JP5524068B2 - 高流動性プロピレンポリマーの製造方法 - Google Patents
高流動性プロピレンポリマーの製造方法 Download PDFInfo
- Publication number
- JP5524068B2 JP5524068B2 JP2010529335A JP2010529335A JP5524068B2 JP 5524068 B2 JP5524068 B2 JP 5524068B2 JP 2010529335 A JP2010529335 A JP 2010529335A JP 2010529335 A JP2010529335 A JP 2010529335A JP 5524068 B2 JP5524068 B2 JP 5524068B2
- Authority
- JP
- Japan
- Prior art keywords
- succinate
- groups
- propylene
- diethyl
- dineopentyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920001155 polypropylene Polymers 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000003054 catalyst Substances 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 23
- 239000001257 hydrogen Substances 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 16
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 239000011949 solid catalyst Substances 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 9
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- 239000005977 Ethylene Substances 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- 125000005842 heteroatom Chemical group 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 239000008096 xylene Substances 0.000 claims description 5
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- -1 2-ethylhexyl Chemical group 0.000 description 48
- 238000006116 polymerization reaction Methods 0.000 description 25
- 229920000642 polymer Polymers 0.000 description 20
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 17
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 16
- 239000010936 titanium Substances 0.000 description 9
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 235000011147 magnesium chloride Nutrition 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 150000002430 hydrocarbons Chemical group 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 150000003609 titanium compounds Chemical class 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002431 hydrogen Chemical group 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- HZXMLBSUEZTYHZ-UHFFFAOYSA-N 4-(cyclohexylmethoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCC1CCCCC1 HZXMLBSUEZTYHZ-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 150000003377 silicon compounds Chemical class 0.000 description 3
- 150000003900 succinic acid esters Chemical group 0.000 description 3
- 238000004438 BET method Methods 0.000 description 2
- GFQUHXOKHFFPGI-UHFFFAOYSA-N CCC(CC)COC(=O)CCC(O)=O Chemical compound CCC(CC)COC(=O)CCC(O)=O GFQUHXOKHFFPGI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000002083 X-ray spectrum Methods 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000007630 basic procedure Methods 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001384 propylene homopolymer Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- NODOBCYQTXMEJS-UHFFFAOYSA-N 1-o-butyl 4-o-(2-methylpropyl) butanedioate Chemical compound CCCCOC(=O)CCC(=O)OCC(C)C NODOBCYQTXMEJS-UHFFFAOYSA-N 0.000 description 1
- CTTZQFZGUIRBLE-UHFFFAOYSA-N 4-(2,6-dimethyl-4-phenylheptan-4-yl)oxy-4-oxobutanoic acid Chemical compound CC(C)CC(CC(C)C)(C1=CC=CC=C1)OC(=O)CCC(=O)O CTTZQFZGUIRBLE-UHFFFAOYSA-N 0.000 description 1
- RYJHSTNVHPTWRC-UHFFFAOYSA-N 4-(2-cyclohexyl-3,3-diethylcyclopentyl)oxy-4-oxobutanoic acid Chemical compound CCC1(CCC(C1C2CCCCC2)OC(=O)CCC(=O)O)CC RYJHSTNVHPTWRC-UHFFFAOYSA-N 0.000 description 1
