RU2011123736A - Cпособ производства ненасыщенного углеводорода и оксигенированного соединения, катализатор и способ его производства - Google Patents

Cпособ производства ненасыщенного углеводорода и оксигенированного соединения, катализатор и способ его производства Download PDF

Info

Publication number
RU2011123736A
RU2011123736A RU2011123736/04A RU2011123736A RU2011123736A RU 2011123736 A RU2011123736 A RU 2011123736A RU 2011123736/04 A RU2011123736/04 A RU 2011123736/04A RU 2011123736 A RU2011123736 A RU 2011123736A RU 2011123736 A RU2011123736 A RU 2011123736A
Authority
RU
Russia
Prior art keywords
catalyst
unsaturated hydrocarbon
oxygen
carrier
stage
Prior art date
Application number
RU2011123736/04A
Other languages
English (en)
Russian (ru)
Inventor
Норитацу ЦУБАКИ
Фуюки АИДА
Original Assignee
ДжейЭкс НИППОН ОЙЛ ЭНД ЭНЕРДЖИ КОРПОРЕЙШН
Нэшнл Юниверсити Корпорейшн Юниверсити Оф Тояма
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ДжейЭкс НИППОН ОЙЛ ЭНД ЭНЕРДЖИ КОРПОРЕЙШН, Нэшнл Юниверсити Корпорейшн Юниверсити Оф Тояма filed Critical ДжейЭкс НИППОН ОЙЛ ЭНД ЭНЕРДЖИ КОРПОРЕЙШН
Publication of RU2011123736A publication Critical patent/RU2011123736A/ru

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/10Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for with the aid of centrifugal force
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889Manganese, technetium or rhenium
    • B01J23/8892Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/617500-1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/638Pore volume more than 1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/65150-500 nm
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425Catalysts; their physical properties
    • C07C1/043Catalysts; their physical properties characterised by the composition
    • C07C1/0435Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32Manganese, technetium or rhenium
    • C07C2523/34Manganese
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
RU2011123736/04A 2008-11-11 2009-11-06 Cпособ производства ненасыщенного углеводорода и оксигенированного соединения, катализатор и способ его производства RU2011123736A (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2008288797A JP2010116328A (ja) 2008-11-11 2008-11-11 不飽和炭化水素および含酸素化合物の製造方法、触媒およびその製造方法
JP2008-288797 2008-11-11
PCT/JP2009/068967 WO2010055808A1 (ja) 2008-11-11 2009-11-06 不飽和炭化水素および含酸素化合物の製造方法、触媒およびその製造方法

Publications (1)

Publication Number Publication Date
RU2011123736A true RU2011123736A (ru) 2012-12-20

Family

ID=42169943

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2011123736/04A RU2011123736A (ru) 2008-11-11 2009-11-06 Cпособ производства ненасыщенного углеводорода и оксигенированного соединения, катализатор и способ его производства

Country Status (7)

Country Link
US (1) US20110213041A1 (enExample)
EP (1) EP2366681A1 (enExample)
JP (1) JP2010116328A (enExample)
CN (1) CN102209699A (enExample)
AU (1) AU2009315025A1 (enExample)
RU (1) RU2011123736A (enExample)
WO (1) WO2010055808A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI473652B (zh) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
JP4586112B1 (ja) * 2010-06-14 2010-11-24 株式会社東産商 フィッシャー・トロプシュ合成用触媒およびその製造方法ならびに炭化水素の製造方法
US20150225309A1 (en) * 2012-08-10 2015-08-13 Sumitomo Chemical Company, Limited Method of producing olefin having 2 to 4 carbon atoms and method of producing propylene
JP2014055126A (ja) * 2012-08-10 2014-03-27 Sumitomo Chemical Co Ltd フィッシャー・トロプシュ反応による炭素原子数2〜4のオレフィンの製造方法
JP2025072167A (ja) * 2023-10-24 2025-05-09 株式会社エフ・シー・シー フィッシャー・トロプシュ反応用触媒およびその製造方法

