RU2715559C2 - Применение стабильных липофильных соединений гидроксиламина для ингибирования полимеризации виниловых мономеров - Google Patents

Применение стабильных липофильных соединений гидроксиламина для ингибирования полимеризации виниловых мономеров Download PDF

Info

Publication number
RU2715559C2
RU2715559C2 RU2017132514A RU2017132514A RU2715559C2 RU 2715559 C2 RU2715559 C2 RU 2715559C2 RU 2017132514 A RU2017132514 A RU 2017132514A RU 2017132514 A RU2017132514 A RU 2017132514A RU 2715559 C2 RU2715559 C2 RU 2715559C2
Authority
RU
Russia
Prior art keywords
polymerization
unsaturated compound
butyl
alkyl
paragraphs
Prior art date
Application number
RU2017132514A
Other languages
English (en)
Russian (ru)
Other versions
RU2017132514A (ru
RU2017132514A3 (enExample
Inventor
Джонатан МАЗЕРЕ
Эндрю НЕЙЛСОН
Русселл ВАТСОН
Original Assignee
ЭКОЛАБ ЮЭсЭй ИНК.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ЭКОЛАБ ЮЭсЭй ИНК. filed Critical ЭКОЛАБ ЮЭсЭй ИНК.
Publication of RU2017132514A publication Critical patent/RU2017132514A/ru
Publication of RU2017132514A3 publication Critical patent/RU2017132514A3/ru
Application granted granted Critical
Publication of RU2715559C2 publication Critical patent/RU2715559C2/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
RU2017132514A 2015-03-18 2016-03-17 Применение стабильных липофильных соединений гидроксиламина для ингибирования полимеризации виниловых мономеров RU2715559C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562134811P 2015-03-18 2015-03-18
US62/134,811 2015-03-18
PCT/US2016/022731 WO2016149433A1 (en) 2015-03-18 2016-03-17 The use of stable lipophilic hydroxylamine compounds for inhibiting polymerization of vinyl monomers

Publications (3)

Publication Number Publication Date
RU2017132514A RU2017132514A (ru) 2019-04-18
RU2017132514A3 RU2017132514A3 (enExample) 2019-08-28
RU2715559C2 true RU2715559C2 (ru) 2020-03-02

Family

ID=56919278

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2017132514A RU2715559C2 (ru) 2015-03-18 2016-03-17 Применение стабильных липофильных соединений гидроксиламина для ингибирования полимеризации виниловых мономеров

Country Status (12)

Country Link
US (1) US9914701B2 (enExample)
EP (1) EP3271331B1 (enExample)
JP (1) JP6730303B2 (enExample)
KR (1) KR102583199B1 (enExample)
CN (1) CN107406388B (enExample)
AR (1) AR103961A1 (enExample)
BR (1) BR112017018283B1 (enExample)
CA (1) CA2979828C (enExample)
ES (1) ES2912329T3 (enExample)
RU (1) RU2715559C2 (enExample)
TW (1) TWI680964B (enExample)
WO (1) WO2016149433A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2019010664A (es) * 2017-03-09 2019-12-02 Ecolab Usa Inc Composiciones de inhibidores de la polimerizacion.
US11802047B2 (en) 2019-04-02 2023-10-31 Ecolab Usa Inc. Pure chlorine dioxide generation system with reduced acid usage
TW202348787A (zh) 2022-04-01 2023-12-16 美商藝康美國公司 用於乙烯系單體流之高苛刻度加工的防汙劑組成物
TW202404930A (zh) 2022-04-01 2024-02-01 美商藝康美國公司 在共軛二烯單體之萃取蒸餾期間減少非所要之乳化聚合
TW202348786A (zh) 2022-04-01 2023-12-16 美商藝康美國公司 用於蒸氣空間應用之防汙劑組成物

