TWI310702B - Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons - Google Patents

Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons Download PDF

Info

Publication number
TWI310702B
TWI310702B TW094109052A TW94109052A TWI310702B TW I310702 B TWI310702 B TW I310702B TW 094109052 A TW094109052 A TW 094109052A TW 94109052 A TW94109052 A TW 94109052A TW I310702 B TWI310702 B TW I310702B
Authority
TW
Taiwan
Prior art keywords
metal
zeolite
catalyst composition
composition
catalyst
Prior art date
Application number
TW094109052A
Other languages
English (en)
Chinese (zh)
Other versions
TW200538201A (en
Inventor
Ranjit Kumar
Original Assignee
Grace W R & Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Grace W R & Co filed Critical Grace W R & Co
Publication of TW200538201A publication Critical patent/TW200538201A/zh
Application granted granted Critical
Publication of TWI310702B publication Critical patent/TWI310702B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/83—Aluminophosphates [APO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1804—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
TW094109052A 2004-04-02 2005-03-24 Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons TWI310702B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/817,069 US20050227853A1 (en) 2004-04-02 2004-04-02 Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons

Publications (2)

Publication Number Publication Date
TW200538201A TW200538201A (en) 2005-12-01
TWI310702B true TWI310702B (en) 2009-06-11

Family

ID=34964277

Family Applications (1)

Application Number Title Priority Date Filing Date
TW094109052A TWI310702B (en) 2004-04-02 2005-03-24 Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons

Country Status (19)

