MX2019009975A - Proceso para preparar poli (furanodicarboxilato de alquileno). - Google Patents
Proceso para preparar poli (furanodicarboxilato de alquileno).Info
- Publication number
- MX2019009975A MX2019009975A MX2019009975A MX2019009975A MX2019009975A MX 2019009975 A MX2019009975 A MX 2019009975A MX 2019009975 A MX2019009975 A MX 2019009975A MX 2019009975 A MX2019009975 A MX 2019009975A MX 2019009975 A MX2019009975 A MX 2019009975A
- Authority
- MX
- Mexico
- Prior art keywords
- range
- alkylene furandicarboxylate
- diol
- polymer
- disclosed
- Prior art date
Links
- -1 poly(alkylene furandicarboxylate Chemical compound 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 abstract 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 abstract 2
- 150000002009 diols Chemical class 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- DNXDYHALMANNEJ-UHFFFAOYSA-N furan-2,3-dicarboxylic acid Chemical compound OC(=O)C=1C=COC=1C(O)=O DNXDYHALMANNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000006068 polycondensation reaction Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 abstract 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/87—Non-metals or inter-compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
Abstract
En la presente se describe un proceso para preparar un polímero de poli (furanodicarboxilato de alquileno). En una modalidad, el proceso comprende a) poner en contacto una mezcla que comprende un éster dialquílico del ácido furanodicarboxílico, un diol que comprende etilenglicol, 1,3- propanodiol, 1,4-butanodiol, 1,4-ciclohexanodimetanol, o mezclas de estos, y un catalizador metálico a una temperatura comprendida en el intervalo de aproximadamente 140 °C a aproximadamente 220 °C para formar un prepolímero, donde la relación molar del éster dialquïlico del ácido furanodicarboxílico respecto al diol está comprendida en el intervalo de 1:1.3 a 1:2.2; b) llevar a cabo una policondensación calentando el prepolímero a presión reducida hasta una temperatura comprendida en el intervalo de aproximadamente 220 °C a aproximadamente 260 °C para formar el polímero de poli (furanodicarboxilato de alquileno); donde la velocidad de policondensación en el paso c) es mayor cuando el compuesto de tipo antraquinona está presente que cuando no lo está; y c) añadir al menos un compuesto de tipo antraquinona tal como se describe en la presente; y.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762462950P | 2017-02-24 | 2017-02-24 | |
PCT/US2018/019340 WO2018156838A1 (en) | 2017-02-24 | 2018-02-23 | Process for preparing poly(alkylene furandicarboxylate) |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2019009975A true MX2019009975A (es) | 2020-01-27 |
Family
ID=61599623
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2019009975A MX2019009975A (es) | 2017-02-24 | 2018-02-23 | Proceso para preparar poli (furanodicarboxilato de alquileno). |
Country Status (10)
Country | Link |
---|---|
US (4) | US20200002471A1 (es) |
EP (2) | EP4276130A1 (es) |
JP (2) | JP7165147B2 (es) |
KR (2) | KR20230169466A (es) |
CN (2) | CN116333280A (es) |
AU (2) | AU2018225190B2 (es) |
CA (1) | CA3054369A1 (es) |
ES (1) | ES2962479T3 (es) |
MX (1) | MX2019009975A (es) |
WO (1) | WO2018156838A1 (es) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2023540343A (ja) * | 2020-09-17 | 2023-09-22 | コーロン インダストリーズ インク | ポリエステル重合体 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG46692A1 (en) * | 1992-03-30 | 1998-02-20 | Telstra Corp Ltd | A cryptographic communications method and system |
TW354305B (en) * | 1994-12-22 | 1999-03-11 | Eastman Chem Co | Production of particular polyesters using a novel catalyst system |
WO1997018253A1 (en) | 1995-11-13 | 1997-05-22 | Eastman Chemical Company | Thermally stable polyesters formed utilizing antimony compounds as catalysts |
JP4529485B2 (ja) | 2003-03-07 | 2010-08-25 | 三菱化学株式会社 | ポリエステル重合触媒、その製造方法、及びそれを用いたポリエステルの製造方法 |
JP2008239771A (ja) | 2007-03-27 | 2008-10-09 | Teijin Fibers Ltd | ポリエチレンテレフタレートの連続式製造方法 |
JP5446121B2 (ja) | 2007-04-24 | 2014-03-19 | 三菱化学株式会社 | フラン構造を含むポリエステル |
NL2002382C2 (en) * | 2008-12-30 | 2010-07-01 | Furanix Technologies Bv | A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and such (co)polymers. |
US20110124839A1 (en) | 2009-11-25 | 2011-05-26 | Canon Kabushiki Kaisha | Flame-retardant polyester copolymer, and production process and molded article thereof |
MX351452B (es) * | 2011-10-24 | 2017-10-16 | Furanix Technologies Bv | Proceso para preparar un producto polimerico que tiene una porcion 2,5-furandicarboxilato dentro de la estructura polimerica que se va a usar en aplicaciones de botellas, peliculas o fibras. |
JP6188144B2 (ja) * | 2013-09-25 | 2017-08-30 | 花王株式会社 | トナー用非晶質ポリエステル系結着樹脂の製造方法 |
KR102205169B1 (ko) * | 2013-12-20 | 2021-01-20 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 폴리(트라이메틸렌-2,5-푸란다이카르복실레이트)(ptf)의 핵형성 결정화 및 그로부터 제조된 물품 |
MX2018003134A (es) * | 2015-09-14 | 2018-06-06 | Synvina C V | Procedimiento para la preparacion de un poliester. |
CN110072908A (zh) * | 2016-10-14 | 2019-07-30 | 纳幕尔杜邦公司 | 用于制备聚(呋喃二甲酸三亚甲酯)的方法 |
-
2018
- 2018-02-23 US US16/485,873 patent/US20200002471A1/en not_active Abandoned
- 2018-02-23 CA CA3054369A patent/CA3054369A1/en active Pending
- 2018-02-23 ES ES18709875T patent/ES2962479T3/es active Active
- 2018-02-23 WO PCT/US2018/019340 patent/WO2018156838A1/en unknown
- 2018-02-23 EP EP23183666.9A patent/EP4276130A1/en not_active Withdrawn
- 2018-02-23 CN CN202310030262.1A patent/CN116333280A/zh active Pending
- 2018-02-23 CN CN201880025375.XA patent/CN110520460B/zh active Active
- 2018-02-23 KR KR1020237041769A patent/KR20230169466A/ko not_active Application Discontinuation
- 2018-02-23 EP EP18709875.1A patent/EP3585828B1/en active Active
- 2018-02-23 JP JP2019567500A patent/JP7165147B2/ja active Active
- 2018-02-23 AU AU2018225190A patent/AU2018225190B2/en active Active
- 2018-02-23 MX MX2019009975A patent/MX2019009975A/es unknown
- 2018-02-23 KR KR1020197027759A patent/KR102611149B1/ko active IP Right Grant
-
2021
- 2021-06-14 US US17/347,115 patent/US20210301080A1/en not_active Abandoned
-
2022
- 2022-10-21 JP JP2022168773A patent/JP2023002705A/ja active Pending
-
2023
- 2023-05-01 US US18/141,613 patent/US20230265239A1/en not_active Abandoned
-
2024
- 2024-03-11 US US18/601,303 patent/US20240218118A1/en active Pending
- 2024-04-04 AU AU2024202161A patent/AU2024202161A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
KR20190117022A (ko) | 2019-10-15 |
US20210301080A1 (en) | 2021-09-30 |
JP7165147B2 (ja) | 2022-11-02 |
JP2023002705A (ja) | 2023-01-10 |
AU2018225190B2 (en) | 2024-01-04 |
KR102611149B1 (ko) | 2023-12-08 |
AU2024202161A1 (en) | 2024-05-02 |
US20240218118A1 (en) | 2024-07-04 |
AU2018225190A1 (en) | 2019-09-05 |
EP3585828B1 (en) | 2023-08-30 |
KR20230169466A (ko) | 2023-12-15 |
EP4276130A1 (en) | 2023-11-15 |
US20230265239A1 (en) | 2023-08-24 |
ES2962479T3 (es) | 2024-03-19 |
CN110520460B (zh) | 2022-12-30 |
CA3054369A1 (en) | 2018-08-30 |
CN110520460A (zh) | 2019-11-29 |
US20200002471A1 (en) | 2020-01-02 |
BR112019017611A2 (pt) | 2020-03-24 |
EP3585828A1 (en) | 2020-01-01 |
WO2018156838A1 (en) | 2018-08-30 |
CN116333280A (zh) | 2023-06-27 |
JP2020508389A (ja) | 2020-03-19 |
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