TW201141710A - Chiral liquid crystal polymer marking - Google Patents
Chiral liquid crystal polymer marking Download PDFInfo
- Publication number
- TW201141710A TW201141710A TW099142549A TW99142549A TW201141710A TW 201141710 A TW201141710 A TW 201141710A TW 099142549 A TW099142549 A TW 099142549A TW 99142549 A TW99142549 A TW 99142549A TW 201141710 A TW201141710 A TW 201141710A
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- TW
- Taiwan
- Prior art keywords
- liquid crystal
- pair
- composition
- palm
- oxy
- Prior art date
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- 229920000106 Liquid crystal polymer Polymers 0.000 title claims abstract description 17
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 title claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 186
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 121
- 239000002243 precursor Substances 0.000 claims abstract description 118
- 238000000034 method Methods 0.000 claims abstract description 37
- 239000000758 substrate Substances 0.000 claims abstract description 31
- 238000010438 heat treatment Methods 0.000 claims abstract description 20
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 62
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 45
- 239000002019 doping agent Substances 0.000 claims description 27
- 238000000576 coating method Methods 0.000 claims description 14
- 230000003287 optical effect Effects 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 12
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 7
- 235000003642 hunger Nutrition 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 3
- -1 packaging Substances 0.000 description 51
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 44
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 19
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 19
- 125000003545 alkoxy group Chemical group 0.000 description 18
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical class OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 17
- 238000007639 printing Methods 0.000 description 17
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 17
- 125000000217 alkyl group Chemical group 0.000 description 16
- 239000000463 material Substances 0.000 description 16
- 239000000976 ink Substances 0.000 description 15
- 239000000594 mannitol Substances 0.000 description 15
- 239000005711 Benzoic acid Substances 0.000 description 14
- 238000007641 inkjet printing Methods 0.000 description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 11
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 235000010233 benzoic acid Nutrition 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 9
- 239000002585 base Substances 0.000 description 9
- 239000000049 pigment Substances 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
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- 238000000151 deposition Methods 0.000 description 7
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- 235000012000 cholesterol Nutrition 0.000 description 6
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- IWPZKOJSYQZABD-UHFFFAOYSA-N 3,5-dimethoxybenzoic acid Chemical compound COC1=CC(OC)=CC(C(O)=O)=C1 IWPZKOJSYQZABD-UHFFFAOYSA-N 0.000 description 5
- 229930195725 Mannitol Natural products 0.000 description 5
- 239000004988 Nematic liquid crystal Substances 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000003570 air Substances 0.000 description 5
- 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000006258 conductive agent Substances 0.000 description 5
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- 235000010355 mannitol Nutrition 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 229940126062 Compound A Drugs 0.000 description 4
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 4
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
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- 150000005690 diesters Chemical class 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 4
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 4
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- XZRHNAFEYMSXRG-UHFFFAOYSA-N 2,5-dimethylbenzoic acid Chemical compound CC1=CC=C(C)C(C(O)=O)=C1 XZRHNAFEYMSXRG-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 101100181504 Mus musculus Clc gene Proteins 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical group C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
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- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 3
- 150000002923 oximes Chemical class 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 150000005846 sugar alcohols Chemical class 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 2
- UMVOQQDNEYOJOK-UHFFFAOYSA-N 3,5-dimethylbenzoic acid Chemical compound CC1=CC(C)=CC(C(O)=O)=C1 UMVOQQDNEYOJOK-UHFFFAOYSA-N 0.000 description 2
- ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 2
- SFHYNDMGZXWXBU-LIMNOBDPSA-N 6-amino-2-[[(e)-(3-formylphenyl)methylideneamino]carbamoylamino]-1,3-dioxobenzo[de]isoquinoline-5,8-disulfonic acid Chemical compound O=C1C(C2=3)=CC(S(O)(=O)=O)=CC=3C(N)=C(S(O)(=O)=O)C=C2C(=O)N1NC(=O)N\N=C\C1=CC=CC(C=O)=C1 SFHYNDMGZXWXBU-LIMNOBDPSA-N 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
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- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229930013930 alkaloid Natural products 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
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- 235000013305 food Nutrition 0.000 description 2
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
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- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
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- ILUJQPXNXACGAN-UHFFFAOYSA-N ortho-methoxybenzoic acid Natural products COC1=CC=CC=C1C(O)=O ILUJQPXNXACGAN-UHFFFAOYSA-N 0.000 description 2
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- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
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- 230000005855 radiation Effects 0.000 description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 2
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- SAJGCUXAHBJVRH-VFQQELCFSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;hydrate Chemical compound O.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SAJGCUXAHBJVRH-VFQQELCFSA-N 0.000 description 1
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- KLDXJTOLSGUMSJ-BXKVDMCESA-N (3s,3as,6s,6as)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3,6-diol Chemical class O[C@H]1CO[C@H]2[C@@H](O)CO[C@H]21 KLDXJTOLSGUMSJ-BXKVDMCESA-N 0.000 description 1
- LLNAMUJRIZIXHF-CLFYSBASSA-N (z)-2-methyl-3-phenylprop-2-en-1-ol Chemical compound OCC(/C)=C\C1=CC=CC=C1 LLNAMUJRIZIXHF-CLFYSBASSA-N 0.000 description 1
- IMSVBNQVZVQSND-UHFFFAOYSA-N 1,5-bis(sulfanyl)pentan-3-one Chemical compound SCCC(=O)CCS IMSVBNQVZVQSND-UHFFFAOYSA-N 0.000 description 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
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- FODBVCSYJKNBLO-UHFFFAOYSA-N 2,3-dimethoxybenzoic acid Chemical compound COC1=CC=CC(C(O)=O)=C1OC FODBVCSYJKNBLO-UHFFFAOYSA-N 0.000 description 1
- KGIUDZYUUVXUEG-UHFFFAOYSA-N 2,5-bis(sulfanyl)benzoic acid Chemical compound OC(=O)C1=CC(S)=CC=C1S KGIUDZYUUVXUEG-UHFFFAOYSA-N 0.000 description 1
- VDNMIIDPBBCMTM-UHFFFAOYSA-N 2-(2-hydroxyethoxy)acetic acid Chemical compound OCCOCC(O)=O VDNMIIDPBBCMTM-UHFFFAOYSA-N 0.000 description 1
