SA519410620B1 - عملية لتحضير ميثاكرولين - Google Patents

عملية لتحضير ميثاكرولين

Info

Publication number
SA519410620B1
SA519410620B1 SA519410620A SA519410620A SA519410620B1 SA 519410620 B1 SA519410620 B1 SA 519410620B1 SA 519410620 A SA519410620 A SA 519410620A SA 519410620 A SA519410620 A SA 519410620A SA 519410620 B1 SA519410620 B1 SA 519410620B1
Authority
SA
Saudi Arabia
Prior art keywords
preparing methacrolein
methacrolein
preparing
methanol
processes
Prior art date
Application number
SA519410620A
Other languages
English (en)
Inventor
جينسو أكسيو،
ريتام تشاكرابارتي،
مارك أيه. سيلفانو،
ديمتري أيه. كرابتشيتوف،
Original Assignee
روم أند هاس كومباني
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by روم أند هاس كومباني filed Critical روم أند هاس كومباني
Publication of SA519410620B1 publication Critical patent/SA519410620B1/ar

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/20Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22Acryaldehyde; Methacryaldehyde
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/75Reactions with formaldehyde
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78Separation; Purification; Stabilisation; Use of additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78Separation; Purification; Stabilisation; Use of additives
    • C07C45/81Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03Monocarboxylic acids
    • C07C57/04Acrylic acid; Methacrylic acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/40Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

يتم توفير عملية لتحضير ميثاكرولين مما يزيد من احتجاز الميثانول لأقصى حد. كما يتم توفير عمليات لإنتاج حمض ميثاكريليك methacrylic acid وميثيل ميثاكريلات methyl methacrylate. [الشكل 1]
SA519410620A 2017-05-25 2019-11-23 عملية لتحضير ميثاكرولين SA519410620B1 (ar)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762510984P 2017-05-25 2017-05-25
PCT/US2018/034272 WO2018217962A1 (en) 2017-05-25 2018-05-24 Process for preparing methacrolein

Publications (1)

Publication Number Publication Date
SA519410620B1 true SA519410620B1 (ar) 2022-04-27

Family

ID=62599717

Family Applications (3)

Application Number Title Priority Date Filing Date
SA519410409A SA519410409B1 (ar) 2017-05-25 2019-10-29 عملية لتحضير ميثاكرولين
SA519410588A SA519410588B1 (ar) 2017-05-25 2019-11-18 عملية لتحضير ميثاكرولين
SA519410620A SA519410620B1 (ar) 2017-05-25 2019-11-23 عملية لتحضير ميثاكرولين

Family Applications Before (2)

Application Number Title Priority Date Filing Date
SA519410409A SA519410409B1 (ar) 2017-05-25 2019-10-29 عملية لتحضير ميثاكرولين
SA519410588A SA519410588B1 (ar) 2017-05-25 2019-11-18 عملية لتحضير ميثاكرولين

Country Status (10)

Country Link
US (3) US10836699B2 (ar)
EP (3) EP3630713B1 (ar)
JP (3) JP7000455B2 (ar)
KR (3) KR102602124B1 (ar)
CN (3) CN110573484B (ar)
BR (1) BR112019023830B1 (ar)
CA (3) CA3064746A1 (ar)
MX (3) MX2019013943A (ar)
SA (3) SA519410409B1 (ar)
WO (3) WO2018217961A1 (ar)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3786146A1 (de) * 2019-08-30 2021-03-03 Röhm GmbH Verfahren zur herstellung von methacrolein aus formaldehyd und propionaldehyd sowie herstellanlage hierfür
EP3786147A1 (de) 2019-08-30 2021-03-03 Röhm GmbH Verfahren zur herstellung von methacrolein aus formaldehyd und propionaldehyd sowie herstellanlage hierfür
WO2023031386A1 (de) 2021-09-06 2023-03-09 Röhm Gmbh Optimierte katalysatoraufarbeitung und -recycling bei der synthese von methacrolein

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3821286A (en) 1971-10-05 1974-06-28 American Cyanamid Co Process for the production of methyl methacrylate
JPS51136611A (en) * 1975-05-23 1976-11-26 Asahi Glass Co Ltd Separation and recovery of unsaturated aldehyde and/or unsaturated car boxylic acid
DE2848369C3 (de) 1977-11-17 1981-08-06 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
JPS55105645A (en) * 1979-02-07 1980-08-13 Toyo Soda Mfg Co Ltd Continuous esterification of methacrylic acid
DE3018071C2 (de) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
US4427486A (en) 1981-12-24 1984-01-24 Polaroid Corporation Apparatus for mounting transparency film
DE3213681A1 (de) * 1982-04-14 1983-10-27 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von (alpha)-alkylacroleinen
US4716250A (en) 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands
US4731486A (en) 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
JPH0798765B2 (ja) * 1988-09-17 1995-10-25 財団法人相模中央化学研究所 アルデヒドの製造方法
JPH03176439A (ja) * 1989-12-04 1991-07-31 Asahi Chem Ind Co Ltd イソブタンおよびメタクロレインの回収方法
US5087763A (en) 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
GB9207756D0 (en) * 1992-04-07 1992-05-27 Davy Mckee London Process
US5288916A (en) 1993-03-25 1994-02-22 Bend Research, Inc. Enantiomeric resolution of 4-(3,4-dichlorophenyl)-3,4-dihydro-1(2H)-naphthalenone
USRE38283E1 (en) 1995-07-18 2003-10-21 Asahi Kasei Kabushiki Kaisha Catalyst for use in producing carboxylic esters
JPH09216850A (ja) 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd カルボン酸エステルの製造方法
TW385304B (en) 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
JP3681285B2 (ja) * 1997-07-08 2005-08-10 旭化成ケミカルズ株式会社 メタクリル酸メチルの製造方法
JP4091766B2 (ja) * 2001-12-27 2008-05-28 三菱レイヨン株式会社 メタクロレインの製造方法
US7141702B2 (en) 2004-03-26 2006-11-28 Council Of Scientific And Industrial Research Process for the synthesis of α-substituted acroleins
JP4756890B2 (ja) 2005-03-29 2011-08-24 日本化薬株式会社 メタクリル酸製造用触媒及びその製造方法
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
JP5768326B2 (ja) * 2010-04-22 2015-08-26 三菱レイヨン株式会社 触媒の製造方法およびメタクリル酸の製造方法
CN102050710B (zh) * 2010-11-29 2013-07-17 烟台万华聚氨酯股份有限公司 一种同时制备2-甲基丙烯醛和2-甲基-2-戊烯醛的方法
JP5903878B2 (ja) * 2011-12-21 2016-04-13 東ソー株式会社 1,3−ブタジエン及びメタクロレインの製造方法
US20140206897A1 (en) 2013-01-22 2014-07-24 Saudi Basic Industries Corporation Method for making methyl methacrylate from propionaldehyde and formaldehyde via oxidative esterification
WO2014157040A1 (ja) 2013-03-28 2014-10-02 日本化薬株式会社 メタクリル酸製造用触媒及びその製造方法並びにメタクリル酸の製造方法
JP6501754B2 (ja) 2013-04-19 2019-04-17 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングEvonik Roehm GmbH メチルメタクリレートの製造方法
EP3024811B1 (de) 2013-07-24 2019-11-20 Röhm GmbH Kreislaufführung und entsorgung der wässrigen katalysatorlösung bei aminkatalytischen prozessen
EP2829531A1 (de) 2013-07-24 2015-01-28 Evonik Industries AG Verfahren zur Regulierung des Wassergehalts in einem kontinuierlichen Verfahren zur Herstellung von Methacrolein
KR102282531B1 (ko) * 2013-09-26 2021-07-27 룀 게엠베하 메타크롤레인의 생산 및 직접 산화적 에스테르화를 위한 그의 조건화/배수 방법
US9751822B2 (en) 2013-10-10 2017-09-05 Nippon Kayaku Kabushiki Kaisha Method for producing unsaturated carboxylic acid and supported catalyst
JP6382969B2 (ja) * 2013-10-28 2018-08-29 ローム アンド ハース カンパニーRohm And Haas Company メタクロレインを分離するための方法
EP2998284A1 (de) * 2014-09-18 2016-03-23 Evonik Röhm GmbH Optimiertes Verfahren zur Herstellung von Methacrolein
EP3023408A1 (de) * 2014-11-19 2016-05-25 Evonik Röhm GmbH Optimiertes Verfahren zur Herstellung von Methacrylsäure
EP3144291A1 (de) 2015-09-16 2017-03-22 Evonik Röhm GmbH Synthese von methacrylsäure aus auf methacrolein basierenden alkylmethacrylat
EP3630711B1 (en) 2017-05-25 2021-03-17 Rohm and Haas Company Process for preparing methacrolein

Also Published As

Publication number Publication date
CN110650940B (zh) 2023-02-17
EP3630712B1 (en) 2021-04-07
CN110650940A (zh) 2020-01-03
MX2019013522A (es) 2020-02-13
KR102567203B1 (ko) 2023-08-16
KR20200015554A (ko) 2020-02-12
MX2019013943A (es) 2020-01-30
BR112019022639A2 (pt) 2020-05-19
CA3064746A1 (en) 2018-11-29
JP7009511B2 (ja) 2022-02-10
BR112019024370A2 (pt) 2020-06-09
MX2019013569A (es) 2019-12-18
CA3064431A1 (en) 2018-11-29
US20200157032A1 (en) 2020-05-21
BR112019023830A2 (pt) 2020-06-09
JP7000455B2 (ja) 2022-02-04
US10836699B2 (en) 2020-11-17
EP3630713B1 (en) 2021-02-17
US20200140363A1 (en) 2020-05-07
KR102602124B1 (ko) 2023-11-14
CN110612280B (zh) 2022-11-01
US10723685B2 (en) 2020-07-28
EP3630712A1 (en) 2020-04-08
US20210403404A1 (en) 2021-12-30
KR20200010310A (ko) 2020-01-30
CN110612280A (zh) 2019-12-24
KR20200015539A (ko) 2020-02-12
EP3630713A1 (en) 2020-04-08
CA3064745A1 (en) 2018-11-29
SA519410588B1 (ar) 2021-11-03
JP2020521733A (ja) 2020-07-27
JP7000457B2 (ja) 2022-02-04
KR102602120B1 (ko) 2023-11-14
CN110573484A (zh) 2019-12-13
BR112019023830B1 (pt) 2023-02-28
WO2018217961A1 (en) 2018-11-29
CN110573484B (zh) 2022-11-01
JP2020521727A (ja) 2020-07-27
EP3630710B1 (en) 2021-02-17
EP3630710A1 (en) 2020-04-08
US11401229B2 (en) 2022-08-02
WO2018217962A1 (en) 2018-11-29
SA519410409B1 (ar) 2021-07-05
WO2018217963A1 (en) 2018-11-29
JP2020521737A (ja) 2020-07-27

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