- APQSAVHZMIVHOP-UHFFFAOYSA-N 4-(2-cyclopentyl-4-ethylhexan-2-yl)oxy-4-oxobutanoic acid Chemical compound CCC(CC)CC(C)(C1CCCC1)OC(=O)CCC(=O)O APQSAVHZMIVHOP-UHFFFAOYSA-N 0.000 description 1
- HTZFWCKERCOKQL-UHFFFAOYSA-N 4-(3-cyclohexylhexan-3-yloxy)-4-oxobutanoic acid Chemical compound CCCC(CC)(C1CCCCC1)OC(=O)CCC(=O)O HTZFWCKERCOKQL-UHFFFAOYSA-N 0.000 description 1
- XWIMEAILKVOUBY-UHFFFAOYSA-N 4-(3-ethyl-2-methylpentan-2-yl)oxy-4-oxobutanoic acid Chemical compound CCC(CC)C(C)(C)OC(=O)CCC(=O)O XWIMEAILKVOUBY-UHFFFAOYSA-N 0.000 description 1
- KAXSCMJDJKSOSD-UHFFFAOYSA-N 4-(3-ethyl-3-methylpentan-2-yl)oxy-4-oxobutanoic acid Chemical compound CCC(C)(CC)C(C)OC(=O)CCC(=O)O KAXSCMJDJKSOSD-UHFFFAOYSA-N 0.000 description 1
- GKGGDGBREDAIRS-UHFFFAOYSA-N 4-(4-chloro-2,3-diethylphenoxy)-4-oxobutanoic acid Chemical compound CCC1=C(C=CC(=C1CC)Cl)OC(=O)CCC(=O)O GKGGDGBREDAIRS-UHFFFAOYSA-N 0.000 description 1
- LNFZQDBPJDGJHC-UHFFFAOYSA-N 4-(4-cyclohexyl-2,7-dimethyloctan-4-yl)oxy-4-oxobutanoic acid Chemical compound CC(C)CCC(CC(C)C)(C1CCCCC1)OC(=O)CCC(=O)O LNFZQDBPJDGJHC-UHFFFAOYSA-N 0.000 description 1
- NHEDUCHUGWSSKQ-UHFFFAOYSA-N 4-(4-ethyl-2-phenylhexan-2-yl)oxy-4-oxobutanoic acid Chemical compound CCC(CC)CC(C)(C1=CC=CC=C1)OC(=O)CCC(=O)O NHEDUCHUGWSSKQ-UHFFFAOYSA-N 0.000 description 1
- AYTWRUIRADOHRS-UHFFFAOYSA-N 4-O-[4,4-bis(2-methylpropyl)cyclohexyl] 1-O-methyl butanedioate Chemical compound C(CCC(=O)OC)(=O)OC1CCC(CC1)(CC(C)C)CC(C)C AYTWRUIRADOHRS-UHFFFAOYSA-N 0.000 description 1
- YMXLMOYJBKNDCH-UHFFFAOYSA-N 4-[2,3-bis(2-methylpropyl)cyclopropyl]oxy-4-oxobutanoic acid Chemical compound CC(C)CC1C(C1OC(=O)CCC(=O)O)CC(C)C YMXLMOYJBKNDCH-UHFFFAOYSA-N 0.000 description 1
- XKWOXZUBHDGJHP-UHFFFAOYSA-N 4-[2,5-dimethyl-3-(2-methylpropyl)hexan-2-yl]oxy-4-oxobutanoic acid Chemical compound CC(C)CC(CC(C)C)C(C)(C)OC(=O)CCC(=O)O XKWOXZUBHDGJHP-UHFFFAOYSA-N 0.000 description 1
- JPBYXSXDQPVPOE-UHFFFAOYSA-N 4-[2-(3-methylbutyl)-3,3-bis(2-methylpropyl)cyclohexyl]oxy-4-oxobutanoic acid Chemical compound CC(C)CCC1C(CCCC1(CC(C)C)CC(C)C)OC(=O)CCC(=O)O JPBYXSXDQPVPOE-UHFFFAOYSA-N 0.000 description 1
- URTQIHDQUVLMFD-UHFFFAOYSA-N 4-[2-cyclohexyl-3,3-bis(2-methylpropyl)cyclopentyl]oxy-4-oxobutanoic acid Chemical compound CC(C)CC1(CCC(C1C2CCCCC2)OC(=O)CCC(=O)O)CC(C)C URTQIHDQUVLMFD-UHFFFAOYSA-N 0.000 description 1
- KDZUTDQCFLDZHO-UHFFFAOYSA-N 4-[2-methyl-4-(2-methylpropyl)nonadecan-5-yl]oxy-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCCCC(C(CC(C)C)CC(C)C)OC(=O)CCC(=O)O KDZUTDQCFLDZHO-UHFFFAOYSA-N 0.000 description 1
- KTKCUBVXNSDYSU-UHFFFAOYSA-N 4-[3,3-diethyl-2-(3-methylbutyl)cyclohexyl]oxy-4-oxobutanoic acid Chemical compound CCC1(CCCC(C1CCC(C)C)OC(=O)CCC(=O)O)CC KTKCUBVXNSDYSU-UHFFFAOYSA-N 0.000 description 1
- CZCHCWAGBIQNMJ-UHFFFAOYSA-N 4-[3,5-dimethyl-3-(2-methylpropyl)hexan-2-yl]oxy-4-oxobutanoic acid Chemical compound CC(C)CC(C)(CC(C)C)C(C)OC(=O)CCC(=O)O CZCHCWAGBIQNMJ-UHFFFAOYSA-N 0.000 description 1
- RTWIQBLTNKAPFA-UHFFFAOYSA-N 4-[3-(2,2-dimethylpropyl)-2,5,5-trimethylhexan-2-yl]oxy-4-oxobutanoic acid Chemical compound CC(C)(C)CC(CC(C)(C)C)C(C)(C)OC(=O)CCC(=O)O RTWIQBLTNKAPFA-UHFFFAOYSA-N 0.000 description 1
