TWI307121B - Method and compositions for hardening photoresist in etching processes - Google Patents
Method and compositions for hardening photoresist in etching processes Download PDFInfo
- Publication number
- TWI307121B TWI307121B TW092121695A TW92121695A TWI307121B TW I307121 B TWI307121 B TW I307121B TW 092121695 A TW092121695 A TW 092121695A TW 92121695 A TW92121695 A TW 92121695A TW I307121 B TWI307121 B TW I307121B
- Authority
- TW
- Taiwan
- Prior art keywords
- plasma
- photoresist
- photoresist material
- wafer
- curing
- Prior art date
Links
- 229920002120 photoresistant polymer Polymers 0.000 title claims description 98
- 238000000034 method Methods 0.000 title claims description 48
- 238000005530 etching Methods 0.000 title claims description 47
- 239000000203 mixture Substances 0.000 title claims description 23
- 239000000463 material Substances 0.000 claims description 92
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 29
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 28
- 229910052794 bromium Inorganic materials 0.000 claims description 28
- 239000007789 gas Substances 0.000 claims description 28
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims description 19
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 6
- 238000001020 plasma etching Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 3
- 238000009738 saturating Methods 0.000 claims 1
- 235000012431 wafers Nutrition 0.000 description 46
- 238000012545 processing Methods 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 7
- 229910052770 Uranium Inorganic materials 0.000 description 6
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 238000000635 electron micrograph Methods 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 229910052732 germanium Inorganic materials 0.000 description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 4
- 229920005591 polysilicon Polymers 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical group FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 239000006117 anti-reflective coating Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 1
- CODXQVBTPQLAGA-UHFFFAOYSA-N Hydroxydecanoate Chemical compound CCCCCCCCCC(=O)OO CODXQVBTPQLAGA-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- ISQINHMJILFLAQ-UHFFFAOYSA-N argon hydrofluoride Chemical compound F.[Ar] ISQINHMJILFLAQ-UHFFFAOYSA-N 0.000 description 1
- IVHJCRXBQPGLOV-UHFFFAOYSA-N azanylidynetungsten Chemical compound [W]#N IVHJCRXBQPGLOV-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- -1 cyclic olefin Chemical class 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31144—Etching the insulating layers by chemical or physical means using masks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/0271—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
- H01L21/0273—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/308—Chemical or electrical treatment, e.g. electrolytic etching using masks
- H01L21/3083—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/3086—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3213—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
- H01L21/32139—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Drying Of Semiconductors (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/219,995 US6923920B2 (en) | 2002-08-14 | 2002-08-14 | Method and compositions for hardening photoresist in etching processes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200407998A TW200407998A (en) | 2004-05-16 |
| TWI307121B true TWI307121B (en) | 2009-03-01 |
Family
ID=31886605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW092121695A TWI307121B (en) | 2002-08-14 | 2003-08-07 | Method and compositions for hardening photoresist in etching processes |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6923920B2 (enExample) |
| EP (1) | EP1529308A1 (enExample) |
| JP (1) | JP2005535936A (enExample) |
| KR (1) | KR100990064B1 (enExample) |
| CN (1) | CN100423191C (enExample) |
| AU (1) | AU2003257999A1 (enExample) |
| TW (1) | TWI307121B (enExample) |
| WO (1) | WO2004017390A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6962878B2 (en) * | 2003-04-17 | 2005-11-08 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method to reduce photoresist mask line dimensions |
| US7005386B1 (en) * | 2003-09-05 | 2006-02-28 | Advanced Micro Devices, Inc. | Method for reducing resist height erosion in a gate etch process |
| JP2005109068A (ja) * | 2003-09-30 | 2005-04-21 | Sanyo Electric Co Ltd | 半導体装置およびその製造方法 |
| US20050147926A1 (en) * | 2004-01-02 | 2005-07-07 | Nanya Technology Corporation | Method for processing photoresist |
