NO312572B1 - Mikrokapsel omfattende en partikkelformig ultrafiolettlysprotektant og eventuelt et biologisk aktivtmateriale, samt fremgangsmåte for fremstilling av mikrokapsler ogsuspensjon av partikkelformig ultrafiolettlysprotektant - Google Patents
Mikrokapsel omfattende en partikkelformig ultrafiolettlysprotektant og eventuelt et biologisk aktivtmateriale, samt fremgangsmåte for fremstilling av mikrokapsler ogsuspensjon av partikkelformig ultrafiolettlysprotektant Download PDFInfo
- Publication number
- NO312572B1 NO312572B1 NO19974947A NO974947A NO312572B1 NO 312572 B1 NO312572 B1 NO 312572B1 NO 19974947 A NO19974947 A NO 19974947A NO 974947 A NO974947 A NO 974947A NO 312572 B1 NO312572 B1 NO 312572B1
- Authority
- NO
- Norway
- Prior art keywords
- ultraviolet light
- liquid
- organic liquid
- biologically active
- water
- Prior art date
Links
- 239000003094 microcapsule Substances 0.000 title claims description 59
- 238000000034 method Methods 0.000 title claims description 40
- 239000011149 active material Substances 0.000 title claims description 25
- 239000000725 suspension Substances 0.000 title claims description 25
- 238000002360 preparation method Methods 0.000 title description 4
- 230000001012 protector Effects 0.000 title 2
- 239000007788 liquid Substances 0.000 claims description 74
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 27
- 239000007787 solid Substances 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 24
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 22
- 239000004094 surface-active agent Substances 0.000 claims description 20
- 239000004408 titanium dioxide Substances 0.000 claims description 20
- 239000002270 dispersing agent Substances 0.000 claims description 18
- 239000008346 aqueous phase Substances 0.000 claims description 15
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 claims description 14
- 239000005910 lambda-Cyhalothrin Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 13
- 230000001681 protective effect Effects 0.000 claims description 12
- 239000000084 colloidal system Substances 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000005056 polyisocyanate Substances 0.000 claims description 7
- 229920001228 polyisocyanate Polymers 0.000 claims description 7
- -1 polymethylene Polymers 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000007764 o/w emulsion Substances 0.000 claims description 6
- 229920002396 Polyurea Polymers 0.000 claims description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- 239000002775 capsule Substances 0.000 claims description 4
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 239000002728 pyrethroid Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims 3
- 150000002513 isocyanates Chemical class 0.000 claims 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 2
- 239000004202 carbamide Substances 0.000 claims 2
- 229920006389 polyphenyl polymer Polymers 0.000 claims 1
- 239000012074 organic phase Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 239000012071 phase Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 239000002904 solvent Substances 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 230000004224 protection Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000000227 grinding Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000700605 Viruses Species 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- LQIAZOCLNBBZQK-UHFFFAOYSA-N 1-(1,2-Diphosphanylethyl)pyrrolidin-2-one Chemical compound PCC(P)N1CCCC1=O LQIAZOCLNBBZQK-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 2