Country Link
US (2) US20050227853A1 (enExample)
EP (1) EP1735408B1 (enExample)
JP (1) JP5039540B2 (enExample)
KR (1) KR101300423B1 (enExample)
CN (1) CN1957070A (enExample)
AR (1) AR050492A1 (enExample)
AU (1) AU2005230817B2 (enExample)
BR (1) BRPI0509537B1 (enExample)
CA (1) CA2561971C (enExample)
IL (1) IL178403A (enExample)
IN (1) IN2006DE05724A (enExample)
MX (1) MXPA06011221A (enExample)
NO (1) NO20065019L (enExample)
PE (1) PE20060204A1 (enExample)
RU (1) RU2382811C2 (enExample)
SG (1) SG152221A1 (enExample)
TW (1) TWI310702B (enExample)
WO (1) WO2005097950A1 (enExample)
ZA (1) ZA200608802B (enExample)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006069535A1 (en) * 2004-12-28 2006-07-06 China Petroleum & Chemical Corporation A catalyst and a hydrocarbon oil cracking method
CN100425534C (zh) * 2005-05-31 2008-10-15 中国石油化工股份有限公司 一种改性β沸石
ES2730002T3 (es) * 2005-06-29 2019-11-07 Grace W R & Co Catalizador de pentasil para olefinas ligeras en unidades catalíticas fluidizadas
CN101454080A (zh) * 2005-11-08 2009-06-10 雅宝荷兰有限责任公司 制备含铝磷酸盐的催化剂组合物的方法
JP4685668B2 (ja) * 2006-03-14 2011-05-18 日揮触媒化成株式会社 炭化水素流動接触分解用触媒組成物およびその製造方法
BRPI0602678B1 (pt) * 2006-07-14 2015-09-01 Petroleo Brasileiro Sa Aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalítico fluido em baixa severidade e processo de preparo do mesmo
CN101134913B (zh) * 2006-08-31 2011-05-18 中国石油化工股份有限公司 一种烃类催化转化方法
JP5478253B2 (ja) * 2007-09-18 2014-04-23 旭化成ケミカルズ株式会社 プロピレンの製造方法
JP5355910B2 (ja) * 2008-03-13 2013-11-27 旭化成ケミカルズ株式会社 シリカ成形体
TW200918486A (en) * 2007-09-18 2009-05-01 Asahi Kasei Chemicals Corp Process for production of propylene
BRPI0705179B1 (pt) 2007-10-10 2016-10-11 Petróleo Brasileiro S A Petrobras aditivo para maximizar olefinas leves em fcc e processo para preparação do mesmo
KR100979580B1 (ko) * 2008-02-05 2010-09-01 에스케이에너지 주식회사 경질올레핀 생산용 탄화수소 접촉 분해 촉매 및 그제조방법
CN102215958A (zh) * 2008-09-15 2011-10-12 环球油品马来西亚有限公司 提高丙烯收率并降低苯石脑油馏分的催化裂化
US8912109B2 (en) * 2008-12-29 2014-12-16 Fina Technology, Inc. Catalyst with an ion-modified binder
WO2010084930A1 (ja) * 2009-01-22 2010-07-29 三菱化学株式会社 窒素酸化物浄化用触媒及びその製造方法
CN102531821B (zh) * 2010-12-28 2015-03-25 中国科学院大连化学物理研究所 采用改性zsm-5分子筛催化剂催化甲醇耦合石脑油催化裂解反应的方法
CN103402635A (zh) * 2011-03-08 2013-11-20 三菱树脂株式会社 催化剂、氮氧化物净化用元件、和氮氧化物净化用系统
CN103813856B (zh) * 2011-07-21 2016-08-10 瑞来斯实业有限公司 流化床催化裂化（fcc）催化剂添加剂及其制备方法
WO2014042641A1 (en) * 2012-09-13 2014-03-20 Basf Corporation Novel catalyst to increase propylene yields from a fluid catalytic cracking unit
US20130131412A1 (en) * 2011-11-18 2013-05-23 Uop Llc Resid catalytic cracker and catalyst for increased propylene yield
CN104822454B (zh) * 2012-11-30 2017-07-04 环球油品公司 金属磷酸盐分子筛、制备和使用方法
KR101800558B1 (ko) * 2013-06-07 2017-11-22 고쿠리츠다이가쿠호진 토쿄고교 다이가꾸 금속 함유 제올라이트 촉매를 사용한 불포화 탄화 수소류의 제조 방법
CN105013526B (zh) * 2014-04-24 2017-11-03 中国石油化工股份有限公司 一种提高低碳烯烃浓度的催化裂化助剂及其制备方法
CN104998677B (zh) * 2014-04-24 2017-11-03 中国石油化工股份有限公司 一种提高低碳烯烃浓度的催化裂化助剂及其制备方法
JP6633268B2 (ja) * 2014-09-03 2020-01-22 グローリー株式会社 センサモジュール及び紙葉類処理装置
US20170332236A1 (en) * 2014-11-29 2017-11-16 Huawei Technologies Co., Ltd. Identity authentication method and wearable device
WO2017015597A1 (en) 2015-07-23 2017-01-26 Albemarle Corporation Fcc catalyst additive and binder
FR3044903B1 (fr) 2015-12-14 2019-05-31 L'oreal Procede de traitement cosmetique des fibres keratiniques mettant en oeuvre deux alcoxysilanes particuliers et une etape de chauffage.
CN107971025B (zh) * 2016-10-21 2020-12-29 中国石油化工股份有限公司 甲醇制烯烃催化剂及其制备方法
RU2688662C1 (ru) * 2018-07-24 2019-05-22 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (Институт катализа СО РАН, ИК СО РАН) Способ каталитического крекинга бутан-бутиленовой фракции и катализатор для его осуществления
CN110980681B (zh) * 2019-11-07 2021-06-01 河北科技大学 一种Na3Mg3(PO4)3/MgO光催化材料、制备方法及用途
BR112022010962A2 (pt) * 2019-12-19 2022-09-06 Albemarle Corp Catalisador com armadilha de vanádio
US11766666B2 (en) * 2020-12-30 2023-09-26 China Investment Corporation Limited Catalyst for converting light olefin to aromatics, method of making and method of using the same
CN116408135A (zh) * 2021-12-29 2023-07-11 中国石油天然气股份有限公司 改性zsm-5分子筛及其制备方法和应用
CN116920920B (zh) * 2022-04-01 2025-11-14 中国石油化工股份有限公司 金属改性磷铝粘结剂、提高汽油芳烃浓度的助剂及其制备方法以及催化剂和应用
CN117658169B (zh) * 2022-08-17 2026-04-14 中国石油化工股份有限公司 一种含铁小晶粒zsm-5分子筛及其制备方法和应用
KR20260100361A (ko) * 2023-10-27 2026-06-29 더블유.알. 그레이스 앤드 캄파니-콘. 바이오-재생가능 공급물의 유동 접촉 분해를 위한 공정

