ATE86885T1 - Hydroformylation von olefinen unter schwachem druck mit einem rhodium-katalysator. - Google Patents

Hydroformylation von olefinen unter schwachem druck mit einem rhodium-katalysator.

Info

Publication number
ATE86885T1
ATE86885T1 AT89420501T AT89420501T ATE86885T1 AT E86885 T1 ATE86885 T1 AT E86885T1 AT 89420501 T AT89420501 T AT 89420501T AT 89420501 T AT89420501 T AT 89420501T AT E86885 T1 ATE86885 T1 AT E86885T1
Authority
AT
Austria
Prior art keywords
hydroformylation
low pressure
under low
rhodium catalyst
olefins under
Prior art date
Application number
AT89420501T
Other languages
English (en)
Inventor
Thomas James Devon
Gerald Wayne Phillips
Thomas Allen Puckette
Jerome Leonard Stavinoha
Jeffrey James Vanderbilt
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Application granted granted Critical
Publication of ATE86885T1 publication Critical patent/ATE86885T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/54—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
AT89420501T 1988-12-22 1989-12-20 Hydroformylation von olefinen unter schwachem druck mit einem rhodium-katalysator. ATE86885T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/288,596 US4960949A (en) 1988-12-22 1988-12-22 Low pressure rhodium catalyzed hydroformylation of olefins
EP89420501A EP0375573B1 (de) 1988-12-22 1989-12-20 Hydroformylation von Olefinen unter schwachem Druck mit einem Rhodium-Katalysator

Publications (1)

Publication Number Publication Date
ATE86885T1 true ATE86885T1 (de) 1993-04-15

Family

ID=23107800

Family Applications (1)

Application Number Title Priority Date Filing Date
AT89420501T ATE86885T1 (de) 1988-12-22 1989-12-20 Hydroformylation von olefinen unter schwachem druck mit einem rhodium-katalysator.

Country Status (8)

