SU1050565A3 - Способ получени натриевой соли @ -фосфонометилглицина - Google Patents
Способ получени натриевой соли @ -фосфонометилглицина Download PDFInfo
- Publication number
- SU1050565A3 SU1050565A3 SU802877858A SU2877858A SU1050565A3 SU 1050565 A3 SU1050565 A3 SU 1050565A3 SU 802877858 A SU802877858 A SU 802877858A SU 2877858 A SU2877858 A SU 2877858A SU 1050565 A3 SU1050565 A3 SU 1050565A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- water
- sodium
- salt
- solution
- product
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract description 6
- 159000000000 sodium salts Chemical class 0.000 title description 4
- 239000011734 sodium Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- NOJNFULGOQGBKB-UHFFFAOYSA-M sodium;3-[3-tert-butylsulfanyl-1-[[4-(6-ethoxypyridin-3-yl)phenyl]methyl]-5-[(5-methylpyridin-2-yl)methoxy]indol-2-yl]-2,2-dimethylpropanoate Chemical compound [Na+].C1=NC(OCC)=CC=C1C(C=C1)=CC=C1CN1C2=CC=C(OCC=3N=CC(C)=CC=3)C=C2C(SC(C)(C)C)=C1CC(C)(C)C([O-])=O NOJNFULGOQGBKB-UHFFFAOYSA-M 0.000 claims 1
- 235000014101 wine Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 abstract description 12
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 230000002363 herbicidal effect Effects 0.000 abstract description 2
- 239000004009 herbicide Substances 0.000 abstract description 2
- 240000000111 Saccharum officinarum Species 0.000 abstract 1
- 235000007201 Saccharum officinarum Nutrition 0.000 abstract 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 abstract 1
- 229930006000 Sucrose Natural products 0.000 abstract 1
- 239000005720 sucrose Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- 239000000047 product Substances 0.000 description 23
- 239000000243 solution Substances 0.000 description 16
- 239000013078 crystal Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000005562 Glyphosate Substances 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229940097068 glyphosate Drugs 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000005457 ice water Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- UCTWMZQNUQWSLP-UHFFFAOYSA-N adrenaline Chemical compound CNCC(O)C1=CC=C(O)C(O)=C1 UCTWMZQNUQWSLP-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- -1 sodium hydrofluoride nonahydrate Chemical compound 0.000 description 2
- 150000004685 tetrahydrates Chemical group 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 241000252505 Characidae Species 0.000 description 1
- 241000337911 Copium Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 101150057615 Syn gene Proteins 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 241000256856 Vespidae Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000008504 concentrate Nutrition 0.000 description 1
- 230000002951 depilatory effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- XGZRAKBCYZIBKP-UHFFFAOYSA-L disodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[Na+] XGZRAKBCYZIBKP-UHFFFAOYSA-L 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002332 glycine derivatives Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000037074 physically active Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- DGPIGKCOQYBCJH-UHFFFAOYSA-M sodium;acetic acid;hydroxide Chemical compound O.[Na+].CC([O-])=O DGPIGKCOQYBCJH-UHFFFAOYSA-M 0.000 description 1
- DFIWJEVKLWMZBI-UHFFFAOYSA-M sodium;dihydrogen phosphate;phosphoric acid Chemical compound [Na+].OP(O)(O)=O.OP(O)([O-])=O DFIWJEVKLWMZBI-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000007966 viscous suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 208000016261 weight loss Diseases 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/866,677 US4140513A (en) | 1978-01-03 | 1978-01-03 | Sodium sesquiglyphosate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1050565A3 true SU1050565A3 (ru) | 1983-10-23 |
Family
ID=25348146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU802877858A SU1050565A3 (ru) | 1978-01-03 | 1980-02-08 | Способ получени натриевой соли @ -фосфонометилглицина |
Country Status (41)
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4481026A (en) * | 1982-11-16 | 1984-11-06 | Stauffer Chemical Company | Aluminum N-phosphonomethylglycine and its use as a herbicide |
| US4472189A (en) * | 1982-12-27 | 1984-09-18 | Stauffer Chemical Co. | Stannic N-phosphonomethyglycine and its use as a herbicide |
| KR860008713A (ko) * | 1985-05-29 | 1986-12-18 | 죤 알. 페넬 | 고체식물 훨성조성물 및 그 제조방법 |
| US5580841A (en) * | 1985-05-29 | 1996-12-03 | Zeneca Limited | Solid, phytoactive compositions and method for their preparation |
| US5468718A (en) * | 1985-10-21 | 1995-11-21 | Ici Americas Inc. | Liquid, phytoactive compositions and method for their preparation |
| BR8600460A (pt) * | 1986-02-04 | 1987-09-01 | Monsanto Brasil | Processo para preparacao de um sal de metal alcalino particulado de n-fosfonometilglicina |
| US5047079A (en) * | 1986-08-18 | 1991-09-10 | Ici Americas Inc. | Method of preparation and use of solid, phytoactive compositions |
| NZ231897A (en) | 1988-12-30 | 1992-09-25 | Monsanto Co | Dry water-soluble granular composition comprising glyphosate and a liquid surfactant |
| DK165156C (da) * | 1989-12-20 | 1993-03-01 | Cheminova Agro As | Herbicid formulering indeholdende glyphosatsyre |
| DE4029304A1 (de) * | 1990-09-15 | 1992-03-19 | Hoechst Ag | Synergistische herbizide mittel |
| US6930075B1 (en) | 1990-11-02 | 2005-08-16 | Monsanto Technology, Llc | Fatty acid-based herbicidal composition |
| IL101539A (en) | 1991-04-16 | 1998-09-24 | Monsanto Europe Sa | Mono-ammonium salts of the history of N phosphonomethyl glycyl which are not hygroscopes, their preparations and pesticides containing |
| MY111437A (en) * | 1992-07-31 | 2000-05-31 | Monsanto Co | Improved glyphosate herbicide formulation. |
| DE19533523A1 (de) * | 1995-09-11 | 1997-03-13 | Bayer Ag | Verwendung von N-Phosphonomethyl-glycinestern in wäßriger Lösung als Herbizide |
| HU228429B1 (en) * | 1997-07-22 | 2013-03-28 | Monsanto Technology Llc | High-loaded ammonium glyphosate formulations |
| AR013936A1 (es) * | 1997-07-30 | 2001-01-31 | Monsanto Technology Llc | Proceso y composiciones que promueven la eficacia biologica de sustancias quimicas exogenas en plantas. |
| ITTO980048A1 (it) * | 1998-01-20 | 1999-07-20 | Ipici Spa | Composizioni erbicide, procedimenti per la loro preparazione ed impieghi |
