SG11201506724VA - Metal carbene olefin metathesis two catalyst composition - Google Patents

Metal carbene olefin metathesis two catalyst composition

Info

Publication number
SG11201506724VA
SG11201506724VA SG11201506724VA SG11201506724VA SG11201506724VA SG 11201506724V A SG11201506724V A SG 11201506724VA SG 11201506724V A SG11201506724V A SG 11201506724VA SG 11201506724V A SG11201506724V A SG 11201506724VA SG 11201506724V A SG11201506724V A SG 11201506724VA
Authority
SG
Singapore
Prior art keywords
catalyst composition
olefin metathesis
metal carbene
carbene olefin
metal
Prior art date
Application number
SG11201506724VA
Other languages
English (en)
Inventor
Anthony R Stephen
Christopher J Cruce
Michael A Giardello
Original Assignee
Materia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Materia Inc filed Critical Materia Inc
Publication of SG11201506724VA publication Critical patent/SG11201506724VA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • B01J31/2278Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F132/00Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F132/08Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3325Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40Polymerisation processes
    • C08G2261/41Organometallic coupling reactions
    • C08G2261/418Ring opening metathesis polymerisation [ROMP]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Catalysts (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
SG11201506724VA 2013-02-27 2014-02-27 Metal carbene olefin metathesis two catalyst composition SG11201506724VA (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361770284P 2013-02-27 2013-02-27
US201361799827P 2013-03-15 2013-03-15
PCT/US2014/019082 WO2014134333A1 (en) 2013-02-27 2014-02-27 Metal carbene olefin metathesis two catalyst composition

Publications (1)

Publication Number Publication Date
SG11201506724VA true SG11201506724VA (en) 2015-09-29

Family

ID=51428812

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201506724VA SG11201506724VA (en) 2013-02-27 2014-02-27 Metal carbene olefin metathesis two catalyst composition

Country Status (11)