Country Link
US (2) US4960949A (de)
EP (2) EP0449966A1 (de)
JP (1) JP2859955B2 (de)
AT (1) ATE86885T1 (de)
CA (1) CA2004707A1 (de)
DE (1) DE68905452T2 (de)
ES (1) ES2039086T3 (de)
WO (1) WO1990006810A1 (de)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4040315A1 (de) * 1990-12-17 1992-06-25 Hoechst Ag Verfahren zur herstellung von aldehyden
FR2671079B1 (fr) * 1990-12-28 1994-06-03 Elf Aquitaine Procede d'hydrogenation de composes organiques et catalyseurs au ruthenium pour sa realisation.
US5232989A (en) * 1991-03-04 1993-08-03 Monsanto Company Functionalized polymers
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
DE4242723A1 (de) * 1992-12-17 1994-06-23 Hoechst Ag Verfahren zur Herstellung von Aldehyden
GB2274457A (en) * 1993-01-25 1994-07-27 Shell Int Research Hydroformylation of unsaturated carbonyl compounds
US5332846A (en) * 1993-06-01 1994-07-26 Eastman Kodak Company Hydroformylation process using novel phosphine-rhodium catalyst system
US5488175A (en) * 1993-09-16 1996-01-30 Shell Oil Company Hydroformylation process
DE4431528A1 (de) * 1994-09-03 1996-03-07 Basf Ag Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol
GB9425911D0 (en) * 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
DE19619527A1 (de) * 1996-05-15 1997-11-20 Hoechst Ag Katalysatorsysteme auf der Basis von Rhodium-Komplexverbindungen mit Diphosphin-Liganden und ihre Verwendung bei der Herstellung von Aldehyden
DE19625168A1 (de) * 1996-06-24 1998-01-08 Hoechst Ag Katalysator und ein Verfahren zur Herstellung von Aldehyden in Gegenwart dieses Katalysators
US5912364A (en) * 1996-10-21 1999-06-15 Eastman Chemical Company Process for the preparation of 3-methyltetrahydrofuran
WO2003080632A1 (fr) * 2002-03-22 2003-10-02 Kuraray Co., Ltd. Bisphosphine, procede de fabrication et utilisation
TWI301481B (en) * 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
US6664427B1 (en) * 2002-08-29 2003-12-16 E. I. Du Pont De Nemours And Company Process for preparing aldehyde compounds
CN1729153A (zh) * 2002-12-17 2006-02-01 国际壳牌研究有限公司 在酸和单叔膦存在下烯属不饱和化合物的加氢甲酰化方法
CA2510284C (en) * 2002-12-17 2011-06-14 Shell Internationale Research Maatschappij B.V. Hydroformylation process for the conversion of an ethylenically unsaturated compound to an alcohol
KR20060038961A (ko) 2003-07-03 2006-05-04 루사이트 인터내셔널 유케이 리미티드 에틸렌으로 불포화된 화합물의 하이드로포르밀화 방법
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
US6909019B1 (en) 2004-05-25 2005-06-21 Eastman Chemical Company Process for preparing aldehydes
GB0411951D0 (en) * 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
KR100596365B1 (ko) * 2004-06-12 2006-07-03 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
WO2006020287A1 (en) 2004-08-02 2006-02-23 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of a hydroformylation process
JP5364367B2 (ja) * 2005-03-16 2013-12-11 ペルストルプ スペシヤルテイ ケミカルズ アーベー 改善されたイソ−選択性を持つヒドロホルミル化法
GB0516556D0 (en) 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
EP1957198B1 (de) 2005-11-17 2018-08-22 Lucite International UK Limited Carbonylierung von ethylenisch ungesättigten verbindungen
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
JP2010511600A (ja) * 2006-12-02 2010-04-15 ルーサイト インターナショナル ユーケー リミテッド 新規のカルボニル化配位子及びエチレン性不飽和化合物のカルボニル化におけるその使用
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
US7674937B2 (en) 2008-05-28 2010-03-09 Eastman Chemical Company Hydroformylation catalysts
GB0812297D0 (en) * 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
US20100069679A1 (en) * 2008-09-12 2010-03-18 Eastman Chemical Company Acetylene tolerant hydroformylation catalysts
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
KR101730278B1 (ko) 2012-11-09 2017-04-25 미쓰이 가가쿠 가부시키가이샤 알데하이드 화합물의 제조 방법
WO2014073672A1 (ja) 2012-11-09 2014-05-15 三井化学株式会社 アルデヒド化合物の製造方法
US9687837B1 (en) 2016-08-31 2017-06-27 Eastman Chemical Company Stable hydroformylation catalyst for preparation of high N/Iso ratio aldehyde product
US9975833B2 (en) 2016-08-31 2018-05-22 Eastman Chemical Company Efficient catalyst for the formation of polyaryl hydrocarbons suitable as precursors for polydentate organophosphorus catalyst ligands
CN111318308A (zh) * 2018-12-17 2020-06-23 中国石油化工股份有限公司 催化剂组合物及其应用和醋酸乙烯酯氢甲酰化的方法
US11946000B2 (en) 2019-05-24 2024-04-02 Eastman Chemical Company Blend small amounts of pyoil into a liquid stream processed into a gas cracker
US11365357B2 (en) 2019-05-24 2022-06-21 Eastman Chemical Company Cracking C8+ fraction of pyoil
WO2020242921A1 (en) 2019-05-24 2020-12-03 Eastman Chemical Company Recycle content cellulose ester
WO2020247192A1 (en) 2019-05-24 2020-12-10 Eastman Chemical Company Recycle content cracked effluent
WO2021021902A1 (en) 2019-07-29 2021-02-04 Eastman Chemical Company Process for the preparation of polyesters with recycled monomers from pyrolysis and methanolysis
EP4003950A4 (de) 2019-07-29 2023-08-30 Eastman Chemical Company (c4)alkansäure mit mit recyceltem inhalt
EP4003948A4 (de) 2019-07-29 2023-09-06 Eastman Chemical Company Kanal mit recyceltem inhalt (c4)
CN114174375B (zh) 2019-07-29 2025-01-28 伊士曼化工公司 回收成分环丁二醇聚酯
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
KR20220091549A (ko) 2019-10-31 2022-06-30 이스트만 케미칼 컴파니 재활용된 폐기물을 위한 열분해 방법 및 시스템
EP4054997A4 (de) 2019-11-07 2024-02-21 Eastman Chemical Company Alpha-olefine und fettalkohole mit recycling-gehalt
EP4055001A4 (de) 2019-11-07 2024-02-14 Eastman Chemical Company Gemischte ester und lösungsmittel mit recyceltem inhalt
US12398328B2 (en) 2020-02-10 2025-08-26 Eastman Chemical Company Chemical recycling of processed mixed plastic waste streams
US12195674B2 (en) 2021-09-21 2025-01-14 Eastman Chemical Company Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic
CN113996347A (zh) * 2021-12-06 2022-02-01 万华化学集团股份有限公司 一种氢甲酰化催化剂组合物及烯丙醇氢甲酰化反应制备羟基丁醛的方法
CN115999539B (zh) * 2022-12-15 2024-11-01 北京化工大学 一种负载型Rh/TiO2-P催化剂的制备方法及应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239566A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4138420A (en) * 1976-01-19 1979-02-06 Celanese Corporation Hydroformylation catalysts
US4277627A (en) * 1977-01-25 1981-07-07 Union Carbide Corporation Hydroformylation process
US4152344A (en) * 1977-08-08 1979-05-01 Celanese Corporation Phosphino-ferrocene ligands
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins
JPS54119407A (en) * 1978-03-09 1979-09-17 Agency Of Ind Science & Technol Preparation of aldehydes
JPS5626830A (en) * 1979-08-10 1981-03-16 Kuraray Co Ltd Hydroformylation of lower olefin
US4352947A (en) * 1981-08-03 1982-10-05 Gulf Research & Development Company Process for producing ethanol
US4612402A (en) * 1982-03-29 1986-09-16 Allied Corporation Oxidation of olefins using rhodium nitro complex
EP0203286B1 (de) * 1985-03-27 1988-09-14 Hoechst Aktiengesellschaft Trägerkatalysator und Verfahren zur Herstellung von Monocarbonsäureanhydriden
US4605781A (en) * 1985-09-03 1986-08-12 Celanese Corporation Production of 2-methylbutanal
US4748261A (en) * 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4694109A (en) * 1986-06-13 1987-09-15 Eastman Kodak Company Chelate ligands for low pressure hydroformylation catalyst and process employing same
US4755624A (en) * 1987-02-18 1988-07-05 Eastman Kodak Company Low pressure hydroformylation process
US4760194A (en) * 1987-02-18 1988-07-26 Eastman Kodak Company Low pressure hydroformylation catalyst employing unique ligands and process using same
US4742178A (en) * 1986-11-10 1988-05-03 Eastman Kodak Company Low pressure hydroformylation of dienes
EP0279018B1 (de) * 1987-02-18 1992-01-29 EASTMAN KODAK COMPANY (a New Jersey corporation) Chelat-Ligandene für Tiefdruck-Hydroformylierungskatalysatoren und Verfahren zu ihrer Verwendung
US4774362A (en) * 1987-04-24 1988-09-27 Eastmank Kodak Company Chelating ligands and catalysts and processes employing the same
US4873213A (en) * 1988-08-12 1989-10-10 Puckette Thomas A Low pressure rhodium catalyzed hydroformylation of olefins