- ZJKWJHONFFKJHG-UHFFFAOYSA-N 2-Methoxy-1,4-benzoquinone Chemical compound COC1=CC(=O)C=CC1=O ZJKWJHONFFKJHG-UHFFFAOYSA-N 0.000 description 1
- LADUENYEZHMRQH-UHFFFAOYSA-N 2-ethoxybenzohydrazide Chemical compound CCOC1=CC=CC=C1C(=O)NN LADUENYEZHMRQH-UHFFFAOYSA-N 0.000 description 1
- OUGRJASIBYFPRJ-UHFFFAOYSA-N 2-methoxybenzenecarbothioic s-acid Chemical compound COC1=CC=CC=C1C(O)=S OUGRJASIBYFPRJ-UHFFFAOYSA-N 0.000 description 1
- KTALPKYXQZGAEG-UHFFFAOYSA-N 2-propan-2-ylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3SC2=C1 KTALPKYXQZGAEG-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
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- SOFPIAMTOZWXKT-UHFFFAOYSA-N 2h-1,2,4-triazine-3-thione Chemical group SC1=NC=CN=N1 SOFPIAMTOZWXKT-UHFFFAOYSA-N 0.000 description 1
- SZYZOUJPUFNQKS-UHFFFAOYSA-N 3,5-bis(sulfanyl)benzoic acid Chemical compound OC(=O)C1=CC(S)=CC(S)=C1 SZYZOUJPUFNQKS-UHFFFAOYSA-N 0.000 description 1
- LBIHNTAFJVHBLJ-UHFFFAOYSA-N 3-(triethoxymethyl)undec-1-ene Chemical compound C(=C)C(C(OCC)(OCC)OCC)CCCCCCCC LBIHNTAFJVHBLJ-UHFFFAOYSA-N 0.000 description 1
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- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical class NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- IPBVNPXQWQGGJP-UHFFFAOYSA-N acetic acid phenyl ester Natural products CC(=O)OC1=CC=CC=C1 IPBVNPXQWQGGJP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 description 1
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- LOMPYPGVYNRXCJ-UHFFFAOYSA-N iodo thiocyanate Chemical compound ISC#N LOMPYPGVYNRXCJ-UHFFFAOYSA-N 0.000 description 1
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- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
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- QJWDYDSKKWMXSO-UHFFFAOYSA-N lanthanum Chemical compound [La].[La] QJWDYDSKKWMXSO-UHFFFAOYSA-N 0.000 description 1
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- GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluic acid Chemical compound CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 description 1
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- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
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- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- 125000005825 oxyethoxy group Chemical group [H]C([H])(O[*:1])C([H])([H])O[*:2] 0.000 description 1
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- 229960005222 phenazone Drugs 0.000 description 1
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- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/28—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/28—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating
- B41M5/281—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating using liquid crystals only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D15/00—Printed matter of special format or style not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/24—Passports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/364—Liquid crystals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- B42D2033/26—
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24835—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including developable image or soluble portion in coating or impregnation [e.g., safety paper, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Business, Economics & Management (AREA)
- Accounting & Taxation (AREA)
- Finance (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Liquid Crystal Substances (AREA)
- Liquid Crystal (AREA)
- Polarising Elements (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Credit Cards Or The Like (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Duplication Or Marking (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Materials For Medical Uses (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26766809P | 2009-12-08 | 2009-12-08 | |
| PCT/EP2010/056873 WO2011069689A1 (en) | 2009-12-08 | 2010-05-19 | Chiral liquid crystal polymer marking |
Publications (1)
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| TW201141710A true TW201141710A (en) | 2011-12-01 |
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| TW099142549A TW201141710A (en) | 2009-12-08 | 2010-12-07 | Chiral liquid crystal polymer marking |
Country Status (25)
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| US (1) | US8426012B2 (enExample) |
| EP (1) | EP2509795B1 (enExample) |
| JP (1) | JP5771850B2 (enExample) |
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| CN (1) | CN102712201B (enExample) |
| AP (1) | AP3100A (enExample) |
| AR (1) | AR080630A1 (enExample) |
| AU (1) | AU2010330331A1 (enExample) |
| BR (1) | BR112012013141A2 (enExample) |
| CA (1) | CA2781429A1 (enExample) |
| CL (1) | CL2012001457A1 (enExample) |
| CO (1) | CO6541580A2 (enExample) |
| EA (1) | EA022257B1 (enExample) |
| ES (1) | ES2439046T3 (enExample) |
| IL (1) | IL219657A0 (enExample) |
| MA (1) | MA33777B1 (enExample) |
| MX (1) | MX2012006164A (enExample) |
| PH (1) | PH12012501031A1 (enExample) |
| SA (1) | SA110310901B1 (enExample) |
| TN (1) | TN2012000208A1 (enExample) |
| TW (1) | TW201141710A (enExample) |
| UA (1) | UA103275C2 (enExample) |
| UY (1) | UY33085A (enExample) |
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| ZA (1) | ZA201204054B (enExample) |
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| WO2011069691A1 (en) * | 2009-12-08 | 2011-06-16 | Sicpa Holding Sa | Marking based on chiral liquid crystal polymers |
| WO2011069692A1 (en) * | 2009-12-08 | 2011-06-16 | Sicpa Holding Sa | Marking based on modified chiral liquid crystal polymers |
| US8426014B2 (en) * | 2009-12-08 | 2013-04-23 | Sicpa Holding Sa | Modified marking based on chiral liquid crystal polymers |
| AR086508A1 (es) * | 2011-05-27 | 2013-12-18 | Sicpa Holding Sa | Sustrato con una marcacion de polimero de cristal liquido modificado |
| KR20150013896A (ko) * | 2012-05-25 | 2015-02-05 | 캠브리지 엔터프라이즈 리미티드 | 습윤 중합체 용액 상의 액정 액적 레이저 공진기의 프린팅 및 이로부터 제조된 생성물 |
| MX2015007822A (es) | 2012-12-20 | 2015-08-20 | Sicpa Holding Sa | Capa o patron de polimero de cristal liquido quiral que comprende crateres aleatoriamente distribuidos en el mismo. |
| CN103343014B (zh) * | 2013-06-21 | 2014-12-03 | 惠州市华阳光学技术有限公司 | 一种液体着色物 |
| TW201502257A (zh) | 2013-07-10 | 2015-01-16 | Sicpa Holding Sa | 包括可印碼與手性液晶聚合物層的標記 |
| TW201520216A (zh) | 2013-10-21 | 2015-06-01 | Sicpa Holding Sa | 對掌性摻雜物與使用聚合性液晶材料標記之識別法及鑑別法 |
| WO2015067683A1 (en) * | 2013-11-08 | 2015-05-14 | Sicpa Holding Sa | Salt-free composite marking based on chiral liquid crystal precursors comprising chiral acrylate dopants |
| BR112016010348B1 (pt) * | 2013-11-08 | 2022-05-24 | Sicpa Holding Sa | Método para prover uma marcação em um substrato, substrato, e método para aumentar uma posição de uma banda de reflexão seletiva |
| TW201518485A (zh) | 2013-11-08 | 2015-05-16 | Sicpa Holding Sa | 以手性液晶前驅物及修飾樹脂爲基礎的複合標記 |
| TW201601928A (zh) | 2014-03-31 | 2016-01-16 | 西克帕控股有限公司 | 包含對掌性液晶聚合物與發光物質的標記 |
| EP3155556B1 (en) | 2014-06-10 | 2019-12-18 | Sicpa Holding SA | Substrate with a fragmented marking thereon |
| DE102014117877A1 (de) * | 2014-12-04 | 2016-06-23 | Leonhard Kurz Stiftung & Co. Kg | Sicherheitselement |
| GB201701003D0 (en) * | 2017-01-20 | 2017-03-08 | Johnson Matthey Plc | Security device, method of making a security device and method of authenticating a product |
