CN104114274B - 用于从合成气合成二甲醚的催化活性体 - Google Patents

用于从合成气合成二甲醚的催化活性体 Download PDF

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Publication number
CN104114274B
CN104114274B CN201380009564.5A CN201380009564A CN104114274B CN 104114274 B CN104114274 B CN 104114274B CN 201380009564 A CN201380009564 A CN 201380009564A CN 104114274 B CN104114274 B CN 104114274B
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weight
component
active body
oxide
value
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Chinese (zh)
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CN104114274A (zh
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A·舍费尔
T·范费伦
R·马顿
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/25—Nitrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380009564.5A 2012-02-15 2013-02-14 用于从合成气合成二甲醚的催化活性体 Expired - Fee Related CN104114274B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261598932P 2012-02-15 2012-02-15
US61/598,932 2012-02-15
PCT/EP2013/052947 WO2013120938A1 (en) 2012-02-15 2013-02-14 Catalytically active body for the synthesis of dimethyl ether from synthesis gas

Publications (2)

Publication Number Publication Date
CN104114274A CN104114274A (zh) 2014-10-22
CN104114274B true CN104114274B (zh) 2016-11-09

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CN201380009564.5A Expired - Fee Related CN104114274B (zh) 2012-02-15 2013-02-14 用于从合成气合成二甲醚的催化活性体

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Country Link
US (1) US9610568B2 (enExample)
EP (1) EP2814601B1 (enExample)
JP (1) JP2015511880A (enExample)
KR (1) KR20140126373A (enExample)
CN (1) CN104114274B (enExample)
CA (1) CA2864377A1 (enExample)
RU (1) RU2014137015A (enExample)
WO (1) WO2013120938A1 (enExample)
ZA (1) ZA201406663B (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
WO2018004992A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Conversion of methane to dimethyl ether
US11529616B2 (en) 2017-12-20 2022-12-20 Basf Se Catalyst system and process for preparing dimethyl ether
CN111556785B (zh) 2017-12-20 2023-11-03 巴斯夫欧洲公司 用于制备二甲醚的催化剂和方法
CN110498738B (zh) * 2018-05-17 2022-03-18 中国科学院大连化学物理研究所 一种合成气直接制备二甲醚的方法
CN111039738B (zh) * 2018-10-11 2021-08-10 中国科学院大连化学物理研究所 一种合成气制取低碳烯烃的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4423155A (en) * 1981-02-20 1983-12-27 Mobil Oil Corporation Dimethyl ether synthesis catalyst
CN1683076A (zh) * 2004-04-16 2005-10-19 中国石油化工股份有限公司 由合成气一步制备二甲醚的催化剂
CN101601995A (zh) * 2008-06-12 2009-12-16 中国石油化工股份有限公司 用于甲醇气相脱水制二甲醚的氧化铝催化剂及其制备方法
CN101722001A (zh) * 2008-10-10 2010-06-09 北京石油化工学院 二甲醚合成所用的复合催化剂、制备方法及其用途

Family Cites Families (15)

* Cited by examiner, † Cited by third party
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US5218003A (en) * 1988-01-14 1993-06-08 Air Products And Chemicals, Inc. Liquid phase process for dimethyl ether synthesis
JPH02280836A (ja) * 1989-04-21 1990-11-16 Mitsubishi Heavy Ind Ltd ジメチルエーテル合成用触媒の製造法
EP0483609A1 (en) * 1990-10-24 1992-05-06 Air Products And Chemicals, Inc. Liquid phase process for dimethyl ether synthesis
CN1043739C (zh) * 1993-08-31 1999-06-23 中国科学院大连化学物理研究所 一种由合成气制取二甲醚反应用催化剂及其制备二甲醚工艺
JPH09173848A (ja) * 1995-12-28 1997-07-08 Nkk Corp ジメチルエーテル製造用触媒およびその製造方法ならびにジメチルエーテルの製造方法
JP3341808B2 (ja) * 1996-12-19 2002-11-05 日本鋼管株式会社 ジメチルエーテル製造用触媒およびジメチルエーテルの製造方法
DK173614B1 (da) 1999-02-02 2001-04-30 Topsoe Haldor As Fremgangsmåde til fremstilling af methanol/dimethyletherblanding fra syntesegas
DE10160486A1 (de) * 2001-12-08 2003-06-12 Sued Chemie Ag Katalysator für die Methanolsynthese
US6608114B1 (en) 2002-03-13 2003-08-19 Air Products And Chemicals, Inc. Process to produce DME
JP2005066516A (ja) * 2003-08-26 2005-03-17 Ishikawajima Harima Heavy Ind Co Ltd ジメチルエーテル改質触媒及びその合成方法
US7485767B2 (en) 2005-06-29 2009-02-03 Exxonmobil Chemical Patents Inc. Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids
KR100812099B1 (ko) * 2006-11-28 2008-03-12 한국가스공사 디메틸에테르 제조용 혼합촉매, 이의 제조방법 및 이를 이용한 디메틸에테르 제조방법
US7906559B2 (en) 2007-06-21 2011-03-15 University Of Southern California Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas
CN101687747A (zh) 2007-07-12 2010-03-31 赫多特普索化工设备公司 二甲醚的制备方法
TWI462777B (zh) 2009-10-30 2014-12-01 Atomic Energy Council 合成甲醇及二甲醚之Ｃｕ－Ｚｎ－Ａｌ觸媒製備方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4423155A (en) * 1981-02-20 1983-12-27 Mobil Oil Corporation Dimethyl ether synthesis catalyst
CN1683076A (zh) * 2004-04-16 2005-10-19 中国石油化工股份有限公司 由合成气一步制备二甲醚的催化剂
CN101601995A (zh) * 2008-06-12 2009-12-16 中国石油化工股份有限公司 用于甲醇气相脱水制二甲醚的氧化铝催化剂及其制备方法
CN101722001A (zh) * 2008-10-10 2010-06-09 北京石油化工学院 二甲醚合成所用的复合催化剂、制备方法及其用途

Also Published As

Publication number Publication date
CA2864377A1 (en) 2013-08-22
US9610568B2 (en) 2017-04-04
EP2814601A1 (en) 2014-12-24
JP2015511880A (ja) 2015-04-23
EP2814601B1 (en) 2016-07-06
RU2014137015A (ru) 2016-04-10
US20130210940A1 (en) 2013-08-15
WO2013120938A1 (en) 2013-08-22
CN104114274A (zh) 2014-10-22
ZA201406663B (en) 2016-07-27
KR20140126373A (ko) 2014-10-30

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