MX166784B - Hidroformilacion usando grupos coordinadores de fosfina de baja volatilidad - Google Patents
Hidroformilacion usando grupos coordinadores de fosfina de baja volatilidadInfo
- Publication number
- MX166784B MX166784B MX009383A MX938387A MX166784B MX 166784 B MX166784 B MX 166784B MX 009383 A MX009383 A MX 009383A MX 938387 A MX938387 A MX 938387A MX 166784 B MX166784 B MX 166784B
- Authority
- MX
- Mexico
- Prior art keywords
- carbon monoxide
- square centimeter
- olefinically unsaturated
- hydrogen
- kilograms per
- Prior art date
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 title 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 3
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 3
- 238000007037 hydroformylation reaction Methods 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- 150000002431 hydrogen Chemical class 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- 239000012429 reaction media Substances 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
- C07C47/55—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/932,002 US4731486A (en) | 1986-11-18 | 1986-11-18 | Hydroformylation using low volatile phosphine ligands |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX166784B true MX166784B (es) | 1993-02-04 |
Family
ID=25461633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX009383A MX166784B (es) | 1986-11-18 | 1987-11-17 | Hidroformilacion usando grupos coordinadores de fosfina de baja volatilidad |
Country Status (28)
| Country | Link |
|---|---|
| US (1) | US4731486A (2) |
| EP (1) | EP0268268B1 (2) |
| JP (1) | JPH0667868B2 (2) |
| KR (1) | KR920003556B1 (2) |
| CN (1) | CN1017145B (2) |
| AR (1) | AR248390A1 (2) |
| AT (1) | ATE77075T1 (2) |
| AU (1) | AU611867B2 (2) |
| BE (1) | BE1000619A5 (2) |
| BR (1) | BR8706223A (2) |
| CA (1) | CA1307296C (2) |
| DE (2) | DE3739064A1 (2) |
| DK (1) | DK605887A (2) |
| ES (3) | ES2009221A6 (2) |
| FI (1) | FI90858C (2) |
| FR (1) | FR2606771B1 (2) |
| GB (1) | GB2197867B (2) |
| HU (1) | HU202177B (2) |
| IN (1) | IN170369B (2) |
| IT (1) | IT1223147B (2) |
| MX (1) | MX166784B (2) |
| NL (1) | NL8702752A (2) |
| NO (1) | NO166440C (2) |
| PL (1) | PL153062B1 (2) |
| RU (1) | RU2002728C1 (2) |
| SE (1) | SE8704533L (2) |
| YU (1) | YU45074B (2) |
| ZA (1) | ZA878638B (2) |
Families Citing this family (85)
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| YU140889A (en) * | 1988-07-14 | 1991-02-28 | Union Carbide Chem Plastic | Process for producing alcohol and aldehide |
| PT91162B (pt) * | 1988-07-14 | 1995-03-01 | Union Carbide Chem Plastic | Processo para a separacao do aldeido produzido, do catalisador usado na reaccao de hidroformilacao |
| US5180854A (en) * | 1988-07-14 | 1993-01-19 | Union Carbide Chemicals & Plastics Technology Corporation | Process for catalyst aldehyde product separation |
| US5059710A (en) * | 1988-08-05 | 1991-10-22 | Union Carbide Chemicals And Plastics Technology Corporation | Ionic phosphites and their use in homogeneous transition metal catalyzed processes |
| US5113022A (en) * | 1988-08-05 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Ionic phosphites used in homogeneous transition metal catalyzed processes |
| US4965404A (en) * | 1989-03-09 | 1990-10-23 | Kuraray Company, Ltd. | Process for the preparation of lithium diphenylphosphinobenzene-m-monosulfonate |
| DE3942954A1 (de) * | 1989-12-23 | 1991-06-27 | Hoechst Ag | Verfahren zur herstellung von aldehyden |
| JPH06503808A (ja) * | 1990-08-31 | 1994-04-28 | ザ ガヴァナーズ オヴ ザ ユニヴァーシティ オヴ アルバータ | 新規の遷移金属触媒先駆物質を用いるメタノールのカルボニル化 |
| US5087763A (en) * | 1990-11-09 | 1992-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process |
