KR830001841A - n-발레르알데히드를 제조하기 위한 하이드로 포르밀레이션 방법 - Google Patents

n-발레르알데히드를 제조하기 위한 하이드로 포르밀레이션 방법 Download PDF

Info

Publication number
KR830001841A
KR830001841A KR1019800001179A KR800001179A KR830001841A KR 830001841 A KR830001841 A KR 830001841A KR 1019800001179 A KR1019800001179 A KR 1019800001179A KR 800001179 A KR800001179 A KR 800001179A KR 830001841 A KR830001841 A KR 830001841A
Authority
KR
South Korea
Prior art keywords
valeraldehyde
butene
rhodium
hydroformulation
absolute
Prior art date
Application number
KR1019800001179A
Other languages
English (en)
Other versions
KR830001167B1 (ko
Inventor
하리스 노만
제임스 데니스 알랜
후리드릭 세블스 토마스
Original Assignee
존 로버트 바췔러
데이비 맥키(오일 앤드 케미칼스)리미티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10504048&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR830001841(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 존 로버트 바췔러, 데이비 맥키(오일 앤드 케미칼스)리미티드 filed Critical 존 로버트 바췔러
Publication of KR830001841A publication Critical patent/KR830001841A/ko
Application granted granted Critical
Publication of KR830001167B1 publication Critical patent/KR830001167B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

n-발레르알데히드를 제조하기 위한 하이드로 포르밀레이션 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
첨부도면은 부텐 하이드로포르밀레이션 플랜트의 개략적 유동도이다.

Claims (1)

  1. 본문에 상술하고 도면에 도시한 바와 같이, 촉매량의 로듐착물촉매(일산화탄소 및 트리유기포스핀과 착물결합되어 있는 로듐으로 구성됨)의 존재하에 약 80-130℃의 온도, 및 약 50kg/㎠(절대)의 총압, 약 1.5kg/㎠(절대) 이하의 일산화탄소의 부분압 및 약 1.0-7.5kg/㎠(절대)의 수소의 부분압에서, 로듐의 그람원자당 최소한 약 100몰의 유리트리유기포스핀 리간드의 존재하에 하이드로포르밀레이션 대역에서 C4-올레핀 원료유(시스-부텐-2, 트란스-부텐-2, 및 이소-부틸렌으로부터 선택된 최소한 하나의 C4올레핀 및 부텐-1로 구성됨)를 일산화탄소 및 수소와 접촉시킨 다음 하이드로포르밀레이션 대역으로부터 미반응 C4-올레핀 및 n-발레르알데히드를 회수하는 것으로 구성된, n-발레르알데히드를 제조하기 위한 하이드로포르밀레이션 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019800001179A 1979-03-21 1980-03-21 n-발레르 알데히드를 제조하기 위한 하이드로 포르밀레이션 방법 KR830001167B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB7910012 1979-03-21
GB79/10012 1979-03-21

Publications (2)

Publication Number Publication Date
KR830001841A true KR830001841A (ko) 1983-05-19
KR830001167B1 KR830001167B1 (ko) 1983-06-20

Family

ID=10504048

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019800001179A KR830001167B1 (ko) 1979-03-21 1980-03-21 n-발레르 알데히드를 제조하기 위한 하이드로 포르밀레이션 방법

Country Status (9)