| US20060154184A1 (en) * | 2005-01-12 | 2006-07-13 | International Business Machines Corporation | Method for reducing feature line edge roughness |
| KR100674967B1 (ko) * | 2005-04-06 | 2007-01-26 | 삼성전자주식회사 | 더블 패터닝 방식을 이용한 미세 피치를 갖는 포토레지스트패턴 형성방법 |
| US7390753B2 (en) * | 2005-11-14 | 2008-06-24 | Taiwan Semiconductor Mfg. Co., Ltd. | In-situ plasma treatment of advanced resists in fine pattern definition |
| JP5362176B2 (ja) * | 2006-06-12 | 2013-12-11 | ルネサスエレクトロニクス株式会社 | 半導体装置の製造方法 |
| US8298958B2 (en) * | 2008-07-17 | 2012-10-30 | Lam Research Corporation | Organic line width roughness with H2 plasma treatment |
| JP5128421B2 (ja) | 2008-09-04 | 2013-01-23 | 東京エレクトロン株式会社 | プラズマ処理方法およびレジストパターンの改質方法 |
| JP5544914B2 (ja) * | 2010-02-15 | 2014-07-09 | 大日本印刷株式会社 | 反射型マスクの製造方法 |
| KR101348655B1 (ko) * | 2010-03-24 | 2014-01-08 | 한국전자통신연구원 | 미세유체 제어 장치 및 그 제조 방법 |
| JP5142236B1 (ja) * | 2011-11-15 | 2013-02-13 | エルシード株式会社 | エッチング方法 |
| US9105587B2 (en) * | 2012-11-08 | 2015-08-11 | Micron Technology, Inc. | Methods of forming semiconductor structures with sulfur dioxide etch chemistries |
| JP6017928B2 (ja) * | 2012-11-09 | 2016-11-02 | 東京エレクトロン株式会社 | プラズマエッチング方法及びプラズマエッチング装置 |
| CN103021925A (zh) * | 2012-12-21 | 2013-04-03 | 上海宏力半导体制造有限公司 | Sti的制作工艺、沟槽的刻蚀方法和光刻胶的处理方法 |
| CN106662816B (zh) * | 2014-07-08 | 2020-10-23 | 东京毅力科创株式会社 | 负性显影剂相容性的光致抗蚀剂组合物及使用方法 |
| JP6736314B2 (ja) * | 2015-06-30 | 2020-08-05 | エイブリック株式会社 | 半導体装置の製造方法 |
| CN107564803B (zh) * | 2017-08-31 | 2020-04-17 | 京东方科技集团股份有限公司 | 刻蚀方法、工艺设备、薄膜晶体管器件及其制造方法 |
| KR102841479B1 (ko) | 2021-05-10 | 2025-07-31 | 삼성전자주식회사 | 반도체 장치의 제조 방법 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5749389A (en) * | 1993-12-22 | 1998-05-12 | Liquid Air Corporation | Purgeable connection for gas supply cabinet |
| US5976769A (en) * | 1995-07-14 | 1999-11-02 | Texas Instruments Incorporated | Intermediate layer lithography |
| JPH09270420A (ja) | 1996-03-29 | 1997-10-14 | Nippon Steel Corp | 半導体装置の製造方法 |
| US5843835A (en) * | 1996-04-01 | 1998-12-01 | Winbond Electronics Corporation | Damage free gate dielectric process during gate electrode plasma etching |
| JP3484317B2 (ja) * | 1997-03-19 | 2004-01-06 | 沖電気工業株式会社 | 半導体装置の製造方法 |
| US6103632A (en) * | 1997-10-22 | 2000-08-15 | Applied Material Inc. | In situ Etching of inorganic dielectric anti-reflective coating from a substrate |
| US6121154A (en) * | 1997-12-23 | 2000-09-19 | Lam Research Corporation | Techniques for etching with a photoresist mask |
| US6121155A (en) * | 1998-12-04 | 2000-09-19 | Advanced Micro Devices | Integrated circuit fabrication critical dimension control using self-limiting resist etch |
| US6299788B1 (en) * | 1999-03-29 | 2001-10-09 | Mosel Vitelic Inc. | Silicon etching process |
| US6335292B1 (en) * | 1999-04-15 | 2002-01-01 | Micron Technology, Inc. | Method of controlling striations and CD loss in contact oxide etch |
| KR100447263B1 (ko) * | 1999-12-30 | 2004-09-07 | 주식회사 하이닉스반도체 | 식각 폴리머를 이용한 반도체 소자의 제조방법 |
| JP2001237218A (ja) | 2000-02-21 | 2001-08-31 | Nec Corp | 半導体装置の製造方法 |
| CN1196175C (zh) * | 2000-05-25 | 2005-04-06 | 凸版印刷株式会社 | 转印掩模的制造方法 |
| US6630288B2 (en) * | 2001-03-28 | 2003-10-07 | Advanced Micro Devices, Inc. | Process for forming sub-lithographic photoresist features by modification of the photoresist surface |
| US6673498B1 (en) * | 2001-11-02 | 2004-01-06 | Lsi Logic Corporation | Method for reticle formation utilizing metal vaporization |
-
2002
- 2002-08-14 US US10/219,995 patent/US6923920B2/en not_active Expired - Lifetime
-
2003
- 2003-07-31 AU AU2003257999A patent/AU2003257999A1/en not_active Abandoned
- 2003-07-31 WO PCT/US2003/024137 patent/WO2004017390A1/en not_active Ceased
- 2003-07-31 EP EP03788310A patent/EP1529308A1/en not_active Withdrawn
- 2003-07-31 JP JP2004529231A patent/JP2005535936A/ja active Pending
- 2003-07-31 KR KR1020057002028A patent/KR100990064B1/ko not_active Expired - Fee Related
- 2003-07-31 CN CNB038191784A patent/CN100423191C/zh not_active Expired - Fee Related
- 2003-08-07 TW TW092121695A patent/TWI307121B/zh not_active IP Right Cessation
-
2005
- 2005-06-20 US US11/157,782 patent/US20050230352A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| KR100990064B1 (ko) | 2010-10-26 |
| US6923920B2 (en) | 2005-08-02 |
| WO2004017390A1 (en) | 2004-02-26 |
| EP1529308A1 (en) | 2005-05-11 |
| AU2003257999A1 (en) | 2004-03-03 |
| US20040079727A1 (en) | 2004-04-29 |
| TW200407998A (en) | 2004-05-16 |
| CN100423191C (zh) | 2008-10-01 |
| JP2005535936A (ja) | 2005-11-24 |
| CN1689142A (zh) | 2005-10-26 |
| US20050230352A1 (en) | 2005-10-20 |
| KR20050047091A (ko) | 2005-05-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |