咪唑之透明 無色液體。 "F-NMR,ppm (溶劑:CD3CN,內部標準:CChF) : -7 8.05 s ( CF3S〇r )。 經濟部智慧財產局員工消費合作社印製 'H-NMR, ppm (溶劑:CD^CN,內部標準:TMS) : 1.48 t ( CH3 ) > 3.89 s ( CHj ) ,4.23 q ( CH2 ) - 7.47 dd ( 1H ), 7.54 dd ( 1H) > 8.74 br.s. ( 1H ) ,J3H,H = 7.3 Hz,JH,H 二 1.8 Hz。 實施例1 1 於800毫升乾己烷中之141.13克( 1.657莫耳)1-甲基吡 啶加至備有回流冷凝器之圓底燒瓶,持續攪拌及以冰浴冷 本纸張尺度適用中國國家標準(CNS ) A4規格{ 210X297公釐) -19 - 1334860 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明() 16 卻下於45分鐘期間加入272克( 1.657莫耳)三氣甲基橫酸甲 酯。然後以油浴替代冰浴,反應混合物回流丨5分鐘(油浴 溫度70-7 5°C )。冷卻至室溫後’將白色沉澱物過濾出,用 100笔升己院清洗兩次,及在ll〇°C及30-100 pa真空下乾燥3 小時,產生409克(產率:99.1%)三氟甲基磺酸ι,ι_二甲基 α比U定。 19F-NMR,ppm (溶劑:CD3CN ’ 內部標準:CC13F ) :-78.00 s ( CF3SO3·)。 'H-NMR,ppm (溶劑:CD3CN,內部標準:TMS) : 2.17 m ( 4H ) > 3.07 s ( CHj ),3.45 m ( 4H )。 實施例1 2 於70毫升乾己烷中之5.77克( 0.0505莫耳)ι,4-二甲基 呢嗪加至備有回流冷凝器之圓底燒瓶,持續擾拌及以冰浴 冷卻下於20分鐘期間加入16.56克( 0.1009莫耳)三氟 磺酸甲酯。然後以油浴替代冰浴,反應混合物回流15分鐘 (油浴溫度70-75°C )。冷卻至室溫後,將白色沉激物過據 出,用10毫升己烷清洗兩次,及在80°C及30-1〇〇 Pa真空下 乾燥3小時,產生20.68克(產率:92.7%)二(三赢甲基擴酸 )1,1,4,4-四甲基嘁嗪。 19F-NMR,ppm (溶劑:(CD〇2S〇2,內部標準:CC13F ):-77.40 s ( CF3SO3' ) ° ’H-NMR,ppm (溶劑:(CD〇2S〇2,內部標準:TMS) : 3.30 s (4CH3 ) ,3.82 s ( 4CHO 。 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 4-----Ί訂 il·——癱 (請先閲讀背面之注意事項再填寫本頁) -20- 1334860 A7 B7 五、發明説明(_) 17 所有19F及1H-NMR光譜係以Bruker WP 80 SY光譜儀紀 錄之(4爲80.11\4112,1汴爲75.4141^)。 經濟部智慧財產局員工消費合作社印製 -----------Φ-----Ίΐτ^----^丨丨· (請先閲讀背面之注意事項再填寫本頁) 本纸張尺度適用中國國家標準(CNS ) Α4規格(210X29*7公釐) -21 -
Claims (1)