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140249A (en) * 1960-07-12 1964-07-07 Socony Mobil Oil Co Inc Catalytic cracking of hydrocarbons with a crystalline zeolite catalyst composite
DE2518964C3 (de) * 1975-04-29 1981-02-05 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung ungesättigter Kohlenwasserstoffe
US4177203A (en) * 1976-02-12 1979-12-04 Schering Aktiengesellschaft Process for the production of hydrocarbons and oxygen-containing compounds and catalysts therefor
NL7612460A (nl) * 1976-11-10 1978-05-12 Shell Int Research Werkwijze voor de bereiding van koolwater- stoffen.
US4206134A (en) 1979-03-12 1980-06-03 Exxon Research & Engineering Co. Ruthenium supported on manganese oxide as hydrocarbon synthesis catalysts in CO/H2 reactions
US4544671A (en) * 1983-12-14 1985-10-01 Exxon Research And Engineering Co. Process for preparing high surface area iron/cobalt Fischer-Tropsch slurry catalysts
US4544672A (en) * 1983-12-14 1985-10-01 Exxon Research And Engineering Co. Cobalt-promoted catalysts for use in Fischer-Tropsch slurry process
US4544674A (en) * 1983-12-14 1985-10-01 Exxon Research And Engineering Co. Cobalt-promoted fischer-tropsch catalysts
JPS60146835A (ja) 1983-12-29 1985-08-02 Res Assoc Petroleum Alternat Dev<Rapad> オレフイン類の製造法
US4683214A (en) * 1984-09-06 1987-07-28 Mobil Oil Corporation Noble metal-containing catalysts
JPS6191139A (ja) * 1984-10-08 1986-05-09 Res Assoc Petroleum Alternat Dev<Rapad> オレフイン類の製造法
JPH062232B2 (ja) * 1985-02-25 1994-01-12 エクソン リサ−チ アンド エンヂニアリング コムパニ− コバルトにより促進されたフイツシヤ−−トロプシユ触媒
JPH0825911B2 (ja) * 1987-12-23 1996-03-13 エクソン リサーチ アンド エンヂニアリング コムパニー フィッシャー・トロプシュ反応においてメタン生成を減じ液体収率を増加させる方法
US5282958A (en) * 1990-07-20 1994-02-01 Chevron Research And Technology Company Use of modified 5-7 a pore molecular sieves for isomerization of hydrocarbons
US5143879A (en) * 1991-07-18 1992-09-01 Mobil Oil Corporation Method to recover organic templates from freshly synthesized molecular sieves
GB9203959D0 (en) * 1992-02-25 1992-04-08 Norske Stats Oljeselskap Method of conducting catalytic converter multi-phase reaction
JPH08215576A (ja) * 1995-02-16 1996-08-27 Ykk Kk 複合超微粒子及びその製造方法並びにメタノールの合成・改質用触媒
US6162530A (en) * 1996-11-18 2000-12-19 University Of Connecticut Nanostructured oxides and hydroxides and methods of synthesis therefor
FR2760385B1 (fr) * 1997-03-05 1999-04-16 Inst Francais Du Petrole Catalyseur a base de tamis moleculaire et procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec ce catalyseur
CN1260823A (zh) * 1997-06-18 2000-07-19 埃克森化学专利公司 用改性的分子筛将合成气转化成低碳烯烃的方法
US6156283A (en) * 1998-03-23 2000-12-05 Engelhard Corporation Hydrophobic catalytic materials and method of forming the same
EP1206509B1 (en) * 1999-08-17 2004-10-06 Battelle Memorial Institute Catalyst structure and method of fischer-tropsch synthesis
US6709570B1 (en) * 1999-09-27 2004-03-23 Shell Oil Company Method for preparing a catalyst
FR2805255B1 (fr) * 2000-02-21 2002-04-12 Inst Francais Du Petrole Zeolithe mtt comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des paraffines lineaires
US7452844B2 (en) * 2001-05-08 2008-11-18 Süd-Chemie Inc High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis
JP2003024786A (ja) * 2001-07-13 2003-01-28 Nippon Oil Corp フィッシャー・トロプシュ合成用触媒および炭化水素の製造法
US7319178B2 (en) * 2002-02-28 2008-01-15 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
CN1203920C (zh) * 2002-06-12 2005-06-01 中国科学院山西煤炭化学研究所 一种用于费托合成的铁/锰催化剂及其制备方法
FI118516B (fi) * 2003-03-14 2007-12-14 Neste Oil Oyj Menetelmä katalyytin valmistamiseksi
US7141529B2 (en) * 2003-03-21 2006-11-28 Chevron U.S.A. Inc. Metal loaded microporous material for hydrocarbon isomerization processes
FR2852865B1 (fr) * 2003-03-24 2007-02-23 Inst Francais Du Petrole Catalyseur et son utilisation pour l'amelioration du point d'ecoulement de charges hydrocarbonnees
US7390763B2 (en) * 2003-10-31 2008-06-24 Chevron U.S.A. Inc. Preparing small crystal SSZ-32 and its use in a hydrocarbon conversion process
AU2004320979A1 (en) * 2004-06-23 2006-01-05 Bp P.L.C. The synthesis of the micro-porous silica gel and its application to the preparation of catalysts for C2 oxygenates synthesis from syngas
JP2006297286A (ja) * 2005-04-20 2006-11-02 Electric Power Dev Co Ltd ヘテロなバイモダル構造を有する触媒
US7368620B2 (en) * 2005-06-30 2008-05-06 Uop Llc Two-stage aromatics isomerization process
JP4551835B2 (ja) * 2005-07-28 2010-09-29 キヤノン株式会社 情報処理装置及び情報処理方法及び印刷制御プログラム
US7393876B2 (en) * 2005-12-16 2008-07-01 Eltron Research, Inc. Fischer-tropsch catalysts
JP4769085B2 (ja) * 2006-01-13 2011-09-07 Jx日鉱日石エネルギー株式会社 ワックスの水素化処理方法
US20080083657A1 (en) * 2006-10-04 2008-04-10 Zones Stacey I Isomerization process using metal-modified small crystallite mtt molecular sieve
US20100093524A1 (en) * 2007-03-19 2010-04-15 Ube Industries, Ltd. Silica-based composite oxide fiber, catalyst fiber comprising the same, and process for producing the same
AU2008268777B2 (en) * 2007-06-27 2011-12-08 Nippon Oil Corporation Hydroisomerization catalyst, method of dewaxing hydrocarbon oil, process for producing base oil, and process for producing lube base oil
EP2165997A1 (en) * 2008-09-18 2010-03-24 Rohm and Haas Company Improved process for the oxidative dehydrogenation of ethane

