MX348494B - Proceso continuo para la carbonilacion de etileno. - Google Patents
Proceso continuo para la carbonilacion de etileno.Info
- Publication number
- MX348494B MX348494B MX2014007326A MX2014007326A MX348494B MX 348494 B MX348494 B MX 348494B MX 2014007326 A MX2014007326 A MX 2014007326A MX 2014007326 A MX2014007326 A MX 2014007326A MX 348494 B MX348494 B MX 348494B
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl ester
- ester product
- product
- alkanol
- distillation column
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Descripción de un proceso continuo para la obtención de un producto de éster alquilo. El proceso comprende los pasos de carbonilación de etileno con monóxido de carbono en presencia de un correactivo alcanol C1-6 para formar el producto de éster alquilo. La carbonilación tiene lugar en presencia de un sistema de catalizadores que comprende; a. un ligando bidentato, b. un metal catalítico seleccionado de un metal de grupo 8, 9 ó 10 o un compuesto del mismo y c. un ácido sulfónico capaz de formar un éster alquilo ácido con el alcanol C1-6. El proceso incluye el paso de separar el producto de éster alquilo de una corriente de producto crudo carbonilado mediante un tratamiento eficaz para evaporar el producto de éster alquilo en una columna de destilación instantánea de una sola etapa y proporcionar una corriente purificada de producto de éster alquilo separada del ligando bidentato y el metal catalítico. La columna de destilación incluye un medio de separación adicional eficaz para la separación adicional del producto.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB201122054A GB201122054D0 (en) | 2011-12-21 | 2011-12-21 | A continuous process for the carbonylation of ethylene |
| PCT/GB2012/053204 WO2013093472A1 (en) | 2011-12-21 | 2012-12-20 | A continuous process for the carbonylation of ethylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014007326A MX2014007326A (es) | 2014-09-22 |
| MX348494B true MX348494B (es) | 2017-06-15 |
Family
ID=45572827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014007326A MX348494B (es) | 2011-12-21 | 2012-12-20 | Proceso continuo para la carbonilacion de etileno. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US9382190B2 (es) |
| EP (1) | EP2794548B1 (es) |
| JP (3) | JP2015502393A (es) |
| KR (1) | KR102105599B1 (es) |
| CN (2) | CN104011007B (es) |
| AU (1) | AU2012356457B2 (es) |
| BR (1) | BR112014015157B1 (es) |
| CA (1) | CA2857572C (es) |
| EA (1) | EA032583B1 (es) |
| ES (1) | ES2742329T3 (es) |
| GB (1) | GB201122054D0 (es) |
| IN (1) | IN2014DN05822A (es) |
| MX (1) | MX348494B (es) |
| MY (1) | MY171403A (es) |
| SG (2) | SG10201700374VA (es) |
| TW (1) | TWI631103B (es) |
| WO (1) | WO2013093472A1 (es) |
| ZA (1) | ZA201404484B (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201122054D0 (en) * | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
| CN112898123B (zh) * | 2019-11-19 | 2022-02-11 | 中国科学院大连化学物理研究所 | 一种制备丙醇的方法 |
| WO2022132048A1 (en) * | 2020-12-15 | 2022-06-23 | Agency For Science, Technology And Research | Phosphorus compounds and methods thereof |
| CN116139939A (zh) * | 2022-12-28 | 2023-05-23 | 浙江新和成股份有限公司 | 催化剂体系和羰基化反应的方法 |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5440901A (en) * | 1977-09-07 | 1979-03-31 | Masabumi Isobe | Flash tank which houses filler |
| US4262138A (en) * | 1979-04-09 | 1981-04-14 | Chem Systems Inc. | Preparation of carboxylic acid esters with BF3 complex catalyst |
| DE3175174D1 (en) | 1981-01-06 | 1986-09-25 | Shell Int Research | Process for the carbonylation of olefins |
| CA1231346A (en) | 1982-09-30 | 1988-01-12 | Eit Drent | Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst |
| JPS62102883A (ja) * | 1985-10-30 | 1987-05-13 | Hitachi Ltd | 廃液濃縮器 |
| GB8531624D0 (en) | 1985-12-23 | 1986-02-05 | Shell Int Research | Carbonylation of ethylenically unsaturated compounds |
| GB8605034D0 (en) | 1986-02-28 | 1986-04-09 | Shell Int Research | Carbonylation of compounds |
| KR880007426A (ko) | 1986-12-24 | 1988-08-27 | 오노 알버어스 | 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법 |
| GB8705699D0 (en) | 1987-03-11 | 1987-04-15 | Shell Int Research | Carbonylation of olefinically unsaturated compounds |
| KR0144567B1 (ko) | 1989-03-03 | 1998-07-15 | 오노 알버어스 | 카르보닐화촉매시스템 |
| CA2034971A1 (en) | 1990-02-05 | 1991-08-06 | Eit Drent | Carbonylation catalyst system |