Country Link
US (1) US4287370A (ko)
EP (1) EP0016286B1 (ko)
JP (1) JPS55127335A (ko)
KR (1) KR830001167B1 (ko)
BR (1) BR8001728A (ko)
DE (2) DE2965158D1 (ko)
IN (1) IN153033B (ko)
PL (1) PL222862A1 (ko)
ZA (1) ZA801127B (ko)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4593141A (en) * 1979-02-12 1986-06-03 Exxon Research And Engineering Co. Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes
US4450299A (en) * 1980-10-01 1984-05-22 Exxon Research And Engineering Co. Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
DE3301591A1 (de) * 1983-01-19 1984-07-19 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US5110990A (en) * 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
US4737588A (en) * 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4593127A (en) * 1985-01-11 1986-06-03 Union Carbide Corporation Hydroformylation process
US4625068A (en) * 1985-03-20 1986-11-25 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of internal olefins
US4642388A (en) * 1985-08-30 1987-02-10 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of alpha-substituted alpha-olefins
US4605781A (en) * 1985-09-03 1986-08-12 Celanese Corporation Production of 2-methylbutanal
US5053551A (en) * 1986-07-01 1991-10-01 Davy Mckee (London) Limited Process for the production of aldehydes by hydroformylation
GB2192182B (en) * 1986-07-01 1990-05-23 Davy Mckee Process for the production of aldehydes
US4827043A (en) * 1988-01-22 1989-05-02 Eastman Kodak Company Impurity removal from carbon monoxide and/or hydrogen-containing streams
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
ZA96178B (en) * 1995-01-18 1997-06-30 Exxon Chemical Patents Inc Organic compounds and processes for their manufacture
DE19530698A1 (de) * 1995-08-21 1997-02-27 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags
DE10006489A1 (de) * 2000-02-14 2001-08-16 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrages
ES2342464T3 (es) * 2002-04-26 2010-07-07 Basf Se Mezclas de alcoxilatos de alcanol c sb 10 /sb y su aplicacion.
CA2483470C (en) 2002-04-26 2010-11-09 Basf Aktiengesellschaft Alkoxylate mixtures and detergents comprising these
CA2483310C (en) * 2002-04-26 2011-09-13 Basf Aktiengesellschaft C10-alkanol alkoxylates and their use
DE10243366A1 (de) 2002-09-18 2004-04-01 Basf Ag Herstellung von Alkoxylaten bei optimierten Reaktionsdrücken
GB0322246D0 (en) * 2003-09-23 2003-10-22 Exxonmobil Chem Patents Inc Improvement in or relating to isobutylene
GB0322247D0 (en) 2003-09-23 2003-10-22 Exxonmobil Chem Patents Inc Improvement in or relating to an isobutylene containing stream
PL209549B1 (pl) * 2004-08-02 2011-09-30 Dow Technology Investments Llc Sposób hydroformylowania
ES2367364T3 (es) * 2004-12-24 2011-11-02 Basf Se Empleo de agentes tensioactivos no iónicos en la obtención de metales.
CN100526279C (zh) * 2006-04-11 2009-08-12 中国科学院兰州化学物理研究所 连续制备正戊醛的工艺过程
JP5631003B2 (ja) * 2006-11-30 2014-11-26 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ オレフィンのヒドロホルミル化法
EP2114844B1 (de) * 2007-01-29 2010-09-29 Basf Se Verzweigte decylnitrate und ihre verwendung als verbrennungsverbesserer und/oder cetanzahlverbesserer in kraftstoffen
DE102008002188A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung
ES2495748T3 (es) 2008-07-03 2014-09-17 Dow Technology Investments Llc Procedimiento de control de productos pesados en una corriente de reciclado de catalizador
TW201031743A (en) 2008-12-18 2010-09-01 Basf Se Surfactant mixture comprising branched short-chain and branched long-chain components
RU2546110C2 (ru) * 2009-12-22 2015-04-10 Дау Текнолоджи Инвестментс Ллс Регулирование соотношения альдегид нормального строения: альдегид изо-строения в процессе гидроформилирования со смешанным лигандом регулированием парциального давления синтез-газа
PL2601280T3 (pl) 2010-08-03 2015-03-31 Basf Se Ciecze nośne do ścierniw
PL226015B1 (pl) * 2011-03-03 2017-06-30 Wrocławskie Centrum Badań Eit + Spółka Z Ograniczoną Liposomowy preparat zawierajacy przeciwnowotworowa substancje aktywna, sposob jego wytwarzania i zawierajaca go kompozycja farmaceutyczna
CN102826967B (zh) * 2011-06-17 2015-07-22 中国石油化工股份有限公司 一种烯烃氢甲酰化反应制备醛的方法
SG10201606190WA (en) 2012-02-01 2016-09-29 Basf Se Cooling and/or lubricating fluids for wafer production
JP2015513553A (ja) 2012-03-07 2015-05-14 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｃ３〜ｃ２０アルデヒドの水素化及び蒸留におけるヒートインテグレーションのための方法
SG10201608258PA (en) 2012-04-12 2016-11-29 Basf Se Method for replenishing the catalyst in continuous hydroformylation
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
RU2559052C1 (ru) * 2014-06-26 2015-08-10 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "РН-ЦИР") Установка для получения альдегидов гидроформилированием олефинов с3-с4 с применением каталитической системы на основе родия
RU2557062C1 (ru) * 2014-06-26 2015-07-20 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "РН-ЦИР") Технологическая установка получения альдегидов, преимущественно из бутенов или пропилена, с применением родиевых катализаторов
RU2751511C9 (ru) 2016-02-11 2021-08-18 Дау Текнолоджи Инвестментс Ллк Способы превращения олефинов в спирты, простые эфиры или их комбинации
US11365357B2 (en) 2019-05-24 2022-06-21 Eastman Chemical Company Cracking C8+ fraction of pyoil
US11946000B2 (en) 2019-05-24 2024-04-02 Eastman Chemical Company Blend small amounts of pyoil into a liquid stream processed into a gas cracker
US20220325036A1 (en) 2019-07-29 2022-10-13 Eastman Chemical Company Process for the preparation of polyesters with recycled monomers from pyrolysis and methanolysis
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
EP4054997A4 (en) 2019-11-07 2024-02-21 Eastman Chem Co ALPHA-OLEFINS AND FAT ALCOHOLS WITH RECYCLING CONTENT