- AXBCMNKRXWPPNI-UHFFFAOYSA-N 4-[4-(2,2-dimethylpropyl)-6,6-dimethyl-2-phenylheptan-2-yl]oxy-4-oxobutanoic acid Chemical compound CC(C)(C)CC(CC(C)(C)C)CC(C)(C1=CC=CC=C1)OC(=O)CCC(=O)O AXBCMNKRXWPPNI-UHFFFAOYSA-N 0.000 description 1
- ULUOWJUTKLRTPH-UHFFFAOYSA-N C(CCC(=O)OC)(=O)OC1C(C(CCC1)(CC)CC)CCCCCCCCCCCCCC Chemical compound C(CCC(=O)OC)(=O)OC1C(C(CCC1)(CC)CC)CCCCCCCCCCCCCC ULUOWJUTKLRTPH-UHFFFAOYSA-N 0.000 description 1
- PHYSAQCROGOAQB-UHFFFAOYSA-N CC(C)(C)CC(CC(C)(C)C)CC(C)(C1CCCC1)OC(CCC(O)=O)=O Chemical compound CC(C)(C)CC(CC(C)(C)C)CC(C)(C1CCCC1)OC(CCC(O)=O)=O PHYSAQCROGOAQB-UHFFFAOYSA-N 0.000 description 1
- LSGKUIMDDPPGJQ-UHFFFAOYSA-N CC(C)(C)CC1(CCC(C1C2CCCCC2)OC(=O)CCC(=O)O)CC(C)(C)C Chemical compound CC(C)(C)CC1(CCC(C1C2CCCCC2)OC(=O)CCC(=O)O)CC(C)(C)C LSGKUIMDDPPGJQ-UHFFFAOYSA-N 0.000 description 1
- OKZPAIRYDKBXPP-UHFFFAOYSA-N CC(C)(C)CC1=C(C(=CC=C1)OC(=O)CCC(=O)O)CC(C)(C)C Chemical compound CC(C)(C)CC1=C(C(=CC=C1)OC(=O)CCC(=O)O)CC(C)(C)C OKZPAIRYDKBXPP-UHFFFAOYSA-N 0.000 description 1
- XMMNDCQURGTSGL-UHFFFAOYSA-N CC(C)(C)CC1=C(C=CC(=C1CC(C)(C)C)Cl)OC(=O)CCC(=O)O Chemical compound CC(C)(C)CC1=C(C=CC(=C1CC(C)(C)C)Cl)OC(=O)CCC(=O)O XMMNDCQURGTSGL-UHFFFAOYSA-N 0.000 description 1
- NMCQLAHQLAUCJA-UHFFFAOYSA-N CC(C)(C)CC1=C(C=CC(=C1CC(C)(C)C)OC(=O)CCC(=O)O)OC Chemical compound CC(C)(C)CC1=C(C=CC(=C1CC(C)(C)C)OC(=O)CCC(=O)O)OC NMCQLAHQLAUCJA-UHFFFAOYSA-N 0.000 description 1
- HANSCPJMFKAFNF-UHFFFAOYSA-N CC(C)(C)CCC(CC(C)(C)C)(C1CCCCC1)OC(=O)CCC(=O)O Chemical compound CC(C)(C)CCC(CC(C)(C)C)(C1CCCCC1)OC(=O)CCC(=O)O HANSCPJMFKAFNF-UHFFFAOYSA-N 0.000 description 1
- HWWWDDXMEILMIA-UHFFFAOYSA-N CC(C)C1C(CCCC1(CC(C)(C)C)CC(C)(C)C)OC(=O)CCC(=O)O Chemical compound CC(C)C1C(CCCC1(CC(C)(C)C)CC(C)(C)C)OC(=O)CCC(=O)O HWWWDDXMEILMIA-UHFFFAOYSA-N 0.000 description 1
- RWTPSXQHMWPJMC-UHFFFAOYSA-N CC(C)CC(CC(C)C)C(CC(C)C)OC(=O)CCC(=O)O Chemical compound CC(C)CC(CC(C)C)C(CC(C)C)OC(=O)CCC(=O)O RWTPSXQHMWPJMC-UHFFFAOYSA-N 0.000 description 1
- HNZOXSCHPIXMFT-UHFFFAOYSA-N CC(C)CC(CC(C)C)CC(C)(C1=CC=CC=C1)OC(=O)CCC(=O)O Chemical compound CC(C)CC(CC(C)C)CC(C)(C1=CC=CC=C1)OC(=O)CCC(=O)O HNZOXSCHPIXMFT-UHFFFAOYSA-N 0.000 description 1
- XYLPDELIRSKGIJ-UHFFFAOYSA-N CC(C)CC(CC(C)C)CC(C)(C1CCCC1)OC(=O)CCC(=O)O Chemical compound CC(C)CC(CC(C)C)CC(C)(C1CCCC1)OC(=O)CCC(=O)O XYLPDELIRSKGIJ-UHFFFAOYSA-N 0.000 description 1
- PHMTXECDYMNPJZ-UHFFFAOYSA-N CC(C)CC(CC(C)C)[Si](C)(C)OC(=O)CCC(=O)O Chemical compound CC(C)CC(CC(C)C)[Si](C)(C)OC(=O)CCC(=O)O PHMTXECDYMNPJZ-UHFFFAOYSA-N 0.000 description 1
- GJCWTGNKFHFOPM-UHFFFAOYSA-N CC(C)CC1(CCCC(C1C(C)C)OC(=O)CCC(=O)O)CC(C)C Chemical compound CC(C)CC1(CCCC(C1C(C)C)OC(=O)CCC(=O)O)CC(C)C GJCWTGNKFHFOPM-UHFFFAOYSA-N 0.000 description 1
- AQFBSQDFFZAQCM-UHFFFAOYSA-N CC(C)CC1=C(C=CC(=C1CC(C)C)Cl)OC(=O)CCC(=O)O Chemical compound CC(C)CC1=C(C=CC(=C1CC(C)C)Cl)OC(=O)CCC(=O)O AQFBSQDFFZAQCM-UHFFFAOYSA-N 0.000 description 1
- UQLRFNGWTNSRDF-UHFFFAOYSA-N CC(C)CC1=C(C=CC(=C1CC(C)C)OC(=O)CCC(=O)O)OC Chemical compound CC(C)CC1=C(C=CC(=C1CC(C)C)OC(=O)CCC(=O)O)OC UQLRFNGWTNSRDF-UHFFFAOYSA-N 0.000 description 1
- OISJMNOGUQJVRX-UHFFFAOYSA-N CC(C)CCC1C(CCCC1(CC(C)(C)C)CC(C)(C)C)OC(=O)CCC(=O)O Chemical compound CC(C)CCC1C(CCCC1(CC(C)(C)C)CC(C)(C)C)OC(=O)CCC(=O)O OISJMNOGUQJVRX-UHFFFAOYSA-N 0.000 description 1
- DQWASBHLFOZAAM-UHFFFAOYSA-N CCC1=C(C=CC(=C1CC)OC(=O)CCC(=O)O)OC Chemical compound CCC1=C(C=CC(=C1CC)OC(=O)CCC(=O)O)OC DQWASBHLFOZAAM-UHFFFAOYSA-N 0.000 description 1
