MX378938B - Proceso para preparar etilenaminas y derivados de etilenaminas superiores. - Google Patents

Proceso para preparar etilenaminas y derivados de etilenaminas superiores.

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Publication number
MX378938B
MX378938B MX2018009317A MX2018009317A MX378938B MX 378938 B MX378938 B MX 378938B MX 2018009317 A MX2018009317 A MX 2018009317A MX 2018009317 A MX2018009317 A MX 2018009317A MX 378938 B MX378938 B MX 378938B
Authority
MX
Mexico
Prior art keywords
sub
ethyleneamines
functional compound
derivatives
amine
Prior art date
Application number
MX2018009317A
Other languages
English (en)
Other versions
MX2018009317A (es
Inventor
Kate Antoon Jacob Berend Ten
Eike Nicolas Kantzer
Karl Fredrik Lake
Per Fredrik Olmo Larsson
Rolf Krister Edvinsson
Original Assignee
Akzo Nobel Chemicals Int Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel Chemicals Int Bv filed Critical Akzo Nobel Chemicals Int Bv
Publication of MX2018009317A publication Critical patent/MX2018009317A/es
Publication of MX378938B publication Critical patent/MX378938B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/06—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups by reactions not involving the formation of carbamate groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
    • C07C273/1836—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety from derivatives of carbamic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
    • C07C273/1863—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety from urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/14—Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/04—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms
    • C07C275/06—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
    • C07C275/14—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton being further substituted by nitrogen atoms not being part of nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/16—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D263/18—Oxygen atoms
    • C07D263/20—Oxygen atoms attached in position 2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para preparar etilenaminas de la fórmula NH2-(C2H4-NH-)pH en donde p es por lo menos 3 o sus derivados en donde una o más unidades -NH-C2H4-NH- pueden estar presentes como una unidad de etilenurea cíclica o entre dos unidades -NH-C2H4-NH- está presente una porción de carbonilo, a través de la reacción de un compuesto etanolamina-funcional, un compuesto amina-funcional en la presencia de un agente de entrega de óxido de carbono, donde la relación molar de compuesto etanolamina-funcional a compuesto amina-funcional es por lo menos 0.7:1 y la relación molar de agente de entrega de óxido de carbono a compuesto amina-funcional es por lo menos 0.05:1.
MX2018009317A 2016-02-12 2017-02-10 Proceso para preparar etilenaminas y derivados de etilenaminas superiores. MX378938B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16155549 2016-02-12
PCT/EP2017/052948 WO2017137532A1 (en) 2016-02-12 2017-02-10 Process to prepare higher ethylene amines and ethylene amine derivatives

Publications (2)

Publication Number Publication Date
MX2018009317A MX2018009317A (es) 2018-11-09
MX378938B true MX378938B (es) 2025-03-10

Family

ID=55398201

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018009317A MX378938B (es) 2016-02-12 2017-02-10 Proceso para preparar etilenaminas y derivados de etilenaminas superiores.

Country Status (8)

Country Link
US (1) US10428011B2 (es)
EP (1) EP3414222B1 (es)
JP (1) JP6671489B2 (es)
KR (1) KR102067452B1 (es)
CN (1) CN108602752B (es)
BR (1) BR112018014272B1 (es)
MX (1) MX378938B (es)
WO (1) WO2017137532A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX390660B (es) * 2016-02-12 2025-03-21 Akzo Nobel Chemicals Int Bv Proceso para preparar etilenaminas superiores y derivados de etilenamina.
BR112018014270B1 (pt) 2016-02-12 2022-10-11 Akzo Nobel Chemicals International B.V. Processo de preparação de etilenoaminas
EP3555041B1 (en) * 2016-12-15 2022-02-02 Nouryon Chemicals International B.V. Process for manufacturing ethylene amines
CN110072841B (zh) 2016-12-15 2022-04-19 阿克苏诺贝尔化学品国际有限公司 制备羟乙基亚乙基胺的方法
US11214549B2 (en) 2017-07-10 2022-01-04 Nouryon Chemicals International B.V. Process for making higher ethylene amines
US11267792B2 (en) 2017-07-10 2022-03-08 Nouryon Chemicals International B.V. Process to prepare ethylene amines and ethylene amine derivatives
EP3652155B1 (en) 2017-07-10 2021-09-01 Nouryon Chemicals International B.V. Process to prepare higher ethylene amines or urea derivatives thereof
CN110891943B (zh) * 2017-07-10 2023-09-22 诺力昂化学品国际有限公司 制备直链和非直链亚乙基胺的混合物的方法
TW201920114A (zh) 2017-08-11 2019-06-01 荷蘭商安科智諾貝爾化學國際公司 製造伸乙基胺化合物之環狀脲加成物的方法
US11919866B2 (en) * 2017-08-11 2024-03-05 Nouryon Chemicals International B.V. Process for preparing cyclic alkylene ureas
US11247963B2 (en) * 2017-08-11 2022-02-15 Nouryon Chemicals International B.V. Process for converting cyclic alkylene ureas into their corresponding alkylene amines
CN110997640B (zh) * 2017-08-11 2023-07-28 诺力昂化学品国际有限公司 将亚乙基胺化合物的环状单脲转化为亚乙基胺化合物的方法
JP7295965B2 (ja) * 2019-02-13 2023-06-21 ヌーリオン ケミカルズ インターナショナル ベスローテン フェノーツハップ エチレンアミン化合物を製造するための方法
JP2025503342A (ja) 2022-01-14 2025-02-03 ビーエーエスエフ ソシエタス・ヨーロピア アルカノールアミンの製造又は変換方法

