RU2381240C2 - Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера этилена - Google Patents
Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера этилена Download PDFInfo
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- RU2381240C2 RU2381240C2 RU2006136414A RU2006136414A RU2381240C2 RU 2381240 C2 RU2381240 C2 RU 2381240C2 RU 2006136414 A RU2006136414 A RU 2006136414A RU 2006136414 A RU2006136414 A RU 2006136414A RU 2381240 C2 RU2381240 C2 RU 2381240C2
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- Prior art keywords
- polymer
- ethylene
- catalyst
- block copolymer
- olefin
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- 0 CCC(C)(*)N[C@](*C)[C@@](C(C)C(C)C)C=CCC Chemical compound CCC(C)(*)N[C@](*C)[C@@](C(C)C(C)C)C=CCC 0.000 description 11
- RPZUBXWEQBPUJR-UHFFFAOYSA-N C(C1)C2C1CCCC2 Chemical compound C(C1)C2C1CCCC2 RPZUBXWEQBPUJR-UHFFFAOYSA-N 0.000 description 1
- JJEPMOGCTQAOBB-UHFFFAOYSA-N CCC1CC(CCC2)C2C1 Chemical compound CCC1CC(CCC2)C2C1 JJEPMOGCTQAOBB-UHFFFAOYSA-N 0.000 description 1
- JNULHHIDKLIRSV-UNXYVOJBSA-N CC[C@@H](CC1)C2C1CCCCC2 Chemical compound CC[C@@H](CC1)C2C1CCCCC2 JNULHHIDKLIRSV-UNXYVOJBSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
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- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2813—Heat or solvent activated or sealable
- Y10T428/2817—Heat sealable
- Y10T428/2826—Synthetic resin or polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
- Y10T428/31587—Hydrocarbon polymer [polyethylene, polybutadiene, etc.]
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Graft Or Block Polymers (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55390604P | 2004-03-17 | 2004-03-17 | |
| US60/553,906 | 2004-03-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006136414A RU2006136414A (ru) | 2008-04-27 |
| RU2381240C2 true RU2381240C2 (ru) | 2010-02-10 |
Family
ID=34963211
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006136412A RU2375381C2 (ru) | 2004-03-17 | 2005-03-17 | Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина |
| RU2006136414A RU2381240C2 (ru) | 2004-03-17 | 2005-03-17 | Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера этилена |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006136412A RU2375381C2 (ru) | 2004-03-17 | 2005-03-17 | Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина |
Country Status (7)
| Country | Link |
|---|---|
| EP (3) | EP2792690B1 (OSRAM) |
| JP (5) | JP5587279B2 (OSRAM) |
| KR (1) | KR101266331B1 (OSRAM) |
| ES (1) | ES2342895T3 (OSRAM) |
| RU (2) | RU2375381C2 (OSRAM) |
| SG (3) | SG183749A1 (OSRAM) |
| TW (3) | TW200536870A (OSRAM) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11299617B2 (en) | 2018-10-02 | 2022-04-12 | Borealis Ag | Low speed cross-linking catalyst for silane-grafted plastomers |
| RU2772246C1 (ru) * | 2018-10-02 | 2022-05-18 | Бореалис Аг | Катализатор для низкоскоростного сшивания привитых силаном пластомеров |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2792690B1 (en) * | 2004-03-17 | 2019-05-15 | Dow Global Technologies LLC | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| CN103562246B (zh) * | 2011-06-02 | 2015-07-15 | 株式会社普利司通 | 共聚物、橡胶组合物、交联橡胶组合物和轮胎 |
| WO2013147186A1 (ja) * | 2012-03-30 | 2013-10-03 | 三菱レイヨン株式会社 | 複合中空糸膜及び中空糸膜モジュール |
| US10385198B2 (en) * | 2015-01-14 | 2019-08-20 | Exxonmobil Chemical Patents Inc. | Polymer compositions with improved rheological properties |
| BR112017015276B1 (pt) | 2015-01-28 | 2022-09-06 | Dow Corning Corporation | Gel, composição em gel curável por condensação, método de fabricação de um gel, e, uso de um gel |
| BR112019001249B1 (pt) | 2016-07-29 | 2022-10-18 | Dow Global Technologies Llc | Elastômero multimodal, olefina termoplástica e método para produzir um elastômero multimodal |
| GB201613397D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Cosmetic composition comprising silicone materials |
| GB201613399D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Cosmetic composition comprising silicone materials |
| GB201613412D0 (en) * | 2016-08-03 | 2016-09-14 | Dow Corning | Elastomeric compositions and their applications |
| CN115260366B (zh) * | 2017-03-15 | 2025-01-28 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
| GB201707439D0 (en) | 2017-05-09 | 2017-06-21 | Dow Corning | Lamination Process |
| GB201707437D0 (en) | 2017-05-09 | 2017-06-21 | Dow Corning | Lamination adhesive compositions and their applications |
| JP7499181B2 (ja) | 2018-03-30 | 2024-06-13 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合活性化剤 |
| CN112041351B (zh) | 2018-03-30 | 2023-12-29 | 陶氏环球技术有限责任公司 | 高度可溶的双硼酸盐作为烯烃聚合的双核助催化剂 |
| SG11202008655RA (en) | 2018-03-30 | 2020-10-29 | Dow Global Technologies Llc | Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations |
| KR20200138272A (ko) | 2018-03-30 | 2020-12-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
| SG11202008667SA (en) * | 2018-03-30 | 2020-10-29 | Dow Global Technologies Llc | Binuclear olefin polymerization activators |
| DE102019004236B4 (de) | 2018-07-02 | 2025-01-02 | Ngk Insulators, Ltd. | Gassensor und Sensorelement |
| CN110628010B (zh) * | 2019-10-18 | 2022-09-27 | 辽宁奥克医药辅料股份有限公司 | 一种催化剂组合物及其应用于制备中等分子量聚乙二醇的方法 |
| CN114846035A (zh) * | 2019-12-27 | 2022-08-02 | 陶氏环球技术有限责任公司 | 乙烯/丁烯多嵌段共聚物及其制备方法 |
| WO2021195504A1 (en) * | 2020-03-27 | 2021-09-30 | Dow Global Technologies Llc | Long-chain branched ethylene-based polymers |
| JP7750859B2 (ja) * | 2020-05-07 | 2025-10-07 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合二金属活性化剤 |
| KR102505939B1 (ko) * | 2020-09-24 | 2023-03-03 | 주식회사 모노리스 | 초저밀도 고탄성을 갖는 폴리올레핀 엘라스토머 공중합체의 제조방법 및 그에 의해 제조된 폴리올레핀 엘라스토머 공중합체 |
Family Cites Families (167)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1807989A (en) * | 1929-09-14 | 1931-06-02 | Krebs Carlos | Reproducing machine |
| US3970719A (en) | 1958-01-16 | 1976-07-20 | Phillips Petroleum Company | Preparation of block copolymers |
| US4039632A (en) | 1958-01-16 | 1977-08-02 | Phillips Petroleum Company | Preparation of block copolymers |
| US3485706A (en) | 1968-01-18 | 1969-12-23 | Du Pont | Textile-like patterned nonwoven fabrics and their production |
| US3758643A (en) | 1971-01-20 | 1973-09-11 | Uniroyal Inc | D polyolefin plastic thermoplastic blend of partially cured monoolefin copolymer rubber an |
| US3806558A (en) | 1971-08-12 | 1974-04-23 | Uniroyal Inc | Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic |
| US4130535A (en) | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
| US4104210A (en) | 1975-12-17 | 1978-08-01 | Monsanto Company | Thermoplastic compositions of high unsaturation diene rubber and polyolefin resin |
| US4340684A (en) | 1977-06-13 | 1982-07-20 | The Firestone Tire & Rubber Company | Thermoplastic elastomer blends |
| US4250273A (en) | 1977-06-13 | 1981-02-10 | The Firestone Tire & Rubber Company | Thermoplastic elastomer blends |
| US4311628A (en) | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| US4202801A (en) | 1977-12-30 | 1980-05-13 | Uniroyal, Inc. | Thermoplastic elastomer composition |
| US4271049A (en) | 1979-09-10 | 1981-06-02 | Monsanto Company | Elastoplastic compositions of cured diene rubber and polypropylene |
| US4322027A (en) | 1980-10-02 | 1982-03-30 | Crown Zellerbach Corporation | Filament draw nozzle |
