MX2012012910A - Procedimiento para produccion de alcohol integrando corriente de alimentacion de acido acetico que comprende agua a partir de un procedimiento de carbonilacion. - Google Patents

Procedimiento para produccion de alcohol integrando corriente de alimentacion de acido acetico que comprende agua a partir de un procedimiento de carbonilacion.

Info

Publication number
MX2012012910A
MX2012012910A MX2012012910A MX2012012910A MX2012012910A MX 2012012910 A MX2012012910 A MX 2012012910A MX 2012012910 A MX2012012910 A MX 2012012910A MX 2012012910 A MX2012012910 A MX 2012012910A MX 2012012910 A MX2012012910 A MX 2012012910A
Authority
MX
Mexico
Prior art keywords
acetic acid
purified acetic
hydrogenation
feed stream
producing ethanol
Prior art date
Application number
MX2012012910A
Other languages
English (en)
Inventor
Mark O Scates
Ronald David Shaver
R Jay Warner
Victor J Johnston
Josefina T Chapman
Heiko Weiner
Tianshu Pan
Radmila Wollrab
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of MX2012012910A publication Critical patent/MX2012012910A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42Separation; Purification; Stabilisation; Use of additives
    • C07C51/43Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

En una modalidad, la invención está dirigida a un procedimiento para producir etanol, que comprende el paso de proporcionar a partir de una columna de destilación en un procedimiento de carbonilación una corriente de ácido acético purificado que comprende hasta 25% en peso de agua; el procedimiento además comprende el paso de hidrogenar ácido acético de la corriente de ácido acético purificado en presencia de un catalizador y bajo condiciones efectivas para formar un producto de etanol crudo que comprende etanol y agua; el etanol se recupera del producto de etanol crudo.
MX2012012910A 2010-05-07 2011-05-06 Procedimiento para produccion de alcohol integrando corriente de alimentacion de acido acetico que comprende agua a partir de un procedimiento de carbonilacion. MX2012012910A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US33269610P 2010-05-07 2010-05-07
US13/094,580 US8569551B2 (en) 2010-05-07 2011-04-26 Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
PCT/US2011/035551 WO2011140460A2 (en) 2010-05-07 2011-05-06 Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process

Publications (1)

Publication Number Publication Date
MX2012012910A true MX2012012910A (es) 2012-12-17

Family

ID=44904504

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012012910A MX2012012910A (es) 2010-05-07 2011-05-06 Procedimiento para produccion de alcohol integrando corriente de alimentacion de acido acetico que comprende agua a partir de un procedimiento de carbonilacion.

Country Status (10)

Country Link
US (1) US8569551B2 (es)
EP (1) EP2566831A2 (es)
CN (1) CN102933536A (es)
AU (1) AU2011247922A1 (es)
BR (1) BR112012028566A2 (es)
CA (1) CA2796779A1 (es)
MX (1) MX2012012910A (es)
SG (1) SG185086A1 (es)
TW (1) TW201202181A (es)
WO (1) WO2011140460A2 (es)

Families Citing this family (13)

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US8680342B2 (en) 2010-05-07 2014-03-25 Celanese International Corporation Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water
US8846986B2 (en) 2011-04-26 2014-09-30 Celanese International Corporation Water separation from crude alcohol product
US9150474B2 (en) 2010-07-09 2015-10-06 Celanese International Corporation Reduction of acid within column through esterification during the production of alcohols
US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
US8907141B2 (en) 2011-04-26 2014-12-09 Celanese International Corporation Process to recover alcohol with secondary reactors for esterification of acid
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US8686201B2 (en) 2011-11-09 2014-04-01 Celanese International Corporation Integrated acid and alcohol production process having flashing to recover acid production catalyst
US8907142B2 (en) 2011-12-29 2014-12-09 Celanese International Corporation Process for promoting catalyst activity for ethyl acetate conversion
US20130172633A1 (en) * 2011-12-29 2013-07-04 Celanese International Corporation Process For Producing Ethanol From Impure Methanol
CN103113187B (zh) * 2013-02-19 2015-09-30 新地能源工程技术有限公司 由乙酸制乙醇并联产乙酸乙酯的方法
US9409846B2 (en) 2013-03-15 2016-08-09 Celanese International Corporation Process for separating product gas using carbonylation processes
US9850512B2 (en) 2013-03-15 2017-12-26 The Research Foundation For The State University Of New York Hydrolysis of cellulosic fines in primary clarified sludge of paper mills and the addition of a surfactant to increase the yield
US9951363B2 (en) 2014-03-14 2018-04-24 The Research Foundation for the State University of New York College of Environmental Science and Forestry Enzymatic hydrolysis of old corrugated cardboard (OCC) fines from recycled linerboard mill waste rejects

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