- ABCD 1334860 、申請專利森属-t· 附件 3A : & .., (請先H-t»背面之注意事項再填寫本頁) 第9 1 1 3628 1號專利申請案 中文申請專利範圍替換本 民國99年9月15日修正 1. 一種製備含有全氟烷磺酸基團之化合物的方法,其特 徵在於全氟烷磺酸與碳酸二烷酯直接反應,其中可存在消 耗水或消耗醇之試劑,而產生全氟烷磺酸烷酯或者產生全 氟烷磺酸烷酯及羧酸酯,其中該消耗水或消耗醇之試劑若 存在則爲有機基團對於全氟烷磺酸係安定之羧酸衍生物且 係選自羧酸幽化物、羧酸酐及混合之羧酸/磺酸酐,而此 方法係在室溫與150°C間之溫度下進行。 2. 如申請專利範圍第1項之方法,其中全氟烷磺酸係與 碳酸二烷酯在消耗水或消耗醇之試劑存在下直接反應,而 產生全氟烷磺酸烷酯或者產生全氟烷磺酸烷酯及羧酸酯。 3. 如申請專利範圍第1項之方法,其中碳酸二烷酯係選 自碳酸二甲酯、碳酸二乙酯、碳酸二丙酯、碳酸二丁酯、 碳酸甲酯乙酯及這些碳酸二烷酯之混合物。 經濟部智慧財產局員工消費合作社印製 4. 如申請專利範圍第1項之方法,其中該羧酸鹵化物係 選自苯甲醯氯、對-硝基苯甲醯氯、2,6-二氟苯甲醯氯、五 氟苯甲醯氯、2-氯苯甲醯氯、3-氯苯甲醯氯、4·氯苯甲醯氯 、2-溴苯甲醯氯、3-溴苯甲醯氯、4-溴苯甲醯氯、2,3_二氯 苯甲醯氯、2,4-二氯苯甲醯氯、2,6·二氯苯甲醯氯、3,4·二 氯苯甲醯氯、3,5-二氯苯甲醯氯及三氯乙醯氯。 5. 如申請專利範圍第1項之方法,其中該羧酸酐係選自 本纸張尺度逍用中國國家標準(CNS ) A4規格(210X297公釐) 經濟部智慧財產局員工消費合作社印製 1334860 、· A8 B8 C8 D8 六、申請專利範圍2 苯甲酸酐、2,2’-二氯苯甲酸酐、3,3、二氯苯甲酸酐、4,4’_二 氯苯甲酸酐、2,2’,3,3、四氯苯甲酸酐、2,2’,4,4’-四氯苯甲酸 酐、2,2’,6,6’-四氯苯甲酸酐、3,3’,4,4、四氯苯甲酸酐、 3,3’,5,5’-四氯苯甲酸酐、2-溴苯甲酸酐、3-溴苯甲酸酐、4-溴苯甲酸酐及2,2’,6,6’-四氟苯甲酸酐。 6. 如申請專利範圍第1項之方法,其係在50°C及110°C 間之溫度下進行。 7. 如申請專利範圍第丨項之方法,其中反應時間在1及1〇 小時之間。 8. 如申請專利範圍第7項之方法,其中反應時間在2及5 小時之間8 9· 一種製備包含全氟烷磺酸基團之化合物的方法,其包 括申請專利範圍第丨至8項中任一項之方法,然後使所製備 之全氟烷磺酸烷酯與下式化合物反應 XR'R'R3 其中 X爲P或N, R、R2及R3爲相同或不同,選擇性藉由單鍵或雙鍵直接連 接彼此,且分別或一起爲 -氫, -具有1至16碳原子之烷基,其可部分或全部被F、Cl、 N ( C n F ( 2 η + 1 - X ) Η X ) 2 ' Ο ( C η F ( 2 η + 1 χ ) Η * ) ' S Ο 2 ( C η F ( 2 η + 1 - χ ) Η χ ) 或 CnF(2….χ)Ηχ 所取代,其中 ΐ$η$6 且 0$χ$2η+1, -具有1至16碳原子之伸烷基的烷芳基,其可部分被F、 本紙張尺度適用中國國家揉準(CNS ) A4政格(210X 297公釐) ---------^----^--ΐτ------^ (請先閲讀背面之注意事項再填寫本頁) -2 - I334860 A8 B8 C8 ______ D8 六、申請專利範圍3 Cl ' Br、N〇2、CN、烷基、芳基或雜環芳基所取代, -芳基’其可部分被F、Cl、Br、N〇2、CN、烷基、芳基 或雜環芳基所取代,或者 -芳族雜環基’其可部分被F、Cl、Br、N〇2、CN、烷基 、芳基或雜環芳基所取代, 其中烷基中之一、二或三個CH2基團可被相同或不同雜原子 替代’雜原子可爲0、NH或具有1至6碳原子之N(烷基), 且其中所有三個R基團不可同時爲全氟化的或全氯化的。 ^----— (請先閲脅背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 本紙張尺度逋用中國國家摞準(CNS ) A4規格(210X297公釐) -3-
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