RU2007141164A - Методы предварительной обработки, не требующие смывания, и композиции для металлических поверхностей - Google Patents

Методы предварительной обработки, не требующие смывания, и композиции для металлических поверхностей Download PDF

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RU2007141164A
RU2007141164A RU2007141164/02A RU2007141164A RU2007141164A RU 2007141164 A RU2007141164 A RU 2007141164A RU 2007141164/02 A RU2007141164/02 A RU 2007141164/02A RU 2007141164 A RU2007141164 A RU 2007141164A RU 2007141164 A RU2007141164 A RU 2007141164A
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ureidosilane
colloidal
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Линьюнь ХЕ (US)
Линьюнь ХЕ
Дональд У. Мл. УАЙЗЕНХАНТ (US)
Дональд У. Мл. УАЙЗЕНХАНТ
Джеффри И. МЕЛЗЕР (US)
Джеффри И. МЕЛЗЕР
Андреа Киз ИОДИС (US)
Андреа Киз ИОДИС
Брет ЧИСХОЛМ (US)
Брет ЧИСХОЛМ
Кристофер М. КАРТЕР (US)
Кристофер М. КАРТЕР
Шиу-Чин Х. СУ (US)
Шиу-Чин Х. СУ
Кендэлл Л. ГАЙЕР (US)
Кендэлл Л. ГАЙЕР
Мэттью М. ХАНТЕР (US)
Мэттью М. ХАНТЕР
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Моментив Перформанс Матириалз Инк. (Us)
Моментив Перформанс Матириалз Инк.
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    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
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    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/50—Treatment of iron or alloys based thereon
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    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/56—Treatment of aluminium or alloys based thereon
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    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/74—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process for obtaining burned-in conversion coatings
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78—Pretreatment of the material to be coated
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/20—Use of solutions containing silanes

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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
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  • Paints Or Removers (AREA)
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Abstract

1. Композиция, включающая (a) частичный или полный конденсат уреидосилана (b) частицы коллоидного оксида и (c) воду. ! 2. Композиция по п. 1, в которой уреидосилан (a) имеет общую формулу (II): ! ! в которой каждый R независимо представляет собой водород, алкил с 1-6 атомами углерода, циклоалкил, алкенил с 1-6 атомами углерода, арилен или алкарилен; R1 представляет собой замещенную или незамещенную алифатическую или ароматическую группу; R2 является одновалентной углеводородной группой с 1-10 атомами углерода; R3, каждый независимо, выбран из группы, содержащей водород, линейный или разветвленный алкил, линейный или разветвленный алкоксизамещенный алкил или линейный или разветвленный ацил; и а = 0, 1 или 2. ! 3. Композиция по п.1, в которой коллоидный оксид является оксидом церия, оксидом кремния или их смесью. ! 4. Композиция по п.1, в которой количество (a) составляет от приблизительно 0,01 до 80 вес.%, а количество (b) составляет от приблизительно 0,001 до 36 вес.%. ! 5. Композиция по п.1, где данная композиция по существу не содержит опасных загрязнений воздуха и/или летучих компонентов. ! 6. Способ обработки металлической поверхности для образования на ней конверсионного или пассивирующего покрытия, включающий контактирование указанной металлической поверхности с композицией, содержащей (a) частичный или полный конденсат уреидосилана; (b) частицы коллоидного оксида металла или частицы коллоидного оксида кремния; с) воду и d) необязательно вспомогательное вещество, которым является алкоксисилан, отличный от уреидоалкоксисилана (а). ! 7. Способ по п.6, в котором уреидосилан имеет общую формулу (II) ! ! в которой каждый R независимо представляет собой водоро�

Claims (10)

1. Композиция, включающая (a) частичный или полный конденсат уреидосилана (b) частицы коллоидного оксида и (c) воду.
2. Композиция по п. 1, в которой уреидосилан (a) имеет общую формулу (II):
Figure 00000001
в которой каждый R независимо представляет собой водород, алкил с 1-6 атомами углерода, циклоалкил, алкенил с 1-6 атомами углерода, арилен или алкарилен; R1 представляет собой замещенную или незамещенную алифатическую или ароматическую группу; R2 является одновалентной углеводородной группой с 1-10 атомами углерода; R3, каждый независимо, выбран из группы, содержащей водород, линейный или разветвленный алкил, линейный или разветвленный алкоксизамещенный алкил или линейный или разветвленный ацил; и а = 0, 1 или 2.
3. Композиция по п.1, в которой коллоидный оксид является оксидом церия, оксидом кремния или их смесью.
4. Композиция по п.1, в которой количество (a) составляет от приблизительно 0,01 до 80 вес.%, а количество (b) составляет от приблизительно 0,001 до 36 вес.%.
5. Композиция по п.1, где данная композиция по существу не содержит опасных загрязнений воздуха и/или летучих компонентов.
6. Способ обработки металлической поверхности для образования на ней конверсионного или пассивирующего покрытия, включающий контактирование указанной металлической поверхности с композицией, содержащей (a) частичный или полный конденсат уреидосилана; (b) частицы коллоидного оксида металла или частицы коллоидного оксида кремния; с) воду и d) необязательно вспомогательное вещество, которым является алкоксисилан, отличный от уреидоалкоксисилана (а).
7. Способ по п.6, в котором уреидосилан имеет общую формулу (II)
Figure 00000001
в которой каждый R независимо представляет собой водород, алкил с 1-6 атомами углерода, циклоалкил, алкенил с 1-6 атомами углерода, арилен или алкарилен; R1 - замещенная или незамещенная алифатическая или ароматическая группа; R2 - одновалентная углеводородная группа с 1-10 атомами углерода; и R3, каждый независимо, выбран из группы, содержащей водород, линейный или разветвленный алкил, линейный или разветвленный алкоксизамещенный алкил или линейный или разветвленный ацил; и а = 0, 1 или 2.
8. Способ по п.6, в котором оксид металла является оксидом церия или в котором композиция дополнительно содержит оксид кремния или смеси оксида церия и оксида кремния.
9. Способ по п.6, в котором конверсионное или пассивирующее покрытие составляет больше 0,5 мг на квадратный фут указанной поверхности.
10. Способ по п.6, в котором композиция по существу не содержит опасных загрязнений воздуха и/или летучих компонентов.
RU2007141164/02A 2005-04-07 2006-03-28 Методы предварительной обработки, не требующие смывания, и композиции для металлических поверхностей RU2410468C2 (ru)

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US11/290,064 US10041176B2 (en) 2005-04-07 2005-11-30 No-rinse pretreatment methods and compositions

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