| JP4669608B2 (ja) * | 1998-02-13 | 2011-04-13 | モンサント テクノロジー エルエルシー | 外因性化学物質およびシロキサン界面活性剤を含有する貯蔵安定性組成物 |
| GB9819693D0 (en) | 1998-09-10 | 1998-11-04 | Zeneca Ltd | Glyphosate formulation |
| DE69920035T2 (de) | 1998-11-23 | 2005-09-15 | Monsanto Technology Llc. | Hochkonzentrierte wässrige glyphosatzusammensetzungen |
| ES2552540T3 (es) | 1998-11-23 | 2015-11-30 | Monsanto Technology Llc | Sistema de almacenamiento y transporte compacto para herbicida glifosato |
| EP1135024B1 (en) | 1998-11-30 | 2004-12-29 | Flamel Technologies | Promoting biological effectiveness of exogenous chemical substances in plants |
| US6369001B1 (en) | 1999-08-11 | 2002-04-09 | Monsanto Technology, Llc | Microemulsion coformulation of a graminicide and a water-soluble herbicide |
| US6746976B1 (en) | 1999-09-24 | 2004-06-08 | The Procter & Gamble Company | Thin until wet structures for acquiring aqueous fluids |
| JP5433120B2 (ja) | 1999-09-30 | 2014-03-05 | モンサント テクノロジー エルエルシー | 向上した安定性を有するパッケージミックス農薬組成物 |
| US6992045B2 (en) * | 2000-05-19 | 2006-01-31 | Monsanto Technology Llc | Pesticide compositions containing oxalic acid |
| US7135437B2 (en) | 2000-05-19 | 2006-11-14 | Monsanto Technology Llc | Stable liquid pesticide compositions |
| MY158895A (en) * | 2000-05-19 | 2016-11-30 | Monsanto Technology Llc | Potassium glyphosate formulations |
| US6300323B1 (en) | 2000-08-08 | 2001-10-09 | Ishihara Sangyo Kaisha, Ltd. | (Poly)ethereal ammonium salts of herbicides bearing acidic moieties and their use as herbicides |
| DE10052489A1 (de) | 2000-10-23 | 2002-05-02 | Hermania Dr Schirm Gmbh | Feste Glyphosat-Formulierung und Verfahren zur Herstellung |
| CA2480192A1 (en) * | 2002-04-01 | 2003-10-16 | Valent Biosciences, Corp. | Enhanced herbicide composition with salts of salicylates |
| WO2004019684A2 (en) * | 2002-08-31 | 2004-03-11 | Monsanto Technology Llc | Process for the preparation of a dry pesticidal composition containing a dicarbodylate component |
| US20050037924A1 (en) * | 2002-08-31 | 2005-02-17 | Monsanto Technology Llc | Sodium glyphosate compositions and process for their preparation |
| US8470741B2 (en) * | 2003-05-07 | 2013-06-25 | Croda Americas Llc | Homogeneous liquid saccharide and oil systems |
| CA2579816C (en) * | 2004-09-17 | 2014-04-29 | Monsanto Technology Llc | Glyphosate formulations with early burndown symptoms |
| US7223718B2 (en) * | 2005-03-07 | 2007-05-29 | Falcon Lab Llc | Enhanced glyphosate herbicidal concentrates |
| US20070049498A1 (en) * | 2005-09-01 | 2007-03-01 | Brigance Mickey R | Agricultural compositions which enhance performance of herbicides |
| EP2306819B1 (en) * | 2008-06-18 | 2016-03-09 | Stepan Company | Ultra-high loading glyphosate concentrate |
| BRPI0915368B1 (pt) | 2008-07-03 | 2019-01-15 | Monsanto Technology Llc | composição compreendendo glifosato ou um sal ou um ester de glifosato e método de controlar crescimento de planta |
| EP2343981B1 (en) | 2008-09-29 | 2017-08-23 | Monsanto Technology LLC | Glyphosate formulations containing amidoalkylamine surfactants |
| BRPI1016258B1 (pt) | 2009-06-30 | 2018-11-21 | Flamel Tech S A | sais derivados de n-fosfonometilglicina guanidina e composição herbicida aquosa |
| US20110071027A1 (en) * | 2009-09-18 | 2011-03-24 | Volker Heide | High strength aqueous glyphosate salt concentrates and methods |
| WO2011057361A1 (en) | 2009-11-16 | 2011-05-19 | Imtrade Australia Pty Ltd | High load glyphosate formulations |
| MX342906B (es) | 2010-10-25 | 2016-10-17 | Stepan Co | Formulaciones de glifosato basadas en composiciones derivadas de la metatesis de aceite natural. |
| AU2015284670B2 (en) | 2014-07-02 | 2018-08-30 | Stepan Company | Agricultural compositions with reduced aquatic toxicity |
| US11452289B2 (en) | 2016-05-11 | 2022-09-27 | Monsanto Technology Llc | Glyphosate formulations containing amidoalkylamine surfactants |
| WO2018031610A1 (en) | 2016-08-09 | 2018-02-15 | Monsanto Technology Llc | Solid herbicidal concentrate compositions |
| EP3628738A1 (en) | 2018-09-25 | 2020-04-01 | KWS SAAT SE & Co. KGaA | Method for controlling weed beets and other weeds |
| EP3628160A1 (en) | 2018-09-25 | 2020-04-01 | KWS SAAT SE & Co. KGaA | Use of glyphosate herbicide for controlling unwanted vegetation in beta vulgaris growing areas |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL38138A (en) * | 1970-11-19 | 1974-07-31 | Ciba Geigy Ag | Process and compositions containing thiourea derivatives for the promotion of fruit abscission |
| PH16509A (en) * | 1971-03-10 | 1983-11-08 | Monsanto Co | N-phosphonomethylglycine phytotoxicant composition |
| US3853530A (en) * | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
| US3799758A (en) * | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
-
1978
- 1978-01-03 US US05/866,677 patent/US4140513A/en not_active Expired - Lifetime
- 1978-12-27 YU YU03101/78A patent/YU310178A/xx unknown
- 1978-12-27 RO RO78115568A patent/RO89365A/ro unknown
- 1978-12-27 RO RO96069A patent/RO79038B/ro unknown
- 1978-12-28 ZA ZA00787349A patent/ZA787349B/xx unknown
- 1978-12-28 CH CH1325478A patent/CH641187A5/de not_active IP Right Cessation
- 1978-12-28 JP JP16599778A patent/JPS54109921A/ja active Granted
- 1978-12-29 NL NL7812635A patent/NL7812635A/xx unknown
- 1978-12-29 BE BE192664A patent/BE873199A/xx not_active IP Right Cessation
- 1978-12-29 ES ES476485A patent/ES476485A1/es not_active Expired
-
1979
- 1979-01-02 ZM ZM2/79A patent/ZM279A1/xx unknown
- 1979-01-02 PH PH22009A patent/PH19009A/en unknown
- 1979-01-02 PT PT69016A patent/PT69016A/pt unknown
- 1979-01-02 AR AR275038A patent/AR221857A1/es active
- 1979-01-02 AU AU43047/79A patent/AU522518B2/en not_active Ceased
- 1979-01-02 SE SE7900016A patent/SE444685B/sv not_active IP Right Cessation
- 1979-01-02 PL PL1979212563A patent/PL114405B1/pl unknown
- 1979-01-02 IT IT19009/79A patent/IT1162701B/it active
- 1979-01-02 FR FR7900052A patent/FR2413398A1/fr active Granted
- 1979-01-02 NO NO790009A patent/NO150841C/no unknown
- 1979-01-02 BR BR7900007A patent/BR7900007A/pt unknown
- 1979-01-02 BG BG7943569A patent/BG40656A3/xx unknown
- 1979-01-02 PL PL1979223647A patent/PL119534B1/pl unknown
- 1979-01-02 EG EG6/79A patent/EG13903A/xx active
- 1979-01-02 BG BG7941935A patent/BG29424A3/xx unknown
- 1979-01-02 IN IN3/CAL/79A patent/IN150741B/en unknown
- 1979-01-02 DE DE2900025A patent/DE2900025C2/de not_active Expired
- 1979-01-02 CS CS7957A patent/CS207728B2/cs unknown
- 1979-01-02 IL IL56356A patent/IL56356A/xx unknown
- 1979-01-02 DD DD79210300A patent/DD140968A5/de not_active IP Right Cessation
- 1979-01-02 AT AT0001179A patent/AT363274B/de not_active IP Right Cessation
- 1979-01-02 MW MW1/79A patent/MW179A1/xx unknown
- 1979-01-02 HU HU79MO1033A patent/HU184659B/hu not_active IP Right Cessation
- 1979-01-02 GB GB7933A patent/GB2011906B/en not_active Expired
- 1979-01-02 DK DK000979A patent/DK158356C/da not_active IP Right Cessation
- 1979-01-02 IE IE10/79A patent/IE47773B1/en unknown
- 1979-01-02 FI FI790006A patent/FI65437C/fi not_active IP Right Cessation
- 1979-01-02 CA CA000318977A patent/CA1120951A/en not_active Expired
- 1979-01-03 MX MX797623U patent/MX5697E/es unknown
-
1980
- 1980-02-08 SU SU802877858A patent/SU1050565A3/ru active
-
1983
- 1983-08-29 SG SG548/83A patent/SG54883G/en unknown
- 1983-10-27 KE KE3342A patent/KE3342A/xx unknown
-
1984
- 1984-01-05 HK HK6/84A patent/HK684A/xx unknown
- 1984-12-30 MY MY322/84A patent/MY8400322A/xx unknown
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SU1050565A3 (ru) | Способ получени натриевой соли @ -фосфонометилглицина | |
| CA1124735A (en) | Preparation of 2-aryl-propionic acids by direct coupling utilizing a mixed magnesium halide complex | |
| JPS5885893A (ja) | ７−β−〔２−（２−アミノチアゾ−ル−４−イル）−２−シン−メトキシイミノアセトアミド〕−３−（５−カルボキシメチル−４−メチル−１，３−チアゾ−ル−２−イルチオメチル）セフ−３−エム−４−カルボン酸の結晶質水溶性塩およびその製造方法 | |
| DK149473B (da) | Fremgangsmaade til fremstilling af aminomethan-phosphonsyrer | |
| JPH03135968A (ja) | トリメルカプト―ｓ―トリアジン六水和物のジナトリウム塩、その製造法および該化合物からなる、重金属を水相から分離するための沈澱剤 | |
| US3033891A (en) | Mono salts of o-hydrocarbyl-carboalkylthiol phosphonic acids | |
| SU790698A1 (ru) | Способ получени щелочных солей комплексов оксиэтилидендифосфоновой кислоты с металлами п группы | |
| NO813398L (no) | Fosfonoformaldehyd, fremgangsmaate til dets fremstilling og dets anvendelse som mellomprodukter til fremstilling av legemidler | |
| US2796321A (en) | Polychlorimidometaphosphates | |
| KR820001201B1 (ko) | N-포스포노메틸글리신의 세스퀴나트륨염의 제조방법 | |
| NO164543B (no) | Fremgangsmaate til fremstilling av n7-amidinosubstituerte mitomycin c-derivater. | |
| US2899461A (en) | Preparation of alkali metal | |
| US2764612A (en) | Process for preparing salts of glutamic acid | |
| JPH04261189A (ja) | トリフルオロメタンスルホン酸スズの製造法 | |
| US4534904A (en) | Process for producing N-phosphonomethylglycine | |
| SU1248954A1 (ru) | Способ получени карбамата кали или натри | |
| SU632694A1 (ru) | Способ получени 3-индолальдегидов | |
| US3708519A (en) | Process for the preparation of an anhydrous alkali metal salt or a p-hydroxybenzoic acid ester | |
| US2889347A (en) | Process for producing alkali metal methyl arsonates | |
| SU983042A1 (ru) | Способ получени кислых триполифосфатов кали | |
| JP3790880B2 (ja) | 新規な２，４，６−トリメルカプト−１，３，５−トリアジンのトリリチウム塩又はトリカリウム塩の水和物並びに水和物及び無水物の製造法 | |
| SU1694589A1 (ru) | Способ получени ди-(2-хлорэтиловых) эфиров алкенилфосфоновых кислот | |
| SU514814A1 (ru) | Способ получени щеелочных солей п-толилтиосульфокислоты | |
| RU1825788C (ru) | Способ получени гидрохлорида бензимидазол-2-илметилкарбамата | |
| SU854879A1 (ru) | Способ получени бората кальци |