RU2683278C1 - Катодный активный материал и фторид-ионный аккумулятор - Google Patents
Катодный активный материал и фторид-ионный аккумулятор Download PDFInfo
- Publication number
- RU2683278C1 RU2683278C1 RU2018119704A RU2018119704A RU2683278C1 RU 2683278 C1 RU2683278 C1 RU 2683278C1 RU 2018119704 A RU2018119704 A RU 2018119704A RU 2018119704 A RU2018119704 A RU 2018119704A RU 2683278 C1 RU2683278 C1 RU 2683278C1
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- Prior art keywords
- active material
- cathode active
- cuf
- layer
- fluoride
- Prior art date
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- 239000006182 cathode active material Substances 0.000 title claims abstract description 158
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 title claims abstract description 56
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 44
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 239000003792 electrolyte Substances 0.000 claims abstract description 5
- 239000006183 anode active material Substances 0.000 claims description 24
- 238000002441 X-ray diffraction Methods 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 13
- 230000005855 radiation Effects 0.000 claims description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 239000011244 liquid electrolyte Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 229910052747 lanthanoid Inorganic materials 0.000 abstract description 2
- 238000007599 discharging Methods 0.000 abstract 1
- 238000004870 electrical engineering Methods 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 229910016509 CuF 2 Inorganic materials 0.000 description 22
- 239000011149 active material Substances 0.000 description 14
- 238000010586 diagram Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 239000004020 conductor Substances 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
- 238000005259 measurement Methods 0.000 description 10
- -1 BiF 3 Inorganic materials 0.000 description 9
- 150000004673 fluoride salts Chemical class 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 238000005191 phase separation Methods 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 238000000227 grinding Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000010416 ion conductor Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 239000006230 acetylene black Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000011532 electronic conductor Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910003480 inorganic solid Inorganic materials 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- 229910052745 lead Inorganic materials 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 2
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 235000019241 carbon black Nutrition 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 2
- 230000005294 ferromagnetic effect Effects 0.000 description 2
- 229910001506 inorganic fluoride Inorganic materials 0.000 description 2
- 239000002608 ionic liquid Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- DSMUTQTWFHVVGQ-UHFFFAOYSA-N 4,5-difluoro-1,3-dioxolan-2-one Chemical compound FC1OC(=O)OC1F DSMUTQTWFHVVGQ-UHFFFAOYSA-N 0.000 description 1
- NKMJZJDVLMDPGO-UHFFFAOYSA-N 5,8-dihydroxy-2-(2-phenylethyl)chromen-4-one Chemical compound OC1=CC=C(O)C(C(C=2)=O)=C1OC=2CCC1=CC=CC=C1 NKMJZJDVLMDPGO-UHFFFAOYSA-N 0.000 description 1
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910021594 Copper(II) fluoride Inorganic materials 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229910008449 SnF 2 Inorganic materials 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 150000005678 chain carbonates Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- GWFAVIIMQDUCRA-UHFFFAOYSA-L copper(ii) fluoride Chemical compound [F-].[F-].[Cu+2] GWFAVIIMQDUCRA-UHFFFAOYSA-L 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001330 spinodal decomposition reaction Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017-109296 | 2017-06-01 | ||
JP2017109296 | 2017-06-01 | ||
