KR102243786B1 - 고 공단량체 함량 프로필렌계 중합체의 제조 - Google Patents

고 공단량체 함량 프로필렌계 중합체의 제조 Download PDF

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KR102243786B1
KR102243786B1 KR1020167016180A KR20167016180A KR102243786B1 KR 102243786 B1 KR102243786 B1 KR 102243786B1 KR 1020167016180 A KR1020167016180 A KR 1020167016180A KR 20167016180 A KR20167016180 A KR 20167016180A KR 102243786 B1 KR102243786 B1 KR 102243786B1
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propylene
based polymer
reactor
fluidized bed
catalyst
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KR20160089418A (ko
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핑 차이
에그몬드 잔 더블유 반
제프리 디 고드
매튜 제이 페덱
차이-징 초우
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더블유.알. 그레이스 앤드 캄파니-콘.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C08F4/6022—Component of C08F4/60 containing at least two different metals
    • C08F4/6026—Component of C08F4/60 containing at least two different metals containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6493—Catalysts containing a specific non-metal or metal-free compound organic containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020167016180A 2013-11-21 2014-11-21 고 공단량체 함량 프로필렌계 중합체의 제조 Active KR102243786B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361907085P 2013-11-21 2013-11-21
US61/907,085 2013-11-21
PCT/US2014/066878 WO2015077598A1 (en) 2013-11-21 2014-11-21 Producing high comonomer content propylene-based polymers

Publications (2)

Publication Number Publication Date
KR20160089418A KR20160089418A (ko) 2016-07-27
KR102243786B1 true KR102243786B1 (ko) 2021-04-22

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US (1) US10093759B2 (enExample)
EP (1) EP3071608B1 (enExample)
KR (1) KR102243786B1 (enExample)
CN (1) CN106414521B (enExample)
BR (1) BR112016011604B1 (enExample)
PL (1) PL3071608T3 (enExample)
RU (1) RU2731442C2 (enExample)
SA (1) SA516371156B1 (enExample)
WO (1) WO2015077598A1 (enExample)

Families Citing this family (7)

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Publication number Priority date Publication date Assignee Title
BR112018013506B1 (pt) 2015-12-31 2022-10-11 Braskem America, Inc Sistema catalisador isento de ftalato
US11384166B2 (en) 2016-09-08 2022-07-12 Sabic Global Technologies B.V. Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent
WO2018046395A1 (en) * 2016-09-08 2018-03-15 Sabic Global Technologies B.V. Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent
JP2018188636A (ja) * 2017-05-10 2018-11-29 日本ポリプロ株式会社 プロピレン・エチレン・１−ブテンターポリマー及びその製造方法
CN116096810A (zh) 2020-06-29 2023-05-09 格雷斯公司 具有高刚度性能的不含邻苯二甲酸酯的聚丙烯均聚物
CN112625156B (zh) * 2020-12-04 2022-10-21 朴蓝聚烯烃科技发展（上海）有限公司 一种适用于气相聚合工艺的聚丙烯制备方法
CA3228234A1 (en) * 2021-08-09 2023-02-16 Ping Cai Process for producing polyolefin granular resin with increased settled bulk density

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US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US5604172A (en) 1984-03-31 1997-02-18 Union Carbide Chemicals & Plastics Technology Corporation Shape-shifted magnesium alkoxide component for polymerizing olefins
IT1243430B (it) 1990-09-28 1994-06-10 Himont Inc Composizioni di polimeri cristallini del propilene aventi bassa temperatura
CA2098664A1 (en) 1992-06-30 1993-12-31 Hajime Sadatoshi Polypropylene random copolymer and film thereof
FI111848B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
US6460412B1 (en) 2000-10-27 2002-10-08 Union Carbide Chemicals & Plastics Technology Corporation Detection of dynamic fluidized bed level in a fluidized bed polymerization reactor using ultrasonic waves or microwaves
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
CN1898307A (zh) * 2003-12-24 2007-01-17 佩特罗基米卡库伊欧公司 密封层树脂组合物
RU2318838C2 (ru) * 2006-03-30 2008-03-10 Ярославский государственный технический университет Резиновый амортизатор с пониженной коррозионной активностью
RU2458734C2 (ru) * 2007-08-03 2012-08-20 Базелль Полиолефин Италия С.Р.Л. Способ получения пропиленовых терполимеров
MX347799B (es) 2007-08-24 2017-05-15 W R Grace & Co -Conn Sistema de catalizador auto-limitante con proporcion de aluminio a sca controlada y metodo.
US8067510B2 (en) * 2007-08-24 2011-11-29 Union Carbide Chemicals & Plastics Technology Llc High melt flow propylene impact copolymer and method
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KR101854479B1 (ko) 2009-12-21 2018-05-03 더블유.알. 그레이스 앤드 캄파니-콘. 다중 유동 체제를 갖는 기상 중합 방법
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WO2014139811A2 (en) * 2013-03-15 2014-09-18 Basell Poliolefine Italia S.R.L. Process for the preparation of propylene terpolymers and terpolymers obtained thereby

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Publication number Publication date
US10093759B2 (en) 2018-10-09
EP3071608B1 (en) 2025-05-28
CN106414521A (zh) 2017-02-15
PL3071608T3 (pl) 2025-09-01
EP3071608A4 (en) 2017-08-09
US20160289357A1 (en) 2016-10-06
WO2015077598A1 (en) 2015-05-28
RU2731442C2 (ru) 2020-09-02
CN106414521B (zh) 2019-07-30
EP3071608A1 (en) 2016-09-28
RU2016124223A (ru) 2017-12-26
EP3071608C0 (en) 2025-05-28
SA516371156B1 (ar) 2019-04-18
BR112016011604B1 (pt) 2022-02-08
KR20160089418A (ko) 2016-07-27
BR112016011604A2 (enExample) 2017-08-08

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