- WXUOQCSOUVGXAS-UHFFFAOYSA-N CCCCCCC(CC(C)C)OC(=O)CCC(=O)O Chemical compound CCCCCCC(CC(C)C)OC(=O)CCC(=O)O WXUOQCSOUVGXAS-UHFFFAOYSA-N 0.000 description 1
- AUYZVPBYGOFSFK-UHFFFAOYSA-N CCCCCCCCCCCCCCC(C(CC(C)(C)C)CC(C)(C)C)OC(=O)CCC(=O)O Chemical compound CCCCCCCCCCCCCCC(C(CC(C)(C)C)CC(C)(C)C)OC(=O)CCC(=O)O AUYZVPBYGOFSFK-UHFFFAOYSA-N 0.000 description 1
- HSRGLQYBHVFSQL-UHFFFAOYSA-N CCCCCCCCCCCCCCC(CCCC1)C1C(CC(C)C)(CC(C)C)OC(CCC(O)=O)=O Chemical compound CCCCCCCCCCCCCCC(CCCC1)C1C(CC(C)C)(CC(C)C)OC(CCC(O)=O)=O HSRGLQYBHVFSQL-UHFFFAOYSA-N 0.000 description 1
- VLYQGGONMXMAAT-UHFFFAOYSA-N CCCCCCCCCCCCCCC1CCCCC1C(CC(C)(C)C)(CC(C)(C)C)OC(=O)CCC(=O)O Chemical compound CCCCCCCCCCCCCCC1CCCCC1C(CC(C)(C)C)(CC(C)(C)C)OC(=O)CCC(=O)O VLYQGGONMXMAAT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- WMNULTDOANGXRT-UHFFFAOYSA-N bis(2-ethylhexyl) butanedioate Chemical compound CCCCC(CC)COC(=O)CCC(=O)OCC(CC)CCCC WMNULTDOANGXRT-UHFFFAOYSA-N 0.000 description 1
- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 description 1
- DGUHDCPCYIQFHO-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-dibenzylbutanedioate Chemical compound C=1C=CC=CC=1CC(C(=O)OCC(C)C)C(C(=O)OCC(C)C)CC1=CC=CC=C1 DGUHDCPCYIQFHO-UHFFFAOYSA-N 0.000 description 1
- HSLLCWNHQWGGHZ-UHFFFAOYSA-N bis(2-methylpropyl) 2-methyl-2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C)(C(C)C)C(=O)OCC(C)C HSLLCWNHQWGGHZ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- AVLHXEDOBYYTGV-UHFFFAOYSA-N diethyl 2,3-bis(2-methylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)C)C(CC(C)C)C(=O)OCC AVLHXEDOBYYTGV-UHFFFAOYSA-N 0.000 description 1
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 description 1
- DQNUPKXJISAAFG-UHFFFAOYSA-N diethyl 2,3-diethyl-2-propan-2-ylbutanedioate Chemical compound CCOC(=O)C(CC)C(CC)(C(C)C)C(=O)OCC DQNUPKXJISAAFG-UHFFFAOYSA-N 0.000 description 1
- ZUCVTIPWILNAMK-UHFFFAOYSA-N diethyl 2,3-ditert-butylbutanedioate Chemical compound CCOC(=O)C(C(C)(C)C)C(C(C)(C)C)C(=O)OCC ZUCVTIPWILNAMK-UHFFFAOYSA-N 0.000 description 1
- JZJPBADSXBZWAZ-UHFFFAOYSA-N diethyl 2-benzylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)CC1=CC=CC=C1 JZJPBADSXBZWAZ-UHFFFAOYSA-N 0.000 description 1
- OZTIOOUTDNFCJG-UHFFFAOYSA-N diethyl 2-ethyl-2-(2-methylpropyl)butanedioate Chemical compound CCOC(=O)CC(CC)(CC(C)C)C(=O)OCC OZTIOOUTDNFCJG-UHFFFAOYSA-N 0.000 description 1
- DJHQJVJMROPIHP-UHFFFAOYSA-N diethyl 2-ethyl-2-methylbutanedioate Chemical compound CCOC(=O)CC(C)(CC)C(=O)OCC DJHQJVJMROPIHP-UHFFFAOYSA-N 0.000 description 1
- MRWFEHLACVTKBG-UHFFFAOYSA-N diethyl 2-ethyl-2-tetradecylbutanedioate Chemical compound CCCCCCCCCCCCCCC(CC)(C(=O)OCC)CC(=O)OCC MRWFEHLACVTKBG-UHFFFAOYSA-N 0.000 description 1
- CNVQQORAGNTULF-UHFFFAOYSA-N diethyl 2-methyl-2-propan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C)(C(C)C)C(=O)OCC CNVQQORAGNTULF-UHFFFAOYSA-N 0.000 description 1
- GEVHQTAWODKPAI-UHFFFAOYSA-N diethyl 2-methyl-3-(3,3,3-trifluoropropyl)butanedioate Chemical compound CCOC(=O)C(C)C(CCC(F)(F)F)C(=O)OCC GEVHQTAWODKPAI-UHFFFAOYSA-N 0.000 description 1
- JVQDNCKPHSZFSO-UHFFFAOYSA-N diethyl 2-phenylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=CC=C1 JVQDNCKPHSZFSO-UHFFFAOYSA-N 0.000 description 1