| EP3778248A4 (en) * | 2018-03-29 | 2021-06-02 | FUJIFILM Corporation | IMAGE GENERATION PROCESS |
| CN114375261B (zh) * | 2019-09-27 | 2023-03-28 | 富士胶片株式会社 | 图像记录方法 |
| JPWO2022138142A1 (enExample) * | 2020-12-25 | 2022-06-30 |
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| DE19836885A1 (de) | 1998-08-14 | 2000-02-17 | Clariant Gmbh | Lasermarkierung von Effektbeschichtungen |
| DE10039377A1 (de) | 1999-09-03 | 2001-03-08 | Merck Patent Gmbh | Thermochromes flüssigkristallines Medium |
| JP2001188119A (ja) * | 1999-12-28 | 2001-07-10 | Seiko Epson Corp | カラーフィルターの製造方法および液晶表示装置の製造方法 |
| EP1295929B1 (en) * | 2001-09-25 | 2009-01-07 | MERCK PATENT GmbH | Anisotropic polymer film |
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-
2010
- 2010-05-19 ES ES10726011.9T patent/ES2439046T3/es active Active
- 2010-05-19 MX MX2012006164A patent/MX2012006164A/es not_active Application Discontinuation
- 2010-05-19 PH PH1/2012/501031A patent/PH12012501031A1/en unknown
- 2010-05-19 CN CN201080054964.4A patent/CN102712201B/zh not_active Expired - Fee Related
- 2010-05-19 EA EA201290452A patent/EA022257B1/ru not_active IP Right Cessation
- 2010-05-19 UA UAA201208183A patent/UA103275C2/ru unknown
- 2010-05-19 EP EP10726011.9A patent/EP2509795B1/en active Active
- 2010-05-19 CA CA2781429A patent/CA2781429A1/en not_active Abandoned
- 2010-05-19 AU AU2010330331A patent/AU2010330331A1/en not_active Abandoned
- 2010-05-19 AP AP2012006295A patent/AP3100A/xx active
- 2010-05-19 WO PCT/EP2010/056873 patent/WO2011069689A1/en not_active Ceased
- 2010-05-19 JP JP2012542407A patent/JP5771850B2/ja not_active Expired - Fee Related
- 2010-05-19 US US12/783,078 patent/US8426012B2/en active Active
- 2010-05-19 KR KR1020127014427A patent/KR20120104989A/ko not_active Withdrawn
- 2010-05-19 BR BR112012013141A patent/BR112012013141A2/pt not_active IP Right Cessation
- 2010-12-06 SA SA110310901A patent/SA110310901B1/ar unknown
- 2010-12-06 UY UY33085A patent/UY33085A/es not_active Application Discontinuation
- 2010-12-07 TW TW099142549A patent/TW201141710A/zh unknown
- 2010-12-07 AR ARP100104531A patent/AR080630A1/es active IP Right Grant
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2012
- 2012-05-08 TN TNP2012000208A patent/TN2012000208A1/en unknown
- 2012-05-08 IL IL219657A patent/IL219657A0/en not_active IP Right Cessation
- 2012-05-31 MA MA34914A patent/MA33777B1/fr unknown
- 2012-06-04 ZA ZA2012/04054A patent/ZA201204054B/en unknown
- 2012-06-04 CL CL2012001457A patent/CL2012001457A1/es unknown
- 2012-06-06 CO CO12095246A patent/CO6541580A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| TN2012000208A1 (en) | 2013-12-12 |
| CL2012001457A1 (es) | 2012-10-05 |
| CN102712201A (zh) | 2012-10-03 |
| EP2509795B1 (en) | 2013-09-11 |
| AP2012006295A0 (en) | 2012-06-30 |
| US8426012B2 (en) | 2013-04-23 |
| UA103275C2 (ru) | 2013-09-25 |
| AP3100A (en) | 2015-01-31 |
| WO2011069689A1 (en) | 2011-06-16 |
| EA022257B1 (ru) | 2015-11-30 |
| UY33085A (es) | 2011-07-29 |
| HK1174877A1 (en) | 2013-06-21 |
| ZA201204054B (en) | 2013-02-27 |
| CN102712201B (zh) | 2015-02-25 |
| MA33777B1 (fr) | 2012-11-01 |
| PH12012501031A1 (en) | 2017-07-26 |
| EP2509795A1 (en) | 2012-10-17 |
| JP5771850B2 (ja) | 2015-09-02 |
| AU2010330331A1 (en) | 2012-06-07 |
| KR20120104989A (ko) | 2012-09-24 |
| JP2013512800A (ja) | 2013-04-18 |
| CA2781429A1 (en) | 2011-06-16 |
| IL219657A0 (en) | 2012-07-31 |
| MX2012006164A (es) | 2012-06-25 |
| EA201290452A1 (ru) | 2013-01-30 |
| SA110310901B1 (ar) | 2014-01-26 |
| CO6541580A2 (es) | 2012-10-16 |
| ES2439046T3 (es) | 2014-01-21 |
| BR112012013141A2 (pt) | 2017-04-04 |
| US20110135890A1 (en) | 2011-06-09 |
| AR080630A1 (es) | 2012-04-25 |
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