| US5288818A (en) * | 1991-08-20 | 1994-02-22 | Exxon Chemical Patents Inc. | Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction |
| US5215667A (en) * | 1991-08-20 | 1993-06-01 | Exxon Chemical Patents Inc. | Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction |
| US5196596A (en) * | 1991-12-26 | 1993-03-23 | Union Carbide Chemicals & Plastics Technology Corporation | Higher aldehyde separation process |
| US5300617A (en) * | 1993-01-21 | 1994-04-05 | Exxon Chemical Patents Inc. | Potassium para-diphenyl phosphino benzene sulfonate ligand |
| DE4400837A1 (de) * | 1994-01-14 | 1995-07-20 | Basf Ag | Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol |
| US6143211A (en) * | 1995-07-21 | 2000-11-07 | Brown University Foundation | Process for preparing microparticles through phase inversion phenomena |
| DE19532393A1 (de) * | 1995-09-02 | 1997-03-06 | Hoechst Ag | Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen |
| CA2204133C (en) * | 1995-09-26 | 2003-08-12 | Toshihiro Omatsu | Hydroformylation process |
| DE19700804C1 (de) * | 1997-01-13 | 1998-08-06 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 6 bis 16 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthaltenden wäßrigen Phase |
| DE19700805C1 (de) * | 1997-01-13 | 1998-08-06 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 3 bis 5 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthhaltenden wäßrigen Phase |
| DE19742305A1 (de) * | 1997-09-25 | 1999-04-01 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung in Gegenwart von Kronenether |
| DE10034360A1 (de) * | 2000-07-14 | 2002-01-24 | Oxeno Olefinchemie Gmbh | Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen |
| FI20002807A0 (fi) * | 2000-09-05 | 2000-12-20 | Neste Chemicals Oy | Menetelmä alkeenien hydroformyloimiseksi |
| KR20040007650A (ko) * | 2001-06-07 | 2004-01-24 | 가부시키가이샤 구라레 | 파라-디아릴포스피노벤젠설폰산 리튬염, 이의 제조방법 및이의 용도 |
| EP1423175B1 (en) * | 2001-08-08 | 2013-10-02 | Brown University Research Foundation | Methods for micronization of hydrophobic drugs |
| AU2002360549A1 (en) * | 2001-12-10 | 2003-06-23 | Spherics, Inc. | Methods and products useful in the formation and isolation of microparticles |
| EP1620387B1 (en) * | 2003-04-25 | 2010-05-19 | Dow Global Technologies Inc. | Aldehyde and alcohol compositions derived from seed oils |
| KR100547587B1 (ko) * | 2004-06-12 | 2006-01-31 | 주식회사 엘지화학 | 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법 |
| MX2007004991A (es) * | 2004-10-25 | 2007-06-14 | Dow Global Technologies Inc | Poliuretanos hechos de acidos grasos conteniendo hidroxi-metilo o esteres de alquilo de tales acidos grasos. |
| SG159502A1 (en) * | 2004-10-25 | 2010-03-30 | Dow Global Technologies Inc | Prepolymers made from hydroxmethyl-containing polyester polyols derived from fatty acids |
| CN101048439B (zh) * | 2004-10-25 | 2011-04-13 | 陶氏环球技术公司 | 由植物油基含羟基的材料制成的聚合物多元醇和聚合物分散体 |
| US7053253B1 (en) * | 2005-05-02 | 2006-05-30 | 3M Innovative Properties Company | Process for purifying hexafluoropropene dimers |
| CA2622112C (en) * | 2005-09-15 | 2013-12-10 | Dow Global Technologies Inc. | Process for the monosulfonation of aromatic phosphines, and zwitterionic product derived therefrom |
| CN100526279C (zh) * | 2006-04-11 | 2009-08-12 | 中国科学院兰州化学物理研究所 | 连续制备正戊醛的工艺过程 |
| CA2652016C (en) * | 2006-05-15 | 2015-02-03 | Dow Global Technologies Inc. | Hydroformylation process and product separation with improved recovery of rhodium |
| CN101573392B (zh) * | 2006-09-21 | 2012-06-20 | 陶氏环球技术有限责任公司 | 具有高气流量的粘弹性泡沫 |
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| WO2008124265A2 (en) * | 2007-04-09 | 2008-10-16 | Dow Global Technologies, Inc. | Capped polyester polyol lubricant composition |
