RU2366505C2 - Носитель катализатора и каталитическая композиция, способы их получения и применения - Google Patents
Носитель катализатора и каталитическая композиция, способы их получения и применения Download PDFInfo
- Publication number
- RU2366505C2 RU2366505C2 RU2006134729/04A RU2006134729A RU2366505C2 RU 2366505 C2 RU2366505 C2 RU 2366505C2 RU 2006134729/04 A RU2006134729/04 A RU 2006134729/04A RU 2006134729 A RU2006134729 A RU 2006134729A RU 2366505 C2 RU2366505 C2 RU 2366505C2
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- carrier
- range
- hydrocracking
- zeolite
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 141
- 238000000034 method Methods 0.000 title claims abstract description 77
- 239000000203 mixture Substances 0.000 title claims abstract description 75
- 238000002360 preparation method Methods 0.000 title abstract description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 82
- 239000010457 zeolite Substances 0.000 claims abstract description 68
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 51
- 229910052751 metal Inorganic materials 0.000 claims abstract description 44
- 239000002184 metal Substances 0.000 claims abstract description 44
- 239000011148 porous material Substances 0.000 claims abstract description 42
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 41
- 238000001354 calcination Methods 0.000 claims abstract description 12
- 238000005470 impregnation Methods 0.000 claims abstract description 12
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 8
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 7
- 238000009826 distribution Methods 0.000 claims abstract description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 5
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 4
- 125000000524 functional group Chemical group 0.000 claims abstract description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 4
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 238000001556 precipitation Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 56
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 47
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 28
- 229910052710 silicon Inorganic materials 0.000 claims description 25
- 239000010703 silicon Substances 0.000 claims description 25
- 238000001125 extrusion Methods 0.000 claims description 20
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 14
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 13
- 229910052721 tungsten Inorganic materials 0.000 claims description 13
- 239000010937 tungsten Substances 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 230000003197 catalytic effect Effects 0.000 claims description 11
- 150000002739 metals Chemical class 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 229910052796 boron Inorganic materials 0.000 claims description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 5
- 235000015165 citric acid Nutrition 0.000 claims description 5
- 239000001630 malic acid Substances 0.000 claims description 5
- 235000011090 malic acid Nutrition 0.000 claims description 5
- 238000002459 porosimetry Methods 0.000 claims description 5
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 239000012013 faujasite Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 238000005259 measurement Methods 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 238000000137 annealing Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 25
- 238000005984 hydrogenation reaction Methods 0.000 abstract description 11
