RU2456077C2 - Каталитические системы для олигомеризации этилена, имеющие повышенную селективность - Google Patents

Каталитические системы для олигомеризации этилена, имеющие повышенную селективность Download PDF

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Publication number
RU2456077C2
RU2456077C2 RU2010105127/04A RU2010105127A RU2456077C2 RU 2456077 C2 RU2456077 C2 RU 2456077C2 RU 2010105127/04 A RU2010105127/04 A RU 2010105127/04A RU 2010105127 A RU2010105127 A RU 2010105127A RU 2456077 C2 RU2456077 C2 RU 2456077C2
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Russia
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methyl
phenyl
pch
methoxyphenyl
ligand
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RU2010105127/04A
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Russian (ru)
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RU2010105127A (ru
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Таек Ку ХАН (KR)
Таек Ку ХАН
Сунг Сиок ЧАИ (KR)
Сунг Сиок ЧАИ
Санг Оок КАНГ (KR)
Санг Оок КАНГ
Канг Ранг ВИ (KR)
Канг Ранг ВИ
Сунг Кван КИМ (KR)
Сунг Кван КИМ
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ЭсКей ЭНЕРДЖИ КО., ЛТД.
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B01J2531/007—Promoter-type Additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0263—Planar chiral ligands, e.g. derived from donor-substituted paracyclophanes and metallocenes or from substituted arenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
RU2010105127/04A 2007-08-16 2007-12-24 Каталитические системы для олигомеризации этилена, имеющие повышенную селективность RU2456077C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2007-0082457 2007-08-16
KR1020070082457A KR101057576B1 (ko) 2007-08-16 2007-08-16 선택적 에틸렌 올리머고화 촉매계

Publications (2)

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RU2010105127A RU2010105127A (ru) 2011-09-27
RU2456077C2 true RU2456077C2 (ru) 2012-07-20

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Country Status (8)

Country Link
US (1) US8309779B2 (zh)
JP (1) JP2010536538A (zh)
KR (1) KR101057576B1 (zh)
CN (1) CN102083867B (zh)
BR (1) BRPI0721866B1 (zh)
CA (1) CA2694065C (zh)
RU (1) RU2456077C2 (zh)
WO (1) WO2009022770A1 (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2525118C1 (ru) * 2013-03-28 2014-08-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Каталитическая система процесса тримеризации этилена в альфа-олефины
RU2549833C1 (ru) * 2014-02-18 2015-04-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Каталитический комплекс селективной тримеризации этилена в 1-гексен
RU2685409C2 (ru) * 2014-11-25 2019-04-18 ВЕРСАЛИС С.п.А. Фосфиновый комплекс ванадия, каталитическая система, содержащая указанный фосфиновый комплекс ванадия, и способ (со)полимеризации сопряженных диенов