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6503410A (enExample) * 1963-02-21 1965-09-20
US3354096A (en) * 1965-04-06 1967-11-21 Union Oil Co Pelleted zeolite compositions possessing improved crushing strength
US3293192A (en) * 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
US3649523A (en) * 1969-04-10 1972-03-14 Standard Oil Co Hydrocracking process and catalyst
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US4178267A (en) * 1976-03-29 1979-12-11 Phillips Petroleum Company Passivating metals on cracking catalysts
US4288647A (en) * 1980-03-10 1981-09-08 Mobil Oil Corporation Shape selective reactions with alkaline earth-modified zeolite catalysts
SU1148847A1 (ru) * 1981-04-20 1985-04-07 Институт неорганической и физической химии АН АзССР Способ получени низкомолекул рных олефинов
US4454241A (en) * 1982-05-24 1984-06-12 Exxon Research And Engineering Co. Phosphorus-containing catalyst
US4498975A (en) * 1982-05-24 1985-02-12 Exxon Research & Engineering Co. Phosphorus-containing catalyst and catalytic cracking process utilizing the same
US4465780A (en) * 1982-10-14 1984-08-14 Exxon Research & Engineering Co. Phosphorus-containing catalyst
US4504382A (en) * 1982-10-14 1985-03-12 Exxon Research And Engineering Co. Phosphorus-containing catalyst and catalytic cracking process utilizing the same
EP0111748B1 (de) * 1982-11-16 1987-03-25 Hoechst Aktiengesellschaft Aluminiumsilikate mit Zeolithstruktur und Verfahren zu ihrer Herstellung
US4605637A (en) * 1983-02-14 1986-08-12 Mobil Oil Corporation Hydrothermal activation of acid zeolites with aluminum phosphates
JPS6115848A (ja) * 1984-06-30 1986-01-23 Agency Of Ind Science & Technol リン酸カルシウム変性ゼオライト型触媒による低級オレフインの製造方法
EP0176150B2 (en) * 1984-09-25 1994-02-02 Catalysts & Chemicals Industries Co., Ltd. Catalytic cracking, process for heavy oil
US4567152A (en) * 1984-12-13 1986-01-28 Exxon Research And Engineering Co. Co-matrixed zeolite and p/alumina
US4584091A (en) * 1984-12-13 1986-04-22 Exxon Research And Engineering Co. Cracking with co-matrixed zeolite and p/alumina
US4724066A (en) * 1985-01-22 1988-02-09 Mobil Oil Corporation Composites of microporous aluminum phosphates and zeolites and conversions over these catalysts
US4629717A (en) * 1985-06-11 1986-12-16 Uop Inc. Phosphorus-modified alumina composite, method of manufacture and use thereof
US4839319A (en) * 1986-07-11 1989-06-13 Exxon Research And Engineering Company Hydrocarbon cracking catalysts and processes for utilizing the same
US4873211A (en) * 1987-07-02 1989-10-10 Phillips Petroleum Company Cracking catalyst and process
US4765884A (en) * 1987-07-02 1988-08-23 Phillips Petroleum Company Cracking catalyst and process
US5194412A (en) * 1991-01-22 1993-03-16 W. R. Grace & Co.-Conn. Catalytic compositions
US5110776A (en) * 1991-03-12 1992-05-05 Mobil Oil Corp. Cracking catalysts containing phosphate treated zeolites, and method of preparing the same
US5302567A (en) * 1991-11-04 1994-04-12 W. R. Grace & Co.-Conn. Zeolite octane additive
US5262371A (en) * 1992-05-06 1993-11-16 Arco Chemical Technology, L.P. Alkylene oxide isomerization process and catalyst
JPH06170233A (ja) * 1992-12-03 1994-06-21 Catalysts & Chem Ind Co Ltd 炭化水素流動接触分解用触媒組成物
CN1034223C (zh) * 1993-03-29 1997-03-12 中国石油化工总公司 制取低碳烯烃的裂解催化剂
US5371312A (en) * 1993-04-05 1994-12-06 Mobil Oil Corp. Shape selective hydrocarbon conversions over modified catalyst
CN1034586C (zh) * 1993-11-05 1997-04-16 中国石油化工总公司 多产低碳烯烃的催化转化方法
US5521133A (en) * 1994-11-29 1996-05-28 Engelhard Corporation Phosphorus bound porous microspheres
US5898089A (en) * 1997-07-09 1999-04-27 Phillips Petroleum Company Hydrocarbon aromatization process using a zeolite
DE69819989T3 (de) * 1997-09-17 2012-10-04 China Petrochemical Corp. Zusammensetzung, die Molekularsiebe vom Pentasil-Typ enthõlt, sowie ihre Herstellung und Verwendung
CO4890864A1 (es) * 1997-10-02 2000-02-28 Colombiana De Petroleos Ecopet Trampas de vanadio para catalizadores de ruptura catalitica
JP3927704B2 (ja) * 1997-10-15 2007-06-13 中国石油化工集団公司 軽質オレフィンの生産のための接触式熱分解プロセスのための触媒およびその調製
US6040257A (en) * 1997-11-07 2000-03-21 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
US6074975A (en) * 1998-03-03 2000-06-13 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
US6080303A (en) * 1998-03-11 2000-06-27 Exxon Chemical Patents, Inc. Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus
US6797155B1 (en) * 1999-12-21 2004-09-28 Exxonmobil Research & Engineering Co. Catalytic cracking process using a modified mesoporous aluminophosphate material