- 230000001737 promoting effect Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract 2
- CFOAUMXQOCBWNJ-UHFFFAOYSA-N [B].[Si] Chemical compound [B].[Si] CFOAUMXQOCBWNJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 23
- 239000007788 liquid Substances 0.000 description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 20
- 239000003921 oil Substances 0.000 description 19
- 239000007789 gas Substances 0.000 description 16
- 239000002210 silicon-based material Substances 0.000 description 16
- 239000000377 silicon dioxide Substances 0.000 description 14
- -1 clays Chemical compound 0.000 description 13
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
- 238000009835 boiling Methods 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 12
- 239000001257 hydrogen Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 229910052717 sulfur Inorganic materials 0.000 description 12
- 239000011593 sulfur Substances 0.000 description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000005336 cracking Methods 0.000 description 9
- 238000001035 drying Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- 239000000969 carrier Substances 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 239000011733 molybdenum Substances 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
- 229960002645 boric acid Drugs 0.000 description 4
- 235000010338 boric acid Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000005486 sulfidation Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 235000004035 Cryptotaenia japonica Nutrition 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 102000007641 Trefoil Factors Human genes 0.000 description 2
- 235000015724 Trifolium pratense Nutrition 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- ONVOAGRVBFOWSS-UHFFFAOYSA-N [B]=O.[Si](=O)=O Chemical compound [B]=O.[Si](=O)=O ONVOAGRVBFOWSS-UHFFFAOYSA-N 0.000 description 2
- 239000002156 adsorbate Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000007373 indentation Methods 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910018125 Al-Si Inorganic materials 0.000 description 1
- 229910018520 Al—Si Inorganic materials 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- OTRAYOBSWCVTIN-UHFFFAOYSA-N OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N Chemical compound OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N OTRAYOBSWCVTIN-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000012050 conventional carrier Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- AZRCNKIZGKJWOA-UHFFFAOYSA-N dioxosilane oxygen(2-) zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4].O=[Si]=O AZRCNKIZGKJWOA-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- GALOTNBSUVEISR-UHFFFAOYSA-N molybdenum;silicon Chemical compound [Mo]#[Si] GALOTNBSUVEISR-UHFFFAOYSA-N 0.000 description 1
- 229910052605 nesosilicate Inorganic materials 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000007793 ph indicator Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- WNUPENMBHHEARK-UHFFFAOYSA-N silicon tungsten Chemical compound [Si].[W] WNUPENMBHHEARK-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04251241 | 2004-03-03 | ||
| EP04251241.8 | 2004-03-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006134729A RU2006134729A (ru) | 2008-04-10 |
| RU2366505C2 true RU2366505C2 (ru) | 2009-09-10 |
Family
ID=34896131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006134729/04A RU2366505C2 (ru) | 2004-03-03 | 2005-03-01 | Носитель катализатора и каталитическая композиция, способы их получения и применения |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20050197249A1 (zh) |
| EP (1) | EP1735094A1 (zh) |
| JP (1) | JP2007526119A (zh) |
| KR (1) | KR20070004776A (zh) |
| CN (1) | CN100428995C (zh) |
| BR (1) | BRPI0508276A (zh) |
| CA (1) | CA2558172A1 (zh) |
| RU (1) | RU2366505C2 (zh) |
| UA (1) | UA91016C2 (zh) |
| WO (1) | WO2005084799A1 (zh) |
| ZA (1) | ZA200606951B (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2633965C1 (ru) * | 2016-10-19 | 2017-10-20 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Способ приготовления катализатора гидрокрекинга углеводородного сырья |
| RU2640804C2 (ru) * | 2012-09-17 | 2018-01-18 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения катализатора гидрокрекинга |
| RU2776810C1 (ru) * | 2018-12-13 | 2022-07-26 | Чайна Петролиум энд Кемикал Корпорейшн | Катализатор гидрокрекинга, способ его получения и его применение |
| US11779909B2 (en) | 2018-12-13 | 2023-10-10 | China Petroleum & Chemical Corporation | Hydrocracking catalyst, preparation method therefor and application thereof |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7169291B1 (en) * | 2003-12-31 | 2007-01-30 | Uop Llc | Selective hydrocracking process using beta zeolite |
| US6974788B2 (en) * | 2004-03-12 | 2005-12-13 | Chevron Oronite Company Llc. | Zeolite Y alkylation catalysts |
| US7507844B2 (en) * | 2005-05-09 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides |
| US7585405B2 (en) * | 2005-11-04 | 2009-09-08 | Uop Llc | Hydrocracking catalyst containing beta and Y zeolites, and process for its use to make jet fuel or distillate |
| US7510645B2 (en) * | 2005-11-04 | 2009-03-31 | Uop Llc | Hydrocracking catalyst containing beta and Y zeolites, and process for its use to produce naphtha |
| EP2823886B1 (en) | 2005-12-14 | 2019-08-14 | Advanced Refining Technologies, LLC | Method of making hydroprocessing catalyst |
| EP2029273B1 (en) * | 2006-06-20 | 2023-08-02 | Shell Internationale Research Maatschappij B.V. | A sulfur tolerant noble metal containing aromatics hydrogenation catalyst and a method of making and using such catalyst |
| US20080011648A1 (en) * | 2006-07-17 | 2008-01-17 | Li Wang | Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate |
| US20080011647A1 (en) * | 2006-07-17 | 2008-01-17 | Li Wang | Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate |
| US20080011649A1 (en) * | 2006-07-17 | 2008-01-17 | Li Wang | Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate |
| RU2469789C2 (ru) * | 2007-08-27 | 2012-12-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Катализатор гидрирования ароматических углеводородов и способ получения и применения такого катализатора |
| US9636662B2 (en) * | 2008-02-21 | 2017-05-02 | Saudi Arabian Oil Company | Catalyst to attain low sulfur gasoline |
| US9199228B2 (en) | 2009-04-29 | 2015-12-01 | Shell Oil Company | Hydrocracking catalyst |
| CA2760181C (en) * | 2009-04-29 | 2016-12-20 | Pq Corporation | Zeolite y |
| DE102009026585A1 (de) * | 2009-05-29 | 2010-12-02 | Evonik Oxeno Gmbh | Herstellung von 3-Methylbut-1-en durch Dehydratisierung von 3-Methylbutan-1-ol |
| US9187702B2 (en) | 2009-07-01 | 2015-11-17 | Chevron U.S.A. Inc. | Hydroprocessing catalyst and method of making the same |
| JP5547923B2 (ja) | 2009-08-03 | 2014-07-16 | 出光興産株式会社 | 重質油水素化分解触媒及びそれを用いた重質油の水素化処理方法 |
| CN103889573B (zh) | 2011-10-24 | 2016-08-24 | 道达尔炼油法国 | 用于制备加氢转化催化剂的方法、由此获得的催化剂及其在加氢转化方法中的用途 |
| EP2794090B1 (en) * | 2011-12-23 | 2016-08-10 | Shell Internationale Research Maatschappij B.V. | Process for preparing hydrocracking catalyst compositions |
| WO2013129614A1 (ja) * | 2012-02-28 | 2013-09-06 | 積水化学工業株式会社 | Ｃ２酸素化物合成用の触媒、ｃ２酸素化物の製造装置及びｃ２酸素化物の製造方法 |
| KR101885247B1 (ko) * | 2012-07-26 | 2018-08-03 | 삼성전자주식회사 | Ｃｏ２ 개질용 촉매, 그 제조 방법, 및 ｃｏ２ 개질 방법 |
| MX349965B (es) * | 2012-11-14 | 2017-08-04 | Univ Mexico Nac Autonoma | Catalizadores soportados para la produccion de combustibles de ultra-bajo azufre. |
| US20150159095A1 (en) * | 2013-12-09 | 2015-06-11 | Bi-Zeng Zhan | Method for making a middle distillate |
| US10138428B2 (en) * | 2014-05-08 | 2018-11-27 | Reliance Industries Limited | Catalyst assisted conversion of biomass to bio-oil |
| US20160121313A1 (en) * | 2014-10-31 | 2016-05-05 | Chevron U.S.A. Inc. | Middle distillate hydrocracking catalyst containing highly a stabilized y zeolite with enhanced acid site distribution |
| US20160121312A1 (en) * | 2014-10-31 | 2016-05-05 | Chevron U.S.A. Inc. | Middle distillate hydrocracking catalyst containing highly nanoporous stabilized y zeolite |
| US10183282B2 (en) * | 2015-01-22 | 2019-01-22 | Chevron U.S.A. Inc. | Noble metal zeolite catalyst for second-stage hydrocracking |
| US10183286B2 (en) * | 2015-08-11 | 2019-01-22 | Chevron U.S.A. Inc. | Noble metal zeolite catalyst for second-stage hydrocracking to make middle distillate |
| CN107344107B (zh) * | 2016-05-05 | 2019-10-15 | 中国石油化工股份有限公司 | 一种加氢改质催化剂及其制备方法 |
| CN107469870A (zh) * | 2017-08-29 | 2017-12-15 | 淄博齐茂催化剂有限公司 | 一种调节孔结构的催化剂的制备方法 |
| US20190126227A1 (en) * | 2017-10-30 | 2019-05-02 | Saudi Arabian Oil Company | Catalyst loading method to disperse heat in hydroconversion reactor |
| FR3130640A1 (fr) | 2021-12-21 | 2023-06-23 | IFP Energies Nouvelles | Catalyseur comprenant un support à base de matrice silico-aluminique et de zéolithe, sa préparation et procédé d’hydrocraquage de charges hydrocarbonées |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3130007A (en) * | 1961-05-12 | 1964-04-21 | Union Carbide Corp | Crystalline zeolite y |
| US4003851A (en) * | 1973-10-31 | 1977-01-18 | American Cyanamid Company | Stable alumina catalyst support, process therefor, and promoted support |
| US3992464A (en) * | 1974-11-08 | 1976-11-16 | Uop Inc. | Hydroprocessing aromatics to make cycloparaffins |
| DE2503712A1 (de) * | 1975-01-30 | 1976-08-05 | Bayer Ag | Brandschutz-dichtungselemente |
| US4085069A (en) * | 1976-08-27 | 1978-04-18 | Filtrol Corporation | Hydrothermally stable catalysts containing ammonium faujasite zeolites |
| US4419271A (en) * | 1979-10-15 | 1983-12-06 | Union Oil Company Of California | Hydrocarbon conversion catalyst |
| US4401556A (en) * | 1979-11-13 | 1983-08-30 | Union Carbide Corporation | Midbarrel hydrocracking |
| US4572778A (en) * | 1984-01-19 | 1986-02-25 | Union Oil Company Of California | Hydroprocessing with a large pore catalyst |
| JPS6115739A (ja) * | 1984-04-25 | 1986-01-23 | Toa Nenryo Kogyo Kk | 水素化処理用触媒 |
| FR2582665B1 (fr) * | 1985-06-04 | 1988-08-05 | Inst Francais Du Petrole | Procede de craquage catalytique |
| JPS62199687A (ja) * | 1986-04-28 | 1987-09-03 | ユニオン・オイル・コンパニ−・オブ・カリフオルニア | 細孔の大きい触媒を用いる水素化法 |
| US5160033A (en) * | 1988-03-30 | 1992-11-03 | Uop | Octane gasoline catalyst and process using same in a hydrocracking process |
| US5223240A (en) * | 1989-08-16 | 1993-06-29 | Degussa Aktiengesellschaft | Method of preparing zeolite Y |
| JP2547115B2 (ja) * | 1990-03-30 | 1996-10-23 | 財団法人石油産業活性化センター | 炭化水素油用水素化処理触媒組成物ならびにそれを用いる水素化処理方法 |
| US5350501A (en) * | 1990-05-22 | 1994-09-27 | Union Oil Company Of California | Hydrocracking catalyst and process |
| ES2086476T3 (es) * | 1990-08-03 | 1996-07-01 | Akzo Nobel Nv | Procedimiento de hidrodesulfuracion. |
| US5507940A (en) * | 1991-08-30 | 1996-04-16 | Shell Oil Company | Hydrodenitrification catalyst and process |
| US5242677A (en) * | 1992-06-11 | 1993-09-07 | Pq Corporation | Stable zeolite of low unit cell constant and method of making same |
| MX9305801A (es) * | 1992-09-29 | 1994-07-29 | Texaco Development Corp | Proceso de hidroconversion novedoso que emplea catalizador con distribucion especificada de tamaño de poro. |
| US5234876A (en) * | 1992-10-20 | 1993-08-10 | Corning Incorporated | Thermally stable chromium-exchanged zeolites and method of making same |
| JPH06154610A (ja) * | 1992-11-27 | 1994-06-03 | Chevron Res & Technol Co | 高いメタル含有量を有する残油用の触媒、その製造法及び使用プロセス |
| US5435987A (en) * | 1993-07-22 | 1995-07-25 | Pq Corporation | Process for preparing ammonium zeolites of low alkali metal content |
| KR19980702741A (ko) * | 1995-03-03 | 1998-08-05 | 반주트펜조한스아아르트 | 촉매 조성물, 및 탄화수소 전환 방법에서의 그것의 용도 |
| FR2779072B1 (fr) * | 1998-05-28 | 2000-07-13 | Inst Francais Du Petrole | Catalyseur comprenant une zeolithe choisie dans le groupe forme par les zeolithes nu-85, nu-86 et nu-87, un element du groupe vb et son utilisation en hydroconversion de charges petrolieres hydrocarbonees |
| FR2780308B1 (fr) * | 1998-06-25 | 2000-08-11 | Inst Francais Du Petrole | Catalyseur comprenant une argile et un element du groupe vb, et son utilisation en hydrocraquage de charges petrolieres hydrocarbonees |
| US6136291A (en) * | 1998-10-08 | 2000-10-24 | Mobile Oil Corporation | Faujasite zeolitic materials |
| CN1096296C (zh) * | 1998-11-13 | 2002-12-18 | 中国石油化工集团公司 | 一种生产中间馏分油的加氢裂化催化剂及其制备 |
| JP3553429B2 (ja) * | 1999-03-29 | 2004-08-11 | 株式会社コスモ総合研究所 | 軽油の水素化処理触媒及び軽油の水素化処理方法 |
| JP4643805B2 (ja) * | 2000-07-28 | 2011-03-02 | 日本ケッチェン株式会社 | 重質炭化水素油の水素化処理触媒および水素化処理方法 |
| CN1108356C (zh) * | 2000-10-26 | 2003-05-14 | 中国石油化工股份有限公司 | 一种高活性高中油性加氢裂化催化剂及其制备方法 |
| FR2819430B1 (fr) * | 2001-01-15 | 2003-02-28 | Inst Francais Du Petrole | Catalyseur comportant une silice-alumine et son utilisation en hydrocraquage de charges hydrocarbonees |
| JP4156859B2 (ja) * | 2001-06-20 | 2008-09-24 | コスモ石油株式会社 | 軽油の水素化処理触媒及びその製造方法並びに軽油の水素化処理方法 |
| US20040064008A1 (en) * | 2002-09-30 | 2004-04-01 | Torsten Maurer | Molecular sieve catalyst composition |
| WO2004050548A2 (en) * | 2002-11-27 | 2004-06-17 | Pq Holding, Inc. | High surface area zeolites and methods for preparation and use thereof |
| US7192900B2 (en) * | 2002-11-27 | 2007-03-20 | Shell Oil Company | Hydrocracking catalyst |
| FR2863913B1 (fr) * | 2003-12-23 | 2006-12-29 | Inst Francais Du Petrole | Catalyseur zeolithique,support a base de matrice silico-aluminique et de zeolithe, et procede d'hydrocraquage de charges hydrocarbonees |
| JP3990673B2 (ja) * | 2004-02-09 | 2007-10-17 | 触媒化成工業株式会社 | 軽油の水素化脱硫方法 |
-
2005
- 2005-03-01 KR KR1020067019894A patent/KR20070004776A/ko not_active Application Discontinuation
- 2005-03-01 UA UAA200610342A patent/UA91016C2/ru unknown
- 2005-03-01 CN CNB2005800099444A patent/CN100428995C/zh active Active
- 2005-03-01 RU RU2006134729/04A patent/RU2366505C2/ru active
- 2005-03-01 JP JP2007501276A patent/JP2007526119A/ja active Pending
- 2005-03-01 BR BRPI0508276-5A patent/BRPI0508276A/pt not_active IP Right Cessation
- 2005-03-01 WO PCT/EP2005/050866 patent/WO2005084799A1/en active Application Filing
- 2005-03-01 EP EP05716843A patent/EP1735094A1/en not_active Withdrawn
- 2005-03-01 US US11/069,425 patent/US20050197249A1/en not_active Abandoned
- 2005-03-01 CA CA002558172A patent/CA2558172A1/en not_active Abandoned
-
2006
- 2006-08-18 ZA ZA2006/06951A patent/ZA200606951B/en unknown
Non-Patent Citations (1)
| Title |
|---|
| Us 2003/173256 A1 18.09.2003. * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2640804C2 (ru) * | 2012-09-17 | 2018-01-18 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения катализатора гидрокрекинга |
| RU2633965C1 (ru) * | 2016-10-19 | 2017-10-20 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Способ приготовления катализатора гидрокрекинга углеводородного сырья |
| RU2776810C1 (ru) * | 2018-12-13 | 2022-07-26 | Чайна Петролиум энд Кемикал Корпорейшн | Катализатор гидрокрекинга, способ его получения и его применение |
| US11779909B2 (en) | 2018-12-13 | 2023-10-10 | China Petroleum & Chemical Corporation | Hydrocracking catalyst, preparation method therefor and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1735094A1 (en) | 2006-12-27 |
| BRPI0508276A (pt) | 2007-08-07 |
| CN1938088A (zh) | 2007-03-28 |
| WO2005084799A1 (en) | 2005-09-15 |
| KR20070004776A (ko) | 2007-01-09 |
| ZA200606951B (en) | 2008-04-30 |
| UA91016C2 (ru) | 2010-06-25 |
| CA2558172A1 (en) | 2005-09-15 |
| JP2007526119A (ja) | 2007-09-13 |
| CN100428995C (zh) | 2008-10-29 |
| US20050197249A1 (en) | 2005-09-08 |
| RU2006134729A (ru) | 2008-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2366505C2 (ru) | Носитель катализатора и каталитическая композиция, способы их получения и применения | |
| RU2338590C2 (ru) | Каталитическая композиция для гидрокрекинга и способ превращения углеводородного сырья в низкокипящие материалы | |
| US10864504B2 (en) | Hydrocracking catalyst | |
| US7300900B2 (en) | Catalyst comprising at least one zeolite chosen from ZBM-30, SM-48 EU-2 and EU-11 and at least one Y zeolite and process of hydroconversion of hydrocarbon charges using such a catalyst | |
| US4661239A (en) | Middle distillate producing hydrocracking process | |
| US9914113B2 (en) | Hydrocracking process using a zeolite catalyst containing two distinct hydrogenating functions | |
| US9718050B2 (en) | Catalyst comprising at least one zeolite NU-86, at least one zeolite USY and a porous mineral matrix and process for hydroconversion of hydrocarbon feeds using said catalyst | |
| KR20000006454A (ko) | 베타제올라이트및ｖｂ족원소를포함하는수소화분해증류촉매 | |
| US6500330B2 (en) | Hydrocracking process with catalyst comprising a zeolite Y not globally dealuminized, an element of group VB, and a promoter element of boron, phosphorus and silicon | |
| JP4644763B2 (ja) | 水素化分解に有用なケイ素含有ｙ型ゼオライトベース触媒 | |
| JP2007506809A (ja) | 炭化水素転化法および触媒 | |
| MX2014007367A (es) | Procedimiento de preparacion de un catalizador utilizable en hidroconversion que comprende por lo menos una zeolita nu-86. | |
| US20070125684A1 (en) | Hydrocracking Catalyst and Process | |
| AU2015339950A1 (en) | Middle distillate hydrocracking catalyst containing highly A stabilized Y zeolite with enhanced acid site distribution | |
| CA2825324C (en) | Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite y and associated hydrocarbon conversion processes | |
| JP4780537B2 (ja) | 部分非晶質ゼオライトｙおよび第ｖｂ族元素を含む触媒、並びに炭化水素石油仕込原料の水素化転換および水素化精製におけるその使用 | |
| WO2014098820A1 (en) | Mesoporous zeolite -y hydrocracking catalyst and associated hydrocracking processes | |
| EP0698074B1 (en) | Process for hydrocracking hydrocarbons | |
| TW202330100A (zh) | 包含基於二氧化矽－氧化鋁基質及沸石之載體之催化劑，其製備方法及對烴進料加氫裂解之方法 | |
| JPH0655951B2 (ja) | 中間留分の水添分解式製造方法及びそれに用いられる触媒組成物 |