| KR20100017381A (ko) | 2007-04-27 | 2010-02-16 | 다우 글로벌 테크놀로지스 인크. | 재생가능한 오일로부터의 저 휘발성 물질 코팅, 실란트 및 결합제 |
| JP5628024B2 (ja) * | 2007-05-15 | 2014-11-19 | ダウ グローバル テクノロジーズ エルエルシー | 高弾性発泡体 |
| WO2008156993A2 (en) * | 2007-06-13 | 2008-12-24 | Dow Global Technologies Inc. | Extraction process for aldehyde product separation and catalyst recovery |
| WO2009009571A1 (en) * | 2007-07-12 | 2009-01-15 | Dow Global Technologies Inc. | Prepolymers and polymers for elastomers |
| BRPI0812635A2 (pt) * | 2007-07-12 | 2015-02-24 | Dow Global Technologies Inc | "poliol de mhms, prepolímero de alcoxissilano de mhms, composição de mhms, polímero de mhms sililado, composição de mhms sililado, processo para preparar um poliol de mhms, processo para preparar pelo menos um prepolímero de alcoxissilanode mhms, processo para preparar pelo menos um polímero de mhms sililado e artigo" |
| EP2176063A1 (en) * | 2007-08-01 | 2010-04-21 | Dow Global Technologies Inc. | Heat bonding polyurethane foams |
| BRPI0905699A2 (pt) * | 2008-01-15 | 2015-07-14 | Dow Global Technologies Inc | Composição, catalisador complexo ou composição de precursor de catalisador complexo, solução de catalisador complexo ou solução de percursor de catalisador complexo e processo de hidroformilação |
| EP2242760B1 (en) * | 2008-01-15 | 2014-03-05 | Dow Global Technologies LLC | Sulfonated organophosphine compounds and use in hydroformylation processes |
| BRPI0905685A2 (pt) * | 2008-01-15 | 2015-07-07 | Dow Global Technologies Inc | Composição, catalisador complexo ou composição precursora de catalisador, complexo, solução de catalisador complexo ou solução de precursor de catalisador complexo e processo de hidroformilação |
| WO2009137675A2 (en) * | 2008-05-09 | 2009-11-12 | Dow Global Technologies Inc. | Natural oil based polyol blends |
| WO2011011587A2 (en) | 2009-07-22 | 2011-01-27 | Dow Global Technologies Inc. | Natural oil based polyurethane foams |
| KR20120089766A (ko) | 2009-12-03 | 2012-08-13 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올의 탈색 |
| WO2011071660A1 (en) | 2009-12-08 | 2011-06-16 | Dow Global Technologies Llc | Process to prepare open cell foams made with natural oil based polyols and poly(propylene oxide) polyols |
| US20120253001A1 (en) | 2009-12-21 | 2012-10-04 | Bindushree Radhakrishnan | Polyurethane-Based Sealant for Insulated Glass Units |
| KR101918054B1 (ko) * | 2009-12-22 | 2018-11-13 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 합성 기체 분압의 조절에 의한 혼합된 리간드 하이드로폼일화 공정에서의 노말:아이소 알데하이드 비의 조절 방법 |
| EP2545094A1 (en) | 2010-03-12 | 2013-01-16 | Dow Global Technologies LLC | Elastomer binding materials made with natural oil based polyols |
| EP2545091A1 (en) | 2010-03-12 | 2013-01-16 | Dow Global Technologies LLC | Gels and soft polyurethane elastomers made with natural oil based polyols |
| WO2011123241A1 (en) | 2010-03-31 | 2011-10-06 | Dow Global Technologies Llc | Polyurethane/polyurea spray elastomers |
| CN103097424B (zh) | 2010-04-14 | 2015-01-14 | 陶氏环球技术有限责任公司 | 聚碳酸酯多元醇以及从其制得的聚氨酯 |
| BR112012032975A2 (pt) | 2010-06-22 | 2019-09-24 | Dow Global Technologies Llc | método para produzir um polímero de silila, polímero de silila e artigo |
| WO2012003187A1 (en) | 2010-06-30 | 2012-01-05 | Dow Global Technologies Llc | Silyl-terminated polymers |
| ITMI20101380A1 (it) | 2010-07-27 | 2012-01-28 | Dow Global Technologies Inc | Pannello composito poliuretanico a basso impatto ambientale |
| CN103314029B (zh) | 2010-11-11 | 2015-05-13 | 陶氏环球技术有限责任公司 | 聚氨酯基绝缘玻璃密封剂 |
| CN103562251A (zh) | 2011-03-31 | 2014-02-05 | 陶氏环球技术有限责任公司 | 用于聚氨酯应用的疏水性聚酯聚碳酸酯多元醇 |
| CN102826974B (zh) * | 2011-06-17 | 2015-11-25 | 中国石油化工股份有限公司 | 一种丙烯氢甲酰化反应制备丁醛的方法 |
| WO2013003051A2 (en) | 2011-06-30 | 2013-01-03 | Dow Global Technologies Llc | Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications |
| US9284387B2 (en) | 2012-09-24 | 2016-03-15 | Exxonmobil Chemical Patents Inc. | Hydroamination of aldehyde-containing macromonomers |
| US9359456B2 (en) | 2012-09-24 | 2016-06-07 | Exxonmobil Chemical Patents Inc. | Catalytic hydroformylation of vinyl terminated polyolefins |
| BR112015004928B1 (pt) | 2012-09-26 | 2021-03-02 | Dow Global Technologies Llc | vedante a base de poliuretano e unidade isolada |
| CN104045532B (zh) | 2013-03-15 | 2018-05-25 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| BR112016008906B1 (pt) | 2013-10-28 | 2021-12-07 | Rohm And Haas Company | Processo para preparar metil metacrilato |
| RU2561171C1 (ru) * | 2014-09-12 | 2015-08-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Способ непрерывного двухступенчатого гидроформилирования олефинов с3, с4 и технологическая установка для его осуществления |
| WO2017160956A1 (en) | 2016-03-18 | 2017-09-21 | Dow Technology Investments Llc | Hydroformylation process |
| MX2019013569A (es) | 2017-05-25 | 2019-12-18 | Rohm & Haas | Proceso para preparar metacroleina. |
| CA3064433A1 (en) | 2017-05-25 | 2018-11-29 | Rohm And Haas Company | Process for preparing methacrolein |
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| US4329511A (en) * | 1979-06-18 | 1982-05-11 | Celanese Corporation | Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters |
| US4283562A (en) * | 1979-10-26 | 1981-08-11 | Union Carbide Corporation | Hydroformylation process using stable rhodium catalyst |
| FR2478078A2 (fr) * | 1980-03-12 | 1981-09-18 | Rhone Poulenc Ind | Procede d'hydroformylation des olefines |
| US4302547A (en) * | 1980-06-30 | 1981-11-24 | Union Carbide Corporation | Novel solvents for the catalytic process for producing polyhydric alcohols |
| GB2085874B (en) * | 1980-09-04 | 1984-08-08 | Johnson Matthey Plc | Hydroformylation of olefins |
| DE3046355A1 (de) * | 1980-12-09 | 1982-07-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zur hydroformylierung von olefinisch ungesaettigten verbindungen |
| US4400548A (en) * | 1981-08-17 | 1983-08-23 | Union Carbide Corporation | Hydroformylation process using bisphosphine monooxide ligands |
| JPS58157739A (ja) * | 1982-03-12 | 1983-09-19 | Kuraray Co Ltd | 1,9−ノナンジア−ルの製造方法 |
| US4453022A (en) * | 1982-04-21 | 1984-06-05 | Union Carbide Corporation | Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts |
| FR2532318B1 (fr) * | 1982-08-31 | 1985-06-14 | Rhone Poulenc Chim Base | Procede de preparation de triarylphosphines sulfonees |
| DE3234701A1 (de) * | 1982-09-18 | 1984-04-05 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3235029A1 (de) * | 1982-09-22 | 1984-03-22 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur rueckgewinnung von wasserloeslichen, rhodium enthaltenden hydroformylierungskatalysatoren |
| DE3235030A1 (de) * | 1982-09-22 | 1984-03-22 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von sulfonierten arylphosphinen |
| US4480138A (en) * | 1982-10-12 | 1984-10-30 | Celanese Corporation | Hydroformylation process |
| DE3245883A1 (de) * | 1982-12-11 | 1984-06-14 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur hydroformylierung von olefinen |
| FR2550202B1 (fr) * | 1983-08-03 | 1986-03-21 | Rhone Poulenc Rech | Procede de preparation de tri(m-sulfophenyl) phosphine |
| DE3341035A1 (de) * | 1983-11-12 | 1985-05-23 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3347406A1 (de) * | 1983-12-29 | 1985-07-11 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese |
| DE3411034A1 (de) * | 1984-03-26 | 1985-09-26 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese |
| DE3412335A1 (de) * | 1984-04-03 | 1985-10-10 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| FR2561650B1 (fr) * | 1984-03-26 | 1987-10-23 | Rhone Poulenc Rech | Perfectionnement au procede de preparation de tri(m-sulfophenyl)phosphine par hydrolyse et dilution controlees du sulfonat |
| DE3413427A1 (de) * | 1984-04-10 | 1985-10-17 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3415968A1 (de) * | 1984-04-28 | 1985-10-31 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3420493A1 (de) * | 1984-06-01 | 1985-12-05 | Ruhrchemie Ag, 4200 Oberhausen | Quartaere ammoniumsalze sulfonierter triarylphosphine |
| DE3420491A1 (de) * | 1984-06-01 | 1985-12-05 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| US4578523A (en) * | 1985-05-29 | 1986-03-25 | Ruhrchemie Aktiengesellschaft | Process for the preparation of aldehydes |
| DE3534314A1 (de) * | 1985-09-26 | 1987-04-02 | Ruhrchemie Ag | Verfahren zur herstellung von aldehyden |
| US4633021A (en) * | 1985-11-29 | 1986-12-30 | National Distillers And Chemical Corporation | Olefin hydroformylation |
| US4716250A (en) * | 1986-07-10 | 1987-12-29 | Union Carbide Corporation | Hydroformylation using low volatile/organic soluble phosphine ligands |
-
1986
- 1986-11-18 US US06/932,002 patent/US4731486A/en not_active Expired - Lifetime
-
1987
- 1987-11-17 RU SU874203758A patent/RU2002728C1/ru active
- 1987-11-17 AU AU81280/87A patent/AU611867B2/en not_active Ceased
- 1987-11-17 EP EP87116971A patent/EP0268268B1/en not_active Expired - Lifetime
- 1987-11-17 AT AT87116971T patent/ATE77075T1/de active
- 1987-11-17 BE BE8701298A patent/BE1000619A5/fr not_active IP Right Cessation
- 1987-11-17 DE DE19873739064 patent/DE3739064A1/de active Granted
- 1987-11-17 MX MX009383A patent/MX166784B/es unknown
- 1987-11-17 DE DE8787116971T patent/DE3779725D1/de not_active Expired - Lifetime
- 1987-11-18 FR FR878715930A patent/FR2606771B1/fr not_active Expired
- 1987-11-18 HU HU875125A patent/HU202177B/hu not_active IP Right Cessation
- 1987-11-18 JP JP62289666A patent/JPH0667868B2/ja not_active Expired - Fee Related
- 1987-11-18 AR AR87309326A patent/AR248390A1/es active
- 1987-11-18 FI FI875087A patent/FI90858C/fi not_active IP Right Cessation
- 1987-11-18 KR KR1019870012952A patent/KR920003556B1/ko not_active Expired
- 1987-11-18 BR BR8706223A patent/BR8706223A/pt not_active Application Discontinuation
- 1987-11-18 SE SE8704533A patent/SE8704533L/ not_active Application Discontinuation
- 1987-11-18 YU YU2091/87A patent/YU45074B/xx unknown
- 1987-11-18 IT IT22675/87A patent/IT1223147B/it active
- 1987-11-18 ES ES8703288A patent/ES2009221A6/es not_active Expired
- 1987-11-18 NO NO874810A patent/NO166440C/no unknown
- 1987-11-18 GB GB8727013A patent/GB2197867B/en not_active Expired - Lifetime
- 1987-11-18 CA CA000552143A patent/CA1307296C/en not_active Expired - Lifetime
- 1987-11-18 CN CN87101178A patent/CN1017145B/zh not_active Expired
- 1987-11-18 NL NL8702752A patent/NL8702752A/nl not_active Application Discontinuation
- 1987-11-18 DK DK605887A patent/DK605887A/da not_active Application Discontinuation
- 1987-11-18 PL PL1987268876A patent/PL153062B1/pl unknown
- 1987-11-18 IN IN834/MAS/87A patent/IN170369B/en unknown
- 1987-11-18 ZA ZA878638A patent/ZA878638B/xx unknown
-
1989
- 1989-04-24 ES ES8901418A patent/ES2012719A6/es not_active Expired - Lifetime
- 1989-04-24 ES ES8901417A patent/ES2012718A6/es not_active Expired - Lifetime
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