ES2007986A6 - Un metodo para la hidroformilacion de compuestos instaurados pra producir aldehidos. - Google Patents

Un metodo para la hidroformilacion de compuestos instaurados pra producir aldehidos.

Info

Publication number
ES2007986A6
ES2007986A6 ES8802493A ES8802493A ES2007986A6 ES 2007986 A6 ES2007986 A6 ES 2007986A6 ES 8802493 A ES8802493 A ES 8802493A ES 8802493 A ES8802493 A ES 8802493A ES 2007986 A6 ES2007986 A6 ES 2007986A6
Authority
ES
Spain
Prior art keywords
olefins
low pressure
catalyzed hydroformylation
rhodium catalyzed
hydroformylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES8802493A
Other languages
English (en)
Inventor
Thomas Allen Puckette
Thomas James Devon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of ES2007986A6 publication Critical patent/ES2007986A6/es
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00Formation or introduction of functional groups containing oxygen
    • C07B41/06Formation or introduction of functional groups containing oxygen of carbonyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE DESCRIBE LA HIDROFORMILACION DE OLEFINAS CON CATALIZADORES DE COMPLEJOS DE RODIO. LOS CATALIZADORES EMPLEADOS COMPRENDEN UN COMPLEJO DE RODIO CON AL MENOS UNA FOSFINA QUE TIENE UNA ESTRUCTURA ESPECIFICA, POR EJEMPLO TRIS(BENCIL)FOSFINA. FOSFINAS PREFERIDAS TIENEN UN PKA EN EL INTERVALO DE APROXIMADAMENTE 3,5 A 5,3 Y UN ANGULO DEL CONO EN EL INTERVALO DE APROXIMADAMENTE 160 A 195G. MEDIANTE LA PRACTICA DEL PRESENTE INVENTO SE OBTIENEN REACCIONES DE HIDROFORMILACION A TEMPERATURAS Y PRESIONES RELATIVAMENTE BAJAS Y A PESAR DE ELLO CON ELEVADAS VELOCIDADES DE REACCION Y UNA ELEVADA SELECTIVIDAD AL PRODUCTO ALDEHIDO.
ES8802493A 1987-08-10 1988-08-09 Un metodo para la hidroformilacion de compuestos instaurados pra producir aldehidos. Expired ES2007986A6 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8333087A 1987-08-10 1987-08-10
US07/225,103 US4871878A (en) 1987-08-10 1988-07-27 Low pressure rhodium catalyzed hydroformylation of olefins

Publications (1)

Publication Number Publication Date
ES2007986A6 true ES2007986A6 (es) 1989-07-01

Family

ID=26769178

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8802493A Expired ES2007986A6 (es) 1987-08-10 1988-08-09 Un metodo para la hidroformilacion de compuestos instaurados pra producir aldehidos.

Country Status (9)

Country Link
US (1) US4871878A (es)
EP (1) EP0379515B1 (es)
JP (1) JP2831011B2 (es)
KR (1) KR960004183B1 (es)
CN (1) CN1031835A (es)
CA (1) CA1305491C (es)
DE (1) DE3885103T2 (es)
ES (1) ES2007986A6 (es)
WO (1) WO1989001467A1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3920423A1 (de) * 1989-06-22 1991-01-03 Basf Ag Verfahren zur herstellung von 2,3-dialkoxypropanalen
US5232989A (en) * 1991-03-04 1993-08-03 Monsanto Company Functionalized polymers
CN1035543C (zh) * 1993-01-09 1997-08-06 厦门大学 高碳数端烯氢甲酰化制高碳醛负载型水溶性催化剂
GB2274457A (en) * 1993-01-25 1994-07-27 Shell Int Research Hydroformylation of unsaturated carbonyl compounds
US5912364A (en) * 1996-10-21 1999-06-15 Eastman Chemical Company Process for the preparation of 3-methyltetrahydrofuran
US5840647A (en) * 1997-09-15 1998-11-24 Eastman Chemical Company Hydroformylation process using novel phosphite-metal catalyst system
US6130358A (en) * 1998-10-16 2000-10-10 Eastman Chemical Company Hydroformylation process using novel phosphite-metal catalyst system
US6225509B1 (en) * 2000-01-06 2001-05-01 Arco Chemical Technology, L.P. Allyl alcohol hydroformylation
US6909019B1 (en) 2004-05-25 2005-06-21 Eastman Chemical Company Process for preparing aldehydes
US8492593B2 (en) 2011-08-16 2013-07-23 Eastman Chemical Company Amido-fluorophosphite compounds and catalysts
US9308527B2 (en) 2014-03-17 2016-04-12 Eastman Chemical Company Phosphorous compounds useful as ligands and compositions and methods regarding them
US11365357B2 (en) 2019-05-24 2022-06-21 Eastman Chemical Company Cracking C8+ fraction of pyoil
US11946000B2 (en) 2019-05-24 2024-04-02 Eastman Chemical Company Blend small amounts of pyoil into a liquid stream processed into a gas cracker
US20220325036A1 (en) 2019-07-29 2022-10-13 Eastman Chemical Company Process for the preparation of polyesters with recycled monomers from pyrolysis and methanolysis
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
KR20220093368A (ko) 2019-11-07 2022-07-05 이스트만 케미칼 컴파니 재활용물 알파 올레핀 및 지방 알코올