Also Published As

Publication number Publication date
WO2010055808A1 (ja) 2010-05-20
EP2366681A1 (en) 2011-09-21
CN102209699A (zh) 2011-10-05
AU2009315025A1 (en) 2010-05-20
US20110213041A1 (en) 2011-09-01
JP2010116328A (ja) 2010-05-27

Similar Documents

Publication Publication Date Title
Mei et al. Brønsted acid-catalyzed stereoselective [4+ 3] cycloadditions of ortho-hydroxybenzyl alcohols with N, N′-cyclic azomethine imines
CN109174085B (zh) 原子级分散钯基纳米金刚石/石墨烯复合材料催化剂及其制备方法和应用
Li et al. Nitrogen-doped porous carbon materials: promising catalysts or catalyst supports for heterogeneous hydrogenation and oxidation
Dreyer et al. Carbocatalysis: Heterogeneous carbons finding utility in synthetic chemistry
Balaraman et al. Iron-catalyzed dehydrogenation reactions and their applications in sustainable energy and catalysis
Ho et al. Highly efficient heterogeneous aerobic cross-dehydrogenative coupling via C–H functionalization of tertiary amines using a nanoporous gold skeleton catalyst
Karimi et al. Palladium containing periodic mesoporous organosilica with imidazolium framework (Pd@ PMO-IL): an efficient and recyclable catalyst for the aerobic oxidation of alcohols
CN105579399B (zh) 利用选择性可渗透膜的方法
Ma et al. Au@ h-Al 2 O 3 analogic yolk–shell nanocatalyst for highly selective synthesis of biomass-derived d-xylonic acid via regulation of structure effects
KR20210137498A (ko) 루테늄 촉진제 촉매 조성물
Wu et al. Ambient reductive synthesis of N-heterocyclic compounds over cellulose-derived carbon supported Pt nanocatalyst under H 2 atmosphere
RU2014127745A (ru) Катализаторы
EP2165972A3 (en) Process for the production of hydrogen gas employing a thermally stable catalyst
Zhang et al. PVP-NiB amorphous catalyst for selective hydrogenation of phenol and its derivatives
Wang et al. The influence of encapsulated cobalt content within N-doped bamboo-like carbon nanotubes catalysts for arylalkanes oxidation
Doroodmand et al. Sulfonated multiwalled carbon nanotubes (MWCNTs) as a new, efficient, and recyclable heterogeneous nanocatalyst for the synthesis of amines
WO2016189553A1 (en) Magnetically separable iron-based heterogeneous catalysts for dehydrogenation of alcohols and amines
WO2016020656A3 (en) Methanol production catalyst and methanol production process
Peng et al. Graphene oxide and its derivatives: Their synthesis and use in organic synthesis
MY162690A (en) Mixed oxide catalysts made of hollow shapes
CN113426472B (zh) 一种钴基催化剂、co2催化加氢制co的方法
Zhang et al. Bio-inspired noble metal-free reduction of nitroarenes using NiS 2+ x/gC 3 N 4
JP2010116328A5 (enExample)
RU2011121361A (ru) Превращение гидрофторхлорпропанов в фторпропены
JP2014527908A5 (enExample)