RU99106200A - Способ получения углерода (варианты) - Google Patents
Способ получения углерода (варианты)Info
- Publication number
- RU99106200A RU99106200A RU99106200/12A RU99106200A RU99106200A RU 99106200 A RU99106200 A RU 99106200A RU 99106200/12 A RU99106200/12 A RU 99106200/12A RU 99106200 A RU99106200 A RU 99106200A RU 99106200 A RU99106200 A RU 99106200A
- Authority
- RU
- Russia
- Prior art keywords
- carbon
- producing carbon
- catalyst
- sio
- transition metal
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims 13
- 229910052799 carbon Inorganic materials 0.000 title claims 13
- 238000004519 manufacturing process Methods 0.000 title claims 6
- 239000003054 catalyst Substances 0.000 claims 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims 4
- 229910052723 transition metal Inorganic materials 0.000 claims 4
- 150000003624 transition metals Chemical class 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 3
- 150000004703 alkoxides Chemical class 0.000 claims 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 2
- 239000001569 carbon dioxide Substances 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 239000008187 granular material Substances 0.000 claims 2
- 239000012495 reaction gas Substances 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- 150000001722 carbon compounds Chemical class 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 238000003980 solgel method Methods 0.000 claims 1
Claims (7)
1. Способ получения углерода путем приведения реакционного газа, содержащего, по меньшей мере, диоксид углерода, и восстановительного газа в контакт с катализатором на основе переходного металла при заданной температуре реакции 400 - 900°С и восстановления указанного диоксида углерода таким путем с осаждением углерода на поверхности указанного катализатора.
2. Способ получения углерода по п. 1, в котором указанный восстановительный газ является водородом.
3. Способ получения углерода по п. 1, в котором указанный катализатор на основе переходного металла представляет Ni/SiO2 в виде гранул, образованный из Ni, нанесенного на двуокись кремния, полученный алкоксидным способом.
4. Способ получения углерода по п. 1, в котором указанный катализатор на основе переходного металла представляет Co/SiO2 в форме гранул, образованный из Co, нанесенного на двуокись кремния, полученный алкоксидным способом.
5. Способ получения углерода путем приведения реакционного газа, содержащего углеродное соединение, в контакт с катализатором на основе переходного металла при заданной температуре реакции 400 - 900°С, с осаждением таким путем углерода на поверхности указанного катализатора, для получения углерода, имеющего другую структуру мелких частиц, путем изменения условия осаждения углерода.
6. Способ получения углерода по п. 5, в котором, в качестве указанного условия осаждения углерода, меняют тип указанного катализатора.
7. Способ получения углерода по п. 6, в котором указанный катализатор выбирают из Ni/SiO2 и Co/SiO2 в форме гранул, полученных способом золь-гель и нанесенных на двуокись кремния.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10-098419 | 1998-03-25 | ||
| JP9841998 | 1998-03-25 | ||
| JP10-242786 | 1998-08-28 | ||
| JP24278698A JP3415038B2 (ja) | 1998-03-25 | 1998-08-28 | カーボンの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU99106200A true RU99106200A (ru) | 2000-12-27 |
| RU2213050C2 RU2213050C2 (ru) | 2003-09-27 |
Family
ID=26439594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU99106200/12A RU2213050C2 (ru) | 1998-03-25 | 1999-03-24 | Способ получения углерода |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6261532B1 (ru) |
| EP (1) | EP0945402B1 (ru) |
| JP (1) | JP3415038B2 (ru) |
| CN (1) | CN1133580C (ru) |
| DE (1) | DE69908998T2 (ru) |
| RU (1) | RU2213050C2 (ru) |
Families Citing this family (63)
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| EP1115655B1 (en) * | 1998-09-18 | 2006-11-22 | William Marsh Rice University | Catalytic growth of single-wall carbon nanotubes from metal particles |
| JP4211882B2 (ja) * | 1999-05-24 | 2009-01-21 | 財団法人地球環境産業技術研究機構 | 炭素製造用触媒 |
| US20030091496A1 (en) | 2001-07-23 | 2003-05-15 | Resasco Daniel E. | Method and catalyst for producing single walled carbon nanotubes |
| US7816709B2 (en) | 1999-06-02 | 2010-10-19 | The Board Of Regents Of The University Of Oklahoma | Single-walled carbon nanotube-ceramic composites and methods of use |
| US6333016B1 (en) | 1999-06-02 | 2001-12-25 | The Board Of Regents Of The University Of Oklahoma | Method of producing carbon nanotubes |
| US6919064B2 (en) | 2000-06-02 | 2005-07-19 | The Board Of Regents Of The University Of Oklahoma | Process and apparatus for producing single-walled carbon nanotubes |
| US6413487B1 (en) | 2000-06-02 | 2002-07-02 | The Board Of Regents Of The University Of Oklahoma | Method and apparatus for producing carbon nanotubes |
| CN100457609C (zh) * | 2000-11-13 | 2009-02-04 | 国际商业机器公司 | 单壁碳纳米管的制造方法及应用 |
| KR100444140B1 (ko) * | 2000-11-24 | 2004-08-09 | 주식회사 동운인터내셔널 | 고성능 이차전지용 도전재 및 이를 이용한 이차전지 |
| KR100444141B1 (ko) * | 2000-11-24 | 2004-08-09 | 주식회사 동운인터내셔널 | 리튬 이차전지용 음극 활물질, 이를 이용한 음극판 및이차전지 |
| JP4872154B2 (ja) * | 2000-12-28 | 2012-02-08 | 株式会社島津製作所 | 微細中空状炭素の製造方法 |
| ITMI20010068A1 (it) * | 2001-01-16 | 2002-07-16 | Getters Spa | Sistemi per la conversione di acqua in gas non ossidanti e dispositivi elettronici che li contengono |
| US6649431B2 (en) * | 2001-02-27 | 2003-11-18 | Ut. Battelle, Llc | Carbon tips with expanded bases grown with simultaneous application of carbon source and etchant gases |
| FR2826646B1 (fr) * | 2001-06-28 | 2004-05-21 | Toulouse Inst Nat Polytech | Procede de fabrication selective de nanotubes de carbone ordonne en lit fluidise |
| US6643165B2 (en) | 2001-07-25 | 2003-11-04 | Nantero, Inc. | Electromechanical memory having cell selection circuitry constructed with nanotube technology |
| US6574130B2 (en) | 2001-07-25 | 2003-06-03 | Nantero, Inc. | Hybrid circuit having nanotube electromechanical memory |
| US6706402B2 (en) | 2001-07-25 | 2004-03-16 | Nantero, Inc. | Nanotube films and articles |
| US6835591B2 (en) | 2001-07-25 | 2004-12-28 | Nantero, Inc. | Methods of nanotube films and articles |
| KR20030033152A (ko) * | 2001-10-17 | 2003-05-01 | 남기석 | 관형 촉매 반응기를 이용한 탄소나노튜브의 대량생산 |
| US6784028B2 (en) | 2001-12-28 | 2004-08-31 | Nantero, Inc. | Methods of making electromechanical three-trace junction devices |
| CA2584508A1 (en) * | 2002-05-09 | 2003-11-09 | Institut National De La Recherche Scientifique | Method for producing single-wall carbon nanotubes |
| KR100473621B1 (ko) * | 2002-05-31 | 2005-03-10 | 한국전기연구원 | 리튬이차전지의 전극제조방법 및 이를 이용한리튬이차전지 |
| US7829622B2 (en) | 2002-06-19 | 2010-11-09 | The Board Of Regents Of The University Of Oklahoma | Methods of making polymer composites containing single-walled carbon nanotubes |
| GB0216654D0 (en) * | 2002-07-17 | 2002-08-28 | Univ Cambridge Tech | CVD Synthesis of carbon nanoutubes |
| KR100475254B1 (ko) * | 2002-08-28 | 2005-03-10 | 주식회사 동운인터내셔널 | 신규 구조의 섬유상 탄소 |
| WO2004046030A1 (en) * | 2002-11-15 | 2004-06-03 | Mgill University | Method for producing carbon nanotubes using a dc non-transferred thermal plasma torch |
| KR100500210B1 (ko) * | 2002-11-20 | 2005-07-11 | 한국화학연구원 | 기계화학적으로 처리된 촉매를 사용하는 탄소 나노튜브의제조방법 |
| CN100411980C (zh) * | 2003-09-30 | 2008-08-20 | 鸿富锦精密工业（深圳）有限公司 | 控制碳纳米管生长密度的方法 |
| US20050112050A1 (en) * | 2003-11-21 | 2005-05-26 | Pradhan Bhabendra K. | Process to reduce the pre-reduction step for catalysts for nanocarbon synthesis |
| CA2549850A1 (en) | 2004-01-09 | 2005-08-04 | Leandro Balzano | Carbon nanotube pastes and methods of use |
| JP4604563B2 (ja) | 2004-06-08 | 2011-01-05 | 住友電気工業株式会社 | カーボンナノ構造体の製造方法 |
| US7500974B2 (en) * | 2005-06-28 | 2009-03-10 | Covidien Ag | Electrode with rotatably deployable sheath |
| KR101289256B1 (ko) | 2005-06-28 | 2013-07-24 | 더 보드 오브 리젠츠 오브 더 유니버시티 오브 오클라호마 | 탄소 나노튜브의 성장 및 수득 방법 |
| EP2419553A4 (en) | 2009-04-17 | 2014-03-12 | Seerstone Llc | PROCESS FOR PRODUCING SOLID CARBON BY REDUCING CARBON OXIDES |
| US10005672B2 (en) | 2010-04-14 | 2018-06-26 | Baker Hughes, A Ge Company, Llc | Method of forming particles comprising carbon and articles therefrom |
| US9205531B2 (en) | 2011-09-16 | 2015-12-08 | Baker Hughes Incorporated | Methods of fabricating polycrystalline diamond, and cutting elements and earth-boring tools comprising polycrystalline diamond |
| JP5572874B2 (ja) * | 2010-11-16 | 2014-08-20 | 学校法人早稲田大学 | カーボンナノチューブの製造方法 |
| RU2014114867A (ru) | 2011-09-16 | 2015-10-27 | Бейкер Хьюз Инкорпорейтед | Способы изготовления поликристаллического алмаза, а также режущих элементов и буровых инструментов, содержащих поликристаллический алмаз |
| JP2013201058A (ja) * | 2012-03-26 | 2013-10-03 | Toyota Motor Corp | 非水電解質二次電池用の負極活物質、及び非水電解質二次電池 |
| JP2013218817A (ja) * | 2012-04-05 | 2013-10-24 | Toyota Motor Corp | 非水電解質二次電池用の負極活物質、及び非水電解質二次電池 |
| CN104321274B (zh) * | 2012-04-16 | 2017-04-26 | 赛尔斯通股份有限公司 | 用于在碳氧化物催化转化器中使用金属催化剂的方法 |
| NO2749379T3 (ru) | 2012-04-16 | 2018-07-28 | ||
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| MX2014012548A (es) | 2012-04-16 | 2015-04-10 | Seerstone Llc | Metodos y estructuras para reducir oxidos de carbono con catalizadores no ferrosos. |
| CN104411629B (zh) * | 2012-04-16 | 2016-08-24 | 赛尔斯通股份有限公司 | 用于产生固体碳纳米管、固体碳簇和林状物的方法和反应器 |
| US9896341B2 (en) | 2012-04-23 | 2018-02-20 | Seerstone Llc | Methods of forming carbon nanotubes having a bimodal size distribution |
| CN104619637B (zh) | 2012-07-12 | 2017-10-03 | 赛尔斯通股份有限公司 | 包含碳纳米管的固体碳产物以及其形成方法 |
| US10815124B2 (en) | 2012-07-12 | 2020-10-27 | Seerstone Llc | Solid carbon products comprising carbon nanotubes and methods of forming same |
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| WO2014111862A1 (en) | 2013-01-17 | 2014-07-24 | Saudi Basic Industries Coporation | Carbon nano-tube production from carbon dioxide |
| WO2014151144A1 (en) | 2013-03-15 | 2014-09-25 | Seerstone Llc | Carbon oxide reduction with intermetallic and carbide catalysts |
| US10115844B2 (en) | 2013-03-15 | 2018-10-30 | Seerstone Llc | Electrodes comprising nanostructured carbon |
| EP3114077A4 (en) | 2013-03-15 | 2017-12-27 | Seerstone LLC | Methods of producing hydrogen and solid carbon |
| EP3129135A4 (en) | 2013-03-15 | 2017-10-25 | Seerstone LLC | Reactors, systems, and methods for forming solid products |
| US9586823B2 (en) | 2013-03-15 | 2017-03-07 | Seerstone Llc | Systems for producing solid carbon by reducing carbon oxides |
| CN104085880B (zh) * | 2014-07-30 | 2016-08-24 | 四川大学 | 一种由二氧化碳转化制备固体碳的方法 |
| US11752459B2 (en) | 2016-07-28 | 2023-09-12 | Seerstone Llc | Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same |
| JP7254809B2 (ja) * | 2017-09-18 | 2023-04-10 | ウェスト バージニア ユニバーシティ | 調整可能な根元成長多層カーボンナノチューブ用の触媒とプロセス |
| CN108502868A (zh) * | 2018-03-14 | 2018-09-07 | 四川大学 | 一种将co2转换为表面富含含氧基团的碳纳米管的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4572813A (en) * | 1983-09-06 | 1986-02-25 | Nikkiso Co., Ltd. | Process for preparing fine carbon fibers in a gaseous phase reaction |
| JPS63159210A (ja) * | 1986-08-22 | 1988-07-02 | Mitsubishi Heavy Ind Ltd | 炭酸ガスの分解方法 |
| JPH01317110A (ja) * | 1988-06-17 | 1989-12-21 | Nippon Steel Corp | 高純度カーボン微粒子の製造方法 |
| JP2746495B2 (ja) * | 1992-01-23 | 1998-05-06 | 株式会社日立製作所 | 二酸化炭素の変換方法及び装置 |
| US5780101A (en) * | 1995-02-17 | 1998-07-14 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Method for producing encapsulated nanoparticles and carbon nanotubes using catalytic disproportionation of carbon monoxide |
| CN1061706C (zh) * | 1996-06-19 | 2001-02-07 | 中国科学院金属研究所 | 一种气相生长纳米碳纤维的制备方法 |
-
1998
- 1998-08-28 JP JP24278698A patent/JP3415038B2/ja not_active Expired - Fee Related
-
1999
- 1999-03-03 EP EP99104291A patent/EP0945402B1/en not_active Expired - Lifetime
- 1999-03-03 DE DE69908998T patent/DE69908998T2/de not_active Expired - Fee Related
- 1999-03-19 CN CNB991030656A patent/CN1133580C/zh not_active Expired - Fee Related
- 1999-03-23 US US09/274,249 patent/US6261532B1/en not_active Expired - Fee Related
- 1999-03-24 RU RU99106200/12A patent/RU2213050C2/ru active
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