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290888A (en) * 1990-07-20 1994-03-01 Ciba-Geigy Corporation Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions
RU2039757C1 (ru) * 1992-05-15 1995-07-20 Нижнекамское производственное объединение "Нижнекамскнефтехим" Способ ингибирования полимеризации винилароматических мономеров
CA2232502A1 (en) * 1997-03-20 1998-09-20 James Tyler Merrill Polymerization inhibitor process
EP0943665A1 (en) * 1998-03-19 1999-09-22 Ciba SC Holding AG Stabilization of wood substrates
RU2260601C2 (ru) * 2000-07-26 2005-09-20 Атофина Способ получения поливинилхлорида
US7132540B1 (en) * 2001-04-30 2006-11-07 Nova Molecular Technologies Inc. Hindered spiro-ketal nitroxides
WO2007045886A1 (en) * 2005-10-20 2007-04-26 A H Marks And Company Limited Inhibition of polymerisation
WO2008103613A2 (en) * 2007-02-22 2008-08-28 Othera Holding, Inc. Hydroxylamine compounds and methods of their use

Family Cites Families (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2455745A (en) 1943-11-19 1948-12-07 Olin Mathieson Stabilization of styrene and polymerizable ring chlorinated styrenes
US2783271A (en) 1954-06-29 1957-02-26 Allied Chem & Dye Corp Continuous production of methacrylic acid esters
US2810651A (en) 1954-12-28 1957-10-22 Universal Oil Prod Co Stabilization of organic compounds
US2965685A (en) 1958-06-24 1960-12-20 Monsanto Chemicals Polymerization inhibitor
NL131752C (enExample) 1960-09-08
US3320305A (en) 1964-01-28 1967-05-16 Exxon Research Engineering Co Process for converting nitriles
US3696050A (en) 1970-08-03 1972-10-03 Eastman Kodak Co Polymerization inhibitors for vinyl monomers and unsaturated polyesters
US3704235A (en) 1971-01-11 1972-11-28 Commissariat Energie Atomique Stable free radicals of the nitroxide type derived from tropane ring compounds
US4202742A (en) 1979-04-30 1980-05-13 Westinghouse Electric Corp. Photopolymerization of ethylenically unsaturated monomers
US4293347A (en) 1980-01-21 1981-10-06 The Dow Chemical Company Process for depolymerization of acrylic acid polymers
US4487981A (en) 1983-09-08 1984-12-11 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US4590231A (en) * 1983-10-11 1986-05-20 Ciba-Geigy Corporation Polyolefin compositions stabilized against degradation using hydroxylamine derivatives
JPH0689061B2 (ja) 1988-12-16 1994-11-09 日本石油株式会社 ブタジエン低重合体付加物の製造方法
KR100193146B1 (ko) * 1990-07-20 1999-06-15 월터 클리웨인, 한스-피터 위트린 안정화된 단량체 조성물
US5221498A (en) 1991-07-22 1993-06-22 Betz Laboratories, Inc. Methods and compositions for inhibitoring polymerization of vinyl monomers
US5235056A (en) 1992-04-22 1993-08-10 Ciba-Geigy Corporation Substituted 1-hydroxy-2,6-diaryl-4-piperidone ketals and polymer compositions stabilized therewith
US5648574A (en) 1992-10-21 1997-07-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US5728872A (en) 1994-06-27 1998-03-17 Lutz Riemenschneider Stabilized acrylic acid compositions
US5426257A (en) 1994-06-30 1995-06-20 Betz Laboratories, Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US5489720A (en) 1994-06-30 1996-02-06 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US5626745A (en) 1994-10-27 1997-05-06 Water Recycling Systems, Inc. Waste water purification system
US5583247A (en) 1995-04-14 1996-12-10 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
US5648573A (en) 1995-06-12 1997-07-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
CN1194256A (zh) * 1997-03-20 1998-09-30 希巴特殊化学控股公司 聚合抑制方法
US5932735A (en) 1997-06-13 1999-08-03 Ciba Specialty Chemicals Corporation Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
EP1000032A1 (en) * 1997-07-23 2000-05-17 Ciba SC Holding AG Inhibition of pulp and paper yellowing using nitroxides and other coadditives
US6020435A (en) 1997-11-05 2000-02-01 Rohm And Haas Company Process for preparing polymer core shell type emulsions and polymers formed therefrom
