MX2019009974A - Proceso para preparar poli (furanodicarboxilato de trimetileno) usando un catalizador de zinc. - Google Patents

Proceso para preparar poli (furanodicarboxilato de trimetileno) usando un catalizador de zinc.

Info

Publication number
MX2019009974A
MX2019009974A MX2019009974A MX2019009974A MX2019009974A MX 2019009974 A MX2019009974 A MX 2019009974A MX 2019009974 A MX2019009974 A MX 2019009974A MX 2019009974 A MX2019009974 A MX 2019009974A MX 2019009974 A MX2019009974 A MX 2019009974A
Authority
MX
Mexico
Prior art keywords
range
zinc catalyst
preparing poly
trimethylene furandicarboxylate
propanediol
Prior art date
Application number
MX2019009974A
Other languages
English (en)
Inventor
Babu Sunkara Hari
Hari Poladi Raja
Original Assignee
Dupont Ind Biosciences Usa Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dupont Ind Biosciences Usa Llc filed Critical Dupont Ind Biosciences Usa Llc
Publication of MX2019009974A publication Critical patent/MX2019009974A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/826—Metals not provided for in groups C08G63/83 - C08G63/86
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/88—Post-polymerisation treatment
    • C08G63/90—Purification; Drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C08K5/08—Quinones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

En la presente se describe un proceso que comprende los pasos de: a) poner en contacto una mezcla que comprende éster dialquílico del ácido furanodicarboxílico, 1,3-propanodiol, un compuesto de zinc y opcionalmente un poli(éter alquilénico)diol, a una temperatura comprendida en el intervalo de aproximadamente 120 °C a aproximadamente 220 °C para formar un prepolímero, donde la relación molar del éster dialquílico del ácido furanodicarboxílico respecto al 1,3-propanodiol está comprendida en el intervalo de 1:1.3 a 1:2.2; y b) calentar el prepolímero a presión reducida hasta una temperatura comprendida en el intervalo de aproximadamente 220 °C a aproximadamente 260 °C para formar el polímero. La mezcla del paso a) puede comprender además un compuesto de tipo antraquinona.
MX2019009974A 2017-02-24 2018-02-23 Proceso para preparar poli (furanodicarboxilato de trimetileno) usando un catalizador de zinc. MX2019009974A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762462948P 2017-02-24 2017-02-24
PCT/US2018/019363 WO2018156859A1 (en) 2017-02-24 2018-02-23 Process for preparing poly(trimethylene furandicarboxylate) using zinc catalyst

Publications (1)

Publication Number Publication Date
MX2019009974A true MX2019009974A (es) 2020-01-27

Family

ID=61563558

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019009974A MX2019009974A (es) 2017-02-24 2018-02-23 Proceso para preparar poli (furanodicarboxilato de trimetileno) usando un catalizador de zinc.

Country Status (10)

Country Link
US (3) US20200017634A1 (es)
EP (2) EP3878886A1 (es)
JP (2) JP7204687B2 (es)
KR (2) KR20190119112A (es)
CN (2) CN116041675A (es)
AU (2) AU2018225205A1 (es)
CA (1) CA3054371A1 (es)
ES (1) ES2880324T3 (es)
MX (1) MX2019009974A (es)
WO (1) WO2018156859A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111116880B (zh) * 2020-01-17 2021-11-30 沈阳化工大学 一种基于呋喃环的全生物基热塑性聚酯弹性体及其制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9611476A (pt) * 1995-11-13 2003-02-11 Eastman Chem Co Poliéster termicamente estável e processo para produzir uma resina de poliéster termicamente estável
CN1552754A (zh) * 2003-06-04 2004-12-08 中国石化集团天津石油化工公司 一种缩短聚酯生产中缩聚反应时间的方法
ES2298645T3 (es) * 2004-05-05 2008-05-16 Saudi Basic Industries Corporation Proceso para la produccion de copoliester de tereftalato de polietileno.
JP2008239771A (ja) * 2007-03-27 2008-10-09 Teijin Fibers Ltd ポリエチレンテレフタレートの連続式製造方法
JP5446121B2 (ja) * 2007-04-24 2014-03-19 三菱化学株式会社 フラン構造を含むポリエステル
CN101899145B (zh) * 2010-07-28 2012-07-11 江南大学 一种2,5-呋喃二甲酸基聚酯的制备方法
EP2771382B1 (en) * 2011-10-24 2018-01-03 Synvina C.V. A process for preparing a polymer product having a 2,5-furandicarboxylate moiety within the polymer backbone to be used in bottle, film or fibre applications
WO2013149157A1 (en) * 2012-03-30 2013-10-03 E. I. Du Pont De Nemours And Company Polyesters and fibers made therefrom
KR101969004B1 (ko) * 2012-06-05 2019-04-15 에스케이케미칼 주식회사 폴리에스테르 수지 및 이의 제조 방법
CA2932931C (en) * 2013-12-20 2023-01-24 Gordon Mark Cohen Nucleated crystallization of poly(trimethylene-2,5-furandicarboxylate) (ptf) and articles made therefrom
WO2015142181A1 (en) * 2014-03-21 2015-09-24 Furanix Technologies B.V. Polyesters comprising 2,5-furandicarboxylate and saturated diol units having a high glass transition temperature
CN106432701A (zh) * 2016-09-14 2017-02-22 中国科学院宁波材料技术与工程研究所 一种生物基不饱和聚酯及其制备方法和应用
US20190309125A1 (en) * 2016-10-14 2019-10-10 E I Du Pont De Nemours And Company Process for preparing poly (trimethylene furandicarboxylate)

Also Published As

Publication number Publication date
CN116041675A (zh) 2023-05-02
EP3585827B1 (en) 2021-04-21
EP3585827A1 (en) 2020-01-01
US20210269589A1 (en) 2021-09-02
JP2020508390A (ja) 2020-03-19
JP2023036861A (ja) 2023-03-14
WO2018156859A1 (en) 2018-08-30
CN110520459B (zh) 2022-12-02
BR112019017619A2 (pt) 2020-03-24
KR20190119112A (ko) 2019-10-21
CN110520459A (zh) 2019-11-29
ES2880324T3 (es) 2021-11-24
AU2018225205A1 (en) 2019-09-05
US20200017634A1 (en) 2020-01-16
AU2023274099A1 (en) 2023-12-14
JP7204687B2 (ja) 2023-01-16
CA3054371A1 (en) 2018-08-30
KR20230067711A (ko) 2023-05-16
EP3878886A1 (en) 2021-09-15
US20230257520A1 (en) 2023-08-17

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