RU2346016C2 - Отверждение покрытий, индуцированное плазмой - Google Patents

Info

Publication number

RU2346016C2

RU2346016C2 RU2004133886/04A RU2004133886A RU2346016C2 RU 2346016 C2 RU2346016 C2 RU 2346016C2 RU 2004133886/04 A RU2004133886/04 A RU 2004133886/04A RU 2004133886 A RU2004133886 A RU 2004133886A RU 2346016 C2 RU2346016 C2 RU 2346016C2

Authority

RU

Russia

Prior art keywords

alkyl

phenyl

compound

composition

hydrogen atom

Prior art date

2002-04-19

Links

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• 238000000576 coating method Methods 0.000 title claims abstract description 128
• 239000011248 coating agent Substances 0.000 title claims abstract description 86
• 230000008023 solidification Effects 0.000 title abstract 4
• 238000007711 solidification Methods 0.000 title abstract 4
• 239000000203 mixture Substances 0.000 claims abstract description 188
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• 238000000034 method Methods 0.000 claims abstract description 84
• 239000000758 substrate Substances 0.000 claims abstract description 50
• 229920000642 polymer Polymers 0.000 claims abstract description 49
• 239000002253 acid Substances 0.000 claims abstract description 38
• 150000003254 radicals Chemical class 0.000 claims abstract description 37
• 239000000178 monomer Substances 0.000 claims abstract description 25
• 125000003118 aryl group Chemical group 0.000 claims abstract description 22
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• 239000002131 composite material Substances 0.000 claims abstract description 8
• 239000012949 free radical photoinitiator Substances 0.000 claims abstract description 7
• 150000001768 cations Chemical class 0.000 claims abstract description 6
• -1 siloxane radical Chemical class 0.000 claims description 228
• 125000000217 alkyl group Chemical group 0.000 claims description 93
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 75
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 48
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 28
• 238000006243 chemical reaction Methods 0.000 claims description 27
• 229920000058 polyacrylate Polymers 0.000 claims description 26
• 125000005843 halogen group Chemical group 0.000 claims description 25
• 229910052757 nitrogen Inorganic materials 0.000 claims description 23
• 229920000728 polyester Polymers 0.000 claims description 23
• 238000006116 polymerization reaction Methods 0.000 claims description 23
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• 150000001412 amines Chemical class 0.000 claims description 20
• 239000000654 additive Substances 0.000 claims description 19
• 239000000049 pigment Substances 0.000 claims description 18
• 230000009471 action Effects 0.000 claims description 16
• 125000002947 alkylene group Chemical group 0.000 claims description 15
• 150000002170 ethers Chemical class 0.000 claims description 15
• 125000001624 naphthyl group Chemical group 0.000 claims description 15
• 229920000877 Melamine resin Polymers 0.000 claims description 13
• 238000007639 printing Methods 0.000 claims description 13
• 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 12
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 12
• 239000004611 light stabiliser Substances 0.000 claims description 12
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 11
• 239000000975 dye Substances 0.000 claims description 11
• 125000004433 nitrogen atom Chemical group N* 0.000 claims description 11
• 150000008064 anhydrides Chemical class 0.000 claims description 10
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 10
• 229910052760 oxygen Inorganic materials 0.000 claims description 10
• 229920001228 polyisocyanate Polymers 0.000 claims description 10
• 239000005056 polyisocyanate Substances 0.000 claims description 10
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• 125000001424 substituent group Chemical group 0.000 claims description 10
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 9
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 9
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• 238000004519 manufacturing process Methods 0.000 claims description 8
• 125000003342 alkenyl group Chemical group 0.000 claims description 7
• 239000012965 benzophenone Substances 0.000 claims description 7
• 125000004432 carbon atom Chemical group C* 0.000 claims description 7
• FAQJJMHZNSSFSM-UHFFFAOYSA-N phenylglyoxylic acid Chemical class OC(=O)C(=O)C1=CC=CC=C1 FAQJJMHZNSSFSM-UHFFFAOYSA-N 0.000 claims description 7
• KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 6
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
• PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 6
• 150000008366 benzophenones Chemical class 0.000 claims description 6
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
• 229910052717 sulfur Inorganic materials 0.000 claims description 6
• 125000003545 alkoxy group Chemical group 0.000 claims description 5
• 150000004056 anthraquinones Chemical class 0.000 claims description 5
• 229910052801 chlorine Inorganic materials 0.000 claims description 5
• HEQOJEGTZCTHCF-UHFFFAOYSA-N 2-amino-1-phenylethanone Chemical class NCC(=O)C1=CC=CC=C1 HEQOJEGTZCTHCF-UHFFFAOYSA-N 0.000 claims description 4
• 125000003860 C1-C20 alkoxy group Chemical group 0.000 claims description 4
• 150000008062 acetophenones Chemical class 0.000 claims description 4
• MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 4
• 229910052799 carbon Inorganic materials 0.000 claims description 4
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 4
• 125000001188 haloalkyl group Chemical group 0.000 claims description 4
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• 125000005146 naphthylsulfonyl group Chemical group C1(=CC=CC2=CC=CC=C12)S(=O)(=O)* 0.000 claims description 4
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• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 4
• 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 claims description 4
• 125000004434 sulfur atom Chemical group 0.000 claims description 4
• 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 3
• 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 3
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• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
• 229910052736 halogen Inorganic materials 0.000 claims description 3
• 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 3
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
• 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 claims description 3
• 125000005561 phenanthryl group Chemical group 0.000 claims description 3
• 230000000379 polymerizing effect Effects 0.000 claims description 3
• 238000002203 pretreatment Methods 0.000 claims description 3
• LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 3
• 125000004641 (C1-C12) haloalkyl group Chemical group 0.000 claims description 2
• 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims description 2
• 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims description 2
• XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 2
• FNDFKMXAOATGJU-UHFFFAOYSA-N 1-phenyl-2-sulfonylethanone Chemical class O=S(=O)=CC(=O)C1=CC=CC=C1 FNDFKMXAOATGJU-UHFFFAOYSA-N 0.000 claims description 2
• MXFOQZLUCVHVRD-UHFFFAOYSA-N 2-methylsulfonyloxyethyl-[2,3,4,5-tetrahydroxy-6-(2-methylsulfonyloxyethylamino)hexyl]azanium;chloride Chemical compound [Cl-].CS(=O)(=O)OCCNCC(O)C(O)C(O)C(O)C[NH2+]CCOS(C)(=O)=O MXFOQZLUCVHVRD-UHFFFAOYSA-N 0.000 claims description 2
• 229910017008 AsF 6 Inorganic materials 0.000 claims description 2
• 229910015892 BF 4 Inorganic materials 0.000 claims description 2
• 229910020366 ClO 4 Inorganic materials 0.000 claims description 2
• 229910021115 PF 6 Inorganic materials 0.000 claims description 2
• 229910018286 SbF 6 Inorganic materials 0.000 claims description 2
• 125000004450 alkenylene group Chemical group 0.000 claims description 2
• 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 2
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• 150000001454 anthracenes Chemical class 0.000 claims description 2
• 125000004429 atom Chemical group 0.000 claims description 2
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• 125000003944 tolyl group Chemical group 0.000 claims description 2
• CDSULTPOCMWJCM-UHFFFAOYSA-N 4h-chromene-2,3-dione Chemical compound C1=CC=C2OC(=O)C(=O)CC2=C1 CDSULTPOCMWJCM-UHFFFAOYSA-N 0.000 claims 2
• UORVGPXVDQYIDP-BJUDXGSMSA-N borane Chemical class [10BH3] UORVGPXVDQYIDP-BJUDXGSMSA-N 0.000 claims 2
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