SU1491338A3 - Способ получени 6-метил-3,4-дигидро-1,2,3-оксатиазин-4-он-2,2-диоксида или его калиевой соли - Google Patents
Способ получени 6-метил-3,4-дигидро-1,2,3-оксатиазин-4-он-2,2-диоксида или его калиевой соли Download PDFInfo
- Publication number
- SU1491338A3 SU1491338A3 SU853933056A SU3933056A SU1491338A3 SU 1491338 A3 SU1491338 A3 SU 1491338A3 SU 853933056 A SU853933056 A SU 853933056A SU 3933056 A SU3933056 A SU 3933056A SU 1491338 A3 SU1491338 A3 SU 1491338A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- fluoride
- base
- inert solvent
- chlorosulfonyl
- acetoacetamide
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 title claims abstract description 5
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims abstract description 15
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 15
- GCPWJFKTWGFEHH-UHFFFAOYSA-N acetoacetamide Chemical compound CC(=O)CC(N)=O GCPWJFKTWGFEHH-UHFFFAOYSA-N 0.000 claims abstract description 12
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical compound FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 claims abstract description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 10
- IXPAAHZTOUOJJM-UHFFFAOYSA-N sulfuryl chloride fluoride Chemical compound FS(Cl)(=O)=O IXPAAHZTOUOJJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005935 Sulfuryl fluoride Substances 0.000 claims abstract description 8
- 239000012442 inert solvent Substances 0.000 claims abstract description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 102100035475 Blood vessel epicardial substance Human genes 0.000 claims 1
- 101001094636 Homo sapiens Blood vessel epicardial substance Proteins 0.000 claims 1
- 101000608194 Homo sapiens Pyrin domain-containing protein 1 Proteins 0.000 claims 1
- 101000595404 Homo sapiens Ribonucleases P/MRP protein subunit POP1 Proteins 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- -1 sulfur oxide compound Chemical class 0.000 claims 1
- 235000013305 food Nutrition 0.000 abstract description 2
- 150000003464 sulfur compounds Chemical class 0.000 abstract description 2
- 235000019605 sweet taste sensations Nutrition 0.000 abstract description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 abstract 4
- 150000002391 heterocyclic compounds Chemical class 0.000 abstract 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 5
- 239000000619 acesulfame-K Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000004809 thin layer chromatography Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- YGCFIWIQZPHFLU-UHFFFAOYSA-N acesulfame Chemical compound CC1=CC(=O)NS(=O)(=O)O1 YGCFIWIQZPHFLU-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002024 ethyl acetate extract Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D291/00—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms
- C07D291/02—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms not condensed with other rings
- C07D291/06—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Seasonings (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843429039 DE3429039A1 (de) | 1984-08-07 | 1984-08-07 | Verfahren zur herstellung von6-methyl-3,4-dihydro-1,2,3-oxathiazin-4-on-2,2-dioxid und dessen nichttoxischen salzen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1491338A3 true SU1491338A3 (ru) | 1989-06-30 |
Family
ID=6242506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU853933056A SU1491338A3 (ru) | 1984-08-07 | 1985-08-05 | Способ получени 6-метил-3,4-дигидро-1,2,3-оксатиазин-4-он-2,2-диоксида или его калиевой соли |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US4625024A (https=) |
| EP (1) | EP0173082B1 (https=) |
| JP (1) | JPS6147473A (https=) |
| KR (1) | KR920008617B1 (https=) |
| AR (1) | AR240454A1 (https=) |
| AT (1) | ATE36851T1 (https=) |
| AU (1) | AU575669B2 (https=) |
| BR (1) | BR8503715A (https=) |
| CA (1) | CA1241955A (https=) |
| DD (1) | DD246298A5 (https=) |
| DE (2) | DE3429039A1 (https=) |
| DK (1) | DK167976B1 (https=) |
| ES (1) | ES8604186A1 (https=) |
| FI (1) | FI81790C (https=) |
| HU (1) | HU197889B (https=) |
| IE (1) | IE58482B1 (https=) |
| IL (1) | IL76027A (https=) |
| MX (1) | MX160726A (https=) |
| NO (1) | NO163772C (https=) |
| SU (1) | SU1491338A3 (https=) |
| ZA (1) | ZA855921B (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3410440A1 (de) * | 1984-03-22 | 1985-09-26 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von 6-methyl-3,4-dihydro-1,2,3-oxathiazin-4-on-2,2-dioxid und dessen nichttoxischen salzen |
| DE3410439A1 (de) * | 1984-03-22 | 1985-09-26 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von 6-methyl-3,4-dihydro-1,2,3-oxathiazin-4-on-2,2-dioxid und dessen nichttoxischen salzen sowie der dabei als zwischenprodukt(e) auftretenden acetoacetamind-n-sulfonsaeure(salze) |
| HUE051396T2 (hu) | 2016-09-21 | 2021-03-01 | Celanese Int Corp | Aceszulfám-kálium kompozíciók és az elõállításukra szolgáló eljárások |
| LT3319948T (lt) | 2016-09-21 | 2021-10-11 | Celanese International Corporation | Kalio acesulfamo kompozicijos ir jų gamybos būdai |
| US10030000B2 (en) | 2016-09-21 | 2018-07-24 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| EP3623363A1 (en) | 2016-09-21 | 2020-03-18 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2001017C3 (de) * | 1970-01-10 | 1978-05-18 | Hoechst Ag, 6000 Frankfurt | 3,4-Dihydro-1,23-oxathiazin-4on-2,2-dioxide, ihre Herstellung und Verwendung |
| DE2264235C3 (de) * | 1972-12-30 | 1980-09-11 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von 6-Methyl-3,4-dihydro-l,23-oxa thiazin-4-on-2,2-dioxid |
| DE2434548C2 (de) * | 1974-07-18 | 1982-11-18 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Fluoridarmem 6-Methyl-3,4-dihydro-1,2,3-oxathiazin-4-on-2,2-dioxid-kalium |
| DE2434549A1 (de) * | 1974-07-18 | 1976-01-29 | Hoechst Ag | Verfahren zur herstellung des suesstoffes 6-methyl-3,4-dihydro-1,2,3-oxathiazin4-on-2,2-dioxid |
| DE2447201A1 (de) * | 1974-10-03 | 1976-04-08 | Hoechst Ag | Verfahren zur herstellung von acetoacetamid-n-sulfofluorid |
| DE3410440A1 (de) * | 1984-03-22 | 1985-09-26 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von 6-methyl-3,4-dihydro-1,2,3-oxathiazin-4-on-2,2-dioxid und dessen nichttoxischen salzen |
| DE3527070A1 (de) * | 1985-07-29 | 1987-01-29 | Hoechst Ag | Verfahren zur herstellung von 6-methyl-3,4-dihydro-1,2,3-oxathiazin-4-on-2,2-dioxid |
| DE3531359A1 (de) * | 1985-09-03 | 1987-03-12 | Hoechst Ag | Verfahren zur herstellung von 6-methyl-3,4-dihydro-1,2,3-oxathiazin-4-on-2,2-dioxid sowie zu dessen reinigung |
| DE3531358A1 (de) * | 1985-09-03 | 1987-03-12 | Hoechst Ag | Verfahren zur herstellung der nicht-toxischen salze des 6-methyl-3,4-dihydro-1,2,3-oxathiazin-4-on-2,2-dioxids |
-
1984
- 1984-08-07 DE DE19843429039 patent/DE3429039A1/de not_active Withdrawn
-
1985
- 1985-07-25 DE DE8585109376T patent/DE3564682D1/de not_active Expired
- 1985-07-25 EP EP85109376A patent/EP0173082B1/de not_active Expired
- 1985-07-25 AT AT85109376T patent/ATE36851T1/de not_active IP Right Cessation
- 1985-08-02 HU HU852963A patent/HU197889B/hu unknown
- 1985-08-05 ES ES545878A patent/ES8604186A1/es not_active Expired
- 1985-08-05 SU SU853933056A patent/SU1491338A3/ru active
- 1985-08-05 FI FI853008A patent/FI81790C/fi not_active IP Right Cessation
- 1985-08-05 US US06/762,563 patent/US4625024A/en not_active Expired - Lifetime
- 1985-08-05 AR AR301184A patent/AR240454A1/es active
- 1985-08-05 DD DD85279371A patent/DD246298A5/de not_active IP Right Cessation
- 1985-08-06 NO NO853103A patent/NO163772C/no unknown
- 1985-08-06 IL IL76027A patent/IL76027A/xx not_active IP Right Cessation
- 1985-08-06 AU AU45835/85A patent/AU575669B2/en not_active Expired
- 1985-08-06 JP JP60171936A patent/JPS6147473A/ja active Granted
- 1985-08-06 BR BR8503715A patent/BR8503715A/pt unknown
- 1985-08-06 CA CA000488177A patent/CA1241955A/en not_active Expired
- 1985-08-06 DK DK358285A patent/DK167976B1/da not_active IP Right Cessation
- 1985-08-06 KR KR1019850005654A patent/KR920008617B1/ko not_active Expired
- 1985-08-06 ZA ZA855921A patent/ZA855921B/xx unknown
- 1985-08-06 IE IE194085A patent/IE58482B1/en not_active IP Right Cessation
- 1985-08-07 MX MX206223A patent/MX160726A/es unknown
Non-Patent Citations (1)
| Title |
|---|
| Патент СССР 1342419, кл. С 07 D 291/06, 22.03.84. * |
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