| US4413110A (en) | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| DZ520A1 (fr) | 1982-03-24 | 2004-09-13 | Union Carbide Corp | Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé. |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4430563A (en) | 1982-04-30 | 1984-02-07 | Minnesota Mining And Manufacturing Company | Data processing form |
| JPS6088016A (ja) * | 1983-10-21 | 1985-05-17 | Mitsui Petrochem Ind Ltd | エチレン共重合体 |
| US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
| US4668566A (en) | 1985-10-07 | 1987-05-26 | Kimberly-Clark Corporation | Multilayer nonwoven fabric made with poly-propylene and polyethylene |
| US4798081A (en) | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5391629A (en) * | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
| US5248729A (en) | 1987-12-28 | 1993-09-28 | Nippon Petrochemicals Company Limited | Process for preparing thermoplastic resin composition |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US4927882A (en) | 1988-10-11 | 1990-05-22 | The West Company, Incorporated | SBR thermoplastic elastomer |
| US5270276A (en) | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
| US5270410A (en) | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
| US4971936A (en) | 1989-07-10 | 1990-11-20 | Shell Oil Company | Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| FR2656314B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
| US5032562A (en) | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
| DE69128028T2 (de) * | 1990-02-09 | 1998-06-10 | Exxon Chemical Patents Inc | Blockcopolymere von ionischen katalysatoren |
| US5089573A (en) | 1990-02-26 | 1992-02-18 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
| US5118767A (en) | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for producing mildly elastomeric primarily isotatic polypropylene and poly-1-butene |
| US5118768A (en) | 1990-05-11 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5051478A (en) | 1990-07-26 | 1991-09-24 | Advanced Elastomer Systems, L. P. | Ethylene copolymer - modified dynamically vulcanized alloys |
| US5134209A (en) | 1990-12-26 | 1992-07-28 | Shell Oil Company | Process of producing ethylene-propylene rubbery copolymer |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5229477A (en) | 1991-08-26 | 1993-07-20 | Shell Oil Company | Process for producing ethylene-propylene-diene monomer terpolymer |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US5525695A (en) | 1991-10-15 | 1996-06-11 | The Dow Chemical Company | Elastic linear interpolymers |
| US5210338A (en) | 1991-10-25 | 1993-05-11 | Ethyl Corporation | Catalyzed chain growth process |
| ES2095037T3 (es) | 1991-12-30 | 1997-02-01 | Dow Chemical Co | Polimerizaciones de interpolimeros de etileno. |
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| ES2111656T3 (es) | 1992-01-06 | 1998-03-16 | Dow Chemical Co | Composicion de catalizador mejorada. |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| BE1005957A5 (fr) | 1992-06-05 | 1994-04-05 | Solvay | Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine. |
| US5276220A (en) | 1992-06-18 | 1994-01-04 | Ethyl Corporation | Actinide catalyzed chain growth process |
| CA2146012A1 (en) | 1992-10-02 | 1994-04-14 | Brian W. S. Kolthammer | Supported homogenous catalyst complexes for olefin polymerization |
| US5608019A (en) | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| ES2149262T3 (es) | 1993-01-29 | 2000-11-01 | Dow Chemical Co | Interpolimerizaciones de etileno. |
| US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
| TW298593B (OSRAM) | 1993-02-12 | 1997-02-21 | Hoechst Ag | |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| AU682821B2 (en) | 1993-04-26 | 1997-10-23 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| BE1007148A3 (fr) | 1993-05-17 | 1995-04-11 | Solvay | Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur. |
