JPS6440434A - Hydroformylation of vinyl compound - Google Patents

Hydroformylation of vinyl compound

Info

Publication number
JPS6440434A
JPS6440434A JP62197028A JP19702887A JPS6440434A JP S6440434 A JPS6440434 A JP S6440434A JP 62197028 A JP62197028 A JP 62197028A JP 19702887 A JP19702887 A JP 19702887A JP S6440434 A JPS6440434 A JP S6440434A
Authority
JP
Japan
Prior art keywords
phosphite
values
substituted aryl
formula
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62197028A
Other languages
Japanese (ja)
Other versions
JP2656257B2 (en
Inventor
Yasuo Tokito
Noriaki Yoshimura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Priority to JP62197028A priority Critical patent/JP2656257B2/en
Publication of JPS6440434A publication Critical patent/JPS6440434A/en
Application granted granted Critical
Publication of JP2656257B2 publication Critical patent/JP2656257B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE:To obtain the aimed compound in high yield and advantageously in hydroformylating a specific vinyl compound containing a direct functional group at the vinyl group in the presence of a rhodium catalyst, adding a tris(substituted aryl) phosphite to the reaction system. CONSTITUTION:A compound shown by the formula (X is H or CH3; A is OCOCH3, COOCH3 or CN) is reacted with a mixed gas of H2 and CO in the presence of a compound shown by the formula P(OR)3 (R is substituted aryl), especially tris(2,4-di-t-butylphenyl) phosphite having 2,080-2,090cm<-1> electronic parameter (upsilon-values) and 135-190 deg. steric parameter (theta-values) to give a hydroformylated product useful as a food additive or a raw material for polymers. This method is industrially advantageous since the reaction can be carried out under relatively low pressure, high reaction rate and high selectivity are obtained by using a rhodium catalyst even with low concentration and the catalyst can be circulated and used.
JP62197028A 1987-08-05 1987-08-05 Hydroformylation of vinyl compounds Expired - Fee Related JP2656257B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62197028A JP2656257B2 (en) 1987-08-05 1987-08-05 Hydroformylation of vinyl compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62197028A JP2656257B2 (en) 1987-08-05 1987-08-05 Hydroformylation of vinyl compounds

Publications (2)

Publication Number Publication Date
JPS6440434A true JPS6440434A (en) 1989-02-10
JP2656257B2 JP2656257B2 (en) 1997-09-24

Family

ID=16367546

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62197028A Expired - Fee Related JP2656257B2 (en) 1987-08-05 1987-08-05 Hydroformylation of vinyl compounds

Country Status (1)

Country Link
JP (1) JP2656257B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5364970A (en) * 1993-01-25 1994-11-15 Shell Oil Company Process for the hydroformylation of unsaturated carbonyl compounds
JP2012188419A (en) * 2011-02-24 2012-10-04 Kuraray Co Ltd Method for producing asymmetric allyl ether compound
JP2014028766A (en) * 2012-07-31 2014-02-13 Kuraray Co Ltd Process for producing allyl ether compound
WO2014073664A1 (en) * 2012-11-09 2014-05-15 三井化学株式会社 Method for producing aldehyde compound
US9475760B2 (en) 2012-11-09 2016-10-25 Mitsui Chemicals, Inc. Preparation method of aldehyde compound using a metal compound and a phosphorus compound

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57123134A (en) * 1980-12-22 1982-07-31 Shell Int Research Olefin hydroformylation
JPS58185534A (en) * 1982-04-23 1983-10-29 Mitsubishi Chem Ind Ltd Preparation of aldehyde
JPS62116587A (en) * 1985-09-05 1987-05-28 ユニオン・カ−バイド・コ−ポレ−シヨン Bisphosphite compound

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57123134A (en) * 1980-12-22 1982-07-31 Shell Int Research Olefin hydroformylation
JPS58185534A (en) * 1982-04-23 1983-10-29 Mitsubishi Chem Ind Ltd Preparation of aldehyde
JPS62116587A (en) * 1985-09-05 1987-05-28 ユニオン・カ−バイド・コ−ポレ−シヨン Bisphosphite compound

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5364970A (en) * 1993-01-25 1994-11-15 Shell Oil Company Process for the hydroformylation of unsaturated carbonyl compounds
JP2012188419A (en) * 2011-02-24 2012-10-04 Kuraray Co Ltd Method for producing asymmetric allyl ether compound
JP2014028766A (en) * 2012-07-31 2014-02-13 Kuraray Co Ltd Process for producing allyl ether compound
WO2014073664A1 (en) * 2012-11-09 2014-05-15 三井化学株式会社 Method for producing aldehyde compound
CN104768923A (en) * 2012-11-09 2015-07-08 三井化学株式会社 Method for producing aldehyde compound
US20150299109A1 (en) * 2012-11-09 2015-10-22 Mitsui Chemicals, Inc. Preparation method of aldehyde compound
JP5841676B2 (en) * 2012-11-09 2016-01-13 三井化学株式会社 Method for producing aldehyde compound
US9475760B2 (en) 2012-11-09 2016-10-25 Mitsui Chemicals, Inc. Preparation method of aldehyde compound using a metal compound and a phosphorus compound
US9487475B2 (en) 2012-11-09 2016-11-08 Mitsui Chemicals, Inc. Preparation method of aldehyde compound with limited amount of acrylonitrile

Also Published As

Publication number Publication date
JP2656257B2 (en) 1997-09-24

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Legal Events

Date Code Title Description
LAPS Cancellation because of no payment of annual fees