PL204175B1 - Sposób wytwarzania polimerowej dyspersji typu woda w wodzie, polimerowa dyspersja wytworzona tym sposobem oraz zastosowania polimerowej dyspersji - Google Patents
Sposób wytwarzania polimerowej dyspersji typu woda w wodzie, polimerowa dyspersja wytworzona tym sposobem oraz zastosowania polimerowej dyspersjiInfo
- Publication number
- PL204175B1 PL204175B1 PL362248A PL36224801A PL204175B1 PL 204175 B1 PL204175 B1 PL 204175B1 PL 362248 A PL362248 A PL 362248A PL 36224801 A PL36224801 A PL 36224801A PL 204175 B1 PL204175 B1 PL 204175B1
- Authority
- PL
- Poland
- Prior art keywords
- acid
- water
- weight
- salt
- dispersion
- Prior art date
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 126
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 238000000034 method Methods 0.000 title claims abstract description 83
- 229920000642 polymer Polymers 0.000 title claims abstract description 48
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 24
- 239000000178 monomer Substances 0.000 claims abstract description 64
- 150000003839 salts Chemical class 0.000 claims abstract description 60
- 239000002253 acid Substances 0.000 claims abstract description 37
- 239000002270 dispersing agent Substances 0.000 claims abstract description 33
- 239000004815 dispersion polymer Substances 0.000 claims abstract description 22
- 239000008346 aqueous phase Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 66
- 238000006116 polymerization reaction Methods 0.000 claims description 29
- 125000004432 carbon atom Chemical group C* 0.000 claims description 25
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 24
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 23
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 22
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 22
- 235000015165 citric acid Nutrition 0.000 claims description 22
- -1 alkali metal salt Chemical class 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 20
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- 125000002091 cationic group Chemical group 0.000 claims description 14
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 12
- 239000005711 Benzoic acid Substances 0.000 claims description 11
- 239000001361 adipic acid Substances 0.000 claims description 11
- 235000011037 adipic acid Nutrition 0.000 claims description 11
- 235000010233 benzoic acid Nutrition 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- 125000002947 alkylene group Chemical group 0.000 claims description 10
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 9
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 150000007522 mineralic acids Chemical class 0.000 claims description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 150000007524 organic acids Chemical class 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- 239000001530 fumaric acid Substances 0.000 claims description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 6
- 239000011976 maleic acid Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 5
- 235000011054 acetic acid Nutrition 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 5
- 235000019260 propionic acid Nutrition 0.000 claims description 5
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 229920006317 cationic polymer Polymers 0.000 claims description 4
- 239000000701 coagulant Substances 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- 150000003973 alkyl amines Chemical class 0.000 claims description 3
- 230000014759 maintenance of location Effects 0.000 claims description 3
- 238000010526 radical polymerization reaction Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 239000003925 fat Substances 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 2
