TW200930731A - Process for the preparation of high fluidity propylene polymers - Google Patents

Process for the preparation of high fluidity propylene polymers Download PDF

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Publication number
TW200930731A
TW200930731A TW097138489A TW97138489A TW200930731A TW 200930731 A TW200930731 A TW 200930731A TW 097138489 A TW097138489 A TW 097138489A TW 97138489 A TW97138489 A TW 97138489A TW 200930731 A TW200930731 A TW 200930731A
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TW
Taiwan
Prior art keywords
succinate
propylene
compound
formula
group
Prior art date
Application number
TW097138489A
Other languages
English (en)
Chinese (zh)
Inventor
Paola Massari
Marco Ciarafoni
Ofelia Fusco
Hirofumi Murakami
Takeshi Nakajima
Shintaro Takemiya
Original Assignee
Basell Poliolefine Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Srl filed Critical Basell Poliolefine Srl
Publication of TW200930731A publication Critical patent/TW200930731A/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
TW097138489A 2007-10-15 2008-10-07 Process for the preparation of high fluidity propylene polymers TW200930731A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP07118446 2007-10-15

Publications (1)

Publication Number Publication Date
TW200930731A true TW200930731A (en) 2009-07-16

Family

ID=40148642

Family Applications (1)

Application Number Title Priority Date Filing Date
TW097138489A TW200930731A (en) 2007-10-15 2008-10-07 Process for the preparation of high fluidity propylene polymers

Country Status (8)

Country Link
US (1) US20100249330A1 (enExample)
EP (1) EP2201049B1 (enExample)
JP (1) JP5524068B2 (enExample)
CN (1) CN101821303B (enExample)
BR (1) BRPI0818758B1 (enExample)
RU (1) RU2471811C2 (enExample)
TW (1) TW200930731A (enExample)
WO (1) WO2009050045A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12103986B2 (en) 2020-12-29 2024-10-01 Formosa Plastics Corporation Polypropylene and method for producing the same, and meltblown fiber fabrics

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI1014019B1 (pt) 2009-06-19 2019-10-22 Basell Poliolefine Italia Srl processo para a preparação de composições de polímeros de propileno resistentes ao impacto
EP2452957A1 (en) * 2010-11-12 2012-05-16 Borealis AG Improved process for producing heterophasic propylene copolymers
EP2452956A1 (en) * 2010-11-12 2012-05-16 Borealis AG Improved process for polymerising propylene
US20140249264A1 (en) * 2011-10-07 2014-09-04 Total Research & Technology Feluy High-fluidity heterophasic propylene copolymer with improved rigidity
JP6144044B2 (ja) * 2011-12-28 2017-06-07 サンアロマー株式会社 バッテリーケース用ポリマー組成物
CN104736627B (zh) 2012-10-03 2018-04-17 胜亚诺盟股份有限公司 蒸煮膜用丙烯树脂组合物
JP6235804B2 (ja) * 2013-06-17 2017-11-22 サンアロマー株式会社 シート成形用ポリプロピレン樹脂組成物
JP6235805B2 (ja) * 2013-06-17 2017-11-22 サンアロマー株式会社 二軸延伸フィルム用ポリプロピレン樹脂組成物
EA032351B1 (ru) 2013-06-19 2019-05-31 Бореалис Аг Полипропилен с широким молекулярно-массовым распределением и способ его получения
EP2829397A1 (en) 2013-07-22 2015-01-28 Basell Poliolefine Italia S.r.l. Heat sealable polyolefin films and sheets
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US9593179B2 (en) 2014-02-07 2017-03-14 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
JP6598284B2 (ja) * 2014-03-26 2019-10-30 サンアロマー株式会社 α−オレフィン類の重合方法
JP6384019B2 (ja) * 2014-07-22 2018-09-05 サンアロマー株式会社 ポリプロピレン系樹脂組成物及びその製造方法
JP6831218B2 (ja) * 2016-11-15 2021-02-17 サンアロマー株式会社 マスターバッチ組成物およびこれを含むポリプロピレン樹脂組成物
WO2019094216A1 (en) 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
JP7096682B2 (ja) 2018-03-16 2022-07-06 サンアロマー株式会社 ポリプロピレン組成物および成形品
JP7096681B2 (ja) 2018-03-16 2022-07-06 サンアロマー株式会社 ポリプロピレン組成物および成形品
CA3102001A1 (en) 2018-06-11 2019-12-19 W.R. Grace & Co.-Conn Propylene-ethylene random copolymers with low xs/et ratio and high mfr
JP7114361B2 (ja) 2018-06-19 2022-08-08 サンアロマー株式会社 ポリプロピレン組成物および成形品
WO2020075755A1 (ja) 2018-10-09 2020-04-16 サンアロマー株式会社 ポリプロピレンシートの製造方法
JP7249126B2 (ja) 2018-10-18 2023-03-30 サンアロマー株式会社 ポリプロピレン組成物および成形品
CN119930881A (zh) 2019-06-17 2025-05-06 胜亚诺盟股份有限公司 超高分子量丙烯聚合物(共聚物)
US12415914B2 (en) 2019-06-17 2025-09-16 Sunallomer Ltd. Polypropylene-based resin composition containing ultrahigh molecular weight propylene (co)polymer
JP7329153B2 (ja) 2020-11-13 2023-08-17 株式会社エフピコ ポリプロピレン多層シート
US20250154348A1 (en) 2021-06-25 2025-05-15 Basell Poliolefine Italia S.R.L. Polypropylene resin composition, sheet molded body, and container
EP4361211A4 (en) 2021-06-25 2025-04-30 Basell Poliolefine Italia S.r.l. Polypropylene-based resin composition and method for producing same, film molded article, package to be brought into contact with food, container to be brought into contact with food, and retort pouch
US20240239942A1 (en) 2021-06-25 2024-07-18 Basell Poliolefine Italia S.R.L. Polypropylene resin composition, method for producing same, sheet molded body and container
WO2023171433A1 (ja) * 2022-03-11 2023-09-14 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分、オレフィン類重合用固体触媒成分の製造方法、オレフィン類重合用触媒、オレフィン類重合体の製造方法及びオレフィン類重合体

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1096661B (it) * 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
IT1190683B (it) * 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
US5221651A (en) * 1989-04-28 1993-06-22 Himont Incorporated Component and catalysts for the polymerization of olefins
JP2879391B2 (ja) * 1992-04-14 1999-04-05 昭和電工株式会社 オレフィン重合用触媒およびオレフィン重合体の製造法
JP3443848B2 (ja) * 1992-11-04 2003-09-08 東ソー株式会社 プロピレンブロック共重合体の製造方法
CA2121721C (en) * 1993-04-29 2004-11-23 Giampiero Morini Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution
RU2138514C1 (ru) * 1993-12-16 1999-09-27 Монтелл Норт Америка, Инк. Гомополимер пропилена, волокно, холст, тканевый материал, пленка
US7049377B1 (en) * 1995-02-21 2006-05-23 Basell Poliolefine Italia S.R.L. 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers
US6323152B1 (en) * 1998-03-30 2001-11-27 Basell Technology Company Bv Magnesium dichloride-alcohol adducts process for their preparation and catalyst components obtained therefrom
DE29813174U1 (de) * 1998-07-25 1999-09-02 Fa. Oskar Braunsberger, 87719 Mindelheim Zentriereinrichtung für flache Bauteile, insbesondere Glastafeln
PL192876B1 (pl) * 1998-11-03 2006-12-29 Montech Usa Inc Kompozycja poliolefinowa
WO2000063261A1 (en) * 1999-04-15 2000-10-26 Basell Technology Company B.V. Components and catalysts for the polymerization of olefins
PL355609A1 (en) * 2000-10-13 2004-05-04 Basell Poliolefine Italia S.P.A. Catalyst components for the polymerization of olefines
TWI268939B (en) * 2001-12-12 2006-12-21 Basell Poliolefine Spa Process for the polymerization of olefins
US7005487B2 (en) * 2002-07-02 2006-02-28 Basell Poliolefine Italia S.R.L. Catalyst system for the polymerization of olefins
TW200427763A (en) * 2003-04-03 2004-12-16 Basell Poliolefine Spa Impact resistant polyolefin compositions
CN1957034B (zh) * 2004-05-21 2011-07-13 巴塞尔聚烯烃意大利有限责任公司 耐冲击聚烯烃组合物
CA2583225A1 (en) * 2004-10-04 2006-04-13 Basell Poliolefine Italia S.R.L. Elastomeric polyolefin compositions
EP1827673B1 (en) * 2004-12-20 2012-02-01 Basell Poliolefine Italia S.r.l. Process and apparatus for the polymerization of propylene
JP4688135B2 (ja) * 2005-01-18 2011-05-25 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分および触媒
EP1717269A1 (en) * 2005-04-28 2006-11-02 Borealis Technology Oy Alpha-olefin homo-or copolymer compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12103986B2 (en) 2020-12-29 2024-10-01 Formosa Plastics Corporation Polypropylene and method for producing the same, and meltblown fiber fabrics

Also Published As

Publication number Publication date
JP5524068B2 (ja) 2014-06-18
EP2201049B1 (en) 2017-05-31
JP2011500907A (ja) 2011-01-06
EP2201049A2 (en) 2010-06-30
US20100249330A1 (en) 2010-09-30
BRPI0818758A2 (pt) 2015-04-07
RU2010119499A (ru) 2011-11-27
RU2471811C2 (ru) 2013-01-10
WO2009050045A3 (en) 2009-07-02
WO2009050045A2 (en) 2009-04-23
BRPI0818758B1 (pt) 2018-11-21
CN101821303A (zh) 2010-09-01
CN101821303B (zh) 2013-10-30

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