US6770222B1 (en) 1998-03-03 2004-08-03 Nippon Zeon Co., Ltd. Polymerization-inhibiting composition, polymerization inhibitor and method for inhibiting polymerization
BR9913523A (pt) 1998-09-09 2001-06-05 Baker Hughes Inc Inibição de polimerização de monÈmero estireno utilizando dihidroxiarenos e nitróxidos substituìdos
AU5817099A (en) 1998-09-09 2000-03-27 Baker Hughes Incorporated Vinyl monomer polymerization inhibition using hindered hydroxylamines
US6599326B1 (en) 1999-01-20 2003-07-29 Ciba Specialty Chemicals Corporation Inhibition of pulp and paper yellowing using hydroxylamines and other coadditives
CA2260310A1 (en) 1999-01-25 2000-07-25 Rene Dijkstra Sulfuric acid recovery process and apparatus
US6180231B1 (en) 1999-03-31 2001-01-30 Union Carbide Chemicals & Plastics Technology Corporation Crosslinkable polyethylene composition
EP1065197B1 (en) 1999-06-28 2002-11-06 Rohm And Haas Company Process for preparing (meth)acrylic acid
AU5917200A (en) 1999-08-18 2001-03-13 Nalco/Exxon Energy Chemicals, L.P. Method of inhibiting vapor phase fouling in vinyl monomer systems
JP2003527326A (ja) * 1999-09-15 2003-09-16 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド パルプまたは紙に対する高い親和性を有するクロロヒドリンおよび陽イオン性化合物
EP1235885B1 (en) 1999-12-03 2007-08-15 Uniroyal Chemical Company, Inc. Composition and method for inhibiting polymerization and polymer growth
US6525146B1 (en) 2000-04-03 2003-02-25 Baker Hughes Incorporated Inhibition of popcorn polymer growth
EP1587887A1 (en) 2003-01-29 2005-10-26 Ciba SC Holding AG Ink-jet ink and recording material
CN1901876B (zh) 2003-10-30 2013-04-10 西巴特殊化学制品控股公司 稳定的身体护理品,家用制品,纺织品和织物
US7282136B2 (en) 2004-05-26 2007-10-16 Nalco Company Method of dispersing hydrocarbon foulants in hydrocarbon processing fluids
KR100676996B1 (ko) 2005-01-18 2007-02-01 여천엔씨씨 주식회사 1,3-부타디엔의 중합방지제 및 이것을 투입하는1,3-부타디엔의 중합방지방법
DK1896550T3 (da) 2005-06-30 2013-11-18 Basf Se Stabiliserede elektrokrome medier
WO2007044396A2 (en) 2005-10-04 2007-04-19 The Research Foundation Of State University Of New York Fibronectin polypeptides and methods of use
US7985826B2 (en) 2006-12-22 2011-07-26 Reichhold, Inc. Molding resins using renewable resource component
WO2008101195A2 (en) * 2007-02-16 2008-08-21 Othera Holding, Inc. Drug resistance reversal in neoplastic disease
CN103254062A (zh) 2007-08-31 2013-08-21 阿科玛股份有限公司 在丙烯酸和丙烯酸酯工艺中抑制聚合和结垢的方法
DE102008061611A1 (de) 2007-12-19 2009-06-25 Basf Se Verhinderung der Polymerisation in Wasser-Aromaten-Mischungen
US8247593B2 (en) 2008-05-13 2012-08-21 Nalco Company Process for preparing substituted 7-cyano quinone methides
EP2233505A1 (en) 2009-03-23 2010-09-29 Total Petrochemicals Research Feluy Stabilised compositions comprising olefins
CN102795966B (zh) 2011-05-24 2014-09-03 江苏恒祥化工有限责任公司 控制1,4-环己烷二甲醇精馏过程中聚合的方法
US8884038B2 (en) 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
DE102013204950A1 (de) 2013-03-20 2014-09-25 Evonik Industries Ag Verfahren und Zusammensetzung zur Inhibierung der Polymerisation von Cyclopentadienverbindungen
US9399622B2 (en) * 2013-12-03 2016-07-26 Ecolab Usa Inc. Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290888A (en) * 1990-07-20 1994-03-01 Ciba-Geigy Corporation Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions
RU2039757C1 (ru) * 1992-05-15 1995-07-20 Нижнекамское производственное объединение "Нижнекамскнефтехим" Способ ингибирования полимеризации винилароматических мономеров
CA2232502A1 (en) * 1997-03-20 1998-09-20 James Tyler Merrill Polymerization inhibitor process
EP0943665A1 (en) * 1998-03-19 1999-09-22 Ciba SC Holding AG Stabilization of wood substrates
RU2260601C2 (ru) * 2000-07-26 2005-09-20 Атофина Способ получения поливинилхлорида
US7132540B1 (en) * 2001-04-30 2006-11-07 Nova Molecular Technologies Inc. Hindered spiro-ketal nitroxides
WO2007045886A1 (en) * 2005-10-20 2007-04-26 A H Marks And Company Limited Inhibition of polymerisation
WO2008103613A2 (en) * 2007-02-22 2008-08-28 Othera Holding, Inc. Hydroxylamine compounds and methods of their use

