RU2014137015A - Каталитически активное тело для синтеза простого диметилового эфира из синтез-газа - Google Patents
Каталитически активное тело для синтеза простого диметилового эфира из синтез-газа Download PDFInfo
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- RU2014137015A RU2014137015A RU2014137015A RU2014137015A RU2014137015A RU 2014137015 A RU2014137015 A RU 2014137015A RU 2014137015 A RU2014137015 A RU 2014137015A RU 2014137015 A RU2014137015 A RU 2014137015A RU 2014137015 A RU2014137015 A RU 2014137015A
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- Prior art keywords
- catalytically active
- active body
- component
- body according
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- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 title claims abstract 10
- 230000015572 biosynthetic process Effects 0.000 title claims abstract 7
- 238000003786 synthesis reaction Methods 0.000 title claims abstract 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract 18
- 239000000203 mixture Substances 0.000 claims abstract 13
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract 10
- 239000005751 Copper oxide Substances 0.000 claims abstract 10
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract 10
- 239000002245 particle Substances 0.000 claims abstract 10
- 239000011787 zinc oxide Substances 0.000 claims abstract 9
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 6
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims abstract 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052796 boron Inorganic materials 0.000 claims abstract 4
- 229910052758 niobium Inorganic materials 0.000 claims abstract 4
- 239000010955 niobium Substances 0.000 claims abstract 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052715 tantalum Inorganic materials 0.000 claims abstract 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000002253 acid Substances 0.000 claims abstract 3
- 239000000654 additive Substances 0.000 claims abstract 3
- 230000000996 additive effect Effects 0.000 claims abstract 3
- 229910001593 boehmite Inorganic materials 0.000 claims abstract 3
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims 11
- 238000001354 calcination Methods 0.000 claims 3
- 238000001556 precipitation Methods 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 239000008187 granular material Substances 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 239000006069 physical mixture Substances 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/25—Nitrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261598932P | 2012-02-15 | 2012-02-15 | |
| US61/598,932 | 2012-02-15 | ||
| PCT/EP2013/052947 WO2013120938A1 (en) | 2012-02-15 | 2013-02-14 | Catalytically active body for the synthesis of dimethyl ether from synthesis gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2014137015A true RU2014137015A (ru) | 2016-04-10 |
Family
ID=47722266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014137015A RU2014137015A (ru) | 2012-02-15 | 2013-02-14 | Каталитически активное тело для синтеза простого диметилового эфира из синтез-газа |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9610568B2 (enExample) |
| EP (1) | EP2814601B1 (enExample) |
| JP (1) | JP2015511880A (enExample) |
| KR (1) | KR20140126373A (enExample) |
| CN (1) | CN104114274B (enExample) |
| CA (1) | CA2864377A1 (enExample) |
| RU (1) | RU2014137015A (enExample) |
| WO (1) | WO2013120938A1 (enExample) |
| ZA (1) | ZA201406663B (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018004992A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Conversion of methane to dimethyl ether |
| WO2018004994A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Fluidized bed membrane reactor |
| WO2018004993A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Reduction of greenhouse gas emission |