- SSQLHHBLAVHVOU-UHFFFAOYSA-N diethyl 2-propan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C(C)C)C(=O)OCC SSQLHHBLAVHVOU-UHFFFAOYSA-N 0.000 description 1
- 229940105984 diethylhexyl succinate Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000005498 phthalate group Chemical group 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Description
(a)Mg、Ti、ハロゲン、及びスクシネートから選択される電子ドナー化合物を含む固体触媒成分;
(b)アルキルアルミニウム共触媒;及び
(c)式:R1Si(OR)3(式中、R1は分岐アルキルであり、Rは、独立してC1〜C10アルキルである)のケイ素化合物;
を含む触媒系の存在下で行う、5より高い多分散性指数、及び30g/10分より高いメルトインデックス(230℃;2.16kg)を有するプロピレンポリマーの製造方法である。
のスクシネートから選択される電子ドナーを含む。
好ましいチタン化合物は、ハロゲン化物、或いは式:TiXn(OR1)4−n(式中、1≦n≦3であり、Xはハロゲン、好ましくは塩素であり、R1はC1〜C10炭化水素基である)の化合物である。特に好ましいチタン化合物は、四塩化チタン、及び式:TiCl3OR1(式中、R1は上記に与える意味を有し、特にメチル、n−ブチル、又はイソプロピルから選択される)の化合物である。
第2級炭素原子を介してSi原子に結合している分岐アルキルの非限定的な例は、イソプロピル、シクロプロピル、シクロペンチル、シクロヘキシルである。
本発明の触媒は、任意の種類のCH2=CHR(式中、Rは水素又はC1〜C10炭化水素基である)のオレフィンを重合することができる。しかしながら、上記で言及したように、これは、30g/10分より高く、好ましくは50g/10分より高く、より好ましくは70g/10分より高いメルトフローレートを、5より高く、好ましくは5.3より高く、より好ましくは6より高いMWD(以下に記載のようにして測定される多分散性指数として表す)と組み合わせて有するプロピレンポリマーの製造に特に適している。
特性分析:
XIの測定:
2.50gのポリマーを、250mLのo−キシレン中に、撹拌下135℃において30分間溶解し、次に溶液を25℃に冷却し、30分後、不溶のポリマーを濾去した。得られた溶液を窒素流中で蒸発させ、残渣を乾燥し、秤量して可溶のポリマーの割合を求め、次に、差によってキシレン不溶フラクション(%)を求めた。
ISO−1133(230℃;2.16kg)にしたがって測定した。
多分散性指数(PI):
200℃の温度において、RHEOMETRICS(米国)によって販売されている平行プレート流量計モデルRMS-800を用い、0.1rad/秒から100rad/秒に増加する振動数で運転することによって測定した。多分散性指数の値は、等式:
PI=105/Gc
(式中、Gcは、G’=G”(ここで、G’は貯蔵弾性率であり、G”は損失弾性率である)における値(Paとして表す)として定義されるクロスオーバー弾性率である)
を用いてクロスオーバー弾性率から誘導した。
ISO−178にしたがって測定した。
アイゾッド衝撃強さ:
ISO−180/1Aにしたがって測定した。
スパイラルフロー評価は、溶融ポリマーを中空スパイラル金型の中心に射出し、固化した樹脂の全長を測定して、圧力及び温度の特定条件下で材料が固化する前にどのくらい流れるかを求めることを含む。
基本手順Aから得られる固体触媒成分に関するプロピレンの基本重合手順:
70℃において窒素流で2時間パージした4Lのオートクレーブ内において、760mgのAlEt3、テキシルトリメトキシシラン(TEAL/テキシルトリメトキシシランのモル比20)、及び10mgの固体触媒成分を含む75mLの無水ヘキサンを、30℃においてプロピレン流中に導入した。オートクレーブを閉止した。表1に報告する量の水素を加え、次に撹拌下で1.2kgの液体プロピレンを供給した。温度を5分間で70℃に上昇させ、この温度において重合を2時間行った。未反応のプロピレンを除去し、ポリマーを回収し、真空下70℃で3時間乾燥し、次に秤量し、Mg残渣を求めるために分析し、これによって触媒の活性を算出した。
液体モノマーループ重合反応器中に、プロピレン流中の触媒成分、アルミニウムトリエチル(TEAL)、外部ドナーとしてテキシルトリメトキシシラン、水素(分子量調整剤として用いた)、及びプロピレンを、別々に連続の一定流で供給して表2に報告する条件に到達させることによって、プロピレンホモポリマー(成分(A))を製造した。
球状付加体を製造するための基本手順:
WO−98/44009の実施例2に記載の方法にしたがって、しかしながらより大きなスケールで運転し、25μmの平均粒径を有する付加体を得るように撹拌条件を設定して、初期量の微細球状MgCl2・2.8C2H5OHを製造した。
固体触媒成分の製造:
窒素でパージした500mLの4つ口丸底フラスコ中に、250mLのTiCl4を0℃において導入した。撹拌しながら、10.0gの微細球状MgCl2・1.8C2H5OH(USP−4,399,054の実施例2に記載の方法にしたがって、しかしながら10000rpmに代えて3000rpmで運転して製造した)、及び9.1ミリモルのジエチル−2,3−(ジイソプロピル)スクシネートを加えた。温度を100℃に上昇させ、120分間保持した。次に、撹拌を停止し、固体生成物を沈降させ、上澄み液を吸い出した。次に、以下の操作を2回繰り返した:250mLの新しいTiCl4を加え、混合物を120℃において60分間反応させ、上澄み液を吸い出した。固体を、60℃において無水ヘキサン(6×100mL)で6回洗浄した。
比較例1〜2:
実施例1及び3と同じ条件を用いて重合を行った。相違点は、テキシルトリメトキシシランの代わりにジシクロペンチルジメトキシシランを用いた点であった。
実施例4及び5に関しては実施例1〜3に記載のものと同じ触媒系を用いて、一方比較例6においてはEP−728769の実施例2に記載の触媒系を用いて、基本重合手順Bにしたがってヘテロ相組成物を製造した。具体的な重合条件及びポリマーの特性を表2に報告する。
実施例1〜3に記載のものと同じ触媒系を用い、重合の第1工程においてより多い量の水素を用いて、基本重合手順Bにしたがってヘテロ相組成物を製造した。具体的な重合条件及びポリマーの特性を表3に報告する。
Claims (3)
- (a)Mg、Ti、及びハロゲン原子、並びに式(I)の化合物から選択される電子ドナー化合物を含む固体触媒成分;
(b)アルキルアルミニウム共触媒;及び
(c)テキシルトリメトキシシラン;
を含む触媒系の存在下で行う、5より高い多分散性指数、及びISO−1133(230℃;2.16kg)にしたがって測定して30g/10分より高いメルトインデックス値を有するプロピレンポリマーの製造方法。 - 第1工程(A)において、93重量%より高い室温におけるキシレン不溶フラクションを有するプロピレンポリマーを製造するために、水素、並びに(a)Mg、Ti、及びハロゲン原子、並びに式(I)の化合物から選択される電子ドナー化合物を含む固体触媒成分;(b)アルキルアルミニウム共触媒;及び(c)テキシルトリメトキシシラン;を含む触媒系の存在下で、プロピレンを重合し;