Country Link
US (2) US20140357820A1 (es)
EP (1) EP2961778A4 (es)
JP (3) JP6271595B2 (es)
KR (1) KR102211385B1 (es)
CN (1) CN105229040B (es)
BR (1) BR112015019868B1 (es)
CA (1) CA2902451C (es)
MX (1) MX2015010583A (es)
MY (2) MY188144A (es)
SG (1) SG11201506724VA (es)
WO (1) WO2014134333A1 (es)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9527982B2 (en) * 2012-12-19 2016-12-27 Materia, Inc. Storage stable adhesion promoter compositions for cyclic olefin resin compositions
US10633484B2 (en) * 2014-01-10 2020-04-28 Materia, Inc. Method and composition for improving adhesion of metathesis compositions to substrates
WO2016129608A1 (ja) * 2015-02-09 2016-08-18 旭硝子株式会社 含フッ素重合体の製造方法
CA2975259C (en) 2015-02-14 2023-03-14 Materia, Inc. Romp polymers having improved resistance to hydrocarbon fluids
US9724650B2 (en) 2015-03-31 2017-08-08 Pall Corporation Hydrophilically modified fluorinated membrane (II)
US9643130B2 (en) 2015-03-31 2017-05-09 Pall Corporation Hydrophilically modified fluorinated membrane (IV)
US9630151B2 (en) 2015-03-31 2017-04-25 Pall Corporation Hydrophilically modified fluorinated membrane (V)
US9636641B2 (en) 2015-03-31 2017-05-02 Pall Corporation Hydrophilically modified fluorinated membrane (I)
US9649603B2 (en) 2015-03-31 2017-05-16 Pall Corporation Hydrophilically modified fluorinated membrane (III)
US9849428B2 (en) 2015-04-30 2017-12-26 Pall Corporation Hydrophilically modified fluorinated membrane (VI)
US9643131B2 (en) 2015-07-31 2017-05-09 Pall Corporation Hydrophilic porous polytetrafluoroethylene membrane (I)
US10315168B2 (en) 2015-07-31 2019-06-11 Pall Corporation Hydrophilic porous polytetrafluoroethylene membrane (II)
EP3353187B1 (en) * 2015-09-24 2021-07-21 Umicore Ag & Co. Kg Metal carbene olefin metathesis catalysts
JP6737885B2 (ja) 2015-11-18 2020-08-12 プロヴィヴィ インコーポレイテッド 昆虫フェロモンの生成のための微生物及び関連する化合物
EP4234522A3 (en) 2015-11-18 2023-10-25 Provivi, Inc. Production of fatty olefin derivatives via olefin metathesis
AR110606A1 (es) 2016-06-06 2019-04-17 Provivi Inc Producción semi-biosintética de alcoholes grasos y aldehídos grasos
PL3528942T3 (pl) 2016-10-19 2021-11-08 Umicore Ag & Co. Kg Synteza i charakterystyka kompleksów ru alkylidenu
WO2018191373A1 (en) * 2017-04-12 2018-10-18 Materia, Inc. Synthesis and characterization of metathesis catalysts
CN110914442A (zh) 2017-05-17 2020-03-24 普罗维维股份有限公司 用于产生昆虫信息素及相关化合物的微生物
CN112867740A (zh) * 2018-09-20 2021-05-28 埃克森美孚化学专利公司 用于聚合环烯烃的易位催化剂体系
CN109799528B (zh) * 2019-01-17 2022-08-19 中国辐射防护研究院 用于放射性污染金属浅层取样的氧化凝胶及其制备方法
CN111393554B (zh) * 2019-05-06 2022-05-20 派迈新材料(成都)有限责任公司 一种聚双环戊二烯坯料及其制备方法
CN112724298A (zh) * 2020-02-20 2021-04-30 派迈新材料(成都)有限责任公司 一种制备高透波天线罩的热固性材料及天线罩制备方法
CN111662435A (zh) * 2020-06-16 2020-09-15 派迈新材料(成都)有限责任公司 一种绝缘基板及其制备方法和用途
CN111777701B (zh) * 2020-06-16 2022-07-22 派迈新材料(成都)有限责任公司 一种树脂组合物在制备绝缘基板或覆铜箔层压板中的用途
BR112023002624A2 (pt) * 2020-08-13 2023-04-04 Materia Inc Composições olefínicas compreendendo resinas de hidrocarboneto
CN112592635A (zh) * 2020-11-27 2021-04-02 济南大学 一种烯烃共聚物的制备及应用
CN112403525B (zh) * 2020-12-03 2021-12-31 大连理工大学 一种具有配体分子內异面结构的金属有机框架催化剂的制备方法及其应用
CN113004516B (zh) * 2021-03-09 2023-01-13 贵州大学 α,ω-多烯单体易位聚合制备聚氨酯的方法及聚氨酯
WO2022216628A1 (en) * 2021-04-06 2022-10-13 University Of Washington Cyclic ruthenium benzylidene initiators for enhanced ring‑expansion metathesis polymerization
CN114907522A (zh) * 2021-07-16 2022-08-16 派迈新材料(成都)有限责任公司 一种防止地下动物破坏的树脂组合物及其在制备燃气管道中的用途
CN115160719A (zh) * 2021-08-06 2022-10-11 派迈新材料(成都)有限责任公司 一种保温油气管道
CN113941361B (zh) * 2021-10-27 2023-11-28 山东新和成维生素有限公司 一种芳构化催化剂及其制备方法和应用
CN114146729B (zh) * 2021-11-16 2023-01-17 大赛璐(中国)投资有限公司 一种双齿卡宾催化剂载体及非均相催化剂
CN116284735B (zh) * 2023-05-04 2023-12-29 辽宁奥克药业股份有限公司 一种制备嵌段聚醚的催化剂、嵌段聚醚的制备方法

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4899005A (en) 1987-11-19 1990-02-06 The B. F. Goodrich Company Method for preparing cycloolefin copolymers with improved heat stability
US5268232A (en) * 1991-10-15 1993-12-07 Hercules Incorporated Dicyclopentadiene polymers with heat-resistant dimensional integrity and high Tg
US5312940A (en) 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
US5831108A (en) 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US5939504A (en) * 1995-12-07 1999-08-17 Advanced Polymer Technologies Method for extending the pot life of an olefin metathesis polymerization reaction
JP2000513393A (ja) 1996-04-04 2000-10-10 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 触媒混合物及び重合性組成物
US6310121B1 (en) 1996-12-02 2001-10-30 Cymetech, Llc Polymeric composites including dicyclopentadiene and related monomers
US5998326A (en) * 1997-05-23 1999-12-07 Ciba Specialty Chemicals Corp. Two-component catalyst for ROMP
US6284852B1 (en) 1997-10-30 2001-09-04 California Institute Of Technology Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
US5977393A (en) 1997-11-21 1999-11-02 California Institute Of Technology Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts
DE19815275B4 (de) 1998-04-06 2009-06-25 Evonik Degussa Gmbh Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese
US6107420A (en) 1998-07-31 2000-08-22 California Institute Of Technology Thermally initiated polymerization of olefins using Ruthenium or osmium vinylidene complexes
DE19902439A1 (de) 1999-01-22 2000-08-03 Aventis Res & Tech Gmbh & Co Homo- und heterobimetallische Alkylidenkomplexe des Rutheniums mit N-heterocyclischen Carbenliganden und deren Anwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese
JP2002536467A (ja) 1999-02-05 2002-10-29 マテリア インコーポレイテッド 様々な密度を有するポリオレフィン組成物ならびに該組成物の製造方法および使用方法
US6225488B1 (en) * 1999-04-02 2001-05-01 Nippon Zeon Co., Ltd. Ruthenium or osmium catalysts for olefin metathesis reactions
US7329758B1 (en) 1999-05-24 2008-02-12 California Institute Of Technology Imidazolidine-based metal carbene metathesis catalysts
JP2001131264A (ja) * 1999-11-01 2001-05-15 Nippon Zeon Co Ltd シクロオレフィンポリマーの製造方法
US6436476B1 (en) 2000-02-14 2002-08-20 Owens Corning Fiberglas Technology, Inc. Polyolefin fiber-reinforced composites using a fiber coating composition compatible with romp catalysts
WO2002014376A2 (en) 2000-08-10 2002-02-21 Trustees Of Boston College Recyclable metathesis catalysts
US6759537B2 (en) 2001-03-23 2004-07-06 California Institute Of Technology Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
US6838489B2 (en) 2001-03-23 2005-01-04 Cymetech, Llc High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor
JP4402354B2 (ja) * 2001-03-23 2010-01-20 カリフォルニア インスティチュート オブ テクノロジー 熱活性化n−複素環カルベン前駆体の使用により生成される高活性金属カルベンメタセシス触媒
US6613910B2 (en) 2001-04-02 2003-09-02 California Institute Of Technology One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts
AU2002307384A1 (en) 2001-04-16 2002-10-28 California Institute Of Technology Group 8 transition metal carbene complexes as enantioselective olefin metathesis catalysts
JP2002363264A (ja) * 2001-06-11 2002-12-18 Nippon Zeon Co Ltd ノルボルネン系樹脂の製造方法
CN1265882C (zh) 2001-08-01 2006-07-26 加州理工学院 六配位钌或锇金属卡宾易位催化剂
US6884859B2 (en) * 2001-08-29 2005-04-26 California Institute Of Technology Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms
AU2002357730A1 (en) 2001-11-15 2003-06-10 Materia, Inc. Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts
EP1743899B1 (en) * 2002-01-22 2009-04-22 Telene SAS Metal complexes for use in metathesis, atom transfer radical reactions, addition polymerisation and vinylation reactions, methods and intermediates for making them
WO2004009507A1 (en) 2002-07-23 2004-01-29 Ppg Industries Ohio, Inc. Glass fiber sizing compositions, sized glass fibers, and polyolefin composites
JP4997096B2 (ja) 2004-02-26 2012-08-08 テレーヌ ソシエテ パル アクシオン サンプリフィエー オレフィンメタセシスおよび原子またはグループ移動反応に使用するための金属錯体
CN101090915A (zh) * 2004-03-29 2007-12-19 加州理工学院 含有n-杂环卡宾配体的潜伏的高活性烯烃置换催化剂
US20050261451A1 (en) 2004-03-29 2005-11-24 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand
GB0514612D0 (en) 2005-07-15 2005-08-24 Sasol Technology Uk Ltd The use of a phosphorus containing ligand and a cyclic organic ligand in a metathesis catalyst
GB0517137D0 (en) 2005-08-22 2005-09-28 Viacatt N V Multicoordinated metal complexes for use in metalthesis reactions
AU2006284134A1 (en) 2005-08-22 2007-03-01 Telene S.A.S. Multicoordinated metal complexes for use in metathesis reactions
US8557921B2 (en) * 2006-08-25 2013-10-15 Dow Global Technologies Llc Production of meta-block copolymers by polymer segment interchange
WO2009020667A1 (en) * 2007-08-09 2009-02-12 Elevance Renewable Science, Inc. Chemical methods for treating a metathesis feedstock
CN102015885B (zh) * 2008-02-29 2014-08-27 日本瑞翁株式会社 固化性树脂组合物、采用其得到的成型体、预浸料以及叠层体
EP2259866A4 (en) * 2008-03-28 2016-12-07 Troy Tech Ii Inc PROCESS FOR PRODUCING A STABLE AQUEOUS DISPERSION OF FINE DIVIDED PARTICLES CONCENTRATED WITH A BIOCID
US8877936B2 (en) * 2008-04-09 2014-11-04 California Institute Of Technology Ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene ligands with substituted backbone
EP2143489A1 (de) * 2008-07-08 2010-01-13 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
US8703985B2 (en) 2008-10-04 2014-04-22 Umicore Ag & Co. Kg Method for preparation of ruthenium-indenylidene carbene catalysts
US8283410B2 (en) * 2009-03-30 2012-10-09 Isp Investments Inc. Ring-opening metathesis polymerization of norbornene and oxanorbornene moieties and uses thereof
EP2280017B1 (en) 2009-07-21 2013-01-02 Rimtec Corporation Catalytic complex for olefin metathesis reactions, process for the preparation thereof and use thereof
WO2011079439A1 (en) 2009-12-30 2011-07-07 Zannan Scitech Co., Ltd. Highly active metathesis catalysts selective for romp and rcm reactions
AU2012271297B2 (en) * 2011-06-17 2016-08-04 Materia, Inc. Adhesion promoters and gel-modifiers for olefin metathesis compositions
CN103732636B (zh) * 2011-08-12 2016-05-18 埃克森美孚化学专利公司 通过开环/交叉易位制备的聚合物

