RU2337925C2 - Способ и устройство для полимеризации этилена - Google Patents

Способ и устройство для полимеризации этилена Download PDF

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RU2337925C2
RU2337925C2 RU2006108546/04A RU2006108546A RU2337925C2 RU 2337925 C2 RU2337925 C2 RU 2337925C2 RU 2006108546/04 A RU2006108546/04 A RU 2006108546/04A RU 2006108546 A RU2006108546 A RU 2006108546A RU 2337925 C2 RU2337925 C2 RU 2337925C2
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ethylene
pipe
gas
stage
reactor
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RU2006108546/04A
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English (en)
Russian (ru)
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RU2006108546A (ru
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Гербен МЕЙЕР (DE)
Гербен МЕЙЕР
Массимо КОВЕЦЦИ (IT)
Массимо КОВЕЦЦИ
Пьетро БАИТА (IT)
Пьетро БАИТА
Габриеле МЕЙ (IT)
Габриеле МЕЙ
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Базелль Полиолефин Италия С.Р.Л.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2435—Loop-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1845—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1854—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement inside the reactor to form a loop
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00619—Controlling the weight
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
RU2006108546/04A 2003-08-20 2004-07-19 Способ и устройство для полимеризации этилена RU2337925C2 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP03077645 2003-08-20
EP03077645.4 2003-08-20
US49790003P 2003-08-25 2003-08-25
US60/497,900 2003-08-25

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RU2006108546A RU2006108546A (ru) 2006-07-27
RU2337925C2 true RU2337925C2 (ru) 2008-11-10

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US (1) US7514508B2 (https=)
EP (1) EP1656398B1 (https=)
JP (1) JP4700610B2 (https=)
KR (1) KR101124187B1 (https=)
CN (1) CN100582125C (https=)
AT (1) ATE347569T1 (https=)
BR (1) BRPI0413229B1 (https=)
CA (1) CA2551017A1 (https=)
DE (1) DE602004003590T2 (https=)
ES (1) ES2278326T3 (https=)
RU (1) RU2337925C2 (https=)
SA (1) SA04250263B1 (https=)
WO (1) WO2005019280A1 (https=)

Cited By (4)

* Cited by examiner, † Cited by third party
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RU2621045C2 (ru) * 2012-10-22 2017-05-31 Базелл Полиолефин Гмбх Полиэтиленовая композиция с высокими механическими свойствами
RU2640045C1 (ru) * 2014-10-13 2017-12-26 ЭлДжи КЕМ, ЛТД. Сополимер этилен/1-гексен или этилен/1-бутен, обладающий отличными технологическими свойствами и сопротивлением разрастанию трещин под действием факторов окружающей среды
RU2781189C1 (ru) * 2018-12-27 2022-10-07 ШЕВРОН ФИЛЛИПС КЕМИКАЛ КОМПАНИ ЭлПи (CHEVRON PHILLIPS CHEMICAL COMPANY LP) Многореакторная и многозональная полимеризация полиолефина
US11845815B2 (en) 2018-12-27 2023-12-19 Chevron Phillips Chemical Company Lp Multiple reactor and multiple zone polyolefin polymerization