| DK3727681T3 (da) | 2017-12-20 | 2022-02-14 | Basf Se | Katalysator og fremgangsmåde til fremstilling af dimethylether |
| EP3727688B1 (en) | 2017-12-20 | 2022-02-16 | Basf Se | Catalyst system and process for preparing dimethyl ether |
| CN110498738B (zh) * | 2018-05-17 | 2022-03-18 | 中国科学院大连化学物理研究所 | 一种合成气直接制备二甲醚的方法 |
| CN111039738B (zh) * | 2018-10-11 | 2021-08-10 | 中国科学院大连化学物理研究所 | 一种合成气制取低碳烯烃的方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4423155A (en) | 1981-02-20 | 1983-12-27 | Mobil Oil Corporation | Dimethyl ether synthesis catalyst |
| US5218003A (en) * | 1988-01-14 | 1993-06-08 | Air Products And Chemicals, Inc. | Liquid phase process for dimethyl ether synthesis |
| JPH02280836A (ja) * | 1989-04-21 | 1990-11-16 | Mitsubishi Heavy Ind Ltd | ジメチルエーテル合成用触媒の製造法 |
| CA2053615C (en) * | 1990-10-24 | 1999-02-02 | Thomas H. Hsuing | Liquid phase process for dimethyl ether synthesis |
| CN1043739C (zh) * | 1993-08-31 | 1999-06-23 | 中国科学院大连化学物理研究所 | 一种由合成气制取二甲醚反应用催化剂及其制备二甲醚工艺 |
| JPH09173848A (ja) * | 1995-12-28 | 1997-07-08 | Nkk Corp | ジメチルエーテル製造用触媒およびその製造方法ならびにジメチルエーテルの製造方法 |
| JP3341808B2 (ja) * | 1996-12-19 | 2002-11-05 | 日本鋼管株式会社 | ジメチルエーテル製造用触媒およびジメチルエーテルの製造方法 |
| DK173614B1 (da) | 1999-02-02 | 2001-04-30 | Topsoe Haldor As | Fremgangsmåde til fremstilling af methanol/dimethyletherblanding fra syntesegas |
| DE10160486A1 (de) * | 2001-12-08 | 2003-06-12 | Sued Chemie Ag | Katalysator für die Methanolsynthese |
| US6608114B1 (en) | 2002-03-13 | 2003-08-19 | Air Products And Chemicals, Inc. | Process to produce DME |
| JP2005066516A (ja) * | 2003-08-26 | 2005-03-17 | Ishikawajima Harima Heavy Ind Co Ltd | ジメチルエーテル改質触媒及びその合成方法 |
| CN100336589C (zh) | 2004-04-16 | 2007-09-12 | 中国石油化工股份有限公司 | 由合成气一步制备二甲醚的催化剂 |
| US7485767B2 (en) | 2005-06-29 | 2009-02-03 | Exxonmobil Chemical Patents Inc. | Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids |
| KR100812099B1 (ko) | 2006-11-28 | 2008-03-12 | 한국가스공사 | 디메틸에테르 제조용 혼합촉매, 이의 제조방법 및 이를 이용한 디메틸에테르 제조방법 |
| US7906559B2 (en) | 2007-06-21 | 2011-03-15 | University Of Southern California | Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas |
| CN101687747A (zh) | 2007-07-12 | 2010-03-31 | 赫多特普索化工设备公司 | 二甲醚的制备方法 |
| CN101601995B (zh) | 2008-06-12 | 2013-04-03 | 中国石油化工股份有限公司 | 用于甲醇气相脱水制二甲醚的氧化铝催化剂及其制备方法 |
| CN101722001A (zh) * | 2008-10-10 | 2010-06-09 | 北京石油化工学院 | 二甲醚合成所用的复合催化剂、制备方法及其用途 |
| TWI462777B (zh) | 2009-10-30 | 2014-12-01 | Atomic Energy Council | 合成甲醇及二甲醚之Ｃｕ－Ｚｎ－Ａｌ觸媒製備方法 |
-
2013
- 2013-02-13 US US13/765,716 patent/US9610568B2/en not_active Expired - Fee Related
- 2013-02-14 RU RU2014137015A patent/RU2014137015A/ru not_active Application Discontinuation
- 2013-02-14 JP JP2014557035A patent/JP2015511880A/ja active Pending
- 2013-02-14 KR KR1020147025549A patent/KR20140126373A/ko not_active Withdrawn
- 2013-02-14 WO PCT/EP2013/052947 patent/WO2013120938A1/en not_active Ceased
- 2013-02-14 EP EP13704769.2A patent/EP2814601B1/en not_active Not-in-force
- 2013-02-14 CN CN201380009564.5A patent/CN104114274B/zh not_active Expired - Fee Related
- 2013-02-14 CA CA2864377A patent/CA2864377A1/en not_active Abandoned
-
2014
- 2014-09-11 ZA ZA2014/06663A patent/ZA201406663B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US9610568B2 (en) | 2017-04-04 |
| CA2864377A1 (en) | 2013-08-22 |
| KR20140126373A (ko) | 2014-10-30 |
| ZA201406663B (en) | 2016-07-27 |
| EP2814601A1 (en) | 2014-12-24 |
| EP2814601B1 (en) | 2016-07-06 |
| CN104114274B (zh) | 2016-11-09 |
| JP2015511880A (ja) | 2015-04-23 |
| WO2013120938A1 (en) | 2013-08-22 |
| US20130210940A1 (en) | 2013-08-15 |
| CN104114274A (zh) | 2014-10-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA94 | Acknowledgement of application withdrawn (non-payment of fees) |
Effective date: 20180523 |