Also Published As

Publication number Publication date
BR112015019868B1 (pt) 2020-06-09
US20140357820A1 (en) 2014-12-04
US20160185885A1 (en) 2016-06-30
WO2014134333A1 (en) 2014-09-04
CA2902451C (en) 2021-05-25
EP2961778A4 (en) 2016-10-05
JP6271595B2 (ja) 2018-01-31
JP2019203130A (ja) 2019-11-28
KR102211385B1 (ko) 2021-02-03
JP2016511789A (ja) 2016-04-21
MY188144A (en) 2021-11-23
JP6607913B2 (ja) 2019-11-20
BR112015019868A2 (pt) 2017-07-18
MY191997A (en) 2022-07-22
MX2015010583A (es) 2016-04-07
KR20150122208A (ko) 2015-10-30
CN105229040B (zh) 2017-05-31
JP2018087338A (ja) 2018-06-07
JP6840191B2 (ja) 2021-03-10
CN105229040A (zh) 2016-01-06
CA2902451A1 (en) 2014-09-04
EP2961778A1 (en) 2016-01-06

Similar Documents

Publication Publication Date Title
SG11201506724VA (en) Metal carbene olefin metathesis two catalyst composition
PL3008078T3 (pl) Katalizatory do wydajnej, Z-selektywnej metatezy
ZA201605136B (en) Continuous ethylene oligomerization with in-situ catalyst preparation
BR112015017202A2 (pt) compostos catalisadores automotivos com uma camada de dois metais
GB201322494D0 (en) Catalyst layer
IL259758A (en) Metathesis catalysts of studios
PL2976387T3 (pl) Kompozycja polipropylenowa wypełniona materiałem mineralnym
ZA201508187B (en) Catalyst
EP2903996A4 (en) PHOTOINITIATED OLEFIN METATHESIS POLYMERIZATION
EP2816578A4 (en) COMMERCIAL VEHICLE
SG11201705448VA (en) Catalyst system for olefin metathesis
GB2513597B (en) SIP signalling
ZA201504907B (en) Cross metathesis process
GB201302016D0 (en) Catalyst
HRP20181183T1 (hr) Biciklički spoj koji sadrži sumpor
ZA201401537B (en) Straddle type vehicle
HUE061030T2 (hu) Metatézis katalizátorok
GB201204715D0 (en) Metathesis of olefins using ruthenium-based catalytic complexes
GB2511396B (en) Pre-turbocharger catalyst
PL2956559T3 (pl) Konwerter przechylny
GB201305858D0 (en) Catalyst composition
PL3353187T3 (pl) Katalizatory metatezy olefin na bazie karbenu metalu
GB201321230D0 (en) Catalysts
GB201321216D0 (en) Hydraulic switch
HRP20170949T1 (hr) Triciklički triazolski spojevi kao ligandi sigma receptora