Also Published As

Publication number Publication date
RU2006138615A (ru) 2008-05-10
WO2005097950A1 (en) 2005-10-20
AU2005230817A1 (en) 2005-10-20
RU2382811C2 (ru) 2010-02-27
IL178403A0 (en) 2007-02-11
AR050492A1 (es) 2006-11-01
CN1957070A (zh) 2007-05-02
JP2007531620A (ja) 2007-11-08
KR20070004856A (ko) 2007-01-09
KR101300423B1 (ko) 2013-08-26
PE20060204A1 (es) 2006-03-15
IN2006DE05724A (enExample) 2007-07-13
BRPI0509537A (pt) 2007-09-18
US20060011513A1 (en) 2006-01-19
EP1735408B1 (en) 2021-10-06
JP5039540B2 (ja) 2012-10-03
US20050227853A1 (en) 2005-10-13
EP1735408A1 (en) 2006-12-27
SG152221A1 (en) 2009-05-29
CA2561971C (en) 2015-03-24
AU2005230817B2 (en) 2011-06-02
TW200538201A (en) 2005-12-01
ZA200608802B (en) 2007-11-28
BRPI0509537B1 (pt) 2015-07-21
IL178403A (en) 2011-03-31
CA2561971A1 (en) 2005-10-20
NO20065019L (no) 2007-01-02
MXPA06011221A (es) 2007-01-16

Similar Documents

Publication Publication Date Title
JP5039540B2 (ja) 金属燐酸塩結合されたゼオライトを含んでなる触媒組成物および炭化水素類を接触分解するためのその使用方法
TWI379711B (en) Catalyst for light olefins and lpg in fluidized catalytic cracking units
CN101134913B (zh) 一种烃类催化转化方法
RU2408655C2 (ru) Композиции и способы, предназначенные для уменьшения выбросов nox в ходе каталитического крекинга с псевдоожиженным катализатором
CN102812109B (zh) 高轻质烯烃fcc催化剂组合物
TWI650176B (zh) 含氧化硼及磷之ｆｃｃ觸媒組合物
US20100010279A1 (en) Catalyst Compositions Comprising Metal Phosphate Bound Zeolite and Methods of Using Same to Catalytically Crack Hydrocarbons
TW201138954A (en) Process for making improved zeolite catalysts from peptized aluminas
TWI668303B (zh) 在ｆｃｃ方法中之氧化硼
CN111437872A (zh) 通过改进的沸石和磷相互作用来增强zsm-5添加剂活性
CN102553633B (zh) 在流化催化装置中用于轻质烯烃的五元环高硅沸石催化剂
EP4200070A1 (en) Fluid catalytic cracking catalyst composition for enhanced butylenes yields with metal passivation functionality
JP7064484B2 (ja) 流動触媒のためにアルミナを解膠するプロセス
TWI382875B (zh) 減低流體觸媒裂解期間ＮＯｘ排放之組成物及方法
TWI444463B (zh) 用於減低流體觸媒裂解之ＮＯｘ排放之組成物及方法
CN101503632B (zh) 流化裂化催化剂及降低流化裂化期间NOx排放量的方法
JP2023510107A (ja) バナジウムトラップのある触媒
JP6307074B2 (ja) マグネシウム安定化超低ソーダ分解触媒
TWI396589B (zh) 用於減低流體觸媒裂解期間之ＮＯｘ排放之組成物及方法
TWI395614B (zh) 用於減低流體觸媒裂解期間之ＮＯｘ排放之鎂鹼沸石
HK1051052B (en) Enhancememt method in reducing gasoline sulfur in fluid catalytic cracking
HK1051052A1 (en) Enhancememt method in reducing gasoline sulfur in fluid catalytic cracking

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees