KR830004193A - 에틸렌과 고급올레핀과의 하이드로포르밀화방법 - Google Patents
에틸렌과 고급올레핀과의 하이드로포르밀화방법 Download PDFInfo
- Publication number
- KR830004193A KR830004193A KR1019800004906A KR800004906A KR830004193A KR 830004193 A KR830004193 A KR 830004193A KR 1019800004906 A KR1019800004906 A KR 1019800004906A KR 800004906 A KR800004906 A KR 800004906A KR 830004193 A KR830004193 A KR 830004193A
- Authority
- KR
- South Korea
- Prior art keywords
- carbon monoxide
- hydrogen
- ethylene
- rhodium
- ligand
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims 4
- 239000005977 Ethylene Substances 0.000 title claims 4
- 150000001336 alkenes Chemical class 0.000 title 1
- 238000007037 hydroformylation reaction Methods 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 7
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 7
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 239000003446 ligand Substances 0.000 claims 3
- 239000010948 rhodium Substances 0.000 claims 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- 229910052703 rhodium Inorganic materials 0.000 claims 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 229910003450 rhodium oxide Inorganic materials 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (1)
- a) 탄소수 3 내지 20의 α-올레핀성 탄화수소,b) 일산화탄소,c) 수소,d) ⅰ) 로듐과 일산화탄소로 이루어진 착화합물 촉매,ⅱ) 로듐과 트리알킬포스파이트, 트리사이클로알킬 포스파이트, 트리아릴포스파이트 또는 트리아릴포스핀과 같은 트리오르가노 포스포러스 배위자로 이루어진 착화합물 촉매, 촉매량(여기서 각 유기부위는 탄소수 18까지를 함유하며, 상기트리오르가노 포스포러스 배위자는 425이상의 ΔHNP 값을 갖는다), 및e) 로듐몰당 상술한 자유배위자 2몰 이상으로 이루어진 반응혼합물을 50℃ 내지 145℃로 유지시키고 일산화탄소 및 수소의 총압력을 450psia 이하로, 일산화탄소의 부분압력을 상기 총압력의 75%이하가 되도록 유지시킨 후 상기 올레핀성 탄화수소를 일산화탄소 및 수소와 반응시켜 상기의 산화된 생성물을 수득함에 있어서, 반응혼합물은 에틸렌과, 에틸렌과 반응하기에 충분한 양이상의 양인 추가분의 일산화탄소 및 수소를 함유하며 에틸렌을 일산화탄소 및 수소와 반응시켜 부가적으로 프로피온 알데하이드를 얻음과 동시에 산화된 생성물을 얻는 것을 특징으로 하는, 산화된 생성물이 다량함유된 n-알데히드의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US108282 | 1979-12-28 | ||
US06/108,282 US4262142A (en) | 1979-12-28 | 1979-12-28 | Hydroformylation of ethylene with higher olefins |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830004193A true KR830004193A (ko) | 1983-07-06 |
KR850000715B1 KR850000715B1 (en) | 1985-05-23 |
Family
ID=22321290
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR8004906A KR850000715B1 (en) | 1979-12-28 | 1980-12-23 | Hydroformylation of ethylene with higher olefins |
Country Status (12)
Country | Link |
---|---|
US (1) | US4262142A (ko) |
EP (1) | EP0031590B2 (ko) |
JP (1) | JPS56100731A (ko) |
KR (1) | KR850000715B1 (ko) |
AU (1) | AU544752B2 (ko) |
BR (1) | BR8008425A (ko) |
CA (1) | CA1137999A (ko) |
DE (1) | DE3065925D1 (ko) |
MX (1) | MX156839A (ko) |
PL (1) | PL128018B1 (ko) |
SG (1) | SG93886G (ko) |
ZA (1) | ZA807635B (ko) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4348539A (en) * | 1979-11-01 | 1982-09-07 | Union Carbide Corporation | Heteronuclear-bridged rhodium clusters |
ATE26696T1 (de) * | 1982-06-11 | 1987-05-15 | Davy Mckee London | Hydroformylierungsverfahren. |
ATE16475T1 (de) * | 1982-06-11 | 1985-11-15 | Davy Mckee London | Hydroformylierungsverfahren. |
US4533756A (en) * | 1983-11-07 | 1985-08-06 | Texaco Inc. | Process for synthesis of acrylic acid precursors via hydroformylation of vinyl ether |
US4594463A (en) * | 1985-01-28 | 1986-06-10 | Union Carbide Corporation | Synthesis of aldehydes from alcohols |
GB2195117B (en) * | 1986-09-16 | 1990-10-31 | Agency Ind Science Techn | Process for direct carbonylation of hydrocarbons |
US4871878A (en) * | 1987-08-10 | 1989-10-03 | Eastman Kodak Company | Low pressure rhodium catalyzed hydroformylation of olefins |
US5675041A (en) * | 1995-01-18 | 1997-10-07 | Exxon Research & Engineering Company | Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene |
EP0804397B1 (en) * | 1995-01-18 | 2002-04-03 | ExxonMobil Chemical Patents Inc. | Oxygenates and processes for their manufacture |
US6265619B1 (en) | 1996-01-17 | 2001-07-24 | Exxon Chemical Patents Inc. | Oxygenates and processes for their manufacture |
DE10149132B4 (de) | 2001-10-05 | 2006-05-04 | Sartorius Ag | Vorrichtung zur Entschaumung eines Bioreaktors |
US20050209469A1 (en) * | 2004-03-22 | 2005-09-22 | Shutt John R | Converting propylene in an oxygenate-contaminated propylene stream to non-polymerization derivative products |
CN101768062B (zh) * | 2009-01-05 | 2013-11-06 | 四川省达科特能源科技有限公司 | 由催化干气提浓气同时制备丙醛和丁醛的工业方法 |
CN101955421B (zh) * | 2010-08-11 | 2013-04-10 | 江苏沿江化工资源开发研究院有限公司 | 外循环溢流反应萃取精馏法制备丙醛的方法 |
WO2014146961A1 (en) * | 2013-03-18 | 2014-09-25 | Evonik Industries Ag | Process for preparation of methacrylic acid and methacrylic acid esters |
JP2016540780A (ja) * | 2013-12-19 | 2016-12-28 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
WO2022066596A1 (en) | 2020-09-25 | 2022-03-31 | Lyondell Chemical Technology, L.P. | Co-feeding ethylene with allyl alcohol in hydroformylation to make 1,4-butanediol and n-propanol |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1086100A (en) * | 1963-10-18 | 1967-10-04 | Eastman Kodak Co | Improvements in the oxo reaction |
CH443251A (de) * | 1963-10-24 | 1967-09-15 | Lonza Ag | Verfahren zur Herstellung von Propionaldehyd |
GB1120277A (en) * | 1965-07-16 | 1968-07-17 | Eastman Kodak Co | Preparation of aldehydes by the oxo process |
US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
CA918673A (en) * | 1969-12-22 | 1973-01-09 | L. Pruett Roy | Hydroformylation process |
US3917661A (en) * | 1970-01-07 | 1975-11-04 | Union Carbide Corp | Hydroformylation of unsaturated organic compounds |
DE2354217A1 (de) * | 1973-10-30 | 1975-05-15 | Basf Ag | Verfahren zur herstellung von aldehyden |
JPS516124A (en) * | 1974-07-05 | 1976-01-19 | Hitachi Chemical Co Ltd | Kikinzoku oyobi ryusandono kaishuhoho |
US4148830A (en) * | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
US4143075A (en) * | 1976-08-12 | 1979-03-06 | Union Carbide Corporation | Control of condensation products in hydroformylation process |
-
1979
- 1979-12-28 US US06/108,282 patent/US4262142A/en not_active Expired - Lifetime
-
1980
- 1980-12-05 ZA ZA00807635A patent/ZA807635B/xx unknown
- 1980-12-17 MX MX185339A patent/MX156839A/es unknown
- 1980-12-19 AU AU65610/80A patent/AU544752B2/en not_active Ceased
- 1980-12-19 CA CA000367258A patent/CA1137999A/en not_active Expired
- 1980-12-22 BR BR8008425A patent/BR8008425A/pt not_active IP Right Cessation
- 1980-12-22 PL PL1980228668A patent/PL128018B1/pl unknown
- 1980-12-23 JP JP18142680A patent/JPS56100731A/ja active Granted
- 1980-12-23 EP EP80108181A patent/EP0031590B2/en not_active Expired - Lifetime
- 1980-12-23 DE DE8080108181T patent/DE3065925D1/de not_active Expired
- 1980-12-23 KR KR8004906A patent/KR850000715B1/ko active
-
1986
- 1986-12-09 SG SG938/86A patent/SG93886G/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR850000715B1 (en) | 1985-05-23 |
PL128018B1 (en) | 1983-12-31 |
JPS56100731A (en) | 1981-08-12 |
EP0031590B1 (en) | 1983-12-14 |
AU6561080A (en) | 1981-07-02 |
US4262142A (en) | 1981-04-14 |
MX156839A (es) | 1988-10-06 |
JPS6254410B2 (ko) | 1987-11-14 |
ZA807635B (en) | 1981-11-25 |
CA1137999A (en) | 1982-12-21 |
EP0031590B2 (en) | 1992-10-21 |
SG93886G (en) | 1993-02-19 |
EP0031590A1 (en) | 1981-07-08 |
PL228668A1 (ko) | 1981-10-16 |
AU544752B2 (en) | 1985-06-13 |
BR8008425A (pt) | 1981-07-14 |
DE3065925D1 (en) | 1984-01-19 |
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