(A)において製造されるプロピレンポリマーの存在下で行う第2工程(B)において、50重量%より高い室温におけるキシレン可溶分を有するエチレンとプロピレンとのコポリマーを製造するために、エチレン及びプロピレンを重合する;ことを含む、プロピレンポリマー組成物の製造方法。 - 工程(A)において製造されるプロピレンポリマーが80g/10分より高いメルトフローレートを有する、請求項2に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07118446 | 2007-10-15 | ||
EP07118446.9 | 2007-10-15 | ||
US99943607P | 2007-10-18 | 2007-10-18 | |
US60/999,436 | 2007-10-18 | ||
PCT/EP2008/063243 WO2009050045A2 (en) | 2007-10-15 | 2008-10-02 | Process for the preparation of high fluidity propylene polymers |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2011500907A JP2011500907A (ja) | 2011-01-06 |
JP2011500907A5 JP2011500907A5 (ja) | 2011-11-17 |
JP5524068B2 true JP5524068B2 (ja) | 2014-06-18 |
Family
ID=40148642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010529335A Active JP5524068B2 (ja) | 2007-10-15 | 2008-10-02 | 高流動性プロピレンポリマーの製造方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US20100249330A1 (ja) |
EP (1) | EP2201049B1 (ja) |
JP (1) | JP5524068B2 (ja) |
CN (1) | CN101821303B (ja) |
BR (1) | BRPI0818758B1 (ja) |
RU (1) | RU2471811C2 (ja) |
TW (1) | TW200930731A (ja) |
WO (1) | WO2009050045A2 (ja) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2672731T3 (es) | 2009-06-19 | 2018-06-15 | Basell Poliolefine Italia S.R.L. | Proceso de preparación de composiciones de polímero de propileno resistentes a los impactos |
EP2452957A1 (en) * | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for producing heterophasic propylene copolymers |
EP2452956A1 (en) * | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for polymerising propylene |
EP2764047A2 (en) * | 2011-10-07 | 2014-08-13 | Total Research & Technology Feluy | High-fluidity heterophasic propylene copolymer with improved rigidity |
JP6144044B2 (ja) * | 2011-12-28 | 2017-06-07 | サンアロマー株式会社 | バッテリーケース用ポリマー組成物 |
CN104736627B (zh) | 2012-10-03 | 2018-04-17 | 胜亚诺盟股份有限公司 | 蒸煮膜用丙烯树脂组合物 |
JP6235805B2 (ja) * | 2013-06-17 | 2017-11-22 | サンアロマー株式会社 | 二軸延伸フィルム用ポリプロピレン樹脂組成物 |
JP6235804B2 (ja) * | 2013-06-17 | 2017-11-22 | サンアロマー株式会社 | シート成形用ポリプロピレン樹脂組成物 |
US9550844B2 (en) | 2013-06-19 | 2017-01-24 | Borealis Ag | Polypropylene with broad molecular weight distribution |
EP2829397A1 (en) | 2013-07-22 | 2015-01-28 | Basell Poliolefine Italia S.r.l. | Heat sealable polyolefin films and sheets |
US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
US9399686B2 (en) | 2014-02-07 | 2016-07-26 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
JP6598284B2 (ja) * | 2014-03-26 | 2019-10-30 | サンアロマー株式会社 | α−オレフィン類の重合方法 |
JP6384019B2 (ja) * | 2014-07-22 | 2018-09-05 | サンアロマー株式会社 | ポリプロピレン系樹脂組成物及びその製造方法 |
JP6831218B2 (ja) * | 2016-11-15 | 2021-02-17 | サンアロマー株式会社 | マスターバッチ組成物およびこれを含むポリプロピレン樹脂組成物 |
WO2019094216A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
JP7096681B2 (ja) | 2018-03-16 | 2022-07-06 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
JP7096682B2 (ja) | 2018-03-16 | 2022-07-06 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
CA3102001A1 (en) | 2018-06-11 | 2019-12-19 | W.R. Grace & Co.-Conn | Propylene-ethylene random copolymers with low xs/et ratio and high mfr |
JP7114361B2 (ja) | 2018-06-19 | 2022-08-08 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
EP3865285A4 (en) | 2018-10-09 | 2022-06-01 | Sunallomer Ltd | POLYPROPYLENE SHEET PRODUCTION METHOD |