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3290379A (en) * 1961-09-01 1966-12-06 Diamond Alkali Co Selective hydroformylation of olefinic compounds
US3965192A (en) * 1967-05-29 1976-06-22 Union Oil Company Of California Hydrocarbonylation process
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3954877A (en) * 1967-10-12 1976-05-04 Jefferson Chemical Co., Inc. Hydroformylation of olefins
CA918673A (en) * 1969-12-22 1973-01-09 L. Pruett Roy Hydroformylation process
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
CA1090823A (en) * 1976-04-08 1980-12-02 Everard A.V. Brewester Cyclic hydroformylation process
BE853377A (fr) * 1976-04-08 1977-10-07 Union Carbide Corp Procede de preparation continue d'aldehydes par hydroformylation
ZA78147B (en) * 1977-01-25 1978-11-29 Union Carbide Corp Improved hydroformylation process

Also Published As

Publication number Publication date
US4287370A (en) 1981-09-01
DE2965158D1 (en) 1983-05-11
EP0016286B1 (en) 1983-04-06
EP0016286A2 (en) 1980-10-01
JPS55127335A (en) 1980-10-02
KR830001167B1 (ko) 1983-06-20
PL222862A1 (ko) 1981-01-02
ZA801127B (en) 1980-12-31
IN153033B (ko) 1984-05-19
JPH0246572B2 (ko) 1990-10-16
DE16286T1 (de) 1983-05-11
EP0016286A3 (en) 1981-01-14
BR8001728A (pt) 1980-11-18

Similar Documents

Publication Publication Date Title
KR830001841A (ko) n-발레르알데히드를 제조하기 위한 하이드로 포르밀레이션 방법
Osborn et al. Mild hydroformylation of olefins using rhodium catalysts
KR920009762A (ko) 개선된 하이드로포밀화 방법
DE68905452T2 (de) Hydroformylation von Olefinen unter schwachem Druck mit einem Rhodium-Katalysator.
NO165915C (no) Hydroformyleringsprosess, diorganofosfitt-ligand og rhodium-komplekskatalysator til bruk ved fremgangsmaaten samt etkatalysatorforloeperpreparat.
SE8007140L (sv) Forfarande for framstellning av aldehyder
SE7707905L (sv) Hydroformyleringsforfarande
KR830004193A (ko) 에틸렌과 고급올레핀과의 하이드로포르밀화방법
SE8004359L (sv) Forfarande for stabilisering och regenerering av en katalysator for hydroformylering av propen
KR830009026A (ko) 2,3-디클로로-5-트리클로로메틸피리딘의 제조방법
SE7709110L (sv) Hydroformyleringsforfarande
Hanson et al. Hydroformylation of 1-hexene utilizing homogeneous rhodium catalysts: Regioselectivity as a function of conversion
JPS611009B2 (ko)
ES466267A1 (es) Mejora en un procedimiento para hidroformilar una alfa-ole- fina.
ES458708A1 (es) Procedimiento para preparar uno o mas alcoholes.
ES474699A1 (es) Un procedimiento continuo para hidroformilar propileno.
ES425590A1 (es) Un procedimiento para el hidrocraqueo de una fraccion de aceite lubricante.
ES450734A1 (es) Un procedimiento mejorado para la hidroformilacion de olefi-nas con hidrogeno y monoxido de carbono.
ES472518A1 (es) Procedimiento para la fabricacion de aldehidos
JPS56118034A (en) Preparation of aldehyde
ES406349A1 (es) Procedimiento para la oxidacion de olefinas.
Iwamoto Reaction of Butadiene in the Presence of a Three-component Catalyst Consisting of Iron (III) acetylacetonate, a Phosphorus Compound, and Bis (diethylaluminum) sulfate
BR8706407A (pt) Processo para a preparacao de aldeidos
RO94855B1 (ro) Procedeu de preparare a aldehidelor prin hidroformilarea olefinelor
ATE2950T1 (de) Hydroformylierungsverfahren.