MXPA02001410A - Copoliesteres grado reactor para aplicaciones de pelicula encogible. - Google Patents
Copoliesteres grado reactor para aplicaciones de pelicula encogible.Info
- Publication number
- MXPA02001410A MXPA02001410A MXPA02001410A MXPA02001410A MXPA02001410A MX PA02001410 A MXPA02001410 A MX PA02001410A MX PA02001410 A MXPA02001410 A MX PA02001410A MX PA02001410 A MXPA02001410 A MX PA02001410A MX PA02001410 A MXPA02001410 A MX PA02001410A
- Authority
- MX
- Mexico
- Prior art keywords
- mole percent
- reactor grade
- copolyester composition
- component
- ethylene glycol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Una composicion de copoliester grado reactor, asi como una pelicula encogible por calor hecha a partir de la misma, tiene inesperadamente una ductilidad superior que una combinacion de componentes multiples de copoliesteres con las mismas concentraciones de monomeros. La composicion de copoliester grado reactor se hace a partir de un componente diacido de al menos aproximadamente 90 por ciento en moles y un componente diol de (a) aproximadamente 72 a aproximadamente 88 por ciento en moles de etilenglicol, aproximadamente 10 a aproximadamente 15 por ciento en moles de 1,4- ciclohexandimetanol, y aproximadamente 2 a aproximadamente 13 por ciento en moles de dietilenglicol, o (b) aproximadamente 59 a aproximadamente 77.5 por ciento en moles de etilenglicol, aproximadamente 15 a aproximadamente 28 por ciento en moles de 1,4- ciclohexandimetanol, y aproximadamente 7.5 a aproximadamente 13 por ciento en moles de dietilenglicol. Adicionalmente, la pelicula encogible por calor puede producirse para adaptar de cerca las caracteristicas de encogimiento de cloruro de polivinilo variando las cantidades del componente diol de la composicion del copoliester grado reactor. Ademas, una composicion de copoliester grado reactor tiene un valor de color b* de -1.0 a menos de 4.5, en donde el componente diacido es al menos aproximadamente 90 por ciento en moles de acido tereftalico y el componente diol es aproximadamente 52 a aproximadamente 88 por ciento en moles de etilenglicol, aproximadamente 10 a aproximadamente 28 por ciento en moles de 1,4-ciclohexandimetanol, y aproximadamente 2 hasta aproximadamente 20 por ciento en moles de dietilenglicol.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14929899P | 1999-08-17 | 1999-08-17 | |
US09/636,320 US6362306B1 (en) | 1999-08-17 | 2000-08-11 | Reactor grade copolyesters for shrink film applications |
PCT/US2000/022296 WO2001012697A1 (en) | 1999-08-17 | 2000-08-15 | Reactor grade copolyesters for shrink film applications |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA02001410A true MXPA02001410A (es) | 2002-07-30 |
Family
ID=26846614
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA02001410A MXPA02001410A (es) | 1999-08-17 | 2000-08-15 | Copoliesteres grado reactor para aplicaciones de pelicula encogible. |
Country Status (8)
Country | Link |
---|---|
US (1) | US6362306B1 (es) |
EP (1) | EP1204694B2 (es) |
JP (2) | JP2003531214A (es) |
CN (1) | CN1210327C (es) |
BR (1) | BR0013359A (es) |
DE (1) | DE60017264T3 (es) |
MX (1) | MXPA02001410A (es) |
WO (1) | WO2001012697A1 (es) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3767511B2 (ja) | 2001-04-26 | 2006-04-19 | 東洋紡績株式会社 | 熱収縮性ポリエステル系フィルムロール |
JP2003292592A (ja) * | 2002-03-29 | 2003-10-15 | Toyobo Co Ltd | 共重合ポリエステルおよびその製造方法 |
KR100549111B1 (ko) * | 2003-06-23 | 2006-02-02 | 도레이새한 주식회사 | 결정성이 우수한 열수축성 폴리에스테르 필름 |
US20070052131A1 (en) * | 2003-09-22 | 2007-03-08 | Nakamoto Packs Co., Ltd. | Method of producing a weld-cut sealing/heat-shrinkable packaging film formed of a polyethylene terephthalate-based block copolymer polyester |
KR100593971B1 (ko) * | 2004-06-18 | 2006-06-30 | 에스케이씨 주식회사 | 내충격성 열수축성 폴리에스터 필름 |
KR101293098B1 (ko) * | 2004-08-30 | 2013-08-12 | 미쓰비시 가가꾸 폴리에스테르 필름 가부시키가이샤 | 이형용 폴리에스테르 필름 |
US20060121219A1 (en) * | 2004-12-07 | 2006-06-08 | Eastman Chemical Co. | Void-containing polyester shrink film with improved density retention |
US7524920B2 (en) * | 2004-12-16 | 2009-04-28 | Eastman Chemical Company | Biaxially oriented copolyester film and laminates thereof |
US7687594B2 (en) * | 2007-11-27 | 2010-03-30 | Industrial Technology Research Institute | Random amorphous copolymer and manufacturing method thereof |
KR101190348B1 (ko) * | 2007-12-11 | 2012-10-11 | 코오롱인더스트리 주식회사 | 열수축성 폴리에스테르계 필름 |
US8980389B2 (en) * | 2008-01-14 | 2015-03-17 | Eastman Chemical Company | Copolyesters and blends with improved recyclability, processes for their manufacture, and articles prepared therefrom |
US20090227735A1 (en) * | 2008-03-07 | 2009-09-10 | Eastman Chemical Company | Miscible polyester blends and shrinkable films prepared therefrom |
CN102015849A (zh) * | 2008-05-16 | 2011-04-13 | Skc株式会社 | 热收缩性聚酯薄膜 |
WO2010001252A2 (en) * | 2008-07-02 | 2010-01-07 | Invista Technologies S.A.R.L. | Copolyester for shrink film applications |
WO2011068195A1 (ja) * | 2009-12-04 | 2011-06-09 | 株式会社クラレ | 常圧可染ポリエステル繊維及びその製造方法 |
EP2766186B1 (en) | 2011-10-14 | 2017-06-28 | Avery Dennison Corporation | Shrink film for label |
US9427945B2 (en) * | 2011-12-30 | 2016-08-30 | Liberman Distributing And Manufacturing Co. | Extendable self-supporting material composites and manufacture thereof |
BR112014009083A2 (pt) | 2012-01-11 | 2017-05-09 | Avery Dennison Corp | película retrátil de multicamada com núcleo de poliolefina |
US10329393B2 (en) | 2012-12-12 | 2019-06-25 | Eastman Chemical Company | Copolysters plasticized with polymeric plasticizer for shrink film applications |
KR102082304B1 (ko) | 2013-05-02 | 2020-02-27 | 에스케이케미칼 주식회사 | 공중합 폴리에스테르 수지 및 이를 이용한 성형제품 |
CN105670233B (zh) * | 2014-11-18 | 2019-05-21 | 东丽纤维研究所(中国)有限公司 | 一种聚酯组合物及其制备方法和用途 |
KR101767132B1 (ko) * | 2016-03-02 | 2017-08-14 | 주식회사 휴비스 | 공중합 폴리에스테르 수지 제조용 화합물 및 이를 이용한 공중합 폴리에스테르 수지의 제조방법 |
US11427688B2 (en) | 2017-04-17 | 2022-08-30 | Eastman Chemical Company | Copolyesters plasticized with polymeric plasticizer |
US10543656B2 (en) | 2018-01-11 | 2020-01-28 | Eastman Chemical Company | Tough shrinkable films |
KR102240877B1 (ko) | 2018-04-30 | 2021-04-19 | 에스케이씨 주식회사 | 폴리에스테르 용기의 재생 방법 및 이로부터 제조된 재생 폴리에스테르 칩 |
KR102153670B1 (ko) | 2018-05-21 | 2020-09-08 | 에스케이씨 주식회사 | 열수축성 필름 및 이의 제조방법 |
WO2020131778A1 (en) * | 2018-12-17 | 2020-06-25 | Eastman Chemical Company | Copolyester from terephthalic acid containing low diethylene glycol |
JP2022553090A (ja) * | 2019-10-25 | 2022-12-21 | イーストマン ケミカル カンパニー | 再資源化物を有する反応器級樹脂から製造される結晶化可能な収縮性フィルムならびに熱成形性フィルムおよびシート |
CN110982052A (zh) * | 2019-12-31 | 2020-04-10 | 上海慧翌新材料科技有限公司 | 一种波斯纶用钛基聚酯及其制备方法 |
CN113334607B (zh) * | 2021-06-09 | 2023-08-29 | 海德里希(厦门)真空机械制造有限公司 | 一种风电叶片生产用多组分混料装置及其控制方法 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4217440A (en) | 1979-08-20 | 1980-08-12 | Eastman Kodak Company | Method for making branched polyesters reproducibly |
US4578437A (en) * | 1983-08-01 | 1986-03-25 | Eastman Kodak Company | Copolyester/polyester blends having reduced carbon dioxide permeability |