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DE602005013495D1 (de) 2004-03-03 2009-05-07 Basell Poliolefine Srl Verfahren zur steuerung des polymerflusses in einem polymerisationsprozess
CN101080270B (zh) * 2004-08-23 2013-09-18 埃克森美孚化学专利公司 用于聚合方法的装置
BRPI0517490B1 (pt) * 2004-12-20 2016-10-04 Basell Poliolefine Srl “Processo para preparar copolímeros heterofásicos de propileno”
KR101240925B1 (ko) 2004-12-21 2013-03-08 바셀 폴리올레핀 이탈리아 에스.알.엘 폴리올레핀 조성물 및 그의 투과성 필름
US7687588B2 (en) * 2005-05-13 2010-03-30 Basel Poliolefine Italia S.R.L. Process for the gas-phase polymerization of olefins
CN105461835A (zh) * 2007-12-21 2016-04-06 巴塞尔聚烯烃意大利有限责任公司 用于烯烃气相聚合的方法
JP5545800B2 (ja) * 2009-06-08 2014-07-09 住友化学株式会社 噴流−流動層型オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
JP5545799B2 (ja) * 2009-06-08 2014-07-09 住友化学株式会社 オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
JP5545801B2 (ja) * 2009-06-08 2014-07-09 住友化学株式会社 噴流層装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
CN102741301B (zh) * 2009-09-11 2014-10-08 巴塞尔聚烯烃意大利有限责任公司 烯烃的气相聚合方法
CN102947356B (zh) * 2010-06-22 2015-09-09 巴塞尔聚烯烃意大利有限责任公司 烯烃气相聚合的方法
CN102585053B (zh) * 2011-01-05 2014-03-12 中国石油化工股份有限公司 一种调节烯烃聚合物分子量分布的方法
EP2495038B1 (en) * 2011-03-02 2020-09-02 Borealis AG A process for the production polymers
PT2495037T (pt) * 2011-03-02 2020-09-15 Borealis Ag Montagem de reator de alto rendimento para a polimerização de olefinas
WO2012152775A1 (en) 2011-05-10 2012-11-15 Basell Polyolefine Gmbh A process for homogenizing and pelletizing a polyethylene composition
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EP2738213A1 (en) 2012-11-28 2014-06-04 Basell Polyolefine GmbH Polyethylene composition having high swell ratio
JP6001187B2 (ja) 2012-10-22 2016-10-05 バーゼル・ポリオレフィン・ゲーエムベーハー 高いスウェル比を有するポリエチレン組成物の製造方法
EP2738211A1 (en) 2012-11-28 2014-06-04 Basell Polyolefine GmbH Polyethylene composition having high swell ratio
EP2738212A1 (en) 2012-11-28 2014-06-04 Basell Polyolefine GmbH Polyethylene composition having high mechanical properties
EP2722347A1 (en) 2012-10-22 2014-04-23 Basell Polyolefine GmbH Multistage process for the polymerization of olefins
CA2901419C (en) 2013-02-27 2017-11-28 Basell Polyolefine Gmbh Polyethylene processes and compositions thereof
EP2818509A1 (en) * 2013-06-25 2014-12-31 Basell Polyolefine GmbH Polyethylene composition for blow molding having high stress cracking resistance
US9671047B2 (en) 2013-10-14 2017-06-06 Basell Polyolefine Gmbh Polyethylene of raised temperature resistance
CN106715481B (zh) * 2014-10-02 2020-05-12 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的催化剂
KR101830040B1 (ko) 2014-11-18 2018-02-19 바젤 폴리올레핀 게엠베하 높은 내응력균열성을 갖는 폴리에틸렌 조성물
US9879099B2 (en) * 2014-11-18 2018-01-30 Basell Polyolefine Gmbh Polyethylene composition having high stress cracking resistance
CN112979842B (zh) 2015-02-05 2022-11-11 博里利斯股份公司 用于生产聚乙烯的方法
JP6554563B2 (ja) 2015-06-26 2019-07-31 バーゼル・ポリオレフィン・ゲーエムベーハー フィルム用ポリエチレン組成物
CN107849317B (zh) 2015-06-26 2020-05-05 巴塞尔聚烯烃股份有限公司 具有高机械性能和可加工性的聚乙烯组合物
US10457800B2 (en) 2015-06-26 2019-10-29 Basell Polyolefine Gmbh Polyethylene composition having high mechanical properties and processability
KR101817772B1 (ko) 2016-07-08 2018-01-11 시엔시피이엘 주식회사 메탈로센 촉매 기반 폴리올레핀 계열의 용액중합 공정의 반응기
CN109863183B (zh) * 2016-11-04 2021-09-07 巴塞尔聚烯烃意大利有限公司 烯烃聚合的工艺
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WO2019219633A1 (en) 2018-05-14 2019-11-21 Basell Polyolefine Gmbh Polyethylene composition having high swell ratio, fnct and impact resistance
FR3083129B1 (fr) * 2018-06-28 2021-06-11 Ifp Energies Now Procede d'oligomerisation d'ethylene avec enchainement reacteur agite gaz/liquide et reacteur piston
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JP2024525006A (ja) * 2021-06-24 2024-07-09 ボレアリス エージー 多段ポリオレフィン製造における膨張剤の使用
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US12415910B2 (en) 2022-09-15 2025-09-16 Basell Polyolefine Gmbh Polyethylene composition for blow molding having an improved swell behavior
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KR20250061763A (ko) 2022-09-15 2025-05-08 바젤 폴리올레핀 게엠베하 개선된 팽윤 거동을 갖는 블로우 성형용 폴리에틸렌 조성물
KR20250061762A (ko) 2022-09-15 2025-05-08 바젤 폴리올레핀 게엠베하 개선된 팽윤 거동을 갖는 블로우 성형용 폴리에틸렌 조성물
JP2025529106A (ja) 2022-09-15 2025-09-04 バーゼル・ポリオレフィン・ゲーエムベーハー 改善された膨潤挙動を有するブロー成形用ポリエチレン組成物
KR20240078753A (ko) * 2022-11-28 2024-06-04 한화토탈에너지스 주식회사 이차전지 분리막용 폴리에틸렌 수지, 이의 제조 방법 및 이를 포함하는 이차전지 분리막 및 이차전지

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EP1656398A1 (en) 2006-05-17
ATE347569T1 (de) 2006-12-15
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ES2278326T3 (es) 2007-08-01
KR101124187B1 (ko) 2012-03-28
SA04250263B1 (ar) 2008-04-16
US7514508B2 (en) 2009-04-07
JP2007502874A (ja) 2007-02-15
RU2006108546A (ru) 2006-07-27
CN1867596A (zh) 2006-11-22
JP4700610B2 (ja) 2011-06-15
DE602004003590D1 (de) 2007-01-18
CN100582125C (zh) 2010-01-20
KR20060083412A (ko) 2006-07-20
US20070093621A1 (en) 2007-04-26
BRPI0413229B1 (pt) 2015-05-05
WO2005019280A1 (en) 2005-03-03
EP1656398B1 (en) 2006-12-06
CA2551017A1 (en) 2005-03-03

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