| FI91135C (fi) | 1990-03-19 | 1994-05-25 | Valmet Paper Machinery Inc | Menetelmä reikien poraamiseksi paperikoneen sylinterin vaippaan ja menetelmässä käytetty laitteisto |
| CA2055628A1 (en) | 1990-12-03 | 1992-06-04 | Eit Drent | Carbonylation process and catalyst composition |
| ES2077337T3 (es) | 1991-01-15 | 1995-11-16 | Shell Int Research | Procedimiento para la carbonilacion de olefinas. |
| EP0495547B1 (en) | 1991-01-15 | 1996-04-24 | Shell Internationale Researchmaatschappij B.V. | Carbonylation of olefins |
| EP0499329B1 (en) | 1991-02-15 | 1994-05-04 | Shell Internationale Researchmaatschappij B.V. | Carbonylation catalyst system |
| JP3489592B2 (ja) * | 1994-02-28 | 2004-01-19 | 三菱瓦斯化学株式会社 | エステル類の製造方法 |
| GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
| JP2922848B2 (ja) * | 1996-06-14 | 1999-07-26 | 株式会社日本触媒 | 芳香族炭酸エステルの製造方法 |
| GB9705699D0 (en) * | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
| US6156934A (en) | 1997-03-26 | 2000-12-05 | Shell Oil Company | Diphosphines |
| MY127358A (en) | 2000-03-14 | 2006-11-30 | Shell Int Research | Process for the carbonylation of ethylenically unsaturated compounds |
| DE10048874A1 (de) | 2000-09-29 | 2002-04-11 | Basf Ag | Katalysatorsystem und Verfahren zur Carbonylierung |
| DE10228293A1 (de) | 2001-07-28 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Dialkylketonen |
| JP2003113138A (ja) * | 2001-10-09 | 2003-04-18 | Mitsubishi Chemicals Corp | （メタ）アクリル酸類の蒸留方法 |
| JP2003267917A (ja) * | 2002-03-15 | 2003-09-25 | Mitsubishi Chemicals Corp | 蒸留塔の運転停止方法 |
| JP4801321B2 (ja) | 2002-02-19 | 2011-10-26 | ルーサイト インターナショナル ユーケー リミテッド | エチレン性不飽和化合物のカルボニル化方法とその触媒 |
| BR0314241B1 (pt) | 2002-09-12 | 2013-04-16 | composto, processos para a preparaÇço do mesmo e para a carbonilaÇço de um composto etilenicamente insaturado, composiÇço, e, uso de um composto ou de uma composiÇço. | |
| WO2004103948A1 (en) | 2003-05-22 | 2004-12-02 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of a conjugated diene |
| GB0403592D0 (en) * | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
| BRPI0507918A (pt) | 2004-02-26 | 2007-07-10 | Shell Int Research | processo para a carbonilação de compostos insaturados, composição de catalisador, e, ligando de difosfina bidentado assimétrico |
| DE602006011899D1 (de) * | 2005-07-18 | 2010-03-11 | Union Engineering As | Verfahren zur rückgewinnung von hochreinem kohlendioxid aus einer stickstoffverbindungen enthaltenden gasförmigen quelle |
| GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
| US20120309613A1 (en) * | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
| GB0921875D0 (en) * | 2009-12-15 | 2010-01-27 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
| GB201122054D0 (en) * | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
-
2011
- 2011-12-21 GB GB201122054A patent/GB201122054D0/en not_active Ceased
-
2012
- 2012-12-20 CN CN201280063887.8A patent/CN104011007B/zh active Active
- 2012-12-20 AU AU2012356457A patent/AU2012356457B2/en not_active Ceased
- 2012-12-20 SG SG10201700374VA patent/SG10201700374VA/en unknown
- 2012-12-20 EP EP12809846.4A patent/EP2794548B1/en active Active
- 2012-12-20 IN IN5822DEN2014 patent/IN2014DN05822A/en unknown
- 2012-12-20 WO PCT/GB2012/053204 patent/WO2013093472A1/en active Application Filing
- 2012-12-20 KR KR1020147020382A patent/KR102105599B1/ko active IP Right Grant
- 2012-12-20 EA EA201491208A patent/EA032583B1/ru not_active IP Right Cessation
- 2012-12-20 BR BR112014015157-1A patent/BR112014015157B1/pt active IP Right Grant
- 2012-12-20 CN CN201710180912.5A patent/CN106928061B/zh active Active
- 2012-12-20 MX MX2014007326A patent/MX348494B/es active IP Right Grant
- 2012-12-20 JP JP2014548192A patent/JP2015502393A/ja active Pending
- 2012-12-20 CA CA2857572A patent/CA2857572C/en active Active
- 2012-12-20 SG SG11201402921RA patent/SG11201402921RA/en unknown
- 2012-12-20 US US14/364,718 patent/US9382190B2/en active Active
- 2012-12-20 ES ES12809846T patent/ES2742329T3/es active Active
- 2012-12-20 MY MYPI2014701673A patent/MY171403A/en unknown
- 2012-12-21 TW TW101149102A patent/TWI631103B/zh active
-
2014
- 2014-06-18 ZA ZA2014/04484A patent/ZA201404484B/en unknown
-
2017
- 2017-07-12 JP JP2017135935A patent/JP6716503B2/ja active Active
-
2019
- 2019-02-28 JP JP2019035068A patent/JP2019089844A/ja not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |