RU2451709C2 - Адгезив на основе полиизоцианурата - Google Patents
Адгезив на основе полиизоцианурата Download PDFInfo
- Publication number
- RU2451709C2 RU2451709C2 RU2009138036/04A RU2009138036A RU2451709C2 RU 2451709 C2 RU2451709 C2 RU 2451709C2 RU 2009138036/04 A RU2009138036/04 A RU 2009138036/04A RU 2009138036 A RU2009138036 A RU 2009138036A RU 2451709 C2 RU2451709 C2 RU 2451709C2
- Authority
- RU
- Russia
- Prior art keywords
- adhesive
- isocyanate
- polyisocyanate
- soft block
- suprasec
- Prior art date
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 116
- 239000000853 adhesive Substances 0.000 title claims abstract description 115
- 229920000582 polyisocyanurate Polymers 0.000 title claims abstract description 12
- 239000011495 polyisocyanurate Substances 0.000 title claims abstract description 12
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 84
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 84
- 239000012948 isocyanate Substances 0.000 claims abstract description 44
- 150000001875 compounds Chemical class 0.000 claims abstract description 43
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 43
- 239000003054 catalyst Substances 0.000 claims abstract description 29
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 29
- 239000011541 reaction mixture Substances 0.000 claims abstract description 18
- 229920000642 polymer Polymers 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 33
- 238000005829 trimerization reaction Methods 0.000 claims description 20
- -1 alkali metal carboxylic acid salt Chemical class 0.000 claims description 17
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract 1
- PGYPOBZJRVSMDS-UHFFFAOYSA-N loperamide hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(C=1C=CC=CC=1)(C(=O)N(C)C)CCN(CC1)CCC1(O)C1=CC=C(Cl)C=C1 PGYPOBZJRVSMDS-UHFFFAOYSA-N 0.000 description 58
- 229920005862 polyol Polymers 0.000 description 34
- 150000003077 polyols Chemical class 0.000 description 34
- 239000004814 polyurethane Substances 0.000 description 34
- 229920002635 polyurethane Polymers 0.000 description 34
- 229920000570 polyether Polymers 0.000 description 20
- 239000004721 Polyphenylene oxide Substances 0.000 description 19
- 239000000758 substrate Substances 0.000 description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Substances OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 150000004982 aromatic amines Chemical class 0.000 description 13
- 239000010410 layer Substances 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000012790 adhesive layer Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 238000013508 migration Methods 0.000 description 4
- 230000005012 migration Effects 0.000 description 4
- 229920005906 polyester polyol Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000035882 stress Effects 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical class CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 150000007519 polyprotic acids Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 235000021058 soft food Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- PAUHLEIGHAUFAK-UHFFFAOYSA-N 1-isocyanato-1-[(1-isocyanatocyclohexyl)methyl]cyclohexane Chemical compound C1CCCCC1(N=C=O)CC1(N=C=O)CCCCC1 PAUHLEIGHAUFAK-UHFFFAOYSA-N 0.000 description 1
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 1
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- KIZQNNOULOCVDM-UHFFFAOYSA-M 2-hydroxyethyl(trimethyl)azanium;hydroxide Chemical compound [OH-].C[N+](C)(C)CCO KIZQNNOULOCVDM-UHFFFAOYSA-M 0.000 description 1
- SDQROPCSKIYYAV-UHFFFAOYSA-N 2-methyloctane-1,8-diol Chemical compound OCC(C)CCCCCCO SDQROPCSKIYYAV-UHFFFAOYSA-N 0.000 description 1
- AJEUSSNTTSVFIZ-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;hydroxide Chemical compound [OH-].C[N+](C)(C)CCCO AJEUSSNTTSVFIZ-UHFFFAOYSA-M 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- PJMDLNIAGSYXLA-UHFFFAOYSA-N 6-iminooxadiazine-4,5-dione Chemical group N=C1ON=NC(=O)C1=O PJMDLNIAGSYXLA-UHFFFAOYSA-N 0.000 description 1
- KYXHKHDZJSDWEF-LHLOQNFPSA-N CCCCCCC1=C(CCCCCC)C(\C=C\CCCCCCCC(O)=O)C(CCCCCCCC(O)=O)CC1 Chemical compound CCCCCCC1=C(CCCCCC)C(\C=C\CCCCCCCC(O)=O)C(CCCCCCCC(O)=O)CC1 KYXHKHDZJSDWEF-LHLOQNFPSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 210000003484 anatomy Anatomy 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- ITCMXBVIXVDAKR-UHFFFAOYSA-M azanium tetrabutylazanium diacetate Chemical compound C(C)(=O)[O-].[NH4+].C(CCC)[N+](CCCC)(CCCC)CCCC.C(C)(=O)[O-] ITCMXBVIXVDAKR-UHFFFAOYSA-M 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- HLJDOURGTRAFHE-UHFFFAOYSA-N isocyanic acid;3,5,5-trimethylcyclohex-2-en-1-one Chemical compound N=C=O.N=C=O.CC1=CC(=O)CC(C)(C)C1 HLJDOURGTRAFHE-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000001617 migratory effect Effects 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- GTCDARUMAMVCRO-UHFFFAOYSA-M tetraethylazanium;acetate Chemical compound CC([O-])=O.CC[N+](CC)(CC)CC GTCDARUMAMVCRO-UHFFFAOYSA-M 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- MRYQZMHVZZSQRT-UHFFFAOYSA-M tetramethylazanium;acetate Chemical compound CC([O-])=O.C[N+](C)(C)C MRYQZMHVZZSQRT-UHFFFAOYSA-M 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- DWBDUFAECGEQOS-UHFFFAOYSA-M triethyl(3-hydroxypropyl)azanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CCCO DWBDUFAECGEQOS-UHFFFAOYSA-M 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
- C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07104276.6 | 2007-03-15 | ||
| EP20070104276 EP1970420A1 (en) | 2007-03-15 | 2007-03-15 | Polyisocyanate-based adhesive composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2009138036A RU2009138036A (ru) | 2011-04-20 |
| RU2451709C2 true RU2451709C2 (ru) | 2012-05-27 |
Family
ID=38442623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2009138036/04A RU2451709C2 (ru) | 2007-03-15 | 2008-03-13 | Адгезив на основе полиизоцианурата |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9534072B2 (enExample) |
| EP (2) | EP1970420A1 (enExample) |
| JP (1) | JP5410300B2 (enExample) |
| KR (1) | KR101547363B1 (enExample) |
| CN (1) | CN101679573B (enExample) |
| AT (1) | ATE533799T1 (enExample) |
| AU (1) | AU2008225757B2 (enExample) |
| BR (1) | BRPI0808552B1 (enExample) |
| CA (1) | CA2679052C (enExample) |
| MX (1) | MX2009009669A (enExample) |
| RU (1) | RU2451709C2 (enExample) |
| WO (3) | WO2008110604A1 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2803042C (en) | 2010-07-08 | 2019-02-12 | Huntsman International Llc | Polyisocyanate-based anti-corrosion coating |
| PL2646488T5 (pl) * | 2010-11-29 | 2019-02-28 | Huntsman International Llc | Środek wiążący na bazie poliizocyjanianów |
| AU2012242949B2 (en) | 2011-04-15 | 2015-09-24 | H.B. Fuller Company | Modified diphenylmethane diisocyanate-based adhesives |
| JP2015510011A (ja) * | 2012-02-28 | 2015-04-02 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンＨｅｎｋｅｌ ＡＧ ＆ Ｃｏ．ＫＧａＡ | 高いガラス転移温度を有する２ｋポリウレタン系 |
| EP2644374A1 (en) | 2012-03-26 | 2013-10-02 | Huntsman International LLC | Insulation board |
| WO2015006391A1 (en) * | 2013-07-11 | 2015-01-15 | Dow Global Technologies Llc | Process for making urethane-isocyanurates |
| JP2015052110A (ja) * | 2013-08-08 | 2015-03-19 | 積水化学工業株式会社 | 難燃性硬化性樹脂組成物 |
| EP2871194B1 (de) | 2013-11-12 | 2016-08-03 | nolax AG | Zwei-Komponenten-Klebstoff |
| EP3115390B1 (en) * | 2014-03-04 | 2019-11-06 | Mitsui Chemicals, Inc. | Isocyanurate composition |
| DE102014226838A1 (de) | 2014-12-22 | 2016-06-23 | Henkel Ag & Co. Kgaa | Oxazolidinon- und Isocyanurat-vernetzte Matrix für faserverstärktes Material |
| DE102014226842A1 (de) | 2014-12-22 | 2016-06-23 | Henkel Ag & Co. Kgaa | Katalysator-Zusammensetzung zur Härtung von Epoxidgruppen-haltigen Harzen |
| ES2938990T3 (es) * | 2015-03-12 | 2023-04-18 | Henkel Ag & Co Kgaa | Poliuretanos ultrabajos en monómeros |
| EP3294552B1 (en) * | 2015-05-15 | 2021-09-22 | Dow Global Technologies LLC | Material delivery system for laminator |
| KR102401314B1 (ko) * | 2016-05-18 | 2022-05-25 | 바스프 에스이 | 폴리이소시아누레이트 경질 폼의 제조 방법 |
| US12594448B2 (en) | 2019-06-22 | 2026-04-07 | Mighty Fire Breaker Llc | Environmentally-clean aqueous-based fire extinguishing biochemical liquid concentrates for mixing with proportioned quantities of water to produce fire extinguishing water streams |
| US11865390B2 (en) | 2017-12-03 | 2024-01-09 | Mighty Fire Breaker Llc | Environmentally-clean water-based fire inhibiting biochemical compositions, and methods of and apparatus for applying the same to protect property against wildfire |
| USD1044825S1 (en) | 2018-09-14 | 2024-10-01 | Boxkingz | Display screen with a graphical user interface for a grid for an online gaming application |
| WO2020079160A1 (de) * | 2018-10-19 | 2020-04-23 | Covestro Deutschland Ag | Wasserfrei härtende klebstoffe auf polyisocyanatbasis |
| JP7328756B2 (ja) * | 2018-12-27 | 2023-08-17 | 理想科学工業株式会社 | 感熱スクリーンマスター用接着剤、感熱スクリーンマスター及び感熱スクリーンマスターの製造方法 |
| EP4076772A1 (en) * | 2019-12-19 | 2022-10-26 | Chemetall GmbH | Polyurea coating systems as sealants for the exterior of fuel tanks |
| US12599797B2 (en) | 2020-03-01 | 2026-04-14 | Mighty Fire Breaker Llc | Environmentally-clean fire inhibiting and extinguishing compositions and products for sorbing flammable liquids while inhibiting ignition and extinguishing fire |
| US12616859B2 (en) | 2021-02-04 | 2026-05-05 | Mighty Fire Breaker Llc | Method of and system for defending home building projects from wildfire during and after construction on property located within a wildfire urban interface (WUI) region |
| EP4587494A1 (en) | 2022-09-09 | 2025-07-23 | Sika Technology AG | Polyisocyanurate plastics with rubber-like properties |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU259367A1 (ru) * | Способ получения полимерных смол с изоциануратными кольцами в цепи | |||
| EP0380178A2 (en) * | 1989-01-27 | 1990-08-01 | HENKEL S.p.A. | Use of crosslinkable hot melt adhesive compositions |
| JP2002294201A (ja) * | 2001-03-30 | 2002-10-09 | Sekisui Chem Co Ltd | 接着剤組成物 |
| RU2005139123A (ru) * | 2003-05-15 | 2006-06-27 | Хантсмэн Интернэшнл Ллс (Us) | Клеящий состав на основе полиизоцианата для применения в панелях типа "сэндвич" |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US787975A (en) * | 1904-06-25 | 1905-04-25 | Frederick C Edelen | Combined house-trap and cellar-drain. |
| US3817939A (en) * | 1973-02-21 | 1974-06-18 | Minnesota Mining & Mfg | Organic carbonate salts as isocyanate trimerization catalysts |
| US4126741A (en) * | 1978-05-15 | 1978-11-21 | The Upjohn Company | High-modulus polyisocyanurate elastomers |
| US4299924A (en) * | 1979-08-10 | 1981-11-10 | Toyota Jidosha Kogyo Kabushiki Kaisha | Polyisocyanurate resin and process for making the same |