Also Published As

Publication number Publication date
ES2039086T3 (es) 1993-08-16
EP0449966A1 (de) 1991-10-09
WO1990006810A1 (en) 1990-06-28
EP0375573B1 (de) 1993-03-17
CA2004707A1 (en) 1990-06-22
US5004823A (en) 1991-04-02
DE68905452T2 (de) 1993-10-21
JP2859955B2 (ja) 1999-02-24
JPH04502463A (ja) 1992-05-07
DE68905452D1 (de) 1993-04-22
EP0375573A1 (de) 1990-06-27
US4960949A (en) 1990-10-02

Similar Documents

Publication Publication Date Title
ATE86885T1 (de) Hydroformylation von olefinen unter schwachem druck mit einem rhodium-katalysator.
ES2007986A6 (es) Un metodo para la hidroformilacion de compuestos instaurados pra producir aldehidos.
US4283562A (en) Hydroformylation process using stable rhodium catalyst
DE69004446D1 (de) Katalysator für Olefinpolymerisation.
US4277627A (en) Hydroformylation process
NO165915C (no) Hydroformyleringsprosess, diorganofosfitt-ligand og rhodium-komplekskatalysator til bruk ved fremgangsmaaten samt etkatalysatorforloeperpreparat.
KR830001841A (ko) n-발레르알데히드를 제조하기 위한 하이드로 포르밀레이션 방법
DE3034352A1 (de) Carbonylation process and novel transition metal catalysts
DE58909871D1 (de) Sulfonierte Phenylphosphane enthaltende Komplexverbindungen
ES449003A1 (es) Procedimiento de hidroformilacion de clefinas alifaticas.
Grenouillet et al. Cationic allylmetal complexes. 9. Dimerization of acrylates catalyzed by allylpalladium complexes. Role of the ligand and indirect evidence for the occurrence of hydridopalladium species
YU46478B (sh) Postupak za dobivanje katalizatora za polimerizaciju olefina
SE7704141L (sv) Hydroformyleringsforfarande
CA1262555A (en) RHODIUM CATALYZED HYDROFORMYLATION OF .alpha.- SUBSTITUTED .alpha.-OLEFINS
Pittman et al. Asymmetric hydroformylation using homogeneous and polymer-bound chiral platinum catalysts
KR830004193A (ko) 에틸렌과 고급올레핀과의 하이드로포르밀화방법
US4388225A (en) Olefin oxidation with supported CuO catalyst
GB1256913A (de)
SE8004359L (sv) Forfarande for stabilisering och regenerering av en katalysator for hydroformylering av propen
SE7709110L (sv) Hydroformyleringsforfarande
US3839486A (en) Process for the isomerization of olefins
US4528278A (en) Catalyst for hydroformylation of olefins
Mirbach et al. Photochemical Hydroformylation
KR890014427A (ko) 로듐-트리시클로헥실포스핀 촉매 시스템을 사용하는 수성 포름알데히드의 히드로포르밀화
IE40058B1 (en) Organotitanium compounds, their production and their use in the catalytic hydrogenation of unsaturated compounds