| FR2705252B1 (fr) | 1993-05-19 | 1995-07-21 | Bp Chemicals Snc | Procédé d'introduction d'un solide dans un réacteur et appareillage. |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
| US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| EP0729477B1 (en) | 1993-11-19 | 1999-10-27 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| JPH07144455A (ja) | 1993-11-25 | 1995-06-06 | Canon Inc | インクジェット記録装置 |
| US5674795A (en) | 1993-12-23 | 1997-10-07 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
| US5648310A (en) | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
| US5461123A (en) | 1994-07-14 | 1995-10-24 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase fluidized bed polyolefin polymerization process using sound waves |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
| JP3275223B2 (ja) * | 1994-09-22 | 2002-04-15 | 科学技術振興事業団 | ポリプロピレン−b−ポリ(エチレン−co−プロピレン)とその製造方法 |
| US6030917A (en) | 1996-07-23 | 2000-02-29 | Symyx Technologies, Inc. | Combinatorial synthesis and analysis of organometallic compounds and catalysts |
| US5543458A (en) | 1995-01-31 | 1996-08-06 | Shell Oil Company | Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones |
| US5550194A (en) | 1995-01-31 | 1996-08-27 | Shell Oil Company | Process for making graft block copolymers by grafting anionic polymer chains onto functionalized polyolefins |
| DE69602331T2 (de) * | 1995-02-07 | 1999-10-14 | Mitsui Chemicals | Verfahren zur herstellung von polyolefin |
| US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
| US5693713A (en) | 1995-05-30 | 1997-12-02 | Shell Oil Company | Process for making block graft copolymers by grafting halosilanes onto polyolefin/diene polymers |
| DE69617371T2 (de) | 1995-06-08 | 2002-08-08 | Showa Denko K.K., Tokio/Tokyo | Ionische Verbindungen und Katalysator für die Olefinpolymerisation, der die Verbindungen verwendet |
| US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
| US6051681A (en) | 1995-11-17 | 2000-04-18 | Dsm N.V. | Process for the preparation of a thermoplastic elastomer |
| CN1214698A (zh) | 1996-03-27 | 1999-04-21 | 陶氏化学公司 | 采用分散的催化剂活化剂进行的溶液聚合方法 |
| CN1120849C (zh) | 1996-03-27 | 2003-09-10 | 陶氏环球技术公司 | 高度可溶性烯烃聚合反应催化活化剂 |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| JP3749756B2 (ja) * | 1996-04-09 | 2006-03-01 | 三井化学株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
| HU223533B1 (hu) * | 1996-06-17 | 2004-08-30 | Exxonmobil Chemical Patents Inc. | Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására |
| WO1998006727A1 (en) | 1996-08-08 | 1998-02-19 | The Dow Chemical Company | 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
| US5854166A (en) | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
| DE69728677T2 (de) | 1996-09-06 | 2005-03-31 | Hyundai Pertrochemical Co., Ltd. | Katalysatorsystem für die (co)polymerisierung von olefinen und verfahren zur herstellung von olefin-(co)polymeren unter verwendung des katalysatorsystems |
| US6015868A (en) | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
| US5783512A (en) | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
| US6177377B1 (en) * | 1996-12-18 | 2001-01-23 | Amherst Polymer Technology, Inc. | Polymer blends and process for preparation |
| US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
| RU2186073C2 (ru) | 1996-12-19 | 2002-07-27 | Дзе Дау Кемикал Компани | Комплексы металлов, содержащие лиганды 3-арилзамещенного инденила, катализатор полимеризации олефинов и способ полимеризации |
| FI970349A7 (fi) | 1997-01-28 | 1998-07-29 | Borealis As | Uudet metalloseeniyhdisteiden aktivaattorisysteemit |
| CN1130406C (zh) * | 1997-02-07 | 2003-12-10 | 埃克森美孚化学专利公司 | 结合有聚乙烯大分子单体的丙烯聚合物 |
| CA2204803C (en) | 1997-05-08 | 2005-11-15 | Nova Chemicals Ltd. | Process to prepare bridged phosphole-cyclopentadienyl compounds |
| WO1998057996A1 (en) * | 1997-06-14 | 1998-12-23 | The Board Of Trustees Of The Leland Stanford, Jr. University | ETHYLENE ENHANCEMENT OF PROCESSES FOR SYNTHESIS OF HIGH MELTING THERMOPLASTIC ELASTOMERIC α-OLEFIN POLYMERS (PRE/EPE EFFECTS) |
| US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| CA2210131C (en) | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
| US6319989B1 (en) | 1997-07-21 | 2001-11-20 | The Dow Chemical Company | Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom |
| US6150297A (en) | 1997-09-15 | 2000-11-21 | The Dow Chemical Company | Cyclopentaphenanthrenyl metal complexes and polymerization process |
| HUP0004655A3 (en) | 1997-09-19 | 2003-05-28 | Dow Chemical Co | Modified alumoxane catalyst activator |
| US6696379B1 (en) | 1997-09-19 | 2004-02-24 | The Dow Chemical Company | Supported modified alumoxane catalyst activator |
| AR012518A1 (es) | 1997-09-19 | 2000-10-18 | Dow Global Technologies Inc | Composicion de polimeros que comprende etileno interpolimerizado con al menos un comonomero insaturado, proceso para prepararla y articulo fabricado que la comprende |
| DE19744102A1 (de) | 1997-10-06 | 1999-04-15 | Targor Gmbh | Katalysatorsystem |
| US5986024A (en) * | 1997-10-17 | 1999-11-16 | Sri International | Preparation of multimodal polymer compositions using multinuclear metallocene catalysts |
| US6380341B1 (en) | 1998-01-09 | 2002-04-30 | The Board Of Trustees Of Leland Stanford Jr. University | Ethylene copolymers with narrow composition distribution and high melting temperatures, and methods of production thereof |
| AU2111599A (en) | 1998-01-09 | 1999-07-26 | Board Of Trustees Of The Leland Stanford Junior University | High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis |
| DE69909057T2 (de) | 1998-02-20 | 2004-05-06 | Dow Global Technologies, Inc., Midland | Expandierte Anionen enthaltende Katalysatoraktivatoren |
| JPH11279216A (ja) * | 1998-03-25 | 1999-10-12 | Sumitomo Chem Co Ltd | オレフィン重合体の製造方法 |
| JP2000072824A (ja) * | 1998-06-19 | 2000-03-07 | Nippon Polyolefin Kk | エチレン・α−オレフィン共重合体、その組成物およびそれらのフィルム |
| ATE222257T1 (de) | 1998-08-11 | 2002-08-15 | Dow Chemical Co | Katalysatoraktivatorverbindung |
| AU4440499A (en) | 1998-08-11 | 2000-03-06 | Dow Chemical Company, The | Ansa-group-4-metal bis (.mu.-substituted) aluminum complexes |
| US6306658B1 (en) | 1998-08-13 | 2001-10-23 | Symyx Technologies | Parallel reactor with internal sensing |
| US6316663B1 (en) | 1998-09-02 | 2001-11-13 | Symyx Technologies, Inc. | Catalyst ligands, catalytic metal complexes and processes using and methods of making the same |
| TW576843B (en) * | 1998-12-25 | 2004-02-21 | Mitsui Chemicals Inc | Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst |
| CN1334817A (zh) | 1999-02-19 | 2002-02-06 | 陶氏化学公司 | 制备三氟芳基铝醚合物的方法 |
| AU4186500A (en) | 1999-04-01 | 2000-10-23 | Symyx Technologies, Inc. | Polymerization catalyst ligands, catalytic metal complexes and compositions and processes using and methods of making same |
| JP2001081120A (ja) * | 1999-09-16 | 2001-03-27 | Agency Of Ind Science & Technol | オレフィン系リビング重合体の製法 |
| DE60001558T2 (de) | 1999-05-13 | 2004-01-08 | Dow Global Technologies, Inc., Midland | Di- und tri-heteroatom-substituierte metall-indenylkomplexe |
| JP2001098162A (ja) * | 1999-09-30 | 2001-04-10 | Daicel Chem Ind Ltd | 熱可塑性樹脂組成物、感熱性粘着シート及び感熱性粘着シートの製造方法 |
| US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| US6399722B1 (en) * | 1999-12-01 | 2002-06-04 | Univation Technologies, Llc | Solution feed of multiple catalysts |
| US6323284B1 (en) * | 1999-12-10 | 2001-11-27 | Exxonmobil Chemical Patents, Inc. | Method of preparation of crosslinked blends of amorphous and crystalline polymers |
| MXPA02005766A (es) | 1999-12-10 | 2004-08-12 | Dow Global Technologies Inc | Complejos sustituidos con metal del grupo 4, catalizadores y proceso de polimerizacion de olefinas. |
| US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| JP2001233923A (ja) * | 1999-12-17 | 2001-08-28 | Idemitsu Petrochem Co Ltd | プロピレン−エチレンブロック共重合体、樹脂組成物及びブロー成形体 |
| EP2267042B1 (en) * | 2000-01-26 | 2015-06-10 | Mitsui Chemicals, Inc. | Olefin diblock copolymer of very low polydispersity and process for preparing the same |
| ATE431353T1 (de) | 2000-06-30 | 2009-05-15 | Dow Global Technologies Inc | Polyzyklische, kondensierte ringverbindungen, metallkomplexe und polymerisationsprozess |
| JP2002105132A (ja) * | 2000-07-26 | 2002-04-10 | Mitsui Chemicals Inc | ポリマーおよびその製造方法 |
| NO20013880L (no) * | 2000-08-22 | 2002-02-25 | Rohm & Haas | Matriks og fremgangsmåte for fremstilling av polyolefiner |
| US6750345B2 (en) | 2000-11-07 | 2004-06-15 | Symyx Technologies, Inc. | Substituted pyridyl amine catalysts, complexes and compositions |
| WO2002046246A2 (en) * | 2000-12-04 | 2002-06-13 | Univaton Technologies, Llc | Polimerization process |
| US20030105250A1 (en) * | 2001-02-23 | 2003-06-05 | Whiteker Gregory T. | Olefin oligomerization catalysts, their production and use |
| JP2002275325A (ja) * | 2001-03-15 | 2002-09-25 | Mitsui Chemicals Inc | プロピレン系重合体組成物 |
| MY131000A (en) * | 2001-03-16 | 2007-07-31 | Dow Global Technologies Inc | High melt strength polymers and method of making same |
| CA2446116A1 (en) | 2001-05-14 | 2002-11-21 | Dow Global Technologies Inc. | 3-aryl-substituted cyclopentadienyl metal complexes and polymerization process |
| US6444867B1 (en) | 2001-05-17 | 2002-09-03 | Bp Corporation North America Inc. | Process for linear alpha olefins |
| US6727329B2 (en) | 2001-07-23 | 2004-04-27 | Dow Global Technology Inc. | Salts of lewis acid/acid adducts and catalyst activators therefrom |
| US7087686B2 (en) * | 2001-08-06 | 2006-08-08 | Bp Chemicals Limited | Chain growth reaction process |
| WO2003022890A1 (en) * | 2001-09-11 | 2003-03-20 | Exxonmobil Chemical Patents Inc. | Method for preparing polyolefins |
| EP1444276A1 (en) * | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| JP2003160684A (ja) * | 2001-11-26 | 2003-06-03 | Chisso Corp | ポリプロピレン樹脂成形体 |
| US7101939B2 (en) * | 2001-11-30 | 2006-09-05 | Exxonmobil Chemical Patents Inc. | Ethylene/α-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use |
| JP4013555B2 (ja) * | 2002-01-11 | 2007-11-28 | 住友化学株式会社 | 収縮包装用フィルムおよびラベル |
| JP2003211481A (ja) * | 2002-01-25 | 2003-07-29 | Chisso Corp | 熱可塑性樹脂と発泡剤を用いた成形方法およびその成形方法により得られた成形体 |
| JP2003238611A (ja) * | 2002-02-18 | 2003-08-27 | Japan Polyolefins Co Ltd | オレフィン類重合用触媒成分、オレフィン類重合用触媒及びポリオレフィン類の製造方法 |
| ES2307956T3 (es) | 2002-03-14 | 2008-12-01 | Dow Global Technologies Inc. | Complejos metalicos con indenilo sustituido y procedimientos de polimerizacion. |
| WO2003078480A2 (en) | 2002-03-14 | 2003-09-25 | Dow Global Technologies Inc. | Polycyclic, fused heteroring compounds, metal complexes and polymerization process |
| DE60335459D1 (de) | 2002-04-24 | 2011-02-03 | Symyx Solutions Inc | Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere |
| US6875828B2 (en) * | 2002-09-04 | 2005-04-05 | Univation Technologies, Llc | Bimodal polyolefin production process and films therefrom |
| JP2005539060A (ja) | 2002-09-12 | 2005-12-22 | ダウ・グローバル・テクノロジーズ・インコーポレイテッド | 金属錯体の製造方法 |
| EP2261292B1 (en) * | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US6797779B1 (en) | 2003-03-28 | 2004-09-28 | The Goodyear Tire & Rubber Company | Thermoplastic composition |
| US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
| KR101277095B1 (ko) * | 2004-03-17 | 2013-06-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 셔틀링제를 포함하는, 에틸렌 공중합체 형성용 촉매 조성물 |
| JP5133050B2 (ja) * | 2004-03-17 | 2013-01-30 | ダウ グローバル テクノロジーズ エルエルシー | エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
| EP2792690B1 (en) * | 2004-03-17 | 2019-05-15 | Dow Global Technologies LLC | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| JP2008509277A (ja) * | 2004-08-09 | 2008-03-27 | ダウ グローバル テクノロジーズ インコーポレイティド | ポリマーの製造のための担持ビス(ヒドロキシアリールアリールオキシ)触媒 |
-
2005
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- 2005-03-17 SG SG200901995-1A patent/SG151301A1/en unknown
- 2005-03-17 RU RU2006136414A patent/RU2381240C2/ru not_active IP Right Cessation
- 2005-03-17 TW TW94108201A patent/TWI391412B/zh not_active IP Right Cessation
- 2005-03-17 ES ES05730993T patent/ES2342895T3/es not_active Expired - Lifetime
- 2005-03-17 TW TW094108182A patent/TW200604224A/zh unknown
- 2005-03-17 EP EP09179528.6A patent/EP2221328B1/en not_active Expired - Lifetime
-
2006
- 2006-09-15 KR KR1020067019103A patent/KR101266331B1/ko not_active Expired - Lifetime
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2011
- 2011-11-18 JP JP2011252527A patent/JP5587279B2/ja not_active Expired - Lifetime
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2013
- 2013-12-17 JP JP2013259896A patent/JP2014065920A/ja active Pending
-
2015
- 2015-12-24 JP JP2015250806A patent/JP6651348B2/ja not_active Expired - Lifetime
-
2018
- 2018-08-06 JP JP2018147762A patent/JP6907163B2/ja not_active Expired - Lifetime
- 2018-12-21 JP JP2018239462A patent/JP6887983B2/ja not_active Expired - Lifetime
Non-Patent Citations (2)
| Title |
|---|
| LIEBER SUSANNA ET AL: "Propene polymerization with catalyst mixtures containing different ansa-circonocenes: chain transfer to alkilaluminum cocatalysts and formation of stereoblock polymers", MACROMOLECULES, 12.12.2000, pages 9192-9199. * |
| PRZYBLA, FINK: "Two different on the same silica supported metallocene catalysts, activated by various trialkilaluminums", ACTA POLYMERICA, vol.50, 21.04.1999, pages 77-83. * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11299617B2 (en) | 2018-10-02 | 2022-04-12 | Borealis Ag | Low speed cross-linking catalyst for silane-grafted plastomers |
| RU2772246C1 (ru) * | 2018-10-02 | 2022-05-18 | Бореалис Аг | Катализатор для низкоскоростного сшивания привитых силаном пластомеров |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2019059955A (ja) | 2019-04-18 |
| TWI391412B (zh) | 2013-04-01 |
| RU2006136412A (ru) | 2008-04-27 |
| JP5587279B2 (ja) | 2014-09-10 |
| TW200604224A (en) | 2006-02-01 |
| SG183748A1 (en) | 2012-09-27 |
| JP2014065920A (ja) | 2014-04-17 |
| JP6907163B2 (ja) | 2021-07-21 |
| EP2221328A2 (en) | 2010-08-25 |
| JP6887983B2 (ja) | 2021-06-16 |
| JP2012082424A (ja) | 2012-04-26 |
| RU2006136414A (ru) | 2008-04-27 |
| EP2221328A3 (en) | 2010-12-22 |
| JP2018188666A (ja) | 2018-11-29 |
| EP2221329B1 (en) | 2014-11-26 |
| EP2221328B1 (en) | 2017-04-19 |
| ES2342895T3 (es) | 2010-07-16 |
| SG183749A1 (en) | 2012-09-27 |
| KR20070004731A (ko) | 2007-01-09 |
| KR101266331B1 (ko) | 2013-05-23 |
| JP6651348B2 (ja) | 2020-02-19 |
| TW200604225A (en) | 2006-02-01 |
| TW200536870A (en) | 2005-11-16 |
| EP2792690A1 (en) | 2014-10-22 |
| RU2375381C2 (ru) | 2009-12-10 |
| JP2016094624A (ja) | 2016-05-26 |
| EP2221329A1 (en) | 2010-08-25 |
| SG151301A1 (en) | 2009-04-30 |
| EP2792690B1 (en) | 2019-05-15 |
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