US4983653A (en) | 1986-11-12 | 1991-01-08 | Diafoil Company, Ltd. | Polyester shrinkable film containing benzotriazole |
JP2943178B2 (ja) * | 1989-10-30 | 1999-08-30 | 東洋紡績株式会社 | 熱収縮性ポリエステル系フイルム |
JP3006001B2 (ja) * | 1989-10-31 | 2000-02-07 | 東洋紡績株式会社 | 熱収縮性ポリエステル系フイルム |
JPH05245930A (ja) * | 1991-12-26 | 1993-09-24 | Sekisui Chem Co Ltd | ポリエステル系熱収縮フイルム |
JP3277576B2 (ja) * | 1992-12-11 | 2002-04-22 | 東レ株式会社 | 金属板貼合わせ用共重合ポリエステルおよびフィルム |
JPH071583A (ja) * | 1993-06-22 | 1995-01-06 | Toyobo Co Ltd | 制電性熱収縮性ポリエステル系フイルム |
JPH0732478A (ja) * | 1993-07-23 | 1995-02-03 | Toyobo Co Ltd | つや消し調熱収縮性ポリエステル系フィルム |
US5340624A (en) * | 1993-08-16 | 1994-08-23 | Eastman Chemical Company | Shrinkable copolyester film |
US5372864A (en) | 1993-09-03 | 1994-12-13 | Eastman Chemical Company | Toners for polyesters |
JPH07138388A (ja) * | 1993-11-17 | 1995-05-30 | Sekisui Chem Co Ltd | ポリエステル系熱収縮性フイルムの製造方法 |
JP3496728B2 (ja) * | 1994-01-25 | 2004-02-16 | 東洋紡績株式会社 | 熱収縮性ポリエステル系フィルム |
JP3365687B2 (ja) * | 1994-07-13 | 2003-01-14 | 三井化学株式会社 | ポリエステル樹脂の製造方法およびポリエステル樹脂 |
US5442036A (en) * | 1994-09-06 | 1995-08-15 | Eastman Chemical Company | Branched copolyesters especially suitable for extrusion blow molding |
JP3367271B2 (ja) * | 1995-02-02 | 2003-01-14 | 三菱化学株式会社 | ポリエステル樹脂組成物およびシート |
JPH08239460A (ja) * | 1995-03-07 | 1996-09-17 | Kanebo Ltd | ポリエステル系熱収縮フィルム |
AR000405A1 (es) * | 1995-03-27 | 1997-06-18 | Eastman Chem Co | Proceso para preparar políesteres |
US5859116A (en) | 1997-01-21 | 1999-01-12 | Eastman Chemical Company | Clarity and adjustable shrinkage of shrink films using miscible polyester blends |
BR9714779A (pt) | 1997-07-09 | 2000-07-25 | Eastman Chem Co | Composição, e, processo para formar partìculas de plaquetas tratadas e incorporar a partìcula de plaquetas tratadas em um poliéster |
DE69836223T2 (de) * | 1997-08-28 | 2007-08-30 | Eastman Chemical Co., Kingsport | Verbesserte copolymerbinderfasern |
US6068910A (en) | 1998-03-17 | 2000-05-30 | Eastman Chemical Company | Polyester resin compositions for calendering |
JP2000195765A (ja) * | 1998-10-21 | 2000-07-14 | Toray Ind Inc | コンデンサ―外装用熱収縮性ポリエステルフィルム |
-
2000
- 2000-08-11 US US09/636,320 patent/US6362306B1/en not_active Expired - Lifetime
- 2000-08-15 MX MXPA02001410A patent/MXPA02001410A/es active IP Right Grant
- 2000-08-15 WO PCT/US2000/022296 patent/WO2001012697A1/en active IP Right Grant
- 2000-08-15 CN CN00814093.6A patent/CN1210327C/zh not_active Expired - Lifetime
- 2000-08-15 DE DE60017264T patent/DE60017264T3/de not_active Expired - Lifetime
- 2000-08-15 JP JP2001517588A patent/JP2003531214A/ja not_active Withdrawn
- 2000-08-15 EP EP00957443A patent/EP1204694B2/en not_active Expired - Lifetime
- 2000-08-15 BR BR0013359-0A patent/BR0013359A/pt not_active Application Discontinuation
-
2012
- 2012-08-10 JP JP2012178189A patent/JP2012211346A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EP1204694B2 (en) | 2011-05-25 |
DE60017264T2 (de) | 2005-06-23 |
CN1399656A (zh) | 2003-02-26 |
EP1204694A1 (en) | 2002-05-15 |
CN1210327C (zh) | 2005-07-13 |
US6362306B1 (en) | 2002-03-26 |
BR0013359A (pt) | 2002-04-30 |
JP2012211346A (ja) | 2012-11-01 |
JP2003531214A (ja) | 2003-10-21 |
DE60017264D1 (de) | 2005-02-10 |
WO2001012697A8 (en) | 2001-10-25 |
WO2001012697A1 (en) | 2001-02-22 |
EP1204694B1 (en) | 2005-01-05 |
DE60017264T3 (de) | 2012-02-09 |
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Legal Events
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FG | Grant or registration |