- 159000000003 magnesium salts Chemical class 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 239000004476 plant protection product Substances 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 125000002577 pseudohalo group Chemical group 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 238000004065 wastewater treatment Methods 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 2
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical group C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 2
- 159000000007 calcium salts Chemical class 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- 229920003169 water-soluble polymer Polymers 0.000 claims 1
- 239000002250 absorbent Substances 0.000 abstract 1
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 235000011167 hydrochloric acid Nutrition 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 9
- 238000005345 coagulation Methods 0.000 description 9
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 4
- 239000001166 ammonium sulphate Substances 0.000 description 4
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
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- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 2
- 244000248349 Citrus limon Species 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- BZQMVMBOKPYBLQ-UHFFFAOYSA-N [Cl-].C[NH+](C)C.C[NH+](C)C.CC(=C)C([O-])=O Chemical compound [Cl-].C[NH+](C)C.C[NH+](C)C.CC(=C)C([O-])=O BZQMVMBOKPYBLQ-UHFFFAOYSA-N 0.000 description 2
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- VIBDJEWPNNCFQO-UHFFFAOYSA-N ethane-1,1,2-triol Chemical compound OCC(O)O VIBDJEWPNNCFQO-UHFFFAOYSA-N 0.000 description 2
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- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
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- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
- 125000006222 dimethylaminomethyl group Chemical group [H]C([H])([H])N(C([H])([H])[H])C([H])([H])* 0.000 description 1
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
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- OXHSYNORMNUBFR-UHFFFAOYSA-N methyl prop-2-enoate trimethylazanium chloride Chemical compound [Cl-].C[NH+](C)C.COC(=O)C=C OXHSYNORMNUBFR-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
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- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- CSMWJXBSXGUPGY-UHFFFAOYSA-L sodium dithionate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)S([O-])(=O)=O CSMWJXBSXGUPGY-UHFFFAOYSA-L 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000004222 uncontrolled growth Effects 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Paper (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Colloid Chemistry (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10061483A DE10061483A1 (de) | 2000-12-08 | 2000-12-08 | Verfahren zur Herstellung von Wasser-in-Wasser-Polymerdispersionen |
| PCT/EP2001/014062 WO2002046275A1 (de) | 2000-12-08 | 2001-12-01 | Verfahren zur herstellung von wasser-in-wasser-polymerdispersionen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL362248A1 PL362248A1 (en) | 2004-10-18 |
| PL204175B1 true PL204175B1 (pl) | 2009-12-31 |
Family
ID=7666565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL362248A PL204175B1 (pl) | 2000-12-08 | 2001-12-01 | Sposób wytwarzania polimerowej dyspersji typu woda w wodzie, polimerowa dyspersja wytworzona tym sposobem oraz zastosowania polimerowej dyspersji |
Country Status (23)
Families Citing this family (48)
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|---|---|---|---|---|
| DE10041395A1 (de) * | 2000-08-23 | 2002-03-07 | Stockhausen Chem Fab Gmbh | Polymerdispersionen zur Feuerverhütung und -bekämpfung mit verbesserter Umweltverträglichkeit |
| DE10041394A1 (de) * | 2000-08-23 | 2002-03-07 | Stockhausen Chem Fab Gmbh | Verwendung von Wasser-in-Wasser-Polymerdispersionen zur Feuerverhütung und -bekämpfung |
| DE10118020A1 (de) | 2001-04-10 | 2002-10-17 | Stockhausen Chem Fab Gmbh | Löschwasser-Additive |
| DE10241296A1 (de) * | 2002-09-04 | 2004-03-18 | Basf Ag | Verwendung von vernetzten kationischen Polymerisaten in der Kosmetik |
| DE10336534A1 (de) * | 2003-08-05 | 2005-02-24 | Stockhausen Gmbh | Verfahren zur Verminderung der Schwermetallkonzentration in Abwasseraufbereitungsschlämmen |
| DE102004013750A1 (de) | 2004-03-18 | 2005-11-03 | Stockhausen Gmbh | Anionische Wasser-in-Wasser-Polymerdispersionen, Verfahren zu deren Herstellung sowie deren Verwendung |
| DE102004063793A1 (de) | 2004-12-30 | 2006-07-13 | Stockhausen Gmbh | Hoch kationische Polymerdispersionen, Verfahren zu deren Herstellung und deren Verwendung |
| DE102004063791A1 (de) * | 2004-12-30 | 2006-07-13 | Stockhausen Gmbh | Kationische Polymerdispersionen, Verfahren zu deren Herstellung und deren Verwendung |
| US7981250B2 (en) * | 2006-09-14 | 2011-07-19 | Kemira Oyj | Method for paper processing |
| US8088250B2 (en) | 2008-11-26 | 2012-01-03 | Nalco Company | Method of increasing filler content in papermaking |
| US7703527B2 (en) | 2007-11-26 | 2010-04-27 | Schlumberger Technology Corporation | Aqueous two-phase emulsion gel systems for zone isolation |
| WO2009095245A2 (en) * | 2008-02-01 | 2009-08-06 | Ashland Licensing And Intellectual Property Llc. | Hydrophobically associated polymers in water-in-water polymer dispersions |
| PL2148001T3 (pl) | 2008-07-23 | 2016-07-29 | Solenis Technologies Cayman Lp | Roztwarzanie materiału celulozowego w obecności polimeru kationowego |
| US8865632B1 (en) | 2008-11-10 | 2014-10-21 | Cesi Chemical, Inc. | Drag-reducing copolymer compositions |
| US20100184631A1 (en) * | 2009-01-16 | 2010-07-22 | Schlumberger Technology Corporation | Provision of viscous compositions below ground |
| CN102803321B (zh) | 2009-04-17 | 2015-07-01 | 索理思科技开曼公司 | 生物分子反相乳液聚合物 |
| KR101533873B1 (ko) | 2009-08-24 | 2015-07-03 | 앳슈랜드 라이센싱 앤드 인텔렉츄얼 프라퍼티 엘엘씨 | 수중수형 중합체 분산물 중의 음이온성 가교결합 중합체 |
| CN102482479B (zh) * | 2009-08-24 | 2015-03-18 | 亚什兰许可和知识产权有限公司 | 水包水型聚合物分散体中的阳离子型交联聚合物 |
| JP6050122B2 (ja) | 2009-12-29 | 2016-12-27 | ソレニス・テクノロジーズ・ケイマン・エル・ピー | ビニルアミン含有ポリマー及びアクリルアミド含有ポリマーを用いた処理による紙の乾燥強度増強法 |
| PL2609250T3 (pl) | 2010-08-25 | 2017-04-28 | Solenis Technologies Cayman, L.P. | Sposób zwiększenia zalet skrobi w przerobionym na masę papierniczą materiale celulozowym w wytwarzaniu papieru i tektury |
| WO2012100156A1 (en) | 2011-01-20 | 2012-07-26 | Hercules Incorporated | Enhanced dry strength and drainage performance by combining glyoxalated acrylamide-containing polymers with cationic aqueous dispersion polymers |
| BR112014004225B1 (pt) | 2011-08-25 | 2021-02-02 | Solenis Technologies Cayman, L.P. | método para fabricar papel, papelão ou papel-cartão e uso |
| US20140246377A1 (en) | 2011-10-19 | 2014-09-04 | Ashland Licensing And Intellectual Property Llc | Composition comprising a non-ionic surfactant and an ionic polymer |
| WO2013179139A1 (en) | 2012-05-30 | 2013-12-05 | Kemira Oyj | Compositions and methods of making paper products |
| BR112015004979B1 (pt) | 2012-09-19 | 2021-07-27 | Solenis Technologies Cayman, L.P. | Processo para melhorar as propriedades reológicas de uma pasta mineral |
| US8894817B1 (en) | 2014-01-16 | 2014-11-25 | Ecolab Usa Inc. | Wet end chemicals for dry end strength |
| US9567708B2 (en) | 2014-01-16 | 2017-02-14 | Ecolab Usa Inc. | Wet end chemicals for dry end strength in paper |
| AU2015247996B2 (en) | 2014-04-16 | 2018-11-15 | Solenis Technologies, L.P. | Modified vinylamine containing polymers and their use in papermaking |
| US9920482B2 (en) | 2014-10-06 | 2018-03-20 | Ecolab Usa Inc. | Method of increasing paper strength |
| US9702086B2 (en) | 2014-10-06 | 2017-07-11 | Ecolab Usa Inc. | Method of increasing paper strength using an amine containing polymer composition |
| CN104449617B (zh) * | 2014-11-26 | 2018-05-08 | 胜利油田胜利化工有限责任公司 | 一种阴离子聚丙烯酰胺水包水乳液堵水调剖剂及其制备方法和使用用法 |
| US9783933B2 (en) | 2015-04-10 | 2017-10-10 | Solenis Technologies, L.P. | Modified vinylamine-containing polymers and their use in papermaking |
| US10648133B2 (en) | 2016-05-13 | 2020-05-12 | Ecolab Usa Inc. | Tissue dust reduction |
| US10787768B2 (en) | 2016-09-07 | 2020-09-29 | Kemira Oyj | Method for manufacture of paper, board or the like and use of the composition |
| EP3512999A1 (en) | 2016-09-16 | 2019-07-24 | Solenis Technologies, L.P. | Increased drainage performance in papermaking systems using microfibrillated cellulose |
| BR112019019603B1 (pt) * | 2017-03-29 | 2023-10-31 | Kemira Oyj | Método para a produção de papel, cartão ou similar e uso de uma celulose microfibrilada |
| EP3692207B1 (en) | 2017-10-03 | 2025-07-30 | Solenis Technologies Cayman, L.P. | Chemical efficiency increase in papermaking process |
| CN110819405A (zh) * | 2019-11-19 | 2020-02-21 | 安徽鑫固环保股份有限公司 | 羟丙基纤维素制备的改性梳型水煤浆分散剂及制备方法 |
| DE102022114644A1 (de) | 2022-06-10 | 2023-12-21 | Solenis Technologies Cayman, L.P. | Hochmolekulare polymerdispersionen mit metallfängern |
| DE102022114642A1 (de) | 2022-06-10 | 2023-12-21 | Solenis Technologies Cayman, L.P. | Polymerdispersionen mit hohem molekulargewicht, hergestellt unter kontrollierten adiabatischen bedingungen |
| DE102022114640A1 (de) | 2022-06-10 | 2023-12-21 | Solenis Technologies Cayman, L.P. | Hochmolekulare polymerdispersionen mit homopolymerem dispergiermittel |
| DE102022114638A1 (de) | 2022-06-10 | 2023-12-21 | Solenis Technologies Cayman, L.P. | Polymerdispersionen mit hohem molekulargewicht |
| DE102022114641A1 (de) | 2022-06-10 | 2023-12-21 | Solenis Technologies Cayman, L.P. | Hochmolekulare polymerdispersionen mit massgeschneidertem molekulargewicht des polymeren dispersionsmittels |
| KR20230170591A (ko) | 2022-06-10 | 2023-12-19 | 솔레니스 테크놀러지스 케이맨, 엘.피. | 제어된 단열 조건 하에 제조된 고분자량 중합체 분산액 |
| DE102023119842A1 (de) | 2023-07-26 | 2025-01-30 | Solenis Technologies Cayman, L.P. | Polymere dispersionen mit hohem molekulargewicht, enthaltend homopolymeres dispergiermittel, hergestellt durch kontrollierte polymerisation |
| DE102023119844A1 (de) | 2023-07-26 | 2025-01-30 | Solenis Technologies Cayman, L.P. | Polymere dispersionen mit hohem molekulargewicht, die im batch-reaktor hergestellt werden |
| DE102023119841A1 (de) | 2023-07-26 | 2025-01-30 | Solenis Technologies Cayman, L.P. | Verfahren zur herstellung einer wasser-in-wasser-polymerdispersion unter anwendung eines scherprofils |
| DE102023119843A1 (de) | 2023-07-26 | 2025-01-30 | Solenis Technologies Cayman, L.P. | Polymeres dispergiermittel zur herstellung einer wasser-in-wasser-dispersion, die durch polymerisation in gegenwart eines amins hergestellt wird |
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|---|---|---|---|---|
| DE2322883A1 (de) * | 1973-05-07 | 1974-11-28 | Roehm Gmbh | Wasserloesliche polymerisate |
| CA1267483A (en) | 1984-11-19 | 1990-04-03 | Hisao Takeda | Process for the production of a water-soluble polymer dispersion |
| DE4124819A1 (de) | 1991-07-26 | 1993-01-28 | Basf Ag | Waessrige polymerisatdispersionen |
| US5330772A (en) | 1992-12-11 | 1994-07-19 | Wm. Wrigley Jr. Company | Use of gum guaiac as an antioxidant in chewing gum |
| ES2126018T3 (es) † | 1993-06-04 | 1999-03-16 | Nalco Chemical Co | Procedimiento de polimerizacion de dispersiones. |
| DE9314249U1 (de) | 1993-09-21 | 1993-12-02 | Klaus Kunststofftechnik Gmbh, 87700 Memmingen | Bausteinsystem |
| US6133368A (en) * | 1993-12-09 | 2000-10-17 | Nalco Chemical Company | Seed process for salt dispersion polymer |
| GB2308123A (en) * | 1995-12-15 | 1997-06-18 | Mitsubishi Chem Corp | Process for the preparation of an aqueous solution or dispersion containing cationic polymer |
| JP3580397B2 (ja) * | 1996-06-20 | 2004-10-20 | 栗田工業株式会社 | 水溶性カチオンポリマー水系分散液の製造方法 |
| MY136998A (en) | 1996-09-24 | 2008-12-31 | Nalco Chemical Co | Hydrophilic dispersion polymers for paper applications |
| CA2264803A1 (en) | 1996-10-03 | 1998-04-09 | Cytec Technology Corp. | Aqueous dispersions |
| MY120719A (en) | 1997-01-20 | 2005-11-30 | Ciba Spec Chem Water Treat Ltd | Polymeric compositions and their production and uses |
| MY118538A (en) * | 1997-01-20 | 2004-12-31 | Ciba Spec Chem Water Treat Ltd | Polymeric compositions and their production and uses |
| US6426383B1 (en) † | 1997-05-28 | 2002-07-30 | Nalco Chemical Company | Preparation of water soluble polymer dispersions from vinylamide monomers |
| DE19851024A1 (de) | 1998-11-05 | 2000-05-11 | Basf Ag | Wäßrige Dispersionen von wasserlöslichen Polymerisaten von N-Vinylcarbonsäureamiden, Verfahren zu ihrer Herstellung und ihre Verwendung |
| EP1183213A4 (en) | 1999-04-09 | 2003-05-28 | Nalco Chemical Co | HIGHLY ACTIVE DISPERSION POLYMER TO SUPPORT CLEANING PROCESSES, DRAINAGE, RETENTION AND DRAINAGE |
-
2000
- 2000-12-08 DE DE10061483A patent/DE10061483A1/de not_active Withdrawn
-
2001
- 2001-12-01 ES ES01990467T patent/ES2256321T5/es not_active Expired - Lifetime
- 2001-12-01 US US10/432,624 patent/US7323510B2/en not_active Expired - Lifetime
- 2001-12-01 MX MXPA03005104 patent/MX243000B/es active IP Right Grant
- 2001-12-01 KR KR1020037007649A patent/KR100886025B1/ko not_active Expired - Fee Related
- 2001-12-01 AT AT01990467T patent/ATE315604T1/de active
- 2001-12-01 AU AU2958502A patent/AU2958502A/xx active Pending
- 2001-12-01 WO PCT/EP2001/014062 patent/WO2002046275A1/de not_active Ceased
- 2001-12-01 PL PL362248A patent/PL204175B1/pl unknown
- 2001-12-01 EP EP01990467A patent/EP1353975B2/de not_active Expired - Lifetime
- 2001-12-01 AU AU2002229585A patent/AU2002229585B2/en not_active Ceased
- 2001-12-01 DE DE50108702T patent/DE50108702D1/de not_active Expired - Lifetime
- 2001-12-01 CN CNB018202527A patent/CN1224637C/zh not_active Expired - Lifetime
- 2001-12-01 CA CA2427713A patent/CA2427713C/en not_active Expired - Lifetime
- 2001-12-01 NZ NZ526739A patent/NZ526739A/en not_active IP Right Cessation
- 2001-12-01 BR BRPI0116006-0A patent/BR0116006B1/pt not_active IP Right Cessation
- 2001-12-01 DK DK01990467T patent/DK1353975T3/da active
- 2001-12-01 PT PT01990467T patent/PT1353975E/pt unknown
- 2001-12-01 JP JP2002548007A patent/JP4012067B2/ja not_active Expired - Fee Related
- 2001-12-04 TW TW090129900A patent/TW591060B/zh not_active IP Right Cessation
- 2001-12-06 CL CL2001002979A patent/CL2001002979A1/xx unknown
- 2001-12-07 AR ARP010105710A patent/AR031647A1/es active IP Right Grant
- 2001-12-07 MY MYPI20015585A patent/MY139509A/en unknown
-
2003
- 2003-04-30 ZA ZA2003/03358A patent/ZA200303358B/en unknown
- 2003-06-10 NO NO20032617A patent/NO20032617L/no not_active Application Discontinuation
-
2006
- 2006-01-27 CL CL2006000179A patent/CL45687B/xx active
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