NO314293B1 - Katalysator for oksyklorering av etylen, fremgangsmåte for fremstilling avkatalysatoren, og fremgangsmåte for oksyklorering - Google Patents
Katalysator for oksyklorering av etylen, fremgangsmåte for fremstilling avkatalysatoren, og fremgangsmåte for oksyklorering Download PDFInfo
- Publication number
- NO314293B1 NO314293B1 NO19964933A NO964933A NO314293B1 NO 314293 B1 NO314293 B1 NO 314293B1 NO 19964933 A NO19964933 A NO 19964933A NO 964933 A NO964933 A NO 964933A NO 314293 B1 NO314293 B1 NO 314293B1
- Authority
- NO
- Norway
- Prior art keywords
- granules
- catalyst
- catalysts
- oxychlorination
- catalysts according
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 71
- 238000000034 method Methods 0.000 title claims description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 16
- 239000005977 Ethylene Substances 0.000 title claims description 16
- 238000002360 preparation method Methods 0.000 title description 2
- 239000008187 granular material Substances 0.000 claims description 37
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 13
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 12
- 239000011148 porous material Substances 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 238000005461 lubrication Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000004480 active ingredient Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 239000000843 powder Substances 0.000 description 8
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 3
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 229960003750 ethyl chloride Drugs 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- HFFLGKNGCAIQMO-UHFFFAOYSA-N trichloroacetaldehyde Chemical compound ClC(Cl)(Cl)C=O HFFLGKNGCAIQMO-UHFFFAOYSA-N 0.000 description 2
- 230000007306 turnover Effects 0.000 description 2
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004605 External Lubricant Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229940105289 carbon black Drugs 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 description 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229940091250 magnesium supplement Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000010702 perfluoropolyether Substances 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229940033134 talc Drugs 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/122—Halides of copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT95MI002396A IT1276155B1 (it) | 1995-11-21 | 1995-11-21 | Catalizzatori per l'ossiclorurazione dell'etilene,procedimento per la loro preparazione e procedimento di ossiclorurazione impiegante gli |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO964933D0 NO964933D0 (no) | 1996-11-20 |
| NO964933L NO964933L (no) | 1997-05-22 |
| NO314293B1 true NO314293B1 (no) | 2003-03-03 |
Family
ID=11372559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19964933A NO314293B1 (no) | 1995-11-21 | 1996-11-20 | Katalysator for oksyklorering av etylen, fremgangsmåte for fremstilling avkatalysatoren, og fremgangsmåte for oksyklorering |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US5905054A (fr) |
| EP (1) | EP0775522B1 (fr) |
| JP (1) | JPH09173851A (fr) |
| KR (1) | KR100451661B1 (fr) |
| AR (1) | AR004622A1 (fr) |
| AT (1) | ATE262377T1 (fr) |
| AU (1) | AU707979B2 (fr) |
| BR (1) | BR9605653A (fr) |
| CA (1) | CA2190704C (fr) |
| CZ (1) | CZ290522B6 (fr) |
| DE (1) | DE69631937T2 (fr) |
| DK (1) | DK0775522T3 (fr) |
| ES (1) | ES2216030T3 (fr) |
| HR (1) | HRP960543B1 (fr) |
| IL (1) | IL119631A (fr) |
| IT (1) | IT1276155B1 (fr) |
| MA (1) | MA24010A1 (fr) |
| MX (1) | MX9605742A (fr) |
| NO (1) | NO314293B1 (fr) |
| PL (1) | PL317089A1 (fr) |
| TR (1) | TR199600926A2 (fr) |
| YU (1) | YU62296A (fr) |
| ZA (1) | ZA969660B (fr) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1282267B1 (it) * | 1995-03-14 | 1998-03-16 | Montecatini Tecnologie Srl | Catalizzatori e supporti per catalizzatori ottenuti per pastigliatura |