| JPS57131275A (en) | 1981-02-09 | 1982-08-14 | Sanyo Chem Ind Ltd | Adhesive and bonding method |
| JPS59100179A (ja) * | 1982-11-30 | 1984-06-09 | Nippon Polyurethan Kogyo Kk | 無溶剤接着組成物 |
| JPS6090281A (ja) * | 1984-08-03 | 1985-05-21 | Sanyo Chem Ind Ltd | 接着剤および接着方法 |
| GB8705801D0 (en) * | 1987-03-11 | 1987-04-15 | Ici Plc | Injection moulding compositions |
| JPH0242068A (ja) * | 1988-08-01 | 1990-02-13 | Sumitomo Bayer Urethane Kk | イソシアヌレート基含有ポリイソシアネートの製法 |
| GB8924127D0 (en) * | 1989-10-26 | 1989-12-13 | Ici Plc | Compositions of matter |
| IT1245632B (it) * | 1990-11-07 | 1994-09-29 | Boston Spa | Composizione adesiva (tipo hot melt) reticolabile e suo procedimento di applicazione |
| CA2049912C (en) * | 1991-03-13 | 1997-01-28 | Arden E. Schmucker | Adhesive composition |
| US5175228A (en) * | 1991-12-09 | 1992-12-29 | Gencorp Inc. | Two-component primerless urethane-isocyanurate adhesive compositions having high temperature resistance |
| US5340901A (en) | 1991-12-09 | 1994-08-23 | Gencorp Inc. | Two-component, primerless, organic phosphorus containing polyurethane adhesive |
| US5322914A (en) * | 1993-09-13 | 1994-06-21 | Air Products And Chemicals, Inc. | Aromatic polyisocyanurate resins and process therefor |
| JPH08291279A (ja) * | 1995-02-21 | 1996-11-05 | Nippon Polyurethane Ind Co Ltd | ラミネート用接着剤組成物、および積層フイルムの製造方法 |
| IT1273616B (it) * | 1995-05-05 | 1997-07-08 | Enichem Spa | Composizioni acquose termoreattive a base di dispersioni o soluzioni poliuretaniche stabili |
| US6072019A (en) * | 1996-07-19 | 2000-06-06 | 3M Innovative Properties Company | Water-based polyurethane polymer, release coating, adhesive tape and process of preparation |
| FR2772780B1 (fr) | 1997-12-19 | 2000-02-04 | Ato Findley Sa | Adhesif polyurethane reticulable par l'humidite et utilisations dans le domaine de l'hygiene |
| JP3981197B2 (ja) * | 1997-12-26 | 2007-09-26 | 三井化学株式会社 | 接着剤、およびリグノセルロース成型板の製造法 |
| PL343177A1 (en) * | 1998-04-03 | 2001-07-30 | Huntsman Int Llc | Polyisocyanurate foams |
| FR2812653A1 (fr) * | 2000-08-03 | 2002-02-08 | Michelin Soc Tech | Colle pour compositions de caoutchouc, son procede de preparation et articles comportant cette colle |
| US6596819B2 (en) | 2001-07-27 | 2003-07-22 | Nippon Polyurethane Industry Co., Ltd. | Polyisocyanate curing agent for laminate adhesive and process for production thereof |
| EP1288239A1 (en) * | 2001-08-30 | 2003-03-05 | Huntsman International Llc | Process for making rigid urethane-modified polyisocyanurate foams |
| US7205374B2 (en) | 2002-10-11 | 2007-04-17 | Bfs Diversified Products, Llc | Two-part polyurethane adhesive for bonding insulation boards to a roof deck |
| MXPA05012544A (es) * | 2003-06-12 | 2006-02-08 | Huntsman Int Llc | Proceso para preparar un material de poliisocianurato-poliuretano. |
| AU2007260124B2 (en) * | 2006-06-14 | 2011-12-01 | Huntsman International Llc | Cross-linkable thermoplastic polyurethanes |
| DE102006052987A1 (de) * | 2006-11-10 | 2008-05-15 | Bayer Materialscience Ag | Kunststoffverbundelemente und ein Verfahren zu ihrer Herstellung |
| EP2025730B1 (en) * | 2006-12-01 | 2014-04-16 | DIC Corporation | Moisture-curable polyurethane hot melt adhesive and multilayer sheet using the same |
-
2007
- 2007-03-15 EP EP20070104276 patent/EP1970420A1/en not_active Ceased
-
2008
- 2008-03-13 MX MX2009009669A patent/MX2009009669A/es active IP Right Grant
- 2008-03-13 WO PCT/EP2008/053018 patent/WO2008110604A1/en not_active Ceased
- 2008-03-13 BR BRPI0808552A patent/BRPI0808552B1/pt not_active IP Right Cessation
- 2008-03-13 WO PCT/EP2008/053019 patent/WO2008110605A1/en not_active Ceased
- 2008-03-13 US US12/529,830 patent/US9534072B2/en active Active
- 2008-03-13 AT AT08717759T patent/ATE533799T1/de active
- 2008-03-13 EP EP08717759A patent/EP2137224B1/en active Active
- 2008-03-13 JP JP2009553148A patent/JP5410300B2/ja not_active Expired - Fee Related
- 2008-03-13 WO PCT/EP2008/053015 patent/WO2008110602A1/en not_active Ceased
- 2008-03-13 RU RU2009138036/04A patent/RU2451709C2/ru active
- 2008-03-13 AU AU2008225757A patent/AU2008225757B2/en not_active Ceased
- 2008-03-13 KR KR1020097021395A patent/KR101547363B1/ko not_active Expired - Fee Related
- 2008-03-13 CA CA2679052A patent/CA2679052C/en active Active
- 2008-03-13 CN CN2008800083882A patent/CN101679573B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU259367A1 (ru) * | Способ получения полимерных смол с изоциануратными кольцами в цепи | |||
| EP0380178A2 (en) * | 1989-01-27 | 1990-08-01 | HENKEL S.p.A. | Use of crosslinkable hot melt adhesive compositions |
| JP2002294201A (ja) * | 2001-03-30 | 2002-10-09 | Sekisui Chem Co Ltd | 接着剤組成物 |
| RU2005139123A (ru) * | 2003-05-15 | 2006-06-27 | Хантсмэн Интернэшнл Ллс (Us) | Клеящий состав на основе полиизоцианата для применения в панелях типа "сэндвич" |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2137224A1 (en) | 2009-12-30 |
| EP1970420A1 (en) | 2008-09-17 |
| CN101679573B (zh) | 2013-07-17 |
| WO2008110605A1 (en) | 2008-09-18 |
| US20100136346A1 (en) | 2010-06-03 |
| AU2008225757A1 (en) | 2008-09-18 |
| BRPI0808552B1 (pt) | 2018-08-28 |
| RU2009138036A (ru) | 2011-04-20 |
| CN101679573A (zh) | 2010-03-24 |
| EP2137224B1 (en) | 2011-11-16 |
| WO2008110604A1 (en) | 2008-09-18 |
| KR20100015553A (ko) | 2010-02-12 |
| KR101547363B1 (ko) | 2015-08-25 |
| AU2008225757B2 (en) | 2012-10-11 |
| ATE533799T1 (de) | 2011-12-15 |
| BRPI0808552A2 (pt) | 2014-08-19 |
| MX2009009669A (es) | 2009-09-24 |
| CA2679052A1 (en) | 2008-09-18 |
| CA2679052C (en) | 2016-01-26 |
| WO2008110602A1 (en) | 2008-09-18 |
| JP2010521546A (ja) | 2010-06-24 |
| US9534072B2 (en) | 2017-01-03 |
| JP5410300B2 (ja) | 2014-02-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101547363B1 (ko) | 폴리이소시아네이트 기재 접착제 | |
| US10400144B2 (en) | Latent two-part polyurethane adhesives | |
| EP3455275B1 (en) | Two-component solventless adhesive compositions comprising an amine-initiated polyol | |
| US5322914A (en) | Aromatic polyisocyanurate resins and process therefor | |
| KR20010031995A (ko) | 고휘발성 단량체의 함량이 낮은 폴리우레탄 결합제 | |
| US6784242B2 (en) | Polyurethane binding agents having a low content of highly volatile monomers | |
| US6596819B2 (en) | Polyisocyanate curing agent for laminate adhesive and process for production thereof | |
| KR102698590B1 (ko) | 접착제 조성물 | |
| EP3884009B1 (en) | Adhesive composition | |
| EP2888303B1 (en) | Solvent free polyurethane laminating adhesive with high oxygen transfer rate | |
| JP2013501828A (ja) | 良好な貯蔵安定性を有するイソシアネート基含有プレポリマー | |
| WO2019109327A1 (en) | Two-part foamable polyurea-polyurethane adhesive composition | |
| JP5578061B2 (ja) | ポリウレア（ウレタン）システム用鎖延長剤 | |
| US20070260031A1 (en) | Moisture-hardening adhesives and sealants | |
| JP2001262114A (ja) | ラミネート接着剤用ポリイソシアネート硬化剤 | |
| KR102363246B1 (ko) | 이소시아네이트-종료된 프레폴리머를 함유하는 1-성분 구조 접착제 | |
| JP2001240839A (ja) | ラミネート接着剤用ポリイソシアネート硬化剤及びその製造方法 | |
| KR20140145636A (ko) | 폴리이소시아네이트 기재 접착제 | |
| KR20020092704A (ko) | 적층 접착제용 폴리이소시아네이트 경화제 및 그 제조방법 | |
| US20140005329A1 (en) | Urethane Resin Adhesive Composition | |
| JP4636422B2 (ja) | ポリイソシアネート硬化剤、その製造方法および該硬化剤を用いたラミネート用形成性接着剤組成物 | |
| CN120152851A (zh) | 可蒸煮的无溶剂层压粘合剂 |