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GB0016895D0 (en) * 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
KR101074202B1 (ko) 2007-01-18 2011-10-14 에스케이종합화학 주식회사 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법
WO2011045701A1 (en) 2009-10-16 2011-04-21 Sasol Technology (Proprietary) Limited Separation of components from a multi-component hydrocarbon stream which includes ethylene
WO2011108772A1 (ko) * 2010-03-03 2011-09-09 에스케이이노베이션 주식회사 고활성과 고선택적인 에틸렌 올리머고화 촉매 및 이를 이용한 헥센 또는 옥텐의 제조방법
KR101471156B1 (ko) * 2011-06-14 2014-12-10 주식회사 엘지화학 선택적 에틸렌 올리고머화 촉매계
KR101846031B1 (ko) 2012-03-16 2018-04-05 에스케이이노베이션 주식회사 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계
BR112014027665B1 (pt) 2012-05-09 2021-04-13 Sasol Technology (Proprietary) Limited Processo para separar um fluxo de hidrocarbonetos multicomponente e processo de oligomerização de etileno
US9499456B2 (en) 2012-05-09 2016-11-22 Sasol Technology (Proprietary) Limited Tetramerisation of ethylene
US9522856B2 (en) 2012-05-09 2016-12-20 Sasol Technology (Proprietary) Limited Process for oligomerising a hydrocarbon to form at least one co-monomer product
ES2750659T3 (es) 2012-05-09 2020-03-26 Sasol Tech Pty Ltd Tetramerización de etileno
KR101513145B1 (ko) * 2012-05-10 2015-04-17 주식회사 엘지화학 리간드 화합물, 크롬 화합물 및 이를 포함하는 촉매계
KR101483248B1 (ko) 2012-11-15 2015-01-16 주식회사 엘지화학 리간드 화합물, 유기크롬 화합물, 에틸렌 올리고머화용 촉매계, 이의 제조 방법 및 이를 이용한 에틸렌 올리고머화 방법
ES2780695T3 (es) 2013-05-09 2020-08-26 Sasol Tech (Proprietary) Limited Tetramerización de etileno
KR102369168B1 (ko) 2013-05-09 2022-03-02 사솔 테크날러지 (프로프라이어터리) 리미티드 에틸렌의 1-헥센 및 1-옥텐의 혼합물로의 올리고머화 방법
CA2908588C (en) 2013-05-09 2021-08-17 Sasol Technology (Proprietary) Limited Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene
KR101666172B1 (ko) 2014-06-18 2016-10-13 주식회사 엘지화학 리간드 화합물, 유기크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
CN105562098B (zh) * 2014-10-08 2018-03-02 中国石油化工股份有限公司 一种乙烯齐聚催化剂组合物及其应用
CN105562099B (zh) * 2014-10-08 2018-01-23 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN105562095B (zh) * 2014-10-08 2018-06-15 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN105566026A (zh) * 2014-10-08 2016-05-11 中国石油化工股份有限公司 一种乙烯三聚的方法
CN105562096B (zh) * 2014-10-08 2018-08-17 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN105566037B (zh) * 2014-10-13 2018-03-02 中国石油化工股份有限公司 一种乙烯四聚的方法
CN105566036B (zh) * 2014-10-13 2018-05-11 中国石油化工股份有限公司 一种乙烯四聚的方法
CN105566040B (zh) * 2014-10-14 2018-11-02 中国石油化工股份有限公司 一种乙烯齐聚连续反应方法
CN105566038B (zh) * 2014-10-14 2018-05-11 中国石油化工股份有限公司 一种乙烯齐聚连续反应方法
CN105566043B (zh) * 2014-10-14 2018-04-10 中国石油化工股份有限公司 一种乙烯齐聚反应的方法
CN105566039B (zh) * 2014-10-14 2018-05-11 中国石油化工股份有限公司 一种乙烯齐聚连续反应方法
CN105566044B (zh) * 2014-10-15 2018-05-11 中国石油化工股份有限公司 一种乙烯齐聚的方法
CN105566045B (zh) * 2014-10-15 2018-03-02 中国石油化工股份有限公司 一种乙烯四聚的方法
CN105566046B (zh) * 2014-10-15 2018-03-02 中国石油化工股份有限公司 一种乙烯四聚的方法
KR101654432B1 (ko) 2014-11-28 2016-09-05 롯데케미칼 주식회사 1-헥센 및 1-옥텐의 제조방법
KR101757369B1 (ko) 2014-12-11 2017-07-12 주식회사 엘지화학 리간드 화합물, 유기크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
JP6500488B2 (ja) * 2015-02-24 2019-04-17 三菱ケミカル株式会社 触媒組成物
KR101757370B1 (ko) * 2015-06-01 2017-07-12 주식회사 엘지화학 1-옥텐 조성물
KR101757835B1 (ko) 2015-06-12 2017-07-13 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
KR101749542B1 (ko) 2015-09-03 2017-06-21 한택규 에틸렌의 선택적 올리고머화 반응 공정
KR101761830B1 (ko) 2015-10-21 2017-07-26 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
KR101982789B1 (ko) 2015-12-04 2019-05-27 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
KR102428770B1 (ko) 2016-07-14 2022-08-04 에스케이이노베이션 주식회사 에틸렌의 올리고머화 방법
WO2018012792A1 (en) 2016-07-14 2018-01-18 Sk Innovation Co., Ltd. Oligomerization of ethylene
CN110869337A (zh) 2017-07-06 2020-03-06 三井化学株式会社 烯烃多聚化用催化剂及在该催化剂存在下进行的烯烃多聚体的制造方法
CN108031493B (zh) * 2017-12-11 2020-11-06 天津科技大学 用于乙烯选择性齐聚的催化剂体系及乙烯齐聚反应方法
KR102581907B1 (ko) * 2018-01-02 2023-09-22 에스케이이노베이션 주식회사 파라핀을 제조하는 방법

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BRPI0721866A2 (pt) 2014-02-18
US8309779B2 (en) 2012-11-13
CN102083867B (zh) 2013-11-13
KR101057576B1 (ko) 2011-08-17
JP2010536538A (ja) 2010-12-02
RU2010105127A (ru) 2011-09-27
CA2694065A1 (en) 2009-02-19
CN102083867A (zh) 2011-06-01
WO2009022770A1 (en) 2009-02-19
BRPI0721866A8 (pt) 2017-12-26
CA2694065C (en) 2014-09-23
KR20090017929A (ko) 2009-02-19
US20100145124A1 (en) 2010-06-10

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