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
DE2045169A1 (en) * 1970-09-12 1972-03-23 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Treatment of oxo reaction mixts - by addn of aqs alkali hydroxide
US4195042A (en) * 1971-08-20 1980-03-25 Phillips Petroleum Company Rhodium hydroformylation catalyst
EP0002908B1 (en) * 1977-12-16 1982-05-12 Monsanto Company Hydroformylation of formaldehyde with rhodium catalyst
US4593141A (en) * 1979-02-12 1986-06-03 Exxon Research And Engineering Co. Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes
US4262142A (en) * 1979-12-28 1981-04-14 Union Carbide Corporation Hydroformylation of ethylene with higher olefins
JPS56125329A (en) * 1980-03-07 1981-10-01 Sagami Chem Res Center Preparation of aldehyde having perfluoro group
CA1166270A (en) * 1981-04-30 1984-04-24 Mitsuo Matsumoto Method of producing 1,9-nonanedial and/or 9-hydroxy-7- nonen-1-al
DE3234701A1 (de) * 1982-09-18 1984-04-05 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
US4528403A (en) * 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
DE3245883A1 (de) * 1982-12-11 1984-06-14 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur hydroformylierung von olefinen
US4533756A (en) * 1983-11-07 1985-08-06 Texaco Inc. Process for synthesis of acrylic acid precursors via hydroformylation of vinyl ether
DE3341035A1 (de) * 1983-11-12 1985-05-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3413427A1 (de) * 1984-04-10 1985-10-17 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
ATE34166T1 (de) * 1984-08-30 1988-05-15 Ruhrchemie Ag Verfahren zur herstellung von aldehyden.
US4578523A (en) * 1985-05-29 1986-03-25 Ruhrchemie Aktiengesellschaft Process for the preparation of aldehydes
DE3534314A1 (de) * 1985-09-26 1987-04-02 Ruhrchemie Ag Verfahren zur herstellung von aldehyden
US4755624A (en) * 1987-02-18 1988-07-05 Eastman Kodak Company Low pressure hydroformylation process
US4760194A (en) * 1987-02-18 1988-07-26 Eastman Kodak Company Low pressure hydroformylation catalyst employing unique ligands and process using same
US4742178A (en) * 1986-11-10 1988-05-03 Eastman Kodak Company Low pressure hydroformylation of dienes

Also Published As

Publication number Publication date
JPH03500770A (ja) 1991-02-21
KR960004183B1 (ko) 1996-03-27
CA1305491C (en) 1992-07-21
CN1031835A (zh) 1989-03-22
KR890701524A (ko) 1989-12-20
EP0379515B1 (en) 1993-10-20
DE3885103T2 (de) 1994-05-19
DE3885103D1 (de) 1993-11-25
US4871878A (en) 1989-10-03
JP2831011B2 (ja) 1998-12-02
WO1989001467A1 (en) 1989-02-23
EP0379515A1 (en) 1990-08-01

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