- 239000011325 microbead Substances 0.000 description 2
- 229920000847 nonoxynol Polymers 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical compound COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 1
- 239000005730 Azoxystrobin Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 239000005892 Deltamethrin Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000002024 Gossypium herbaceum Species 0.000 description 1
- 235000004341 Gossypium herbaceum Nutrition 0.000 description 1
- WXZVAROIGSFCFJ-UHFFFAOYSA-N N,N-diethyl-2-(naphthalen-1-yloxy)propanamide Chemical compound C1=CC=C2C(OC(C)C(=O)N(CC)CC)=CC=CC2=C1 WXZVAROIGSFCFJ-UHFFFAOYSA-N 0.000 description 1
- 239000005585 Napropamide Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000005924 Pirimiphos-methyl Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- NRXQIUSYPAHGNM-UHFFFAOYSA-N ioxynil Chemical compound OC1=C(I)C=C(C#N)C=C1I NRXQIUSYPAHGNM-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- QHOQHJPRIBSPCY-UHFFFAOYSA-N pirimiphos-methyl Chemical group CCN(CC)C1=NC(C)=CC(OP(=S)(OC)OC)=N1 QHOQHJPRIBSPCY-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- 229940070846 pyrethrins Drugs 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/18—In situ polymerisation with all reactants being present in the same phase
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/430,030 US5846554A (en) | 1993-11-15 | 1995-04-27 | Microcapsules containing suspensions of biologically active compounds and ultraviolet protectant |
PCT/GB1996/000935 WO1996033611A2 (en) | 1995-04-27 | 1996-04-18 | Microcapsules containing suspensions of biologically active compounds and ultraviolet protectant |
Publications (3)
Publication Number | Publication Date |
---|---|
NO974947D0 NO974947D0 (no) | 1997-10-24 |
NO974947L NO974947L (no) | 1997-12-22 |
NO312572B1 true NO312572B1 (no) | 2002-06-03 |
Family
ID=23705786
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19974947A NO312572B1 (no) | 1995-04-27 | 1997-10-24 | Mikrokapsel omfattende en partikkelformig ultrafiolettlysprotektant og eventuelt et biologisk aktivtmateriale, samt fremgangsmåte for fremstilling av mikrokapsler ogsuspensjon av partikkelformig ultrafiolettlysprotektant |
Country Status (36)
Country | Link |
---|---|
US (3) | US5846554A (el) |
EP (1) | EP0824313B1 (el) |
JP (2) | JP3961021B2 (el) |
KR (1) | KR100316311B1 (el) |
CN (1) | CN1127291C (el) |
AP (1) | AP873A (el) |
AR (1) | AR003681A1 (el) |
AT (1) | ATE195216T1 (el) |
AU (1) | AU711892B2 (el) |
BG (1) | BG63522B1 (el) |
BR (1) | BR9604990A (el) |
CA (1) | CA2219001C (el) |
CO (1) | CO5040219A1 (el) |
CZ (1) | CZ295114B6 (el) |
DE (1) | DE69609712T2 (el) |
DK (1) | DK0824313T3 (el) |
EA (1) | EA000219B1 (el) |
EG (1) | EG20936A (el) |
ES (1) | ES2148749T3 (el) |
GR (1) | GR3034610T3 (el) |
HU (1) | HU220881B1 (el) |
MX (1) | MX9708219A (el) |
MY (1) | MY113602A (el) |
NO (1) | NO312572B1 (el) |
NZ (1) | NZ305421A (el) |
OA (1) | OA10530A (el) |
PE (1) | PE44197A1 (el) |
PL (1) | PL184931B1 (el) |
PT (1) | PT824313E (el) |
RO (1) | RO120446B1 (el) |
SK (1) | SK283290B6 (el) |
TR (1) | TR199701259T1 (el) |
TW (1) | TW299223B (el) |
UA (1) | UA46025C2 (el) |
WO (1) | WO1996033611A2 (el) |
