RU2731442C2 - Получение полимеров на основе пропилена с высоким содержанием сомономера - Google Patents

Получение полимеров на основе пропилена с высоким содержанием сомономера Download PDF

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RU2731442C2
RU2731442C2 RU2016124223A RU2016124223A RU2731442C2 RU 2731442 C2 RU2731442 C2 RU 2731442C2 RU 2016124223 A RU2016124223 A RU 2016124223A RU 2016124223 A RU2016124223 A RU 2016124223A RU 2731442 C2 RU2731442 C2 RU 2731442C2
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propylene
reactor
catalyst
based polymer
fluidized bed
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RU2016124223A
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Russian (ru)
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RU2016124223A (ru
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Пин ЦАЙ
ЭГМОНД Ян В. ВАН
Джеффри Д. ГОУД
Мэттью Дж. ФЕДЕК
Чай-Дзинг ЧОУ
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У.Р. Грейс Энд Ко.-Конн
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C08F4/6022—Component of C08F4/60 containing at least two different metals
    • C08F4/6026—Component of C08F4/60 containing at least two different metals containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6493—Catalysts containing a specific non-metal or metal-free compound organic containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
RU2016124223A 2013-11-21 2014-11-21 Получение полимеров на основе пропилена с высоким содержанием сомономера RU2731442C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361907085P 2013-11-21 2013-11-21
US61/907,085 2013-11-21
PCT/US2014/066878 WO2015077598A1 (en) 2013-11-21 2014-11-21 Producing high comonomer content propylene-based polymers

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RU2016124223A RU2016124223A (ru) 2017-12-26
RU2731442C2 true RU2731442C2 (ru) 2020-09-02

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US (1) US10093759B2 (enExample)
EP (1) EP3071608B1 (enExample)
KR (1) KR102243786B1 (enExample)
CN (1) CN106414521B (enExample)
BR (1) BR112016011604B1 (enExample)
PL (1) PL3071608T3 (enExample)
RU (1) RU2731442C2 (enExample)
SA (1) SA516371156B1 (enExample)
WO (1) WO2015077598A1 (enExample)

Cited By (1)

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RU2850411C1 (ru) * 2020-10-15 2025-11-11 Чайна Петролеум Энд Кемикал Корпорейшн Пропилен-бутеновый сополимер, способ его получения и его применение

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EP3397657B1 (en) * 2015-12-31 2024-06-12 Braskem America, Inc. Non-phthalate catalyst system and its use in the polymerization of olefins
CN109937213B (zh) * 2016-09-08 2021-03-02 Sabic环球技术有限责任公司 通过不连续添加热失控减少剂制备聚烯烃的方法
WO2018046395A1 (en) * 2016-09-08 2018-03-15 Sabic Global Technologies B.V. Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent
JP2018188636A (ja) * 2017-05-10 2018-11-29 日本ポリプロ株式会社 プロピレン・エチレン・１−ブテンターポリマー及びその製造方法
CN116096810A (zh) 2020-06-29 2023-05-09 格雷斯公司 具有高刚度性能的不含邻苯二甲酸酯的聚丙烯均聚物
CN112625156B (zh) * 2020-12-04 2022-10-21 朴蓝聚烯烃科技发展（上海）有限公司 一种适用于气相聚合工艺的聚丙烯制备方法
CN118055955A (zh) * 2021-08-09 2024-05-17 格雷斯公司 用于生产具有提高的沉降堆积密度的聚烯烃粒状树脂的方法

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WO2005066247A1 (en) * 2003-12-24 2005-07-21 Petroquimica Cuyo S.A.I.C. Sealing layer resin compositions
RU2318838C2 (ru) * 2006-03-30 2008-03-10 Ярославский государственный технический университет Резиновый амортизатор с пониженной коррозионной активностью
RU2458734C2 (ru) * 2007-08-03 2012-08-20 Базелль Полиолефин Италия С.Р.Л. Способ получения пропиленовых терполимеров

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WO2005066247A1 (en) * 2003-12-24 2005-07-21 Petroquimica Cuyo S.A.I.C. Sealing layer resin compositions
RU2318838C2 (ru) * 2006-03-30 2008-03-10 Ярославский государственный технический университет Резиновый амортизатор с пониженной коррозионной активностью
RU2458734C2 (ru) * 2007-08-03 2012-08-20 Базелль Полиолефин Италия С.Р.Л. Способ получения пропиленовых терполимеров

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2850411C1 (ru) * 2020-10-15 2025-11-11 Чайна Петролеум Энд Кемикал Корпорейшн Пропилен-бутеновый сополимер, способ его получения и его применение

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EP3071608C0 (en) 2025-05-28
EP3071608A1 (en) 2016-09-28
US10093759B2 (en) 2018-10-09
EP3071608B1 (en) 2025-05-28
KR20160089418A (ko) 2016-07-27
US20160289357A1 (en) 2016-10-06
PL3071608T3 (pl) 2025-09-01
KR102243786B1 (ko) 2021-04-22
CN106414521A (zh) 2017-02-15
BR112016011604A2 (enExample) 2017-08-08
CN106414521B (zh) 2019-07-30
BR112016011604B1 (pt) 2022-02-08
EP3071608A4 (en) 2017-08-09
WO2015077598A1 (en) 2015-05-28
RU2016124223A (ru) 2017-12-26
SA516371156B1 (ar) 2019-04-18

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