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2812333A (en) 1954-09-27 1957-11-05 Union Carbide Corp Process for the preparation of 1-(2-hydroxyethyl) imidazolidine-2
CH478180A (de) 1966-11-07 1969-09-15 Francis Dr Pascoe Peter Verfahren zur Herstellung von Polyäthylenaminen
GB1510538A (en) 1974-06-22 1978-05-10 Bayer Ag Colourless triethylene tetramine and tetraethylene pentamine
US4123462A (en) 1976-01-07 1978-10-31 Union Carbide Corporation Amination process using nickel-rhenium catalysts
US4503250A (en) * 1981-09-30 1985-03-05 Union Carbide Corporation Preparation of polyalkylene polyamines
CA1202328A (en) 1981-09-30 1986-03-25 William B. Herdle Preparation of polyalkylene polyamines
US4387249A (en) 1981-12-18 1983-06-07 The Dow Chemical Company Process for the manufacture of diethylenetriamine
IT1159074B (it) 1982-06-24 1987-02-25 Stoppani Luigi Spa Composto di addizione fra menadione e tiamina a reciproca stabilizzazione
NL8204546A (nl) 1982-11-23 1984-06-18 Akzo Nv Werkwijze voor het winnen van ethyleenamines uit waterige oplossing.
JPS59161338A (ja) 1983-03-04 1984-09-12 Toyo Soda Mfg Co Ltd エチレンアミン類炭酸塩水溶液からエチレンアミン類を得る方法
US4684729A (en) * 1983-07-15 1987-08-04 The Dow Chemical Company Polyethylene polypiperazine compositions
JPS60120842A (ja) 1983-12-03 1985-06-28 Toyo Soda Mfg Co Ltd エチレンアミン類炭酸塩からエチレンアミン類を得る方法
JPS60126248A (ja) 1983-12-09 1985-07-05 Toyo Soda Mfg Co Ltd エチレンアミン類炭酸塩水溶液の脱炭酸方法
EP0222934A1 (en) 1985-09-11 1987-05-27 The Dow Chemical Company Process for preparation of polyalkylenepolyamines
DE3744120A1 (de) 1987-12-24 1989-07-06 Basf Ag Verfahren zur herstellung von 1,3-dialkyl-2-imidazolidinonen
US5112984A (en) 1990-09-20 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Processes for the preparation of cyclic nitrogen-containing compounds
US5262534A (en) 1990-09-20 1993-11-16 Union Carbide Chemicals & Plastics Technology Corporation Process for the preparation of nonaromatic cyclic nitrogen-containing compounds
US5364971A (en) 1993-08-25 1994-11-15 Texaco Chemical Inc. Decolorization of polyethylene polyamines using ruthenium
US5491263A (en) * 1993-12-21 1996-02-13 The Dow Chemical Company Aminoethylation process for production of substituted ethylene diamines
JPH1045682A (ja) 1996-08-05 1998-02-17 Tosoh Corp 高品位ポリエチレンポリアミン類の製造方法
DE10335991A1 (de) 2003-08-01 2005-02-24 Basf Ag Verfahren zur Herstellung von Ethylenaminen
EP2129651B1 (de) 2007-03-01 2013-04-10 Basf Se Neues verfahren zur herstellung von teta über eddn
JP5377335B2 (ja) 2007-03-01 2013-12-25 ビーエーエスエフ ソシエタス・ヨーロピア テトラエチレンペンタアミンの製造方法
CN102171178B (zh) 2008-10-06 2015-07-29 联合碳化化学品及塑料技术公司 乙二胺和其它乙撑胺的连续氨基转移
WO2010042159A1 (en) * 2008-10-06 2010-04-15 Union Carbide Chemicals & Plastics Technology Llc Methods of making cyclic, n-amino functional triamines
ES2561362T3 (es) 2008-10-06 2016-02-25 Union Carbide Chemicals & Plastics Technology Llc Método de fabricación de etilenaminas
US9321951B2 (en) 2009-12-21 2016-04-26 Schlumberger Technology Corporation Hydrogen bonding material for oilfield application
FR2955105B1 (fr) 2010-01-11 2012-04-20 Arkema France Procede de preparation d'aminoethyl imidazolidone ou de son thiocarbonyle
WO2013110092A1 (en) 2012-01-20 2013-07-25 Board Of Regents, The University Of Texas System Blends of amines with piperazine for co2 capture
RU2728827C2 (ru) 2016-01-05 2020-07-31 Цзянсу Хэнжуй Медицин Ко., Лтд. Кристаллическая форма ингибитора тирозинкиназы брутона и способ её получения
BR112018014270B1 (pt) 2016-02-12 2022-10-11 Akzo Nobel Chemicals International B.V. Processo de preparação de etilenoaminas
MX390660B (es) 2016-02-12 2025-03-21 Akzo Nobel Chemicals Int Bv Proceso para preparar etilenaminas superiores y derivados de etilenamina.

Also Published As

Publication number Publication date
BR112018014272B1 (pt) 2021-12-28
US20190031597A1 (en) 2019-01-31
MX2018009317A (es) 2018-11-09
EP3414222A1 (en) 2018-12-19
WO2017137532A1 (en) 2017-08-17
US10428011B2 (en) 2019-10-01
KR102067452B1 (ko) 2020-01-17
CN108602752A (zh) 2018-09-28
JP6671489B2 (ja) 2020-03-25
CN108602752B (zh) 2021-07-02
EP3414222B1 (en) 2021-09-01
KR20180099842A (ko) 2018-09-05
JP2019504844A (ja) 2019-02-21
BR112018014272A2 (en) 2018-12-18

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