JP2018039805A JP6852701B2 (ja) | 2017-06-01 | 2018-03-06 | 正極活物質およびフッ化物イオン電池 |
JP2018-039805 | 2018-03-06 |
Publications (1)
Publication Number | Publication Date |
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RU2683278C1 true RU2683278C1 (ru) | 2019-03-27 |
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RU2018119704A RU2683278C1 (ru) | 2017-06-01 | 2018-05-29 | Катодный активный материал и фторид-ионный аккумулятор |
Country Status (2)
Country | Link |
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JP (1) | JP6852701B2 (ja) |
RU (1) | RU2683278C1 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2019187942A1 (ja) * | 2018-03-27 | 2019-10-03 | 本田技研工業株式会社 | フッ化物イオン二次電池用正極活物質、当該活物質を用いた正極、およびフッ化物イオン二次電池、並びに当該活物質の製造方法 |
JP7228775B2 (ja) * | 2018-05-22 | 2023-02-27 | パナソニックIpマネジメント株式会社 | フッ化物イオン二次電池用活物質、及びそれを用いたフッ化物イオン二次電池 |
JP7088126B2 (ja) * | 2019-06-03 | 2022-06-21 | トヨタ自動車株式会社 | フッ化物イオン電池 |
JP7200843B2 (ja) * | 2019-06-21 | 2023-01-10 | トヨタ自動車株式会社 | 正極活物質層 |
US20230054742A1 (en) * | 2020-01-31 | 2023-02-23 | Sumitomo Chemical Company, Limited | Laminate |
WO2021261561A1 (ja) * | 2020-06-25 | 2021-12-30 | 宇部興産株式会社 | 全固体二次電池用電極、全固体二次電池、及び全固体二次電池の製造方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20070117826A (ko) * | 2006-06-09 | 2007-12-13 | 한양대학교 산학협력단 | 리튬 이차 전지용 양극, 및 그를 포함하는 리튬 이차 전지 |
KR20090111549A (ko) * | 2008-04-22 | 2009-10-27 | 엘에스엠트론 주식회사 | 리튬 이차 전지용 양극 활물질의 제조방법 및 이를포함하는 리튬 이차 전지 |
RU2464673C1 (ru) * | 2011-06-14 | 2012-10-20 | Владимир Павлович Пониматкин | Способ получения фторированного углеродного материала |
WO2014144179A1 (en) * | 2013-03-15 | 2014-09-18 | Wildcat Discovery Technologies, Inc. | High energy materials for a battery and methods for making and use |
WO2015146265A1 (en) * | 2014-03-28 | 2015-10-01 | Toyota Jidosha Kabushiki Kaisha | Liquid electrolyte for fluoride ion battery and fluoride ion battery |
EP2999044A1 (en) * | 2014-09-19 | 2016-03-23 | Toyota Jidosha Kabushiki Kaisha | Liquid electrolyte for fluoride ion battery and fluoride ion battery |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4399204A (en) * | 1981-06-30 | 1983-08-16 | Union Carbide Corporation | Solid cathode comprising a lead fluoride/tin fluoride compound |
JPH05325973A (ja) * | 1992-05-18 | 1993-12-10 | Matsushita Electric Ind Co Ltd | 正極活物質並びにそれを用いた電池 |
US9159994B2 (en) * | 2013-03-15 | 2015-10-13 | Wildcat Discovery Technologies, Inc. | High energy materials for a battery and methods for making and use |
JP6250879B2 (ja) * | 2013-12-26 | 2017-12-20 | 国立大学法人京都大学 | 二次電池 |
JP2017010865A (ja) * | 2015-06-25 | 2017-01-12 | 株式会社日立製作所 | 二次電池 |
JP6486814B2 (ja) * | 2015-11-04 | 2019-03-20 | 本田技研工業株式会社 | 結晶体の製造方法、結晶体及びフッ化物イオン2次電池用電解質 |
CN110021739B (zh) * | 2019-02-28 | 2022-06-24 | 湘潭大学 | 一种基于锡基氟化物MSnF4层状氟离子电解质的室温固态氟离子电池的制备方法 |
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2018
- 2018-03-06 JP JP2018039805A patent/JP6852701B2/ja active Active
- 2018-05-29 RU RU2018119704A patent/RU2683278C1/ru active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20070117826A (ko) * | 2006-06-09 | 2007-12-13 | 한양대학교 산학협력단 | 리튬 이차 전지용 양극, 및 그를 포함하는 리튬 이차 전지 |
KR20090111549A (ko) * | 2008-04-22 | 2009-10-27 | 엘에스엠트론 주식회사 | 리튬 이차 전지용 양극 활물질의 제조방법 및 이를포함하는 리튬 이차 전지 |
RU2464673C1 (ru) * | 2011-06-14 | 2012-10-20 | Владимир Павлович Пониматкин | Способ получения фторированного углеродного материала |
WO2014144179A1 (en) * | 2013-03-15 | 2014-09-18 | Wildcat Discovery Technologies, Inc. | High energy materials for a battery and methods for making and use |
WO2015146265A1 (en) * | 2014-03-28 | 2015-10-01 | Toyota Jidosha Kabushiki Kaisha | Liquid electrolyte for fluoride ion battery and fluoride ion battery |
EP2999044A1 (en) * | 2014-09-19 | 2016-03-23 | Toyota Jidosha Kabushiki Kaisha | Liquid electrolyte for fluoride ion battery and fluoride ion battery |
Also Published As
Publication number | Publication date |
---|---|
JP2018206755A (ja) | 2018-12-27 |
JP6852701B2 (ja) | 2021-03-31 |
BR102018011064A2 (pt) | 2018-12-18 |
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