ZA (1) | ZA963303B (el) |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5846554A (en) * | 1993-11-15 | 1998-12-08 | Zeneca Limited | Microcapsules containing suspensions of biologically active compounds and ultraviolet protectant |
ATE197869T1 (de) * | 1995-06-07 | 2000-12-15 | Zeneca Ltd | Trockene wasserdispergierbare zusammensetzungen von mikroverkapselten pestiziden |
US6080418A (en) * | 1997-04-07 | 2000-06-27 | 3M Innovative Properties Company | Suspensions of microcapsules containing biologically active ingredients and adhesive microspheres |
US6248364B1 (en) | 1997-04-07 | 2001-06-19 | 3M Innovative Properties Company | Encapsulation process and encapsulated products |
US6544540B2 (en) * | 1998-07-29 | 2003-04-08 | Syngenta Limited | Base-triggered release microcapsules |
CA2338997C (en) * | 1998-07-29 | 2008-04-08 | Zeneca Limited | Base-triggered release microcapsules |
PT1218096E (pt) * | 1999-09-10 | 2004-08-31 | Syngenta Ltd | Microcapsulas de libertacao variavel |
WO2001068234A1 (de) | 2000-03-17 | 2001-09-20 | Bayer Aktiengesellschaft | Mikrokapsel-suspensionen |
US6428654B1 (en) | 2000-04-05 | 2002-08-06 | Hercules Incorporated | Fungicidal method |
US7758888B2 (en) * | 2000-04-21 | 2010-07-20 | Sol-Gel Technologies Ltd. | Composition exhibiting enhanced formulation stability and delivery of topical active ingredients |
JP4979109B2 (ja) | 2000-04-21 | 2012-07-18 | ゾル−ゲル テクノロジーズ リミテッド | 局所的有効成分の増強された配合安定性および送達を示す組成物 |
GB0015395D0 (en) * | 2000-06-26 | 2000-08-16 | Ciba Spec Chem Water Treat Ltd | Stabilisation of light sensitive substances |
US7923030B2 (en) | 2003-03-14 | 2011-04-12 | Sol-Gel Technologies, Inc. | Agent-encapsulating micro- and nanoparticles, methods for preparation of same and products containing same |
GB0312703D0 (en) * | 2003-06-03 | 2003-07-09 | Oxonica Ltd | Agricultural compositions |
WO2005009604A1 (en) * | 2003-07-31 | 2005-02-03 | Sol-Gel Technologies Ltd. | Microcapsules loaded with active ingredients and a method for their preparation |
JP4794120B2 (ja) * | 2003-08-20 | 2011-10-19 | 住化エンビロサイエンス株式会社 | マイクロカプセル化組成物 |
WO2005072680A2 (en) * | 2004-01-28 | 2005-08-11 | Oxonica, Ltd | Surface-doped particles of ti02 or zno and their use |
US7951390B2 (en) * | 2004-06-30 | 2011-05-31 | United Phosphorus, Ltd. | Slow-release microcapsule composition for safe delivery of agriculturally active material |
GB0501030D0 (en) * | 2005-01-19 | 2005-02-23 | Central Science Lab The | Formulation |
AU2006218077B2 (en) * | 2005-02-24 | 2012-03-29 | Syngenta Limited | Pesticidal capsule formulation |
CN101277757B (zh) * | 2005-08-02 | 2011-11-30 | 索尔-格尔科技有限公司 | 非水溶性成分的金属氧化物涂布 |
ITMI20051558A1 (it) * | 2005-08-09 | 2007-02-10 | Isagro Spa | Miscele e-o composizioni sinergiche cin elevata attivita'fungicida |
US20080254082A1 (en) * | 2005-09-27 | 2008-10-16 | Sol-Gel Technologies Ltd. | Methods for Crop Protection |
WO2007036710A2 (en) * | 2005-09-27 | 2007-04-05 | Syngenta Limited | Insecticidal textile material |
JP2007223907A (ja) * | 2006-02-21 | 2007-09-06 | Sumika Enviro-Science Co Ltd | マイクロカプセル剤及びその製造方法 |
US20070224135A1 (en) | 2006-03-24 | 2007-09-27 | Xianbin Liu | Stable aqueous suspension concentrate for delivery of UV-labile water-insoluble biocides |
GB0617859D0 (en) * | 2006-09-11 | 2006-10-18 | Syngenta Ltd | Compositions for photoprotection |
US20080167374A1 (en) * | 2007-01-09 | 2008-07-10 | Loveland Products, Inc. | Pesticide composition and method of use |
KR20090125243A (ko) | 2007-02-01 | 2009-12-04 | 솔-겔 테크놀로지스 리미티드 | 퍼옥사이드 및 레티노이드를 함유하는 국소 도포용 조성물 |
BRPI0808160A2 (pt) * | 2007-02-01 | 2014-09-23 | Sol Gel Technologies Ltd | Processo para revestir um material particulado sólido, insolúvel em água, com um óxido de metal, material particulado revestido, partículas, métodos para tratar uma condição de superfície em um indivíduo, e para prevenir, reduzir, ou eliminar pragas em um local, e, uso de material particulado revestido |
EP2148643A1 (en) * | 2007-05-21 | 2010-02-03 | Aquea Scientific Corporation | Highly charged microcapsules |
JP5051641B2 (ja) * | 2007-09-12 | 2012-10-17 | 日信工業株式会社 | 炭素繊維複合材料の製造方法 |
GB0804700D0 (en) | 2008-03-13 | 2008-04-16 | Syngenta Ltd | Microencapsulation |
AU2009259456A1 (en) * | 2008-06-20 | 2009-12-23 | Basf Se | Agrochemical formulations comprising a pesticide, an organic UV-photoprotective filter and coated metal-oxide nanoparticles |
EP2225940B1 (en) * | 2009-03-05 | 2014-03-12 | GAT Microencapsulation GmbH | Oil dispersions of nAChR binding neonicotinoids |
JP5603645B2 (ja) * | 2009-04-30 | 2014-10-08 | 日本エンバイロケミカルズ株式会社 | マイクロカプセル剤およびその製造方法 |
TW201041507A (en) | 2009-04-30 | 2010-12-01 | Dow Agrosciences Llc | Pesticide compositions exhibiting enhanced activity and methods for preparing same |
TW201041508A (en) * | 2009-04-30 | 2010-12-01 | Dow Agrosciences Llc | Pesticide compositions exhibiting enhanced activity |
PT104692B (pt) * | 2009-07-29 | 2013-06-18 | Univ Do Minho | Revestimento fotocatalitico para libertação controlada de agentes voláteis |
WO2011028884A1 (en) * | 2009-09-02 | 2011-03-10 | The Regents Of The University Of California | Microcapsule and methods of making and using microcapsules |
AR079413A1 (es) | 2009-10-07 | 2012-01-25 | Basf Se | Uso de particulas polimericas que comprenden insecticida para mejorar la movilidad en el suelo de insecticidas, formulaciones insecticidas, particulas polimericas que comprenden insecticida, y metodos para controlar plagas |
CN102946723A (zh) | 2010-04-21 | 2013-02-27 | 康奈尔大学 | 由生长介质的pH改变触发的种子和土壤处理的受控释放 |
BR112013017684B1 (pt) | 2011-01-11 | 2018-12-11 | Basf Se | microcápsulas, método para preparar as microcápsulas, composição aquosa e método para controle de fungo fitopatogênico |
EP2589290B1 (en) * | 2011-11-04 | 2014-11-26 | Endura S.p.a. | Microcapsules comprising a pyrethroid and/or neonicontinoid and a synergizing agent |
US8927619B2 (en) | 2011-12-21 | 2015-01-06 | Jorg Thomas Wilken | Color-stabilized iodopropynyl butylcarbamate |
PT106198B (pt) | 2012-03-08 | 2014-10-07 | Sapec Agro S A | Formulação inseticida, método para a sua preparação e utilização da mesma |
BR112014031664A2 (pt) | 2012-06-26 | 2017-06-27 | Sumitomo Chemical Co | microcápsula |
CN102766934A (zh) * | 2012-06-27 | 2012-11-07 | 吴江亚太化纺有限公司 | 一种远红外锦纶6 fdy纤维纺丝工艺 |
CN102766958A (zh) * | 2012-06-28 | 2012-11-07 | 吴江亚太化纺有限公司 | 防紫外线的运动服用dty高弹丝 |
US9687465B2 (en) | 2012-11-27 | 2017-06-27 | Sol-Gel Technologies Ltd. | Compositions for the treatment of rosacea |
US9494327B2 (en) * | 2013-06-06 | 2016-11-15 | Trane International Inc. | UV lamp service life indicator device and method of using the same |
CN103392735A (zh) * | 2013-06-30 | 2013-11-20 | 广东中迅农科股份有限公司 | 一种含有无机纳米材料的农药悬浮剂及其制备方法 |
US10881100B2 (en) * | 2014-01-29 | 2021-01-05 | Rotam Agrochem International Company Limited Chai Wan | Aqueous suspoemulsion containing lambda-cyhalothrin and methods for making and using the same |
CN104430321B (zh) * | 2014-12-01 | 2016-05-25 | 苏州市相城区盛胡特种养殖专业合作社 | 一种环保型农药助剂 |
PT108665B (pt) | 2015-07-05 | 2020-11-02 | Universidade Do Minho | Micro ou nanocápsulas com propriedades fotocatalíticas para libertação controlada de agentes difusores e respetivo método de obtenção |
CN105200800A (zh) * | 2015-09-17 | 2015-12-30 | 无锡市长安曙光手套厂 | 一种织物材料 |
JP6899821B2 (ja) * | 2015-10-22 | 2021-07-07 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 微小粒子の水性分散液を製造する方法 |
CA3019934A1 (en) * | 2015-12-07 | 2017-06-15 | Valent Biosciences Llc | Concentrated gibberellin solution formulations |
CN105557747A (zh) * | 2016-02-02 | 2016-05-11 | 南京高正农用化工有限公司 | 一种稳定型农药微囊悬浮剂 |
CN105941468A (zh) * | 2016-05-11 | 2016-09-21 | 安徽省益农化工有限公司 | 一种含草甘膦、唑嘧磺草胺和双草醚的混合除草剂 |
CN105794836A (zh) * | 2016-05-11 | 2016-07-27 | 安徽省益农化工有限公司 | 一种含草甘膦的除草剂及其制备方法 |
GB2551814B (en) * | 2016-06-30 | 2021-02-24 | Syngenta Participations Ag | Microcapsules encapsulating lambda-cyhalothin |
WO2018054719A1 (en) * | 2016-09-20 | 2018-03-29 | Firmenich Sa | Hybrid microcapsules |
JP6347355B2 (ja) | 2016-12-21 | 2018-06-27 | 大阪ウイントン株式会社 | 鳥類忌避塗料 |
JP6782021B2 (ja) * | 2018-03-29 | 2020-11-11 | 平岡織染株式会社 | 防虫効果持続性に優れたシート |
EP3829309A1 (en) * | 2018-07-31 | 2021-06-09 | Bayer Aktiengesellschaft | Capsule suspensions with agrochemical active ingredients |
CN111134121B (zh) * | 2019-12-30 | 2021-08-10 | 东华大学 | 一种具有驱蚊和抗紫外双功能的微胶囊及其制备方法 |
EP3868207A1 (de) | 2020-02-24 | 2021-08-25 | Bayer Aktiengesellschaft | Verkapselte pyrethroide mit verbesserter wirksamkeit bei boden- und blattanwendungen |
Family Cites Families (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US29238A (en) * | 1860-07-24 | grover | ||
US2090109A (en) * | 1933-11-15 | 1937-08-17 | Mayne R Coe | Stabilized insecticide of plant origin |
NL95045C (el) * | 1953-06-30 | |||
US3242051A (en) * | 1958-12-22 | 1966-03-22 | Ncr Co | Coating by phase separation |
GB929402A (en) * | 1958-12-22 | 1963-06-19 | Upjohn Co | Encapsulated emulsions and processes for their preparation |
US3541203A (en) * | 1969-05-08 | 1970-11-17 | Ncr Co | Protected virus composition for insect control |
US3839561A (en) * | 1970-07-22 | 1974-10-01 | Scm Corp | Insecticidal compositions stabilized by certain diisophorone derivatives |
US4285720A (en) * | 1972-03-15 | 1981-08-25 | Stauffer Chemical Company | Encapsulation process and capsules produced thereby |
USRE29238E (en) * | 1973-09-27 | 1977-05-31 | Westvaco Corporation | Composites of lignin and biologically active materials |
US4094969A (en) * | 1973-10-29 | 1978-06-13 | Sandoz, Inc. | Pesticide compositions stabilized with sulfonated catechin/leucocyanidin copolymer and method of using same |
US4056610A (en) * | 1975-04-09 | 1977-11-01 | Minnesota Mining And Manufacturing Company | Microcapsule insecticide composition |
FR2314719A1 (fr) * | 1975-04-11 | 1977-01-14 | Roussel Uclaf | Nouveau medicament notamment diuretique |
US4184866A (en) * | 1975-05-28 | 1980-01-22 | Westvaco Corporation | Sustained release pesticide compositions and process for making same |
US4140516A (en) * | 1977-05-31 | 1979-02-20 | Stauffer Chemical Company | Encapsulation process employing phase transfer catalysts |
FR2413123A1 (fr) * | 1977-12-30 | 1979-07-27 | Philagro Sa | Procede d'encapsulation par polycondensation interfaciale |
US4328203A (en) * | 1979-04-27 | 1982-05-04 | Battelle Development Corporation | Microbial insecticide |
CA1179682A (en) * | 1980-03-05 | 1984-12-18 | Imperial Chemical Industries Plc | Stabilised compositions containing behaviour modifying compounds |
US4956129A (en) * | 1984-03-30 | 1990-09-11 | Ici Americas Inc. | Microencapsulation process |
JPS58124705A (ja) * | 1982-01-18 | 1983-07-25 | Kureha Chem Ind Co Ltd | マイクロカプセル化農薬及びその製造方法 |
HU186056B (en) * | 1982-04-06 | 1985-05-28 | Egyt Gyogyszervegyeszeti Gyar | Insecticide preparate consisting of /2e-4e/-3,7,11-trimetil-11-metoxi-2,4-dodecaidienacid-propilesther |
ATE77916T1 (de) * | 1985-09-13 | 1992-07-15 | Ciba Geigy Ag | Verfahren zur herstellung von mikrokapseln. |
US4722838A (en) * | 1986-05-09 | 1988-02-02 | E. I. Du Pont De Nemours And Company | Self-microencapsulating controlled release pesticide compositions |
JPS6397668A (ja) * | 1986-10-13 | 1988-04-28 | Lion Corp | 耐光性カロチン |
US4915947A (en) * | 1986-11-07 | 1990-04-10 | Pennwalt Corporation | Microencapsulated fungicide |
JPS63268777A (ja) * | 1987-04-25 | 1988-11-07 | Kanzaki Paper Mfg Co Ltd | マイクロカプセルインキ組成物 |
US4844896A (en) * | 1987-11-02 | 1989-07-04 | Lim Technology Laboratories, Inc. | Microencapsulated insecticidal pathogens |
US4948586A (en) * | 1987-11-02 | 1990-08-14 | Lim Technology Laboratories, Inc. | Microencapsulated insecticidal pathogens |
US5206021A (en) * | 1988-05-09 | 1993-04-27 | Rhone-Poulenc Ag Company | Stabilized oil-in-water emulsions or suspoemulsions containing pesticidal substances in both oil and water phases |
US5254344A (en) * | 1988-05-09 | 1993-10-19 | Rhone-Poulenc Inc. | Oil-in-water pesticidal emulsion, process for application |
GB8827029D0 (en) * | 1988-11-18 | 1988-12-21 | Ici Plc | Insecticidal compositions |
US5759561A (en) * | 1988-12-28 | 1998-06-02 | Novartis Corporation | Pest control |
DE59102751D1 (de) * | 1990-03-02 | 1994-10-06 | Mannesmann Ag | Eine wässrige phase enthaltende mikrokapseln. |
US5418010A (en) * | 1990-10-05 | 1995-05-23 | Griffith Laboratories Worldwide, Inc. | Microencapsulation process |
US5120349A (en) * | 1990-12-07 | 1992-06-09 | Landec Labs, Inc. | Microcapsule having temperature-dependent permeability profile |
IL101774A0 (en) * | 1991-05-06 | 1992-12-30 | Lim Lab Inc | Microencapsulated agriculturally active agents,and their production |
DE59208063D1 (de) * | 1991-09-11 | 1997-04-03 | Ciba Geigy Ag | Pestizidformulierungen |
US5476662A (en) * | 1992-11-13 | 1995-12-19 | Isp Investments Inc. | Pesticide or herbicide polymer complexes for forming aqueous dispersions |
TW235900B (en) * | 1993-07-19 | 1994-12-11 | Ind Tech Res Inst | The compositions of biocides for anti-UV damage |
US5846554A (en) * | 1993-11-15 | 1998-12-08 | Zeneca Limited | Microcapsules containing suspensions of biologically active compounds and ultraviolet protectant |
JP3848676B2 (ja) * | 1993-11-15 | 2006-11-22 | シンジェンタ リミテッド | 生物学的に活性な化合物の懸濁液を含有するマイクロカプセル |
-
1995
- 1995-04-27 US US08/430,030 patent/US5846554A/en not_active Expired - Lifetime
-
1996
- 1996-04-18 AU AU53409/96A patent/AU711892B2/en not_active Expired
- 1996-04-18 HU HU9900466A patent/HU220881B1/hu unknown
- 1996-04-18 DK DK96910109T patent/DK0824313T3/da active
- 1996-04-18 CN CN96194163A patent/CN1127291C/zh not_active Expired - Lifetime
- 1996-04-18 KR KR1019970707629A patent/KR100316311B1/ko not_active IP Right Cessation
- 1996-04-18 WO PCT/GB1996/000935 patent/WO1996033611A2/en active IP Right Grant
- 1996-04-18 JP JP53224496A patent/JP3961021B2/ja not_active Expired - Lifetime
- 1996-04-18 DE DE69609712T patent/DE69609712T2/de not_active Expired - Lifetime
- 1996-04-18 AP APAP/P/1997/001130A patent/AP873A/en active
- 1996-04-18 CA CA002219001A patent/CA2219001C/en not_active Expired - Lifetime
- 1996-04-18 PL PL96323051A patent/PL184931B1/pl unknown
- 1996-04-18 TR TR97/01259T patent/TR199701259T1/xx unknown
- 1996-04-18 SK SK1456-97A patent/SK283290B6/sk not_active IP Right Cessation
- 1996-04-18 RO RO97-01996A patent/RO120446B1/ro unknown
- 1996-04-18 PT PT96910109T patent/PT824313E/pt unknown
- 1996-04-18 EP EP96910109A patent/EP0824313B1/en not_active Expired - Lifetime
- 1996-04-18 NZ NZ305421A patent/NZ305421A/xx not_active IP Right Cessation
- 1996-04-18 ES ES96910109T patent/ES2148749T3/es not_active Expired - Lifetime
- 1996-04-18 EA EA199700343A patent/EA000219B1/ru not_active IP Right Cessation
- 1996-04-18 UA UA97115651A patent/UA46025C2/uk unknown
- 1996-04-18 BR BR9604990A patent/BR9604990A/pt not_active IP Right Cessation
- 1996-04-18 MX MX9708219A patent/MX9708219A/es unknown
- 1996-04-18 AT AT96910109T patent/ATE195216T1/de active
- 1996-04-18 CZ CZ19973401A patent/CZ295114B6/cs not_active IP Right Cessation
- 1996-04-19 MY MYPI96001486A patent/MY113602A/en unknown
- 1996-04-23 EG EG35096A patent/EG20936A/xx active
- 1996-04-23 PE PE1996000277A patent/PE44197A1/es not_active IP Right Cessation
- 1996-04-24 CO CO96019784A patent/CO5040219A1/es unknown
- 1996-04-25 ZA ZA963303A patent/ZA963303B/xx unknown
- 1996-04-25 TW TW085104947A patent/TW299223B/zh not_active IP Right Cessation
- 1996-04-26 AR ARP960102364A patent/AR003681A1/es active IP Right Grant
-
1997
- 1997-10-24 NO NO19974947A patent/NO312572B1/no not_active IP Right Cessation
- 1997-10-24 OA OA70116A patent/OA10530A/en unknown
- 1997-10-24 BG BG101990A patent/BG63522B1/bg unknown
-
1998
- 1998-07-22 US US09/120,965 patent/US6149843A/en not_active Expired - Lifetime
- 1998-07-23 US US09/122,218 patent/US6077522A/en not_active Expired - Lifetime
-
2000
- 2000-10-12 GR GR20000402294T patent/GR3034610T3/el unknown
-
2006
- 2006-10-30 JP JP2006294980A patent/JP2007039468A/ja not_active Withdrawn
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
NO312572B1 (no) | Mikrokapsel omfattende en partikkelformig ultrafiolettlysprotektant og eventuelt et biologisk aktivtmateriale, samt fremgangsmåte for fremstilling av mikrokapsler ogsuspensjon av partikkelformig ultrafiolettlysprotektant | |
NO312571B1 (no) | Mikrokapsler som inneholder suspensjoner av biologisk aktive forbindelser samt fremgangsmåte for fremstilling derav | |
NO148703B (no) | Fremgangsmaate til fremstilling av polyurea-mikrokapsler | |
US4643764A (en) | Multiple types of microcapsules and their production | |
SK17432002A3 (sk) | Kvapalná suspenzia mikrokapsúl a postup na jej výrobu | |
CA1245917A (en) | Process for producing multiple types of microcapsules | |
Mulqueen | Recent developments on safer formulations of agrochemicals | |
US5993842A (en) | Microcapsules containing suspensions of biologically active compounds | |
NO316498B1 (no) | Fast mikroinnkapslet produkt og fremgangsmåte for fremstilling derav | |
KR20000015910A (ko) | 마이크로캡슐화된 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK1K | Patent expired |