Also Published As

Publication number Publication date
CN107406388B (zh) 2021-06-18
US9914701B2 (en) 2018-03-13
ES2912329T3 (es) 2022-05-25
EP3271331A1 (en) 2018-01-24
CA2979828A1 (en) 2016-09-22
KR102583199B1 (ko) 2023-09-25
TW201704212A (zh) 2017-02-01
EP3271331B1 (en) 2022-03-02
BR112017018283A2 (pt) 2018-04-10
EP3271331A4 (en) 2018-08-15
KR20170129242A (ko) 2017-11-24
AR103961A1 (es) 2017-06-14
US20160272586A1 (en) 2016-09-22
RU2017132514A (ru) 2019-04-18
RU2017132514A3 (enExample) 2019-08-28
CN107406388A (zh) 2017-11-28
CA2979828C (en) 2023-08-29
TWI680964B (zh) 2020-01-01
WO2016149433A1 (en) 2016-09-22
BR112017018283B1 (pt) 2022-07-12
JP6730303B2 (ja) 2020-07-29
JP2018511592A (ja) 2018-04-26

Similar Documents

Publication Publication Date Title
RU2715559C2 (ru) Применение стабильных липофильных соединений гидроксиламина для ингибирования полимеризации виниловых мономеров
US9957209B2 (en) Use of quinone methides as antipolymerants for vinylic monomers
CN1082499C (zh) 含单体和稳定剂的混合物
KR102861372B1 (ko) 스티렌 공정에서 dvb 가교 및 불용성 중합체 형성을 개선하기 위한 첨가제
WO2010129067A1 (en) Improved methylidene malonate process
US10138183B2 (en) Process and composition for inhibiting the polymerization of cyclopentadiene compounds
RU2746125C2 (ru) Пространственно затрудненные гидрохиноны в качестве средств, предохраняющих от обрастания, в отношении ненасыщенных мономеров
KR20050107811A (ko) 방향족 비닐 화합물의 중합 억제제 및 중합 억제 방법
JP6021700B2 (ja) アルキル基中に少なくとも４個の炭素原子を有する（メタ）アクリル酸の３級アルキルエステルの製造法
JP2022514026A (ja) ヒドロキシル化キノン重合防止剤および使用方法
TW202348786A (zh) 用於蒸氣空間應用之防汙劑組成物
JP3534701B2 (ja) 不飽和有機化合物を重合から安定化する方法
CA2861418A1 (en) Improved 1,1-disubstituted ethylene process
JP2008222702A (ja) ビニル基含有化合物の重合防止剤および重合防止方法
JP3978132B2 (ja) アダマンチルエステルモノマー組成物
JP4165812B2 (ja) 芳香族ビニル化合物の重合抑制剤および重合抑制方法
JP4820369B2 (ja) 重合禁止剤としてのスルホン化ニトロフェノール
CN119285813A (zh) 一种用于丁二烯不饱和烯烃聚合的阻聚剂及其制备方法
JP2005500380A (ja) エチレン性不飽和化合物のアミドキシムによる安定化
JP2006176417A (ja) 芳香族ビニル化合物の重合抑制方法