MX390660B - Proceso para preparar etilenaminas superiores y derivados de etilenamina. - Google Patents

Proceso para preparar etilenaminas superiores y derivados de etilenamina.

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Publication number
MX390660B
MX390660B MX2018009318A MX2018009318A MX390660B MX 390660 B MX390660 B MX 390660B MX 2018009318 A MX2018009318 A MX 2018009318A MX 2018009318 A MX2018009318 A MX 2018009318A MX 390660 B MX390660 B MX 390660B
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MX
Mexico
Prior art keywords
sub
derivatives
ethylenemine
present
functional compound
Prior art date
Application number
MX2018009318A
Other languages
English (en)
Other versions
MX2018009318A (es
Inventor
Kate Antoon Jacob Berend Ten
Eike Nicolas Kantzer
Karl Fredrik Lake
Per Fredrik Olmo Larsson
Rolf Krister Edvinsson
Original Assignee
Akzo Nobel Chemicals Int Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Akzo Nobel Chemicals Int Bv filed Critical Akzo Nobel Chemicals Int Bv
Publication of MX2018009318A publication Critical patent/MX2018009318A/es
Publication of MX390660B publication Critical patent/MX390660B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/06—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups by reactions not involving the formation of carbamate groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
    • C07C273/1836—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety from derivatives of carbamic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
    • C07C273/1863—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety from urea
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/04—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms
    • C07C275/06—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
    • C07C275/14—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton being further substituted by nitrogen atoms not being part of nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/32—One oxygen atom
    • C07D233/36—One oxygen atom with hydrocarbon radicals, substituted by nitrogen atoms, attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
    • C08G71/02—Polyureas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0616—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/14—Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para preparar etilenaminas de la fórmula NH2-(C2H4-NH-)pH, en donde p es por lo menos 3, o derivados de las mismas, en donde pueden estar presentes una o más unidades -NH-C2H4-NH- como una unidad de etilenurea cíclica, o entre dos unidades -NH-C2H4-NH- está presente una porción carbonilo, haciendo reaccionar un compuesto etanolamina funcional, un compuesto amina funcional, en presencia de un agente de liberación de óxido de carbono, en donde la proporción molar de agente de liberación de óxido de carbono a compuesto amina funcional es de por lo menos 0.6 a 1.
MX2018009318A 2016-02-12 2017-02-10 Proceso para preparar etilenaminas superiores y derivados de etilenamina. MX390660B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16155545 2016-02-12
PCT/EP2017/052946 WO2017137531A1 (en) 2016-02-12 2017-02-10 Process to prepare higher ethylene amines and ethylene amine derivatives

Publications (2)

Publication Number Publication Date
MX2018009318A MX2018009318A (es) 2018-11-09
MX390660B true MX390660B (es) 2025-03-21

Family

ID=55353139

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018009318A MX390660B (es) 2016-02-12 2017-02-10 Proceso para preparar etilenaminas superiores y derivados de etilenamina.

Country Status (8)

Country Link
US (1) US10844001B2 (es)
EP (1) EP3414221B1 (es)
JP (1) JP6836596B2 (es)
KR (1) KR102139560B1 (es)
CN (1) CN108713012B (es)
BR (1) BR112018014267B1 (es)
MX (1) MX390660B (es)
WO (1) WO2017137531A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112018014270B1 (pt) 2016-02-12 2022-10-11 Akzo Nobel Chemicals International B.V. Processo de preparação de etilenoaminas
US10428011B2 (en) 2016-02-12 2019-10-01 Nouryon Chemicals International B.V. Process to prepare higher ethylene amines and ethylene amine derivatives
CN110072841B (zh) 2016-12-15 2022-04-19 阿克苏诺贝尔化学品国际有限公司 制备羟乙基亚乙基胺的方法
EP3555041B1 (en) * 2016-12-15 2022-02-02 Nouryon Chemicals International B.V. Process for manufacturing ethylene amines
US11267792B2 (en) * 2017-07-10 2022-03-08 Nouryon Chemicals International B.V. Process to prepare ethylene amines and ethylene amine derivatives
US11247963B2 (en) * 2017-08-11 2022-02-15 Nouryon Chemicals International B.V. Process for converting cyclic alkylene ureas into their corresponding alkylene amines
US11919866B2 (en) * 2017-08-11 2024-03-05 Nouryon Chemicals International B.V. Process for preparing cyclic alkylene ureas
TW201920114A (zh) 2017-08-11 2019-06-01 荷蘭商安科智諾貝爾化學國際公司 製造伸乙基胺化合物之環狀脲加成物的方法
CN110997640B (zh) * 2017-08-11 2023-07-28 诺力昂化学品国际有限公司 将亚乙基胺化合物的环状单脲转化为亚乙基胺化合物的方法
CN113061249B (zh) * 2021-04-29 2022-06-07 中山大学 聚乙烯亚胺的制备方法

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JPS5538329A (en) * 1978-09-13 1980-03-17 Toyo Soda Mfg Co Ltd Preparation of polyethylenepolyamine
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JP6496088B2 (ja) 2016-02-12 2019-04-03 アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップＡｋｚｏ Ｎｏｂｅｌ Ｃｈｅｍｉｃａｌｓ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｂ．Ｖ． 環状アルキレン尿素をそれらの対応するアルキレンアミンに変換するプロセス
US10428011B2 (en) * 2016-02-12 2019-10-01 Nouryon Chemicals International B.V. Process to prepare higher ethylene amines and ethylene amine derivatives
BR112018014270B1 (pt) 2016-02-12 2022-10-11 Akzo Nobel Chemicals International B.V. Processo de preparação de etilenoaminas

Also Published As

Publication number Publication date
EP3414221B1 (en) 2021-09-01
JP2019504845A (ja) 2019-02-21
WO2017137531A1 (en) 2017-08-17
CN108713012A (zh) 2018-10-26
CN108713012B (zh) 2021-07-02
US20190039993A1 (en) 2019-02-07
BR112018014267B1 (pt) 2021-12-28
EP3414221A1 (en) 2018-12-19
MX2018009318A (es) 2018-11-09
JP6836596B2 (ja) 2021-03-03
BR112018014267A2 (pt) 2018-12-18
KR102139560B1 (ko) 2020-07-31
US10844001B2 (en) 2020-11-24
KR20180103154A (ko) 2018-09-18

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