JPS5538329A - Preparation of polyethylenepolyamine - Google Patents
Preparation of polyethylenepolyamineInfo
- Publication number
- JPS5538329A JPS5538329A JP11167078A JP11167078A JPS5538329A JP S5538329 A JPS5538329 A JP S5538329A JP 11167078 A JP11167078 A JP 11167078A JP 11167078 A JP11167078 A JP 11167078A JP S5538329 A JPS5538329 A JP S5538329A
- Authority
- JP
- Japan
- Prior art keywords
- polyethylenepolyamine
- pref
- monoethanolamine
- acyclic
- ethylenediamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare an acyclic polyethylenepolyamine, in high purity and yield, by contacting monoethanolamine or ethylene glycol with ethylenediamine in liquid phase in the presence of an inorganic compound mainly composed of alumina or silica, at a specific temperature.
CONSTITUTION: An acyclic polyethylenepolyamine containing only extremely small amount of heterocyclic amines, is prepared by reacting (A) (1 mole of) monoethanolamine or ethylene glycol with (B) (pref. 2W10 moles of) ethylenediamine, in the presence of (C) 0.5W30wt%, based on (A)+(B), of an inorganic catalyst composed mainly of alumina or silica, pref. zeolite, active clay, diatomaceous earth, etc., at 250W350°C.
EFFECT: The reaction product is obtained as a free amine, and the process is simple and economical. The catalyst is low-cost, thermally and chemically stable, solid and easily handleable.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11167078A JPS5538329A (en) | 1978-09-13 | 1978-09-13 | Preparation of polyethylenepolyamine |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11167078A JPS5538329A (en) | 1978-09-13 | 1978-09-13 | Preparation of polyethylenepolyamine |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5538329A true JPS5538329A (en) | 1980-03-17 |
JPS6341897B2 JPS6341897B2 (en) | 1988-08-19 |
Family
ID=14567194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11167078A Granted JPS5538329A (en) | 1978-09-13 | 1978-09-13 | Preparation of polyethylenepolyamine |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5538329A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0150558A2 (en) * | 1983-12-16 | 1985-08-07 | Texaco Development Corporation | The preparation of linear polyethylene polyamines with silica-alumina catalysts |
US5073635A (en) * | 1990-06-22 | 1991-12-17 | The Dow Chemical Company | Process of preparing linearly-extended polyalkylenepolyamines employing metal silicate catalysts |
CN108713012A (en) * | 2016-02-12 | 2018-10-26 | 阿克苏诺贝尔化学品国际有限公司 | The method for preparing advanced ethylene amines and ethyleneamine derivatives |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51147600A (en) * | 1975-06-02 | 1976-12-17 | Texaco Development Corp | Process for preparing polyalkylene polyamine |
JPS52209A (en) * | 1975-06-02 | 1977-01-05 | Texaco Development Corp | Process for preparing polyalkylenepolyamine |
-
1978
- 1978-09-13 JP JP11167078A patent/JPS5538329A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51147600A (en) * | 1975-06-02 | 1976-12-17 | Texaco Development Corp | Process for preparing polyalkylene polyamine |
JPS52209A (en) * | 1975-06-02 | 1977-01-05 | Texaco Development Corp | Process for preparing polyalkylenepolyamine |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0150558A2 (en) * | 1983-12-16 | 1985-08-07 | Texaco Development Corporation | The preparation of linear polyethylene polyamines with silica-alumina catalysts |
US4547591A (en) * | 1983-12-16 | 1985-10-15 | Texaco Inc. | Preparation of linear polyethylenepolyamines with silica-alumina catalysts |
US5073635A (en) * | 1990-06-22 | 1991-12-17 | The Dow Chemical Company | Process of preparing linearly-extended polyalkylenepolyamines employing metal silicate catalysts |
CN108713012A (en) * | 2016-02-12 | 2018-10-26 | 阿克苏诺贝尔化学品国际有限公司 | The method for preparing advanced ethylene amines and ethyleneamine derivatives |
CN108713012B (en) * | 2016-02-12 | 2021-07-02 | 阿克苏诺贝尔化学品国际有限公司 | Process for preparing higher ethyleneamines and ethyleneamine derivatives |
Also Published As
Publication number | Publication date |
---|---|
JPS6341897B2 (en) | 1988-08-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS5538329A (en) | Preparation of polyethylenepolyamine | |
JPS5528928A (en) | Preparation of methoxysilane | |
JPS52113974A (en) | Synthesis of benzotriazole derivatives | |
JPS5291810A (en) | Preparation of alkylene glycols | |
JPS5334716A (en) | Preparation of amide amine amphoteric surface active agent | |
JPS52102273A (en) | Synthesis of 5-oxo-2-(alpha,alpha-disubstituted benzyloxyethyl)pyrrolidines | |
JPS52113973A (en) | Synthesis of benzotriazole derivatives | |
JPS5325530A (en) | Purification of aldehydes | |
JPS51115402A (en) | Process for preparation of alpha-amino acid | |
JPS5545630A (en) | Preparation of 4-chloropyridine hydrochloride | |
JPS55102521A (en) | Improved method for preparation of styrene | |
JPS539730A (en) | Preparation of optical active n-substituted diarylsulfinylimines | |
JPS5515425A (en) | Preparation of p-halogenothiophenol | |
JPS5377023A (en) | Preparation of aromatic diamine | |
JPS5363347A (en) | Substd. benzoic acid amide and process for preparing them | |
JPS54160310A (en) | Preparation of olefin oxide | |
JPS51138649A (en) | P rocess for preparing cyclohexene | |
JPS52125142A (en) | Preparation of n,n-dialkyltoluamides | |
JPS57188548A (en) | Preparation of beta-chloroalanine | |
JPS54112881A (en) | Preparation of 2-mercaptopyrimidine hydrochloride | |
JPS5219660A (en) | Preparation of cyclic iminoethers | |
JPS549225A (en) | Preparation of hydrazinoalkanesulfonic acid derivatives | |
JPS5295610A (en) | Preparation of alpha-thioamino acid derivatives | |
JPS537620A (en) | Synthesis of d-penicillamine | |
JPS5629579A (en) | Preparation of novel cyclic urethane compound |