RU99107976A - Конденсационные сополимеры, поглощающие кислород, для изготовления бутылок и упаковок - Google Patents
Конденсационные сополимеры, поглощающие кислород, для изготовления бутылок и упаковокInfo
- Publication number
- RU99107976A RU99107976A RU99107976/04A RU99107976A RU99107976A RU 99107976 A RU99107976 A RU 99107976A RU 99107976/04 A RU99107976/04 A RU 99107976/04A RU 99107976 A RU99107976 A RU 99107976A RU 99107976 A RU99107976 A RU 99107976A
- Authority
- RU
- Russia
- Prior art keywords
- oxygen
- copolymers according
- segments
- oligoolefin
- copolymers
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title claims 21
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 title claims 14
- 229910052760 oxygen Inorganic materials 0.000 title claims 14
- 239000001301 oxygen Substances 0.000 title claims 14
- 230000005494 condensation Effects 0.000 title 1
- 238000009833 condensation Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000728 polyester Polymers 0.000 claims 5
- 239000000126 substance Substances 0.000 claims 3
- 239000005062 Polybutadiene Substances 0.000 claims 2
- 238000010521 absorption reaction Methods 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 230000000875 corresponding Effects 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 239000005022 packaging material Substances 0.000 claims 2
- 229920002857 polybutadiene Polymers 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-Methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 1
- 229920001634 Copolyester Polymers 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000004806 packaging method and process Methods 0.000 claims 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims 1
- 229920002239 polyacrylonitrile Polymers 0.000 claims 1
- 238000006068 polycondensation reaction Methods 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- -1 polypropylene Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
Claims (19)
1. Поликонденсационные сополимеры, способные поглощать кислород в твердом состоянии при температурах ниже температуры их стеклования, состоящие, в основном, из сегментов полиэфира и сегментов олигоолефина в количестве, обеспечивающем способность поглощать кислород, причем олигоолефин выбран из группы, включающей полипропилен, поли(4-метил)-1-пентен, негидрированный полибутадиен и их смеси, и его мол.вес находится в пределах от 100 до 10 000.
2. Сополимеры по п. 1, отличающиеся тем, что олигоолефин представляет собой негидрированный полибутадиен.
3. Сополимеры по п. 1, отличающиеся тем, что мол.вес олигоолефина находится в пределах от 1 000 до 3 000.
4. Сополимеры по п. 1, отличающиеся тем, что размер поперечного сечения сегментов олигоолефина преимущественно находится в области менее, примерно, 3000 ангстрем.
5. Сополимеры по п. 1, отличающиеся тем, что после получения из них биаксиально ориентированной 2,5 х 4,0 пленки толщиной 1 - 10 мил (0,0025 - 0,25 см) они имеют прозрачность, равную, по меньшей мере, 70% от соответствующего показателя для таким же образом ориентированных пленок такой же толщины из немодифицированного полиэфира, на основе которого получены сегменты полиэфира, причем указанная величина, равная 70%, измерена при длине волны света, равной 400-800 нм.
6. Сополимеры по п. 1, отличающиеся тем, что сегменты олигоолефина составляют 0,5 - 12% от веса сополимера.
7. Сополимеры по п. 1, отличающиеся тем, что сегменты олигоолефина составляют 2 - 8% от веса сополимера.
8. Сополимеры по п. 1, отличающиеся тем, что сегменты полиэфира представляют собой элементарные звенья, выбранные из группы, состоящей из звеньев формулы IV и формулы V, где n в каждой из формул IV и V имеет значение 2-4.
10. Сополимеры по п. 1, отличающиеся тем, что они дополнительно содержат катализатор окисления.
11. Способ защиты чувствительных к кислороду веществ от разложения под действием кислорода, отличающийся тем, что он включает упаковку указанных чувствительных к кислороду веществ в соответствующее изделие, изготовленное из сополимеров по п. 1 в количестве, достаточном для обеспечения защиты от кислорода.
12. Способ по п. 11, отличающийся тем, что указанное изделие дополнительно содержит катализатор на основе переходного металла, повышающий скорость поглощения кислорода.
13. Способ по п. 11, отличающийся тем, что указанное изделие дополнительно содержит фотоактивные вещества, способные поглощать кислород при облучении УФ-светом, достаточном для их активации и повышения скорости поглощения кислорода.
14. Контейнеры, защищающие от кислорода, включающие один или несколько слоев, выполненных из сополимеров по п. 1.
15. Контейнеры по п. 14, отличающиеся тем, что они включают внутренний слой из сополимеров по п. 1, расположенный между слоями из полиэфира.
16. Контейнеры по п. 14, отличающиеся тем, что сополимер содержит сегменты из сополиэфира, выбранного из группы, состоящей из ПЭТ и ПЭН.
17. Контейнеры, защищающие от кислорода, выполненные из смеси сополимеров по п. 1 с поликонденсатами.
18. Упаковочные материалы, защищающие от кислорода, включающие один или несколько слоев из сополимеров по п. 1.
19. Упаковочные материалы по п. 18, отличающиеся тем, что указанный сополимер содержит сегменты полиэфира, выбранного из группы, состоящей из ПЭТ и ПЭН.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/717,370 | 1996-09-23 | ||
US08/717,370 US6083585A (en) | 1996-09-23 | 1996-09-23 | Oxygen scavenging condensation copolymers for bottles and packaging articles |
Publications (2)
Publication Number | Publication Date |
---|---|
RU99107976A true RU99107976A (ru) | 2001-01-27 |
RU2182157C2 RU2182157C2 (ru) | 2002-05-10 |
Family
ID=24881757
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU99107976/04A RU2182157C2 (ru) | 1996-09-23 | 1997-09-22 | Конденсационные сополимеры, поглощающие кислород, для изготовления бутылок и упаковок |
RU2000110132/13A RU2198123C2 (ru) | 1996-09-23 | 1998-02-17 | Слоистый материал, защищающий от кислорода, способ защиты продукта и упаковочное изделие с его использованием, материал, поглощающий кислород |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2000110132/13A RU2198123C2 (ru) | 1996-09-23 | 1998-02-17 | Слоистый материал, защищающий от кислорода, способ защиты продукта и упаковочное изделие с его использованием, материал, поглощающий кислород |
Country Status (23)
Country | Link |
---|---|
US (5) | US6083585A (ru) |
EP (1) | EP0927218B1 (ru) |
JP (1) | JP3657275B2 (ru) |
KR (1) | KR100495207B1 (ru) |
CN (1) | CN1097067C (ru) |
AR (1) | AR008475A1 (ru) |
AU (1) | AU718541B2 (ru) |
BR (1) | BR9711522A (ru) |
CA (1) | CA2266402C (ru) |
CZ (1) | CZ298554B6 (ru) |
DE (1) | DE69701637T2 (ru) |
DK (1) | DK0927218T3 (ru) |
ES (1) | ES2147457T3 (ru) |
HK (1) | HK1020746A1 (ru) |
ID (1) | ID19778A (ru) |
IL (3) | IL160186A0 (ru) |
MY (1) | MY138894A (ru) |
NO (1) | NO325609B1 (ru) |
NZ (1) | NZ334570A (ru) |
RU (2) | RU2182157C2 (ru) |
UA (2) | UA56190C2 (ru) |
WO (1) | WO1998012244A1 (ru) |
ZA (1) | ZA978062B (ru) |
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