SU1192612A3 - Способ получени @ -изомеров @ , @ -диалкил-2-хлорпропионамидов - Google Patents
Способ получени @ -изомеров @ , @ -диалкил-2-хлорпропионамидов Download PDFInfo
- Publication number
- SU1192612A3 SU1192612A3 SU823387235A SU3387235A SU1192612A3 SU 1192612 A3 SU1192612 A3 SU 1192612A3 SU 823387235 A SU823387235 A SU 823387235A SU 3387235 A SU3387235 A SU 3387235A SU 1192612 A3 SU1192612 A3 SU 1192612A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- isomers
- mol
- alkyl
- dialkyl
- general formula
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 7
- 150000002148 esters Chemical class 0.000 claims abstract 3
- 150000001412 amines Chemical class 0.000 claims abstract 2
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 150000001408 amides Chemical class 0.000 abstract description 3
- 230000003287 optical effect Effects 0.000 abstract description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 1
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- WORKHWHULFDZDE-UHFFFAOYSA-N 2-chloro-n,n-diethylpropanamide Chemical compound CCN(CC)C(=O)C(C)Cl WORKHWHULFDZDE-UHFFFAOYSA-N 0.000 description 1
- AEEGJNJYJCGJFZ-UHFFFAOYSA-N 2-methylpropyl 2-chloropropanoate Chemical compound CC(C)COC(=O)C(C)Cl AEEGJNJYJCGJFZ-UHFFFAOYSA-N 0.000 description 1
- 101150111724 MEP1 gene Proteins 0.000 description 1
- QCOGKXLOEWLIDC-UHFFFAOYSA-N N-methylbutylamine Chemical compound CCCCNC QCOGKXLOEWLIDC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- VIRPUNZTLGQDDV-UHFFFAOYSA-N chloro propanoate Chemical compound CCC(=O)OCl VIRPUNZTLGQDDV-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940096717 pamine Drugs 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- CXYRUNPLKGGUJF-RAFJPFSSSA-M scopolamine methobromide Chemical compound [Br-].C1([C@@H](CO)C(=O)O[C@H]2C[C@@H]3[N+]([C@H](C2)[C@@H]2[C@H]3O2)(C)C)=CC=CC=C1 CXYRUNPLKGGUJF-RAFJPFSSSA-M 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/02—Preparation of carboxylic acid amides from carboxylic acids or from esters, anhydrides, or halides thereof by reaction with ammonia or amines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/294,101 US4358612A (en) | 1981-01-02 | 1981-08-21 | Process for production of α-haloalkylamides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1192612A3 true SU1192612A3 (ru) | 1985-11-15 |
Family
ID=23131880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU823387235A SU1192612A3 (ru) | 1981-08-21 | 1982-02-02 | Способ получени @ -изомеров @ , @ -диалкил-2-хлорпропионамидов |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US4358612A (enExample) |
| EP (1) | EP0072884B1 (enExample) |
| JP (1) | JPS5835154A (enExample) |
| KR (1) | KR870000981B1 (enExample) |
| AR (1) | AR227701A1 (enExample) |
| AT (1) | ATE21508T1 (enExample) |
| AU (1) | AU545658B2 (enExample) |
| BR (1) | BR8200247A (enExample) |
| CA (1) | CA1183551A (enExample) |
| CS (1) | CS227036B2 (enExample) |
| DD (1) | DD202427A5 (enExample) |
| DE (1) | DE3272648D1 (enExample) |
| ES (1) | ES8300681A1 (enExample) |
| HU (1) | HU193632B (enExample) |
| MX (1) | MX155242A (enExample) |
| PL (1) | PL138545B1 (enExample) |
| PT (1) | PT74339B (enExample) |
| RO (1) | RO85392B (enExample) |
| SU (1) | SU1192612A3 (enExample) |
| YU (1) | YU43067B (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK129783A (da) * | 1982-04-12 | 1983-10-13 | Stauffer Chemical Co | Fremgangsmaade til fremstilling af alfa-halogen-n,n-dimethylpropionamider |
| US4675441A (en) * | 1983-09-23 | 1987-06-23 | Texaco Inc. | Preparation of N-substituted acrylamides |
| JPH082682B2 (ja) * | 1986-03-07 | 1996-01-17 | 松下電器産業株式会社 | 印字装置 |
| JPH0628281Y2 (ja) * | 1986-07-04 | 1994-08-03 | セイコー電子工業株式会社 | プリンタ |