JP7249126B2 (ja) | 2018-10-18 | 2023-03-30 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
CN114008132B (zh) | 2019-06-17 | 2023-08-29 | 胜亚诺盟股份有限公司 | 含有超高分子量丙烯聚合物(共聚物)的聚丙烯类树脂组合物 |
EP3985034A4 (en) | 2019-06-17 | 2023-06-14 | Sunallomer Ltd | ULTRA HIGH MOLECULAR WEIGHT PROPYLENE (CO)POLYMER |
CA3198133A1 (en) | 2020-11-13 | 2022-05-19 | Fp Corporation | Polypropylene multilayer sheet |
TWI762127B (zh) | 2020-12-29 | 2022-04-21 | 臺灣塑膠工業股份有限公司 | 聚丙烯與其製作方法及熔噴纖維布 |
WO2022270629A1 (ja) | 2021-06-25 | 2022-12-29 | サンアロマー株式会社 | ポリプロピレン系樹脂組成物、シート成形体及び容器 |
JPWO2022270625A1 (ja) | 2021-06-25 | 2022-12-29 | ||
US20240239942A1 (en) | 2021-06-25 | 2024-07-18 | Basell Poliolefine Italia S.R.L. | Polypropylene resin composition, method for producing same, sheet molded body and container |
CN118679192A (zh) * | 2022-03-11 | 2024-09-20 | 东邦钛株式会社 | 烯烃类聚合用固体催化剂成分、烯烃类聚合用固体催化剂成分的制造方法、烯烃类聚合用催化剂、烯烃类聚合物的制造方法和烯烃类聚合物 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1096661B (it) * | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
US5221651A (en) * | 1989-04-28 | 1993-06-22 | Himont Incorporated | Component and catalysts for the polymerization of olefins |
JP2879391B2 (ja) * | 1992-04-14 | 1999-04-05 | 昭和電工株式会社 | オレフィン重合用触媒およびオレフィン重合体の製造法 |
JP3443848B2 (ja) * | 1992-11-04 | 2003-09-08 | 東ソー株式会社 | プロピレンブロック共重合体の製造方法 |
CA2121721C (en) * | 1993-04-29 | 2004-11-23 | Giampiero Morini | Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution |
RU2138514C1 (ru) * | 1993-12-16 | 1999-09-27 | Монтелл Норт Америка, Инк. | Гомополимер пропилена, волокно, холст, тканевый материал, пленка |
US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
US6323152B1 (en) * | 1998-03-30 | 2001-11-27 | Basell Technology Company Bv | Magnesium dichloride-alcohol adducts process for their preparation and catalyst components obtained therefrom |
DE29813174U1 (de) * | 1998-07-25 | 1999-09-02 | Fa. Oskar Braunsberger, 87719 Mindelheim | Zentriereinrichtung für flache Bauteile, insbesondere Glastafeln |
KR100580897B1 (ko) * | 1998-11-03 | 2006-05-17 | 바셀테크 유에스에이 인크 | 강성과 충격 강도의 높은 균형을 갖는 폴리올레핀 조성물 |
RU2225415C2 (ru) * | 1999-04-15 | 2004-03-10 | Базелль Текнолоджи Компани Б.В. | Компоненты и катализаторы полимеризации олефинов |
ATE407153T1 (de) * | 2000-10-13 | 2008-09-15 | Basell Poliolefine Srl | Katalysatorbestandteile zur olefinpolymerisation |
MY136330A (en) * | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
US7005487B2 (en) * | 2002-07-02 | 2006-02-28 | Basell Poliolefine Italia S.R.L. | Catalyst system for the polymerization of olefins |
TW200427763A (en) * | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
CN1957034B (zh) * | 2004-05-21 | 2011-07-13 | 巴塞尔聚烯烃意大利有限责任公司 | 耐冲击聚烯烃组合物 |
WO2006037705A1 (en) * | 2004-10-04 | 2006-04-13 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
US7524903B2 (en) * | 2004-12-20 | 2009-04-28 | Basell Poliolefine Italia S.R.L. | Process and apparatus for the polymerization of propylene |
JP4688135B2 (ja) * | 2005-01-18 | 2011-05-25 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒 |
EP1717269A1 (en) * | 2005-04-28 | 2006-11-02 | Borealis Technology Oy | Alpha-olefin homo-or copolymer compositions |
-
2008
- 2008-10-02 BR BRPI0818758A patent/BRPI0818758B1/pt active IP Right Grant
- 2008-10-02 RU RU2010119499/04A patent/RU2471811C2/ru not_active IP Right Cessation
- 2008-10-02 EP EP08839744.3A patent/EP2201049B1/en active Active
- 2008-10-02 JP JP2010529335A patent/JP5524068B2/ja active Active
- 2008-10-02 US US12/734,174 patent/US20100249330A1/en not_active Abandoned
- 2008-10-02 CN CN200880111534.4A patent/CN101821303B/zh active Active
- 2008-10-02 WO PCT/EP2008/063243 patent/WO2009050045A2/en active Application Filing
- 2008-10-07 TW TW097138489A patent/TW200930731A/zh unknown
Also Published As
Publication number | Publication date |
---|---|
CN101821303A (zh) | 2010-09-01 |
WO2009050045A3 (en) | 2009-07-02 |
RU2471811C2 (ru) | 2013-01-10 |
US20100249330A1 (en) | 2010-09-30 |
BRPI0818758B1 (pt) | 2018-11-21 |
CN101821303B (zh) | 2013-10-30 |
TW200930731A (en) | 2009-07-16 |
EP2201049B1 (en) | 2017-05-31 |
WO2009050045A2 (en) | 2009-04-23 |
RU2010119499A (ru) | 2011-11-27 |
BRPI0818758A2 (pt) | 2015-04-07 |
EP2201049A2 (en) | 2010-06-30 |
JP2011500907A (ja) | 2011-01-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5524068B2 (ja) | 高流動性プロピレンポリマーの製造方法 | |
RU2557057C2 (ru) | Композиция прокатализатора, содержащая адамантан, и способ | |
KR101564178B1 (ko) | 지글러-나타 촉매화된, 핵형성된 폴리프로필렌 및 메탈로센 촉매화된 폴리프로필렌의 원위치 반응기 배합물 | |
US6818583B1 (en) | Components and catalysts for the polymerization of olefins | |
US6825146B2 (en) | Olefin polymerization catalyst compositions and method of preparation | |
JP4602484B2 (ja) | オレフィンの重合用成分および触媒 | |
JP4306807B2 (ja) | オレフィンの重合用成分および触媒 | |
US6239236B1 (en) | Components and catalysts for the polymerization of olefins | |
US9200094B2 (en) | Catalyst components for the polymerization of olefins | |
JP2011528384A (ja) | ポリエチレンの製造プロセス | |
JP2006521429A (ja) | マグネシウムジクロリド−アルコール付加物およびそれから得られる触媒成分 | |
EP1735353A1 (en) | Olefin polymerization procatalyst compositions and method of preparation | |
US20100240846A1 (en) | Catalyst component for the polymerization of olefins based on 1,3-diethers | |
US7307035B2 (en) | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom | |
US10167349B2 (en) | Catalyst system for the polymerization of olefins | |
JP2014500384A (ja) | アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品 | |
EP1525231B1 (en) | Catalyst system for the polymerization of olefins | |
JPH11269218A (ja) | オレフィン重合体製造用固体触媒成分、オレフィン重 合体製造用触媒およびオレフィン重合体の製造方法 | |
JP4018893B2 (ja) | オレフィン重合用固体触媒成分、オレフィン重合用触媒及びオレフィン重合体の製造方法 | |
US20130203948A1 (en) | Process for the preparation of high purity propylene polymers | |
JP2003201311A (ja) | オレフィン重合用固体触媒成分、オレフィン重合用触媒及びオレフィン重合体の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110929 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110929 |
|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20130402 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20130402 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130814 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130822 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131021 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20131115 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140214 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20140221 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140311 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140409 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5524068 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |