NL8100835A - Pyrrolidine-ring-bevattende samenstelling voor toepassing als anti-ultravioletstabilisator in kunststofmaterialen. - Google Patents
Pyrrolidine-ring-bevattende samenstelling voor toepassing als anti-ultravioletstabilisator in kunststofmaterialen. Download PDFInfo
- Publication number
- NL8100835A NL8100835A NL8100835A NL8100835A NL8100835A NL 8100835 A NL8100835 A NL 8100835A NL 8100835 A NL8100835 A NL 8100835A NL 8100835 A NL8100835 A NL 8100835A NL 8100835 A NL8100835 A NL 8100835A
- Authority
- NL
- Netherlands
- Prior art keywords
- ultraviolet
- ultraviolet stabilizer
- plastic materials
- polyolefin polymers
- acid ester
- Prior art date
Links
- 239000000326 ultraviolet stabilizing agent Substances 0.000 title claims description 11
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 title claims description 9
- 239000000203 mixture Substances 0.000 title claims description 8
- 239000000463 material Substances 0.000 title description 3
- 239000004033 plastic Substances 0.000 title description 3
- 229920003023 plastic Polymers 0.000 title description 3
- -1 straight chain fatty acid ester Chemical class 0.000 claims description 21
- 229920000642 polymer Polymers 0.000 claims description 11
- 229920000098 polyolefin Polymers 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 230000002411 adverse Effects 0.000 claims 1
- 230000002939 deleterious effect Effects 0.000 claims 1
- 229940070765 laurate Drugs 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 description 10
- 229920001155 polypropylene Polymers 0.000 description 10
- 239000003381 stabilizer Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 5
- 229910052753 mercury Inorganic materials 0.000 description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- 229940024874 benzophenone Drugs 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- NOXHNAYUTJEYNN-UHFFFAOYSA-N 2,2,3,4,5,5-hexamethylpyrrolidine Chemical compound CC1C(C)C(C)(C)NC1(C)C NOXHNAYUTJEYNN-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- AAEJQHLAJICLHR-UHFFFAOYSA-N 1,2,2,3,3,4-hexamethylpyrrolidine Chemical compound CC1CN(C)C(C)(C)C1(C)C AAEJQHLAJICLHR-UHFFFAOYSA-N 0.000 description 1
- HICQVZTYLBJIIY-UHFFFAOYSA-N 2-(2,2,3,3,4,4-hexamethylpyrrolidin-1-yl)ethanol Chemical compound CC1(C)CN(CCO)C(C)(C)C1(C)C HICQVZTYLBJIIY-UHFFFAOYSA-N 0.000 description 1
- ZFMPCFWNBXALCU-UHFFFAOYSA-N 2-(2,2,3,4,5,5-hexamethylpyrrolidin-1-yl)ethanol Chemical compound CC1C(C)C(C)(C)N(CCO)C1(C)C ZFMPCFWNBXALCU-UHFFFAOYSA-N 0.000 description 1
- OCAQNEYBPDEIGD-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)OCC.CC1C(C(N(C1)C)(C)C)(C)C Chemical compound C(CCCCCCCCCCC)(=O)OCC.CC1C(C(N(C1)C)(C)C)(C)C OCAQNEYBPDEIGD-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- NQGIJDNPUZEBRU-UHFFFAOYSA-N dodecanoyl chloride Chemical compound CCCCCCCCCCCC(Cl)=O NQGIJDNPUZEBRU-UHFFFAOYSA-N 0.000 description 1
- XBRDBODLCHKXHI-UHFFFAOYSA-N epolamine Chemical compound OCCN1CCCC1 XBRDBODLCHKXHI-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012259 ether extract Substances 0.000 description 1
- LDOZSADIRVDPKA-UHFFFAOYSA-N ethyl hexadecanoate 1,2,2,3,3,4-hexamethylpyrrolidine Chemical compound C(CCCCCCCCCCCCCCC)(=O)OCC.CC1C(C(N(C1)C)(C)C)(C)C LDOZSADIRVDPKA-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- ARBOVOVUTSQWSS-UHFFFAOYSA-N hexadecanoyl chloride Chemical compound CCCCCCCCCCCCCCCC(Cl)=O ARBOVOVUTSQWSS-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 150000002942 palmitic acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
- C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Cosmetics (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20001/80A IT1174663B (it) | 1980-02-19 | 1980-02-19 | Composizioni pirrolidiniche e loro uso quali stabilizzanti uv per materie plastiche |
| IT2000180 | 1980-02-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8100835A true NL8100835A (nl) | 1981-09-16 |
Family
ID=11162984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8100835A NL8100835A (nl) | 1980-02-19 | 1981-02-19 | Pyrrolidine-ring-bevattende samenstelling voor toepassing als anti-ultravioletstabilisator in kunststofmaterialen. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4325864A (enExample) |
| JP (1) | JPS56131644A (enExample) |
| BE (1) | BE887565A (enExample) |
| CH (1) | CH652730A5 (enExample) |
| DE (1) | DE3106217C2 (enExample) |
| DK (1) | DK56081A (enExample) |
| FR (1) | FR2476105A1 (enExample) |
| GB (2) | GB2069507B (enExample) |
| IE (1) | IE50926B1 (enExample) |
| IT (1) | IT1174663B (enExample) |
| LU (1) | LU83146A1 (enExample) |
| NL (1) | NL8100835A (enExample) |
| NO (1) | NO810527L (enExample) |
| SE (1) | SE8100746L (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1196327B (it) * | 1984-11-16 | 1988-11-16 | Consiglio Nazionale Ricerche | 3-aza-7-idrossi-2,2,4,4-tetraalchilbiciclo (3.3.0) ottani,procedimento per la loro preparazione,intermedi adatti allo scopo e procedimento per l'ottenimento di questi ultimi |
| US5350786A (en) * | 1986-06-30 | 1994-09-27 | Enichem Synthesis S.P.A. | Process of (co)polymerization of α-olefins in the presence of stabilizers |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE923915C (de) * | 1951-05-05 | 1955-02-24 | Upjohn Co | Verfahren zur Herstellung von spasmolytisch wirksamen Pyrrolidinverbindungen |
| GB1398414A (en) * | 1972-07-28 | 1975-06-18 | Ciba Geigy Ag | Piperidine derivatives |
| GB1437002A (en) * | 1972-09-13 | 1976-05-26 | Ici Ltd | Cyclic amines |
| DE2459331A1 (de) * | 1973-12-28 | 1975-07-10 | Ciba Geigy Ag | Pyrrolidin-dicarbonsaeuren und ihre ester als lichtstabilisatoren |
| GB1467672A (en) * | 1974-04-11 | 1977-03-16 | Ciba Geigy Ag | Stabilised epoxy resin |
| US4093586A (en) * | 1975-01-15 | 1978-06-06 | Ciba-Geigy Corporation | Pyrrolidine dicarboxylic acids and esters and stabilized compositions |
| US4111901A (en) * | 1977-06-06 | 1978-09-05 | Borg-Warner Corporation | Hindered five-membered nitrogen rings as polyolefin stabilizers |
| IT1160064B (it) * | 1978-11-10 | 1987-03-04 | Anic Spa | Procedimento per la stabilizzazione di polimeri mediante impiego di sali di nichel di pirrolidinditiocarbammati sostituiti |
-
1980
- 1980-02-19 IT IT20001/80A patent/IT1174663B/it active
- 1980-12-05 US US06/213,653 patent/US4325864A/en not_active Expired - Lifetime
-
1981
- 1981-01-30 SE SE8100746A patent/SE8100746L/xx not_active Application Discontinuation
- 1981-02-04 GB GB8103466A patent/GB2069507B/en not_active Expired
- 1981-02-10 DK DK56081A patent/DK56081A/da not_active Application Discontinuation
- 1981-02-16 CH CH1015/81A patent/CH652730A5/it not_active IP Right Cessation
- 1981-02-17 NO NO810527A patent/NO810527L/no unknown
- 1981-02-17 FR FR8103117A patent/FR2476105A1/fr active Granted
- 1981-02-18 JP JP2162481A patent/JPS56131644A/ja active Pending
- 1981-02-18 BE BE0/203829A patent/BE887565A/fr not_active IP Right Cessation
- 1981-02-18 IE IE322/81A patent/IE50926B1/en unknown
- 1981-02-18 LU LU83146A patent/LU83146A1/fr unknown
- 1981-02-19 NL NL8100835A patent/NL8100835A/nl not_active Application Discontinuation
- 1981-02-19 DE DE3106217A patent/DE3106217C2/de not_active Expired
-
1983
- 1983-06-20 GB GB08316728A patent/GB2129813B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB2129813A (en) | 1984-05-23 |
| SE8100746L (sv) | 1981-08-20 |
| GB8316728D0 (en) | 1983-07-20 |
| CH652730A5 (it) | 1985-11-29 |
| NO810527L (no) | 1981-08-20 |
| DK56081A (da) | 1981-08-20 |
| DE3106217A1 (de) | 1982-01-21 |
| IE810322L (en) | 1981-08-19 |
| GB2069507B (en) | 1984-02-08 |
| FR2476105A1 (fr) | 1981-08-21 |
| GB2129813B (en) | 1984-11-21 |
| IE50926B1 (en) | 1986-08-20 |
| GB2069507A (en) | 1981-08-26 |
| JPS56131644A (en) | 1981-10-15 |
| IT1174663B (it) | 1987-07-01 |
| IT8020001A0 (it) | 1980-02-19 |
| FR2476105B1 (enExample) | 1984-02-24 |
| DE3106217C2 (de) | 1985-03-28 |
| LU83146A1 (fr) | 1981-09-11 |
| US4325864A (en) | 1982-04-20 |
| BE887565A (fr) | 1981-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BA | A request for search or an international-type search has been filed | ||
| BB | A search report has been drawn up | ||
| A85 | Still pending on 85-01-01 | ||
| BV | The patent application has lapsed |