| JPS638964U (enExample) * | 1986-07-04 | 1988-01-21 | ||
| KR101174962B1 (ko) | 2007-05-04 | 2012-08-20 | 유나이티드 포스포러스 리미티드 | 고순도 Ｄ-(-)-Ｎ, Ｎ-디에틸-2-(α-나프톡시)프로피온아미드의 제조방법 |
| JP2017533892A (ja) * | 2014-10-03 | 2017-11-16 | ピュラック バイオケム ビー． ブイ． | Ｎ，ｎ−ジアルキルラクトアミドの製造法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2268129A (en) * | 1937-11-27 | 1941-12-30 | Gen Aniline & Film Corp | Process for making amines of the acetylene series |
| US3655690A (en) * | 1968-11-08 | 1972-04-11 | Monsanto Co | 1 2 3 5-tetramethyl pyrazolium chloride and method for preparation |
| US3763234A (en) * | 1970-12-03 | 1973-10-02 | Halcon International Inc | Preparation of amides |
| JPS5476501A (en) * | 1977-11-29 | 1979-06-19 | Tokyo Kougiyou Daigakuchiyou | Manufacture of organic carboxylic acid amides |
| CH650493A5 (en) | 1977-12-24 | 1985-07-31 | Hoechst Ag | D-(+)-alpha-phenoxypropionic acid derivatives |
| US4259259A (en) * | 1979-11-15 | 1981-03-31 | Texaco Development Corp. | Preparation of β-aminopropionamides |
| US4258200A (en) * | 1980-03-11 | 1981-03-24 | Air Products And Chemicals, Inc. | Production of carboxylic acid amides and carbamates using cobalt catalysts |
-
1981
- 1981-08-21 US US06/294,101 patent/US4358612A/en not_active Expired - Lifetime
-
1982
- 1982-01-13 AU AU79472/82A patent/AU545658B2/en not_active Ceased
- 1982-01-13 CA CA000394019A patent/CA1183551A/en not_active Expired
- 1982-01-14 ES ES508729A patent/ES8300681A1/es not_active Expired
- 1982-01-15 AT AT82100272T patent/ATE21508T1/de not_active IP Right Cessation
- 1982-01-15 EP EP82100272A patent/EP0072884B1/en not_active Expired
- 1982-01-15 DE DE8282100272T patent/DE3272648D1/de not_active Expired
- 1982-01-18 BR BR8200247A patent/BR8200247A/pt unknown
- 1982-01-20 HU HU82159A patent/HU193632B/hu not_active IP Right Cessation
- 1982-01-23 RO RO106422A patent/RO85392B/ro unknown
- 1982-01-25 JP JP57008959A patent/JPS5835154A/ja active Granted
- 1982-01-26 PT PT74339A patent/PT74339B/pt unknown
- 1982-01-29 CS CS82630A patent/CS227036B2/cs unknown
- 1982-02-01 AR AR288311A patent/AR227701A1/es active
- 1982-02-02 SU SU823387235A patent/SU1192612A3/ru active
- 1982-02-11 MX MX191334A patent/MX155242A/es unknown
- 1982-02-18 YU YU369/82A patent/YU43067B/xx unknown
- 1982-02-20 PL PL1982235164A patent/PL138545B1/pl unknown
- 1982-03-09 DD DD82237999A patent/DD202427A5/de unknown
- 1982-04-03 KR KR8201480A patent/KR870000981B1/ko not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| Патент US № 3998880, кл. 260-559 В, опублик. 1976. Патент US № 3763234, кл. 260558 Р, опублик. 1973. Вьшоженна за вка DE № 2546845, кл. С 07 D 215/20, опублик. 1977. * |
Also Published As
| Publication number | Publication date |
|---|---|
| PT74339A (en) | 1982-02-01 |
| AU545658B2 (en) | 1985-07-25 |
| MX155242A (es) | 1988-02-09 |
| KR870000981B1 (ko) | 1987-05-16 |
| US4358612A (en) | 1982-11-09 |
| ATE21508T1 (de) | 1986-09-15 |
| ES508729A0 (es) | 1982-11-01 |
| DD202427A5 (de) | 1983-09-14 |
| DE3272648D1 (en) | 1986-09-25 |
| ES8300681A1 (es) | 1982-11-01 |
| PL138545B1 (en) | 1986-10-31 |
| BR8200247A (pt) | 1983-04-12 |
| YU43067B (en) | 1989-02-28 |
| JPH0338264B2 (enExample) | 1991-06-10 |
| AU7947282A (en) | 1983-02-24 |
| RO85392B (ro) | 1984-11-30 |
| EP0072884B1 (en) | 1986-08-20 |
| CA1183551A (en) | 1985-03-05 |
| JPS5835154A (ja) | 1983-03-01 |
| PL235164A1 (en) | 1983-08-15 |
| HU193632B (en) | 1987-11-30 |
| EP0072884A3 (en) | 1984-02-22 |
| YU36982A (en) | 1985-03-20 |
| RO85392A (ro) | 1984-10-31 |
| CS227036B2 (en) | 1984-04-16 |
| KR830010048A (ko) | 1983-12-24 |
| EP0072884A2 (en) | 1983-03-02 |
| AR227701A1 (es) | 1982-11-30 |
| PT74339B (en) | 1983-07-04 |
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