| EP0931587A1 (fr) * | 1998-01-08 | 1999-07-28 | Evc Technology Ag | Catalyseur, procédé pour sa préparation et son utilisation pour la synthèse de 1,2-dichlorétane |
| GB9807131D0 (en) * | 1998-04-03 | 1998-06-03 | Ici Plc | Copper-containing materials |
| IT1306194B1 (it) * | 1999-01-08 | 2001-05-30 | Sued Chemie Mt Srl | Catalizzatori per reazioni esotermiche su letto fisso. |
| EP1053789B1 (fr) * | 1999-05-21 | 2004-07-14 | Evc Technology Ag | Catalyseur et procédé d'oxychlorination l'utilisant |
| DE10003510A1 (de) * | 2000-01-27 | 2001-08-02 | Basf Ag | Verfahren zur Herstellung von 1,2-Dichlorethan |
| DE10009017A1 (de) * | 2000-02-25 | 2001-09-06 | Basf Ag | Geformte Katalysatoren |
| KR101169626B1 (ko) * | 2005-05-12 | 2012-08-03 | 솔베이(소시에떼아노님) | 옥시염소화 촉매 및 상기 촉매를 이용한 방법 |
| TW200719968A (en) | 2005-10-31 | 2007-06-01 | Sued Chemie Ag | Catalyst molding for partial oxidation reactions |
| JP4943307B2 (ja) * | 2007-11-27 | 2012-05-30 | 日揮触媒化成株式会社 | オキシクロリネーション用触媒の製造方法 |
| ITMI20082333A1 (it) * | 2008-12-29 | 2010-06-30 | Sud Chemie Catalysts Italia S R L | Precursori di catalizzatori di ossiclorurazione dell'etilene a dicloroetano. |
| TWI642481B (zh) * | 2013-07-17 | 2018-12-01 | 東楚股份有限公司 | Catalyst system for the production of heterogeneous catalysts and 1,2-dichloroethane |
| JP2015098443A (ja) * | 2013-11-18 | 2015-05-28 | 東ソー株式会社 | １，２−ジクロロエタンの製造用触媒システム及びそれを用いた１，２−ジクロロエタンの製造方法 |
| JP6866344B2 (ja) | 2015-07-22 | 2021-04-28 | ビーエーエスエフ コーポレーション | 酢酸ビニルモノマー生成のための高い幾何学的表面積の触媒 |
| RU2677875C1 (ru) * | 2017-12-18 | 2019-01-22 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Катализатор и способ получения обогащенной по водороду газовой смеси из диметилового эфира и воздуха |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD136026A5 (de) * | 1977-04-20 | 1979-06-13 | Thomae Gmbh Dr K | Verfahren zum bespruehen der verdichtungswerkzeuge mit schmiermitteln |
| DE2932069A1 (de) * | 1979-08-08 | 1981-03-26 | Dr. Karl Thomae Gmbh, 88400 Biberach | Verfahren zum beschichten von formwerkzeugen mittels diskreter troepfchen fluessiger oder suspendierter schmiermittel bei der herstelllung von formlingen im pharma-, lebensmittel- oder katalysatorenbereich |
| US4441990A (en) * | 1982-05-28 | 1984-04-10 | Mobil Oil Corporation | Hollow shaped catalytic extrudates |
| US4460699A (en) * | 1982-08-04 | 1984-07-17 | Conoco Inc. | Fixed bed catalyst for oxychlorination |
| DE3607449A1 (de) * | 1986-03-07 | 1987-09-10 | Basf Ag | Geformter traegerkatalysator und dessen verwendung bei der oxichlorierung von ethylen |
| US4738934A (en) * | 1986-05-16 | 1988-04-19 | American Telephone And Telegraph Company, At&T Bell Laboratories | Method of making indium phosphide devices |
| DE4018512A1 (de) * | 1990-06-09 | 1991-12-12 | Wacker Chemie Gmbh | Zylindrisch geformter katalysator und dessen verwendung bei der oxichlorierung von ethylen |
| US5292703A (en) * | 1992-07-28 | 1994-03-08 | The Geon Company | Catalyst and process for oxychlorination of ethylene to EDC |
| IT1274033B (it) * | 1994-04-05 | 1997-07-14 | Montecatini Tecnologie Srl | Catalizzatore in granuli per la sintesi di 1-2 dicloroetano e preprocedimento di ossiclorurazione a letto fisso dell'etilene che utilizza tale catalizzatore. |
| IT1256156B (it) * | 1992-10-06 | 1995-11-29 | Montecatini Tecnologie Srl | Catalizzatore in granuli particolarmente per la deidrogenazione ossidativa di metanolo a formaldeide |
| IT1282267B1 (it) * | 1995-03-14 | 1998-03-16 | Montecatini Tecnologie Srl | Catalizzatori e supporti per catalizzatori ottenuti per pastigliatura |
-
1995
- 1995-11-21 IT IT95MI002396A patent/IT1276155B1/it active IP Right Grant
-
1996
- 1996-11-12 CZ CZ19963323A patent/CZ290522B6/cs not_active IP Right Cessation
- 1996-11-15 MA MA24396A patent/MA24010A1/fr unknown
- 1996-11-15 JP JP8305233A patent/JPH09173851A/ja active Pending
- 1996-11-15 HR HR960543A patent/HRP960543B1/xx not_active IP Right Cessation
- 1996-11-18 ES ES96118468T patent/ES2216030T3/es not_active Expired - Lifetime
- 1996-11-18 DE DE69631937T patent/DE69631937T2/de not_active Expired - Fee Related
- 1996-11-18 AT AT96118468T patent/ATE262377T1/de not_active IP Right Cessation
- 1996-11-18 IL IL11963196A patent/IL119631A/xx not_active IP Right Cessation
- 1996-11-18 EP EP96118468A patent/EP0775522B1/fr not_active Expired - Lifetime
- 1996-11-18 DK DK96118468T patent/DK0775522T3/da active
- 1996-11-19 ZA ZA969660A patent/ZA969660B/xx unknown
- 1996-11-19 US US08/751,812 patent/US5905054A/en not_active Expired - Lifetime
- 1996-11-19 CA CA002190704A patent/CA2190704C/fr not_active Expired - Fee Related
- 1996-11-19 KR KR1019960055426A patent/KR100451661B1/ko not_active IP Right Cessation
- 1996-11-20 AU AU71894/96A patent/AU707979B2/en not_active Ceased
- 1996-11-20 PL PL96317089A patent/PL317089A1/xx unknown
- 1996-11-20 NO NO19964933A patent/NO314293B1/no not_active IP Right Cessation
- 1996-11-20 AR ARP960105251A patent/AR004622A1/es active IP Right Grant
- 1996-11-21 BR BR9605653A patent/BR9605653A/pt not_active Application Discontinuation
- 1996-11-21 YU YU62296A patent/YU62296A/sh unknown
- 1996-11-21 TR TR96/00926A patent/TR199600926A2/xx unknown
- 1996-11-21 MX MX9605742A patent/MX9605742A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL317089A1 (en) | 1997-05-26 |
| IL119631A0 (en) | 1997-02-18 |
| HRP960543A2 (en) | 1997-12-31 |
| IT1276155B1 (it) | 1997-10-27 |
| BR9605653A (pt) | 1998-08-18 |
| MA24010A1 (fr) | 1997-07-01 |
| AU7189496A (en) | 1997-05-29 |
| NO964933L (no) | 1997-05-22 |
| AU707979B2 (en) | 1999-07-22 |
| KR970025710A (ko) | 1997-06-24 |
| CA2190704C (fr) | 2002-03-19 |
| CZ332396A3 (en) | 1997-06-11 |
| NO964933D0 (no) | 1996-11-20 |
| CZ290522B6 (cs) | 2002-08-14 |
| IL119631A (en) | 2000-06-29 |
| ATE262377T1 (de) | 2004-04-15 |
| ZA969660B (en) | 1997-06-10 |
| YU62296A (sh) | 1998-12-23 |
| US5905054A (en) | 1999-05-18 |
| JPH09173851A (ja) | 1997-07-08 |
| MX9605742A (es) | 1997-05-31 |
| ITMI952396A1 (it) | 1997-05-21 |
| DE69631937T2 (de) | 2005-02-03 |
| DK0775522T3 (da) | 2004-05-10 |
| ITMI952396A0 (fr) | 1995-11-21 |
| EP0775522B1 (fr) | 2004-03-24 |
| HRP960543B1 (en) | 2002-02-28 |
| ES2216030T3 (es) | 2004-10-16 |
| AR004622A1 (es) | 1998-12-16 |
| EP0775522A1 (fr) | 1997-05-28 |
| TR199600926A2 (xx) | 1998-03-21 |
| CA2190704A1 (fr) | 1997-05-22 |
| KR100451661B1 (ko) | 2004-11-20 |
| DE69631937D1 (de) | 2004-04-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO314293B1 (no) | Katalysator for oksyklorering av etylen, fremgangsmåte for fremstilling avkatalysatoren, og fremgangsmåte for oksyklorering | |
| JP3781453B2 (ja) | １，２−ジクロロエタン合成に用いる顆粒状触媒及び該触媒を用いるエチレンのオキシクロル化のための固定床法 | |
| US4366093A (en) | Cylindrical molded catalyst | |
| US5861353A (en) | Catalyst in granular form for 1,2-dichloroethane synthesis | |
| KR100993061B1 (ko) | 선택적인 발열반응을 위한 촉매의 담체로서 적합한 중공펠렛 | |
| JP4638975B2 (ja) | 触媒およびそれを用いたオキシ塩素化法 | |
| KR20100074017A (ko) | 1,2-디클로로에탄으로의 에틸렌의 고정층 옥시염소화 반응용 촉매 | |
| JPH04227065A (ja) | 円筒形の触媒および１，２−ジクロロエタンの製造方法 | |
| KR20100070293A (ko) | 1,2-디클로로에탄으로의 에틸렌의 옥시염소화 반응용 촉매 | |
| US20130190541A1 (en) | Catalyst system, comprising catalyst pellets and diluent beads with predefined dimensions and physicochemical properties | |
| JP3690949B2 (ja) | エチレンの１，２−ジクロロエタンへのオキシ塩素化用触媒 | |
| CA2293983A1 (fr) | Catalyseur pour reactions exothermiques sur lit fixe | |
| JP2012513884A (ja) | エチレンのジクロロエタンへのオキシ塩素化用の触媒の前駆体 | |
| RU2172211C2 (ru) | Катализатор окислительного хлорирования этилена, способ его получения и способ окислительного хлорирования с его использованием | |
| JP6604874B2 (ja) | エチレンのオキシ塩素化による１，２−ジクロロエタンの合成に用いる触媒 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |