DE69727684D1 - Durch übergangsmetallkomplexe mit zyklischen chiralen liganden katalysierte asymmetrische synthese - Google Patents

Durch übergangsmetallkomplexe mit zyklischen chiralen liganden katalysierte asymmetrische synthese

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Publication number
DE69727684D1
DE69727684D1 DE69727684T DE69727684T DE69727684D1 DE 69727684 D1 DE69727684 D1 DE 69727684D1 DE 69727684 T DE69727684 T DE 69727684T DE 69727684 T DE69727684 T DE 69727684T DE 69727684 D1 DE69727684 D1 DE 69727684D1
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asymmetric synthesis
transition metal
metal complexes
chiral ligands
synthesis catalyzed
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DE69727684T
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English (en)
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Xumu Zhang
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Penn State Research Foundation
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Penn State Research Foundation
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    • C07B53/00—Asymmetric syntheses
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    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
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    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
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    • B01J31/2476—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
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    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
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    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
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    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
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    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms

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  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
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DE69727684T 1996-06-14 1997-06-13 Durch übergangsmetallkomplexe mit zyklischen chiralen liganden katalysierte asymmetrische synthese Expired - Lifetime DE69727684D1 (de)

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PCT/US1997/010436 WO1997047633A1 (en) 1996-06-14 1997-06-13 Asymmetric synthesis catalyzed by transition metal complexes with cyclic chiral phosphine ligands

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BR9709790A (pt) 1999-08-10
JP2002513376A (ja) 2002-05-08
AU3397197A (en) 1998-01-07
IL127397A (en) 2001-12-23
EP0918781A4 (de) 1999-07-28
PL330414A1 (en) 1999-05-10
CZ393798A3 (cs) 1999-11-17
US6037500A (en) 2000-03-14
IL127397A0 (en) 1999-10-28
TR199802588T2 (xx) 2000-12-21
WO1997047633A1 (en) 1997-12-18
EP0918781B1 (de) 2004-02-18
KR20000016597A (ko) 2000-03-25
ATE259819T1 (de) 2004-03-15
CA2258018A1 (en) 1997-12-18

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